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Effects of Ethanol and Organic Acids on Color, Fishy Odor and in vitro Absorption Rate of Calcium of Dried Large Anchovy (자건대멸의 색택, 어취 및 in vitro 칼슘 흡수율에 미치는 주정과 유기산 처리의 효과)

  • Jo, Jin-Ho;Jang, Hae-Jin;Cho, Seung-Mock;Lee, Yang-Bong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.9
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    • pp.1471-1476
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    • 2005
  • The optimization of ethanol treatment was carried out by response surface methodology (RSM) which was expressed through change of ${\Delta}$E value for improvement of color of dried large anchovy. The optimum condition was shown as treatment with 7 volumes (v/m) of ethanol at $50^{\circ}C$ for 9 hrs. At this condition, the removal rates of trimethylamine (TMA) and fat considered as fishy odor-causing materials were 81.1 and $77.4\%$, respectively, when analyzed by solid phase microextraction (SPME)/gas chromatography and soxhlet method, respectively The effect of citric acid on the removal rate of TMA was the highest one among organic acid treatments. The removal rate of TMA was affected greatly by the concentration of organic acid rather than the temperature and time of treatment. $73\%$ of TMA was removed by treatment of $1\%$ of citric acid at $20^{\circ}C$ for 20 min. Specially, above $90\%$ of TMA could be removed by the combination of alcohol and citric acid treatment. In vitro absorption rate of calcium was also increased to $12.3\%$ by the combination of alcohol and citric acid treatment compared with $2.9\%$ of control.

Formation of Brushite (CaHPO4 · 2H2O) in the Oyster Extracts (굴 엑기스에서 결정물질 Brushite(CaHPO4 · 2H2O)의 생성)

  • Lee, Jong-Soo;Yoon, So-Mi;Jang, Jun-Ho;Lim, Chi-Won;Choi, Kwang-Yeol
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.6
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    • pp.729-733
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    • 2006
  • Small yellowish brown crystals were found in some concentrated oyster extracts which prepared by heating with the drip and washed water of boiled oyster in oyster processing factories. We collected those crystals by filtering the oyster extracts and analysed X ray diffraction (XRD), scanning electron microscopy (SEM) and minerals by ICP. Those were composed of moisture (8.1%), organic materials (21.6%) and inorganic materials (70.2%). Those major inorganic materials were determined as Ca (53.8%) and P (43.8%), from the ICP and elucidated those crystal as brushite $(CaHPO_4{\cdot}2H_2O)$ by XRD and SEM. Organic materials contained crude protein (33.7%) consisting of 7 amino acids. It is presumed that brushite may be formed by the reaction of excess Ca with P in the oyster extracts during concentrating process under higher temperature.

A Development of Food Preservative with the Waste of Crab Processing (게 가공폐기물을 이용한 식품보존료의 개발에 관한 연구)

  • CHANG Dong-Suck;CHO Hak-Rae;GOO Hyo-Young;CHOE Wi-Kung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.22 no.2
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    • pp.70-78
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    • 1989
  • This experiment was carried out to develop the preparation method of chitosan which has strong antimicrobial activity, and also tried to investigate as a natural food preservative with this chitosan. The antimicrobial activity of chitosan was the strongest when deacetylation of chitin was conducted at $146^{\circ}C$ for 8 hours with $50\%$ sodium hydroxide. The growth of Escherichia coil was completely inhibited by adding this low molecular weight chitosan (M. W, 35,000) at the level of concentration of 75ppm to the medium. The antimicrobial activity was strong enough against such Gram positive bacteria as Staphylococcus sp. and Bacillus sp.. The growth of these strains was inhibited by the concentration of 50ppm but it was varied in its kinds against Gram negative bacteria. The concentration of chitosan re-quired for growth inhibition of microorganisms was 100ppm against Pseudomonas sp. and Vibrio sp., 2,000ppm against Salmonella sp.. The growth of Saccharomyces sp. was inhibited by the concentration of 100ppm, but Hansenula sp., Aspergillus sp., Penicillium sp. and Mu-cor sp. did not inhibited by even more than the concentration of 5,000ppm. The shelf life of Mulkimchi (pickle type Kimchi), containing $0.2\%$ chitosan was 10 days longer than control stored at $5^{\circ}C$.

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Disease Control Efficacy of the Extract of Magnolia officinalis against Perilla and Zoysiagrass Rusts (후박 추출물의 들깨 녹병과 잔디 녹병에 대한 방제 효과)

  • Yoon, Mi-Young;Choi, Yong Ho;Kang, Mun Seong;Lee, Jae Hong;Han, Seong Sook;Myoung, In Sik;Han, Byoung Soo;Choi, Gyung Ja;Jang, Kyoung Soo;Kim, Jin-Cheol
    • Research in Plant Disease
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    • v.19 no.1
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    • pp.45-48
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    • 2013
  • Rusts are plant diseases caused by pathogenic fungi of the order Pucciniales. Rusts can affect a variety of plants. Development of new effective and environmentally benign agents against rusts is of great interest. In this study, we investigated the disease control efficacy of the emulsion concentrate (EC10) and wettable powder (WP20) type formulations of the extract of Magnolia officinalis (Magjia90; containing honokiol and magnolol at 90%) against rust diseases of perilla and zoysiagrass in fields. The treatment of EC10 and WP20 of Magjia90 showed control values of 47.9% to 69.6% and Magjia90-WP20 reduced more effectively the development of rust symptoms on perilla plants than Magjia90-EC10. Magjia90-WP20 also highly suppressed zoysiagrass rust with control values of 65.7% to 80.5%. On the other hand, no harmful effect of Magjia90-EC10 and Magjia90-WP20 was observed on the perilla and zoysiagrass plants tested. The results strongly indicate that the extract of M. officinalis (Magjia90) can be used as a natural fungicide for the control of rust diseases.

Rheological Properties of Rehydrated Suspensions of Freeze Dried Kochujang Powders (동결건조 분말고추장의 재수화시 리올로지 특성)

  • Kim, Suk-Shin;Chang, Kyu-Seob;Yoon, Han-Kyo;Lee, Sang-Kyu;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.81-88
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    • 1987
  • Rheological properties of rehydrated suspensions of two kinds of freeze dried Kochujang powders, processed at different freezing rates, were compared with raw Kochujang using Brookfield wide-gap rotational viscometer at $25^{\circ}C-60^{\circ}C$. Shear rates ranged from $0.1965\;sec^{-1}$ to $1.9650\;sec^{-1}$ and solid content ranged from 47% to 56%. Rehydrated suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang exhibited pseudoplastic behaviors with yield stress and presented thixotropic properties which followed the second-order kinetic behavior proposed by Tiu. Suspensions of Kochujang powders exhibited considerably higher decaying rates than raw Kochujang. The dependency of the equilibrium structure parameter on the shear rate was weak, and there were no significant differences among the values of structure parameters of three samples. The temperature dependency of the apparent viscosity of Kochujang suspension was fully expressed by Arrhenius equation and activation energies of suspensions of quickly frozen Kochujang powder and slowly frozen Kochujang powder, and raw Kochujang were 2.21, 2.18, and 2.32 Kcal/g.mole respectively. Consistency indices of three samples increased with solid content and decreased with temperature. Flow behavior indices of three samples showed no considerable dependency on the temperature and solid content. There were no significant differences in the rheological properties between two Kochujang powders.

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Volatile Compounds of Chonggugjang Prepared by Different Fermentation Methods and Soybean Cultivars (발효방법 및 대두품종을 달리한 청국장의 향기성분)

  • Yoo, Seon-Mi;Kim, Haeng-Ran;Kim, Jin-Sook;Chang, Chang-Moon;Choe, Jeong-Sook
    • Applied Biological Chemistry
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    • v.42 no.2
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    • pp.111-115
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    • 1999
  • This study was attempted to develop technique of masking the pungent odor of chonggugjang using two-stage fermentation method with mixed pure cultures. Cooked soybeans were fermented with Lactobacilli or Aspergillus oryzae at $38^{\circ}C$ for 36 hrs, and then re-fermented with Bacillus subtilis for 12 hrs. The volatile compounds of chonggugjang were obtained with a SDE(Simultaneous steam Distillation and solvent Extraction) system and the extracts were identified by GC and GC-MS. The experimental results revealed the presence of 35 volatile compounds in control chonggugjang(only Bacillus subtilis inoculation). Among them, the major volatile compounds were 2,5-dimethyl pyrazine, 2,3,5-trimethyl pyrazine and 2-methyl pyrazine. Twenty-nine kinds of volatile compounds were in chonggugjang prepared by two-stage fermentation method with Lactobacilli and Bacillus subtilis(II), and major volatile compounds were identified to be 2,3,5-trimethyl pyrazine and 2,5-dimethyl Pyrazine. In chonggugjang(Asp. oryzae and then Bacillus subtilis inoculation(III)), the contents of hexadecanoic acid and 2-methyl pyrazine were patricularly high and the main components of chonggugjang fermented with rice straw(IV) were 2,5-dimethyl pyrazine, 2,3,5-trimethyl pyrazine etc. In conclusion, the flavor compounds such as 2, 5-dimethyl pyrazine, 2,3,5-trimethyl pyrazine and 2-methyl pyrazine were increased by the inoculation of Lactobacilli or Asp. oryzae, where as unpleasant odor components-butyric acid and valeric acid were decreased. Compared with volatile compounds of chonggugjang made from different soybean cultivars, the flavor compounds (2-methyl pyrazine 2,5-dimethyl pyrazine 2,6-dimethyl pyrazine 2,3-dimethyl pyrazine 2-acetyl pyrazine 2,3,5-trimethyl pyrazine 2-ethyl-3,5-dimethyl pyrazine) of chonggugiang prepared with Sinpaldalkong were high.

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Recycling of Acidic Etching Waste Solution Containing Heavy Metals by Nanofiltration (II) : Dead-end Nanofiltration of PCB Etching Waste Solution Containing Copper Ion (나노여과에 의한 중금속 함유 산성 폐에칭액의 재생(II) : 구리이온을 함유한 PCB 폐에칭액의 Dead-end 나노여과)

  • Nam, Sang-Won;Jang, Kyung-Sun;Youm, Kyung-Ho
    • Membrane Journal
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    • v.23 no.1
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    • pp.92-99
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    • 2013
  • In this study the nanofiltration (NF) membrane treatment of a sulfuric acid waste solutions containing copper ion ($Cu^{+2}$) discharging from the etching processes of the printed circuit board (PCB) manufacturing industry has been studied for the recycling of acid etching solution. SelRO MPS-34 4040 NF membrane from Koch company was tested to obtain the basic NF data for recycling of etching solution and separation efficiency (total rejection) of copper ion. NF experiments were carried out with a dead-end membrane filtration laboratory system. The pure water flux was increased with the increasing storage time in sulfuric acid solution and lowering pH of acid solution because of the enhancement of NF membrane damage by sulfuric acid. The permeate flux of acid solution was decreased with the increasing copper ion concentration. Total rejection of copper ion was decreased with the increasing storage time in sulfuric acid solution and copper ion concentration, and lowering the pH of acid solution. The total rejection of copper ion was decreased from initial 37% to 15% minimum value.

고주파 스퍼터링법으로 증착한 ZnO 박막의 응력 형성

  • 곽상현;이재빈;김형준
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.193-193
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    • 2000
  • 박막 내의 잔류 응력은 막의 기계적 전기적 물성을 변화시키는 등 박막에 많은 영향을 끼치는 것으로 알려져 있다. 이러한 응력은 박막의 증착 공정중 여러 가지 증착 조건에 의해서 변화하게 되는데, 특히 스퍼터링 시스템의 경우에는 증착 압력과 사용하는 가스, 인가되는 전력 등 기본적인 증착조건들에 상당한 영향을 받는다. 이러한 영향은 금속 박막의 경우 상당히 잘 알려져 있다. 또한 반도체 공정에서 금속화 과정중 금속 전극의 단락등을 막기 위해 많은 연구가 진행되어 왔다. 본 논문에서는 고주파 마그네트론 스퍼터링 시스템을 사용하여 산화 아연(ZnO)을 증착하고 여러 공정 변수들에 따른 응력의 변화를 관찰하였다. 실험에서 ZnO 타겟을 사용하였으며, 작동 가스로는 아르곤과 산소를 사용하였다. 증착한 박막들은 모두 압축 응력을 보였으며, 박막의 응력에 가장 큰 영향을 미치는 요소들은 압력, 산소와 아르곤의 비, 기판과 타겟과의 거리 등이었는데, 인가 전력에는 거의 영향을 받지 않았다. 일반적으로 스퍼터링 시스템에서의 압축응력은 atomic peening에 의해서 형성되는데, 박막을 두드리는 높은 에너지의 아르곤이나 산소의 유량과 에너지의 1/2승에 비례하는 것으로 알려져 있다. 그러나 본 시스템에서는 인가 전력을 높여도 응력이 증가하지 않았고, 타겟과의 거리를 줄이면 오히려 응력이 감소함을 보였다. 이는 박막의 응력이 peening 하는 입자의 에너지뿐만이 아니라 증착되는 물질의 증착 속도와도 밀접한 관련이 있음을 보여준다. 즉, 증착속도가 증가하면 peening하는 입자가 끼치는 응력의 효과가 반감되기 때문으로 수식을 통해 증명할 수 있었다.진탄화 처리시간을 변화시켰을 때 화합물층의 생성은 ${\gamma}$'상으로부터 시작되고 $\varepsilon$상은 즉시 ${\gamma}$'상을 소모하면서 생성되어 일정시간이 지난 후 $\varepsilon$상은 안정화되며 질소가스농도가 증가할수록 화합물 층내의 $\varepsilon$상분율은 역시 증가하였다. 한편 CH4 가스농도는 처리되는 강종에 따라 차이를 보이며 적정 CH4 가스농도를 초과시에는 $\varepsilon$상 생성은 억제되고 시멘타이트상이 생성되었다.e에서 발생된 질소 플라즈마를 구성하는 이온들의 종류와 그 구성비율을 연구하였다.여러 가지 응용으로의 가능성을 가지고 있다. 그 예로 plasma processing, plasma wave에 의한 입자 가속, 그리고 가스 레이저 활성 매질 발생 등이 있다. 특히 plasma processing의 경우 helicon plasma는 높은 밀도, 비교적 낮은 자기장, remote operation 등이 가능하다는 점에서 현재 연구가 활발히 진행되고 있다. 상업용으로도 PMT와 Lucas Signatone Corp.에 서 helicon source가 제작되었다. 또한 높은 해리율을 이용하여 저유전 물질인 SiOF의 증착에서 적용되고 있다. 이 외에도 다수의 연구결과들이 발표되었다. 잘 일치하였다.ecursor 분자들이 큰 에너지를 가지고 기판에 유입되어 치밀한 박막이 형성되었기 때문으로 사료된다.을수 있었다.보았다.다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인

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Optimum Chemical Cleaning Conditions for Ceramic Microfiltration Membrane Process (세라믹 정밀여과막 공정을 위한 최적 약품세척 방안)

  • Lim, Jae-Lim;Lee, Kyung-Hyuk;Lee, Young-Joo;Park, Jong-Yul
    • Membrane Journal
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    • v.22 no.6
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    • pp.461-469
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    • 2012
  • This study was carried out to find the optimum chemical cleaning (CIP) conditions for ceramic microfiltration membrane process of Y drinking water treatment plant. B train consists of coagulation as pretreatment process with membrane was chemically cleaned 9 times more than that of A train with ozonation and coagulation. The frequent CIP of B train was due to improper CIP method suggested by membrane manufacture as well as different membrane fouling between A and B train resulting from the different pretreatment processes. That is, recovery rate of CIP was overestimated because the rate was calculated based on normalized trans membrane pressure (TMP) rather than normalized permeability. And also, iron oxide fouling was ineffectively removed by citric acid. By using a mixture of 1% citric acid and 0.1 N sulfuric acid as reagent for acid CIP step, the recovery rate of CIP was the highest while CIP efficiency by 0.1 N sulfuric acid was the lowest. When sulfuric acid concentration increased from 0.1 N to 0.3 N in mixture, total recovery rate of CIP was not increased due to the decreased CIP efficiency in alkali CIP step by 0.3% NaOCl although its rate in acid CIP step was increased. It was proved through the experiment result of CIP sequence changes that an acid followed by alkali CIP was more effective than that of the reverse method.

A National Vision of the Hydrogen Economy and Action Plan ('친환경 수소경제' 구현을 위한 마스터플랜 - 연료전지산업 및 중장기 신.재생에너지 개발비전 -)

  • Boo Kyung-Jin
    • Journal of Energy Engineering
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    • v.15 no.2 s.46
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    • pp.83-95
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    • 2006
  • This study is to establish a national vision of the hydrogen economy and design a roadmap to materialize it. A goal is set to supply 15% of final energy consumption with hydrogen energy in Korea by 2040. Selecting the transportation sorter as the main target, more than 50% of vehicles on the road will be replaced with fuel cell vehicles (FCVs) while $20{\sim}30%$ of electricity demand in the residential and commercial sectors might be replaced with power generation by fuel cells. If this goals were attained as planned, primary energy demand would be reduced by 9%, resulting in improved energy mix in which fossil fuel consumption is greatly reduced whereas renewable energy increases by 47%. Furthermore, GHG emissions will be reduced by 20% and self-sufficiency in energy is enhanced up to 23%. If the hydrogen economy is to materialize, the government needs to implement institutional arrangements such as new legislations, organizations, and fiscal measures to facilitate the process. In addition, the private sector's participation is highly recommended to mobilize fund needed for the huge investment to build an infrastructure in preparation for the hydrogen economy. Arrangements for codes and standards are also required to promote industrialization of fuel cells and hydrogen production and consumption.