• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.366-370
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• 2005

Pervaporation process using a NaY zeolite membrane was applied for separation of water generated in an esterification process as a byproduct. From the binary mixture of water and either ethyl acetate or acetic acid and the ternary mixture of water, ethanol and ethyl acetate which might be present in an esterification reaction for manufacturing ethyl acetate, water was separated by the membrane pervaporation. It was investigated how the operating parameters such as an organic concentration and a temperature affected the permeate flux and the separation factor of water. For the feed mixture of water/ethyl acetate, the total flux and the separation factor of water were observed to be $930-5,000g/m^2/hr$ and 3,700-8,000, respectively. Also it was found for ternary mixtures of water/ethanol/ethyl acetate that the total flux was $1,300-3,900g/m^2/hr$ and the separation factor was 530-1,600. A pervaporation process might be applied in an esterification process since both the total flux and the separation factor of water through the NaY zeolite membrane were shown to be very high.

• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.778-784
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• 2017

Membranes were prepared by incorporating Na-Y zeolite particles into poly(vinyl alcohol) (PVA) cross-linked with poly(acrylic acid) (PAA). The membrane was characterized by FT-IR spectroscopy, contact angle measurement, swelling test, SEM analysis, and XRD analysis. The pervaporation separation of water/acetic acid mixtures was carried out using prepared membranes. From the results, it was shown that the hydrophilic property of prepared membrane increased with increase of zeolite contents and the PVA/PAA membrane with zeolite addition showed higher permeation flux than that of without zeolite membrane. The PVA/PAA membrane containing 8 wt% zeolite showed the highest permeation flux and separation in the feed solution containing 10 wt% acetic acid.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.476-481
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• 2013

Ethylbenzene (EB) which has a similar physical properties with p-xylene (pX) was separated from EB/pX mixture by using MFI-type zeolite (TS-1, ZSM-5, and Silicalite-1) coated membranes. The zeolites were synthesized by microwave method to reduce the synthesis time and uniformly formed zeolite particles were coated on the ${\alpha}$-almina tubular support with a thickness of $3-4{\mu}m$. Separation factor and permeation flux of the synthesized zeolite coated membranes were measured to survey the best performance of ethylbenzene separation from different composition of EB/pX mixtures. When the EB/pX mixture of 5:5 molar ratio applied for the separation experiment, it represented the highest separation factor. We also have studied about the effect of the atomic composition of zeolites on the separation performance within the temperature range from 160 to $220^{\circ}C$. TS-1 showed the highest permeation flux of $1,666mol/m^{2*}s^*Pa$ and Silicate-1 showed the highest separation factor of 1.73 at $200^{\circ}C$ respectively.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05b
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• pp.110-114
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• 2004

분리막을 이용한 분리기술은 증류, 액체-액체 추출, 탄소 흡착과 같은 일반적인 수분 제거 방법[1,2]에 비해 에너지 소모가 적고 공정이 간단하다는 장점이 있어 알코올/물 혼합계에 대하여 높은 투과 선택성을 갖는 여러 가지 막 소재와 공정개발이 이루어지고 있다.(중략)

• Proceedings of the Membrane Society of Korea Conference
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• 2005.11a
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• pp.295-299
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• 2005

• Membrane Journal
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• v.16 no.2
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• pp.159-166
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• 2006

MFI(Mobil Five) structured hydrophobic ZSM-5 zeolite membrane was used for selective pervaporation of trichlorinated organic compounds(trichloromethane, trichloroethane, trichloroethylene) from their aqueous solutions. ZSM-5 zeolite membrane was hydrothermally synthesized on the inside of a porous stainless steel tube by secondary growth employing ZSM-5 seed powders. Separation factors for each binary mixtures were observed $16{\sim}66$ for trichloromethane/water, $3.3{\sim}4.6$ for trichloroethane/water and $1.4{\sim}8$ for trichloroethylene/water at the experimental conditions of the feed mole fraction from 0.0001 to 0.001 with temperature ranged $25{\sim}35^{\circ}C$.

• Membrane Journal
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• v.18 no.1
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• pp.103-107
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• 2008

Membrane process has been focused as an alternative separation process because not only it exhibits a high selectivity compared with a traditional distillation process, but also it is known to be an energy saving separation process. Inorganic membrane, especially zeolite membrane, has been studied since it can be operated in severe conditions compared to the organic membranes. Recently, new zeolite materials are tested as an inorganic membrane material to overcome disadvantages of existing zeolite membranes. Kalsilite can be used as an inorganic membrane material for gas separation and selective water separation from water/organic mixtures because it is expected to be hydrophilic resulted from Si/Al ratio of 1 like zeolite 4A and has a narrow pore size of 0.36 nm. In this study, kalsilite was synthesized by a new economical hydrothermal process using Si : Al : K : $H_2O$ mole ratio of 1 : 1 : 8 : 60. The synthesized kalsilite powder was confirmed by XRD and has a mean diameter of $2.73{\mu}m$. The vapor adsorption test showed the synthesized kalsilite is hydrophilic.

• The Journal of the Convergence on Culture Technology
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• v.6 no.4
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• pp.599-604
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• 2020

Since Corona 19, awareness about antibacterial bacteria has changed. Hand washing after going out became a necessity. Also, fogging occurs a lot on the glasses depending on the wearing of the mask. This problem has caused a lot of discomfort in our daily life and changed our perception of antibacterial and anti-fogging. Therefore, in this study, we studied whether mugwort extract is effective in preventing antibacterial and fogging. To obtain the mugwort extract, mugwort was dried, alcohol extracted, and freeze-dried. An antibacterial test was performed using a mixture of mugwort extract, zinc oxide and natural zeolite mixed in 3:7, and a fogging test was performed using mugwort extract and other mixtures. As a result, in the case of E. coli and K. pneumoniae, which were used as test strains in the antibacterial test, the bacteria were not cultured from the medium added with 1% mugwort extract, and the antibacterial activity against representative Gram-negative bacteria was confirmed. In the anti-fog test, a 10 wt% mixture of mugwort extract showed very good results in both the hot and cold parts. We expect the mugwort extract to be effective in antibacterial and anti-fogging, thus helping to overcome Corona 19.

• Membrane Journal
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• v.23 no.6
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• pp.409-417
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• 2013

Adsorptive permeation hollow fiber membrane (APM) has been developed for effectively separating $CO_2$ from gas mixture. Inside the APM, zeolite 13X particles were uniformly dispersed without covering their surfaces by a symmetric porous structure of polypropylene lattice. In this study, $CO_2/N_2$ mixture was used as a simulated gas mixture. Separation was achieved by adsorbing $CO_2$ on the zeolite particles in the APM and then permeating $N_2$ into permeate side in passing all the feed gas through the APM. Adsorptive permeation tests were carried out with a set of APM modules, and the adsorptive permeation performances of the modules were analyzed from the test results. After saturation of the adsorbent with $CO_2$, the APM was regenerated by desorption of $CO_2$ from it through vacuuming both inside of outside of the APM hollow fiber, and the regeneration process of the APM by vacuuming was discussed in terms of regeneration efficiency and energy consumption.

• Membrane Journal
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• v.16 no.1
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• pp.25-30
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• 2006

The NaA zeolite membrane was synthesized on the surface of a porous ${\alpha}$-alumina support from the reaction solution composed of 1Si : 1Na : 4Na $6H_{2}O$. The pervaporation performance of the synthesized NaA zeolite membrane was investigated for the iso-propyl alcohol (IPA) aqueous solution according to the different feed concentration and the different operating temperature. The total flux decreases by increasing the feed IPA concentration and increases by increasing the temperature. The total flux was about $4.0{\times}10^3g/m^2\;hr\;at\;60^{\circ}C$ and 0.6 mole fraction of IPA and the separation factor was $1.8{\times}10^7\;at\;60^{\circ}C$ and 0.8 mole fraction of IPA. The separation performance of water through the NaA membrane was found to be superior to that obtainable with a distillation process just by comparison of the vapor-liquid equilibrium data.