• Korean Journal of Materials Research
• /
• v.4 no.2
• /
• pp.213-218
• /
• 1994

제올라이트 분말을 기본재료로 하는 전기유변유체의 전기 및 유변학적 특성이 연구되었다. 전기장 인가시 높은 한계응력을 얻기 위하여 비교적 유전상슈가 큰 5종류의 유전유체를 선택하여 제올라이트 분말과 혼합하여 전기유변유체를 준비하였다. Couette형 rheometer를 이용하여 유변유체의 한계응력을 인가된 전기장 및 온도의 함수로서 측정하였다. 이중 chlorinate hydrocabon oil과 제올라이트 분말을 혼합한 전기유변유체의 한계응력은 6KPa(E=4KV/mm, T=$25^{\circ}C$)로서 최대치를 기록하였다. 측정된 한계응력은 온도가 상승하면 점차 감소하는 반면 전류밀도는 온도에 따라 증가하였다. 전류밀도에 대한 Arrhenius 그라프에서 전기전도에 대한 활성화 에너지는 약 0.7eV였으며 이는 제올라이트 분말에 포함된 $Na^{+}$ 이온의 확산에 기인하는 것으로 분석되었다.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2003.11a
• /
• pp.110-110
• /
• 2003

제올라이트는 다양한 유기질 분리의 촉매제 및 광학, 화학 센서, 기체 분리 등의 고기능 소재로서 크게 주목받고 있으며, 그 중 MFI type(ZSM-5, Silicalite-1) 제올라이트는 주로 석유화학공정에 주로 이용되고 있고, 분리막으로서 이산화탄소의 분리/회수 및 물/유기 혼합물의 분리 등에 대한 연구가 활발히 진행되고 있다. 본 연구에서는 분리막 제조에 유리할 것으로 판단되어지는 적합한 크기와 형상을 갖춘 나노크기의 제올라이트 분말을 수열합성법과 마이크로웨이브 합성법을 이용하여 합성하였으며, 위의 조건으로 다공질 알루미나 지지 체 위에서 알루미나/제올라이트 분리막 제조를 하는데 성공하였다. 또 한 다양한 조건(시간, 온도, 조성)에 따른 막의 두께변화와 균열발생정도를 관찰한 결과 합성시간, 건조온도에 따라서 같은 조건의 분리막 사이에서도 현격한 차이가 나타남을 알 수 있었다. 얻어진 MFI type제올라이트 분말과 분리막은 XRD, SEM, BET, TGA, FT-IR등의 분석수단을 이용하여 물성평가를 실시하였다.

• Polymer(Korea)
• /
• v.28 no.5
• /
• pp.374-381
• /
• 2004

Gas permeability of low density polyethylene (LDPE) film containing zeolite powder for $CO_2,\;O_2$ and $N_2$ were investigated. Zeolite powders modified by cations or surfactant were compounded with LDPE to produce $20 wt\%$ masterbatch. After blending the masterbatch with LDPE, zeolite filled films were prepared by the blown film process. Finally, the composite films containing zeolite loadings of 0, 3,5, and $10 wt\%$ were produced. A gas permeability apparatus based on the variable volume principle was designed to analyze the characteristics of films. Experiments showed a general trend that gas permeabilities first decreased and then increased as the zeolite content was increased. Surfactant modified zeolite showed a better interfacial adhesion with the matrix, but the film did not show a discernible difference in gas permeability compared with the other modified films. The difference of temperature dependences in the gas permeabilities of composite films was slightly smaller than that of LDPE film.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.9 no.4
• /
• pp.609-616
• /
• 2021

In this experimental, water-repellent powder, which is a metal salt-based inorganic substance, and natural zeolite powder, which is a pozzolan-based material, were mixed into cement mortar, and their physical properties and resistance to moisture were confirmed. It was confirmed that the test specimen using natural zeolite at the same time had excellent resistance in the water permeation test and the chloride penetration test as compared with the test specimen in which the inorganic metal salt-based water-repellent powder was mixed alone. When a metal salt-based water-repellent powder is used, it cannot be uniformly dispersed inside water due to its insoluble property, and is limited to the surface. When used at the same time as natural zeolite, the setting time at the initial stage of hydration is fast due to the pozzolan reaction, and the water-repellent powder adheres to the porous of the natural zeolite and is evenly distributed inside the test specimen to generate some water resistance.

• Journal of the Mineralogical Society of Korea
• /
• v.21 no.3
• /
• pp.307-312
• /
• 2008

Rietveld analysis using synchrotron X-ray powder diffraction data collected at 15 K reveals that CFC-13 ($CF_{3}Cl;$ chlorotrifluoromethane) sorbed on Na,K-LSX binds through fluorine to sodium ions around the single 6-ring aperture in the supcrgage.

• Journal of the Mineralogical Society of Korea
• /
• v.3 no.1
• /
• pp.7-17
• /
• 1990

화산 유리질 암석을 출발 물질로 사용하여 저온 ($80^{\circ}C$)에서 수열 처리하여 Na-P Na-X 및 Na-A 제올라이트를 합성하였다. 합성과정은 (1) 유리질 분말 시료와 알칼리 용액과의 용해.변질 반응에 의한 1차적인 Na-P의 합성 방식과 (2) 여기서 잔류된 규산질 모액에 Al(OH)3나 NaAlO2의 수용액을 공급하여 보다 고순도의 Na-P, Na-X 및 Na-A를 효과적으로 합성할 수 있었다. 원암의 암상과 조성은 제올라이트들의 화학 조성과 순도 및 백색도같은 물리적 특성에는 영향을 주지만, 합성된 제올라이트의 광물종을 규제하는 주된 요인은 아닌 것으로 해석된다. 합성된 제올라이트의 광물상은 반응 용액의 pH, Al(OH)4 및 Na+에 대한 농도 조건에 주로 의존되는 경향을 나타낸다. 또한 화산 유리질 암석을 제올라이트 합성원료로 활용하는 데에 있어서 (2)와 같음 합성 방안이 보완적으로 시행되면 그 생산성과 효율성을 제고시킬 수 있을 것으로 여겨진다.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.17 no.3
• /
• pp.95-101
• /
• 2007

The synthesis of NaA zeolite membrane on a porous alumina support from clear solution by using hydrothermal reaction was investigated. Effects of reaction temperature, reaction time and seeding for transformation of zeolite A membrane and powder which are produced in the reactor were monitored through X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). The transformation process of producing Zeolite A membrane starts from the formation of the compact and continuous membrane on the surface of porous support from clear solution. The large Zeolite A poly-crystal was then farmed through the dissolution process. Finally, the process was advanced from sodalite to amorphous. In case of powder, sodalite is formed in the early stage of reaction because of surrounding space difference between membrane and powder crystal. Discrete surrounding space of powder crystal makes easy to transform to sodalite. From Zeolite A to amorphous through transformed product was rapidly advanced at high temperature while the membrane with somewhat low coverage was obtained at low temperature. A compact and continuous zeolite A membrane was synthesized at $120^{\circ}C$ in 12-hour period.

• Journal of the Korea Institute of Building Construction
• /
• v.23 no.2
• /
• pp.153-164
• /
• 2023

The objective of this study is to examine the removal rate of air pollutants, specifically sulfur oxides (SO_x) and nitrogen oxides(NO_x), using concrete permeable blocks containing zeolite beads coated with materials capable of eliminating these pollutants. Titanium dioxide(TiO₂) powder and coconut shell powder were utilized for the removal of SO_x and NO_x and were applied as coatings on the zeolite beads. Concrete permeable block specimens embedded with the coated zeolite beads were produced using an actual factory production line. Test results demonstrated that the concrete permeable block containing zeolite beads coated with coconut shell powder in the surface layer achieved SO_x and NO_x removal rates of 12.5% and 99%, respectively, exhibiting superior performance compared to other blocks. Additionally, the flexural strength and slip resistance were 5.3MPa and 65BPN or higher, respectively, satisfying the requirements specified in KS F 4419 and KS F 4561. Conversely, the permeability coefficient exhibited low permeability, with grades 2 and 3 before and after contaminant pollution, according to the standard for 'design, construction, and maintenance of pavement using permeable block'. In conclusion, incorporating zeolite beads coated with coconut shell powder in the surface layer enables simultaneous removal of SO_x and NO_x, irrespective of ultraviolet rays, while maintaining adequate flexural strength and slip resistance. However, the permeability is significantly reduced, necessitating further improvements.

• 레미콘
• /
• no.1 s.50
• /
• pp.16-28
• /
• 1997

• Resources Recycling
• /
• v.10 no.6
• /
• pp.29-34
• /
• 2001

Fly ash powders were refined and separated into fine and coarse size by multi-air classification, and each particle was used for synthesizing mullite and zeolite. Mullite was prepared by sintering the mixture of fine fly ash with mean size of 6.5 $\mu$m and $A1_2$$O_3$powder at above $1450^{\circ}C$. Zeolite was synthesized through hydrothermal reaction with coarse fly ash mean size of $56.3\mu$m in 3.5 M NaOH solution at $120^{\circ}C$. The whole range of particle size can be recycled through size classification into fine and coarse fractions, which are used for syntheses of inorganic materials.