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The Solidification Microstructure of X%C-5%Cr-5%V-5%Mo-5%W-5%Co Multi-Component White Cast Iron (X%C-5%Cr-5%V -5%Mo-5%W-5%Co 다합금계백주철의 응고조직에 관한 연구)

  • Yu, Sung-Kon;Yasuhiro Matsubara
    • Korean Journal of Materials Research
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    • v.11 no.6
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    • pp.472-476
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    • 2001
  • Type and three-dimensional morphology of carbides precipitated in the X(X= 1.70, 1.92, 2.21, 2.50, 2.86)%C-5%Cr-5%V-5%Mo-5%W-5%Co multi-component white cast iron were investigated using an optical microscope and SEM. The types of carbides precipitated were MC, M$_2$C and M$_{7}$C$_{3}$. Morphology of the MC carbide took three forms, that it petal-like, nodular and coral-like. MC carbide seemed to change its morphology from petal-like through nodular, and finally to coral-like with an increase in carbon content. M7C carbide was classified into lamellar and plate-like type. The lamellar M$_2$C arbide precipitated in the iron with low molybdenum and tungsten contents, and higher contents of both elements in the iron were needed to form the plate-like M$_2$C carbide. The morphology of M$_{7}$C$_{3}$ was rod-like similar to that observed in high chromium white cast iron. However, cobalt does not affect the type and morphology of precipitated carbides.des.

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Compositional Variation of Arsenopyrites in Arsenic and Polymetallic Ores from the Ulsan Mine, Republic of Korea, and their Application to a Geothermometer (울산광산산(蔚山鑛山産) 유비철석(硫砒鐵石)의 조성변화(組成變化) 및 지질온도계(地質溫度計)에 대(對)한 적용(適用))

  • Choi, Seon-Gyu;Chung, Jae-Ill;Imai, Naoya
    • Economic and Environmental Geology
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    • v.19 no.3
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    • pp.199-218
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    • 1986
  • Arsenopyrite in arsenic and polymetallic ores from calcic Fe-W skarn deposit of the Ulsan mine, Republic of Korea, has been investigated by means of electron microprobe analysis and X-ray diffractometry. As a result, it is revealed that the Ulsan arsenopyrite may be classified into the following three species with different generation on the basis of its mode of occurrence, chronological order during polymetallic mineralization and chemical composition; arsenopyrites I, II and III. 1) Arsenopyrite I-(Ni, Co)-bearing species belonging to the oldest generation, which has crystallized together with (Ni, Co)-arsenides and -sulpharsenides in the early stage of polymetallic mineralization. In rare cases, it contains a negligible amount of antimony. It occurs usually as discrete grains with irregular outline, showing rarely subhedral form, and is diffused in skarn zone. The maximum contents of nickel and cobalt are 10.04 Ni and 2.45 Co (in weight percent). Occasionally, it shows compositional zoning with narrow rim of lower (Ni+Co) content. 2) Arsenopyrite II-arsenian species, in which (Ni+Co) content is almost negligible, may occur widely in arsenic ores, and its crystallization has followed that of arsenopyrite I. It usually shows subhedral to euhedral form and is closely associated with $l{\ddot{o}}llingite$, bismuth, bismuthinite, chalcopyrite, sphalerite, bismuthian tennantite, etc. It is worthy of note that arsenopyrite II occasionally contains particles consisting of both bismuth and bismuthinite. 3) Arsenopyrite III-(Ni, Co)-free, S-excess and As-deficient species is close to the stoichiometric composition, FeAsS. It occurs in late hydrothermal veins, which cut clearly the Fe-W ore pipe and the surrounding skarn zone. It shows euhedral to subhedral form, being extremely coarse-grained, and is closely associated with pyrite, "primary" monoclinic pyrrhotite, galena, sphalerite, etc. Among three species of the Ulsan arsenopyrite, arsenopyrite I does not serve as a geothermometer, because (Ni+Co) content always exceeds 1 weight percent. In spite of the absence of Fe-S minerals as sulphur-buffer assemblage, the presence of $Bi(l)-Bi_2S_3$ sulphur-buffer enables arsenopyrite II to apply successfully to the estimation of either temperature and sulphur fugacity, the results are, $T=460{\sim}470^{\circ}C$, and log $f(S_2)=-7.4{\sim}7.0$. With reference to arsenopyrite III, only arsenopyrite coexisting with pyrite and "primary" monoclinic pyrrhotite may serve to restrict the range of both temperature and sulphur fugacity, $T=320{\sim}440^{\circ}C$, log $f(S_2)=-9.0{\sim}7.0$. These temperature data are consistent with those obtained by fluid inclusion geothermometry on late grandite garnet somewhat earlier than arsenopyrite II. At the beginning of this paper, the geological environments of the ore formation at Ulsan are considered from regional and local geologic settings, and physicochemical conditions are suspected, in particular the formation pressure (lithostatic pressure) is assumed to be 0.5kb (50MPa). The present study on arsenopyrite geothermometry, however, does not bring about any contradictions against the above premises. Thus, the following genetical view on the Ulsan ore deposit previously advocated by two of the present authors (Choi and Imai) becomes more evident; the ore deposit was formed at shallow depth and relatively high-temperature with steep geothermal gradient-xenothermal conditions.

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Formation Process and Its Mechanism of the Sancheong Anorthosite Complex, Korea (산청 회장암복합체의 형성과정과 그 메커니즘)

  • Kang, Ji-Hoon;Lee, Deok-Seon
    • Economic and Environmental Geology
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    • v.48 no.6
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    • pp.431-449
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    • 2015
  • The study area is located in the western part of the Precambrian stock type of Sancheong anorthosite complex, the Jirisan province of the Yeongnam massif, in the southern part of the Korean Peninsula. We perform a detailed field geological investigation on the Sancheong anorthosite complex, and report the characteristics of lithofacies, occurrences, foliations, and research formation process and its mechanism of the Sancheong anorthosite complex. The Sancheong anorthosite complex is classified into massive and foliation types of Sancheong anorthosite (SA), Fe-Ti ore body (FTO), and mafic granulite (MG). Foliations are developed in the Sancheong anorthosite complex except the massif type of SA. The foliation type of SA, FTO, MG foliations are magmatic foliations which were formed in a not fully congealed state of SA from a result of the flow of FTO and MG melts and the kinematic interaction of SA blocks, and were continuously produced in the comagmatic differentiation. The Sancheong anorthosite complex is formed as the following sequence: the massive type of SA (a primary fractional crystallization of parental magmas under high pressure)${\rightarrow}$ the foliation type of SA [a secondary fractional crystallization of the plagioclase-rich crystal mushes (anorthositic magmas) primarily differentiated from parental magmas under low pressure]${\rightarrow}$the FTO (an injection by filter pressing of the residual mafic magmas in the last differentiation stage of anorthositic magmas into the not fully congealed SA)${\rightarrow}$the MG (a solidification of the finally residual mafic magmas). It indicates that the massive and foliation types of SA, the FTO, and the MG were not formed from the intrusion and differentiation of magmas which were different from each other in genesis and age but from the multiple fractionation and polybaric crystallization of the coeval and cogenetic magma.

A Preliminary Study on the Igneous Layering and Concentration of Fe-Ti Oxide Minerals within Amphibolite in Soyeonpyeong Island (소연평도 각섬암 내 화성기원 층상구조와 Fe-Ti 산화광물의 농집에 관한 예비연구)

  • Kim, Eui-Jun
    • Economic and Environmental Geology
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    • v.50 no.5
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    • pp.375-387
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    • 2017
  • Amphibolite-hosted Fe-Ti mineralization at the Soyeonpyeong Island, located in central western part of the Korean Peninsula is a typical orthomagmatic Fe-Ti oxide deposit in South Korea. The amphibolite intruded into NW-SE trending Precambrian metasedimentary rocks. Lower amphibolite is characterized by igneous layering, consisting of feldspar-dominant and amphibole-Fe-Ti oxide-dominant layers. The igneous layering shows complicated and/or sharp contact. In contrast, upper amphibolite has a more complicated lithofacies (garnet-bearing, coarser, and schistose), and massive Fe-Ti oxide ore alternates with schistose amphibolite. NS- and EW-trending fault systems lead to redistribute upper amphibolite-hosted Fe-Ti orebody and igneous layering of lower amphibolite, respectively. The whole-rock compositions of amphibolite and Fe-Ti oxide ore reflect their constituent minerals. Amphibolite shows significantly positive Eu anomalies whereas Fe-Ti oxide ore has weak negative Eu anomalies. Plagioclase (Andesine to oligoclase) and Fe-Ti oxide minerals have constant composition regardless of their distribution. Amphibole has a compositionally variable but it doesn't reflect the chemical evolution. Mineral compositions within individual layers and successive layers are relatively constant not showing any stratigraphic evolution. This suggests that there are no successive injections of Fe-rich magma or assimilation with Fe-rich country rocks. Contrasting Eu anomalies between amphibolite and Fe-Ti oxide ore also suggest that extensive plagioclase fractionation during early crystallization stage cause increase in $Fe_2O_3/FeO$ ratio and overall Fe contents in the residual magma. Thus, Fe-rich residual liquids may migrate at the upper amphibolite by filter pressing mechanism and then produce sheeted massive Fe-Ti mineralization during late fractional crystallization.

Esthetic Realignment of Periodontally Compromised Anterior Teeth (치주질환으로 인한 전치부 정출(Extrusion)의 심미적 수복에 관한 증례)

  • Choi, Won-Seok
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.8 no.1
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    • pp.60-63
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    • 1999
  • Dental clinicians commonly encounter extrusion of the anterior teeth due to localized alveolar bone loss in adult patients with chronic periodontitis. This pathologic migration of the anterior not only may cause loss of functional anterior guidance and continuous periodontal destruction, but also can lead to esthetic disaster. In fact, most frequently reported chief complaint of the patients with extruded anterior teeth is the 'loss of esthetics', not the periodontal problem itself. The utilization of the expertise and skills in the various dental disciplines is thought to be the best treatment modality for the ultimate functional and esthetic attainment. Interdisciplinary therapy, involving periodontics, orthodontics, and restorative dentistry, was performed for the highest levels of patient and provider satisfaction in this case.

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Petrology of Latite Ridge Latite in the East Tintic Velcanic Field, Utah in U.S.A. (미국 유타주 이스트틴틱 화산지대에 분포하는 Latite Ridge Latite에 대한 암석학적 연구)

  • Kim, Choon-Sik
    • The Journal of the Petrological Society of Korea
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    • v.8 no.1
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    • pp.1-13
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    • 1999
  • The Latite Ridge Latite in the East Tintic volcanic field, Utah in USA occurs as a welded ash-flow tuff, has 63.7-66 wt% $SiO_2$ on an anhydrous basis, and shows calc-alkaline affinities. The rocks fall in the trachyte field of IUGS classification. It is characterized by unusally high $K_2O$ content (5.9-7.6 wt%), relatively high equilibration temperature (950-973$^{\circ}C$), and biotites with high $TiO_2$ content (7.4-8.2wt%). Various differentiation processes were tested using the XLFRAC program to infer the origin of the Latite Ridge Latite. The results suggests that crystal fractionation from shoshonite is one possible process to generate the Latite Ridge Latite. Shoshonite of the East Tintic volcanic field was possibly formed by crystal fractionation from a subduction-related K-, Mg-rich mafic magma.

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Orthodontic Treatment of Molar Teeth Impacted by Local Factors (국소적 원인으로 매복된 구치의 교정치료)

  • Kim, Seong-Sik;Son, Woo-Sung
    • The korean journal of orthodontics
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    • v.29 no.1 s.72
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    • pp.129-136
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    • 1999
  • Etiologies of the molar teeth impaction are cyst, supernumerary teeth, ankylosis by replacement resorption, abnormal eruptive path, improper orthodontic treatment, etc. If the impacted teeth were untreated, the sequallae was as follows : loss of occlusal function, loss of permanent tooth, extrusion of opposite tooth, root resolution of adjacent teeth. The most important factor of solution of impacted teeth is treatment timing & proper application of orthodontic forces.

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Treatment of ankylosed posterior teeth: Subluxation and Extrusion Method (골유착 대구치의 교정적 치험례)

  • Mun, Cheol-Hyeon
    • The Journal of the Korean dental association
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    • v.38 no.10 s.377
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    • pp.962-968
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    • 2000
  • 치조골과 백악질이 치근막에 의하여 경계되어지지 않고 직접 접촉된 상태인 골유착치는 치조골성장장애, 불안전 맹출, 대합치의 정출, 인접치와의 불안정한 관계 등 다양한 문제를 야기한다. 골유착치의 진단은 방사선 사진에서 치근막의 소실, 타진시의 독특한 소리, periotest를 이용한 동요도 검사 등 다양한 방법이 사용되나 그 신뢰성은 높지 않은 편이다. 따라서 저자는 통산적인 방법은 견인을 시행한 후 견인여부를 평가하여 골유착 여부를 판단하는 임상적 진단법을 사용하고 있다. 골유착치의 치료는 subluxation & extrusion법, autotransplantation법, corticotomy법, segmental osteotomy법, ostectomy법등 다양한 방법이 제시되고 있다. Subluxation & extrusion법은 적용이 간편한 장점이 있으나 골유착의 재발로 인한 교정치료의 실패가능성이 높은 단점이 있다. 본 증례는 다수치의 부분맹출 및 골유착으로 인한 구치부 개방교합이 주소인 환자로 소구치는 통산적인 교정치료법으로 골유착된 대구치는 subluxation & extrusion법을 적용하여 양호한 치료 결과를 얻을 수 있었다.

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Solidifications Simulation of Gray Iron Sheave Product with Consideration of Graphite Precipitation (흑연정출을 고려한 회주철제 시브제품의 응고해석)

  • Ryu, Seong-Gon
    • Korean Journal of Materials Research
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    • v.9 no.2
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    • pp.139-143
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    • 1999
  • Solidification simulation of gray cast iron sheave product was conducted with the consideration of graphite precipitation during solidification, and of casting processes such as post-inoculation method, treatment and rate, the result of which was aimed to be adopted in the field. In risering design(I), shrinkage cavities were predicted to occur in the part below the risers and center part of the product. While the former defect was considered to be due to the solidification behaviour of riser neck, the latter was due to the feeding channel. In design(II), the length of the riser neck was reduced and one top open riser was attached in the center of the product to prevent the formation of shrinkage cavities, whereby defect-free product was produced.

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Surgical extrusion of immature permanent tooth with crown-root fractures: a case report with 36-month follow up (외과적 정출술을 이용한 치관-치근 파절된 미성숙 영구치의 치료: 3년 간의 증례보고)

  • Jeon, Su-jin
    • The Journal of the Korean dental association
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    • v.57 no.11
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    • pp.679-688
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    • 2019
  • A 8-year-old patient presented with a crown-root fracture of the maxillary right central incisor with an oblique subgingival fracture line. A multidisciplinary treatment approach including endodontic treatment, surgical extraction and intraalveolar repositioning was used to gain sufficient crown length of the fractured maxillary incisor. The coronally repositioned maxillary right central incisor was stabilized by a resin wire splint. Apexification using MTA was performed. Resin core and direct resin restoration(Cl IV) on fractured teeth was built up. Clinical and radiographic follow-up of the maxillary right central incisor after 36 months showed no signs of root resorption or pathology and acceptable aesthetics and functions were maintained. Surgical extrusion can be considered as a good treatment modality for young patients.

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