• Title/Summary/Keyword: 정제유

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석유물류네트워크의 로버스트 추계적 최적화 모형

  • Kim, Mun-Ju;Kim, Si-Hwa
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2018.05a
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    • pp.135-137
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    • 2018
  • 다수의 원유 선적항으로부터 여러 정유공장으로 수송된 원유를 정제하여 생산한 제품유를 글로벌 수요시장으로 배분하는 2단계 석유물류네트워크의 최적화는 글로벌 석유 메이저의 중요한 의사결정문제이다. 본 연구는 제품유 시장의 가격 및 수요 변동의 영향을 반영하여 원유 수송, 정제 및 제품유 배분을 최적화하기 위한 석유물류네트워크의 로버스트 추계적 모형을 제시하고 있다. 계산실험은 제품유 시장의 가격 및 수요 변동에 관한 시나리오 기반의 데이터를 사용하여 최적화 모형에 적용하였으며, 그 결과를 바탕으로 제시한 최적화모형의 유용성과 타당성을 검증하여 보고하고 있다.

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The Oxidation Stability and Flavor Acceptability of Oil from Roasted Soybean (볶은 대두로부터 착유한 대두유의 산화 안정성 및 향기 기호도)

  • Im, Moo-Hyeog;Choi, Jong-Dong;Choi, Kwang-Soo
    • Applied Biological Chemistry
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    • v.38 no.5
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    • pp.425-430
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    • 1995
  • The effects of oxidation stability and flavor acceptability of soybean oil by roasting and refining treatment were investigated in this study. The peroxide values of crude oil from unroasted soybean(COUS) were more increased than those of crude oil from unroasted soybean(CORS) during storage under fluorescence light at $45^{\circ}C$. Induction time by the Rancimat Method was 44.9 and above 88.7 hours on COUS and CORS respectively. The order of oxidation stability of oil was crude>degummed>alkali-refining>deodorized>bleached oil in terms of peroxide value, while that of oxidation stability of oil was crude>degummed>deodorized>alkali-refining>bleached oil in regard to induction time by the Rancimat Method. The correlation coefficients between induction time and two charateristics(absorbance of browning reaction products and phosphorous contents) were highly significant, while that between induction time and tocopherol contents was not high during refining stages. The scores for the sensory evaluation of flavor on sesame oil and CORS was 9.269 and 8.269 respectively, but it was not significant between two oils.

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Gasification Performance with Key Operating Variables Using a Heavy Residual Oil (중잔유 사용시 주요 운전 변수에 따른 가스화 성능 예측)

  • 이승종;윤용승
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2000.11a
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    • pp.49-54
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    • 2000
  • 중잔유(heavy residual oil)는 원유 정제 후 남는 원유의 잔여물로서, 세계적으로 정제공정(즉, SOx 및 NOx 방출량)과 정제물의 질에 대한 환경 규제가 계속 강화되고 있는 추세에비추어 다른 유류나 석탄에 비해 유황과 중금속(특히 바나듐)을 많이 포함하고 있는 중잔유를 환경적합적으로 활용하는 문제는 시급히 해결해야 하는 과제가 되고 있다.(중략)

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Combustion Reactivity Assessments of Oils Used for the Cold Start-Up Operation of Large Scale Boiler (대용량 보일러의 냉간기동용 액체 연료에 대한 연소 반응성 평가)

  • LEE, JANG HO;PARK, HO YOUNG
    • Journal of Hydrogen and New Energy
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    • v.33 no.1
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    • pp.77-84
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    • 2022
  • The experimental work has been carried out for the study of pyrolysis of oil samples used in industrial and utility boilers in Korea. For five oil samples, the characteristics of pyrolysis have been investigated with a thermogravimetric analyzer (TGA), and their kinetic parameters were obtained and compared each other. The rate order of pyrolysis rate for five oils were as follows: by-product fuel oil, pyrolysis oil, diesel, a heavy oil and refined oil. The pyrolysis of refined oil has been successfully described by the three step, first order reaction model while the single step reaction model has been used for other oils. For the reaction temperature over 550 K, the reactivity of refined oil was very poor compared with other oils.

Extraction of Soybean Oil Using Supercritical Carbon Dioxide and Its Characteristics (초임계 탄산가스를 이용한 대두유의 추출과 추출대두유의 성질)

  • Kim, In-Hwan;Yoon, Suk-Hoo
    • Korean Journal of Food Science and Technology
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    • v.23 no.6
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    • pp.677-682
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    • 1991
  • Extraction of soybean oil from full tat soybean flour was performed using a supercritical carbon dioxide extraction system. Extraction pressure and temperature of the process were 3,000-7,000 psig and $40-70^{\circ}C$, repectively. For the extraction of lg of soybean oil, 25l of carbon was consumed at 7,000 psig and $60^{\circ}C$, whereas more than 2501 of carbon dioxide was consumed at 3,000 psig and $60^{\circ}C$. The solubility of soybean oil in supercritical carbon dioxide decreased with the increase in temperature below 6,000 psig, and the reverse trend was observed above 6,000 psig. At 6,000 psig the solubilities were shown to be, constant regardless of extraction temperature. Soybean oils , extracted with supercritical carbon dioxide were lighter in color and contained less phosphorus than those extracted with hexane.

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Benzo(a)pyrene Contents in Commercial Vegetable Oils and Changes during Processing of Vegetable Oils (국내 유통 식용유지 및 식용유지 종류별 제조 공정에 따른 벤조피렌 함량)

  • Sung, Tae-Kyung;Lee, Ji-Soo;Lee, Hyeon-Gyu
    • Korean Journal of Food Science and Technology
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    • v.44 no.3
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    • pp.269-273
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    • 2012
  • The principal objective of this study was to estimate the benzo(a)pyrene contents in commercial vegetable oils available in the Korean market and to assess the effects of various processing steps for vegetable oils on the contents of benzo(a)pyrene. Benzo(a)pyrene content in the studied commercial vegetable oils, crude oils, and raw materials were found to be lower than the maximum levels of 2 ppb. In both refined and pressed oil, the benzo(a)pyrene contents can be reduced through refining steps. However, an evident increase of benzo(a)pyrene contents during both the expeller process for corn oil and the roasting process for sesame oil was observed. This result indicates that the processing procedure, particularly heat treatment and refining steps would be critical in managing the benzo(a)pyrene contents in vegetable oils.

Antioxidative Activities of Spices Extracts on Peroxidation of Refined Sardine Oil (정제정어리유에 대한 향신료 추출물의 항산화작용)

  • JI Cheong-Il;KANG Jin-Hoon;PARK Yeung-Beom;LEE Tae-Gee;KIM Seon-Bong;PARK Yeung-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.25 no.5
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    • pp.325-330
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    • 1992
  • This paper deals with the antioxidative activities of some spices on the autoxidation of refined sardine oil. The various spices powders(120mesh) were added into the refined sardine oil at the level of $0.1\%$ (w/w), and then incubated at $37^{\circ}C$ Among spices tested, herb spices showed higher antioxidative activities than spicy and seed spices. Especially, the antioxidative activities of herb spices on peroxidation of refined sardine oil were most effective in rosemary and sage. Furthermore, the available antioxidative compounds of rosemary and sage were fractionated into petroleum ether-soluble and -insolubles. Petroleum ether-soluble fractions(PESF) obtained from rosemary and sage on the autoxidation of refined sardine oil had a great antioxidative activities. The yields of PESF obtained from rosemary and sage were $10.3\%\;and\;12.6\%$, respectively. The PESF of rosemary and sage showed higher antioxidative effects than butylated hydroxytoluene(BHT), and indicated predominant metal ion-scavenging effect in PESF-refined sardine oil systems.

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The Proteinase Distributed in the Intestinal Organs of Fish 1. Purification of the Three Alkaline Proteinases from the Pyloric Caeca of Mackerel, Scomber japonicus (어류의 장기조직에 분포하는 단백질분해효소에 관한 연구 1. 고등어 유문수조직으로부터 3종의 알칼리성 단백질분해효소의 분리${\cdot}$정제)

  • PYEUN Jae-Hyeung;KIM Hyeung-Rak
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.6
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    • pp.537-546
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    • 1986
  • In the previous paper(Kim et al, 1986), the alkaline proteinase from the pyloric caeca of mackerel was shown relatively strong activity in the alkaline pH range. Therefore purification of the enzyme has been undertaken to identify the proteolytic enzyme and three alkaline proteinases were isolated by ammonium sulfate fractionation, DEAE-Sephadex A-50 column chromatography and Sephadex G-100 gel filtration. One percent sodium chloride solution was the most effective for the extraction of alkaline proteinase from the pyloric caeca of mackerel. Three alkaline proteinases temporarily designated Enz. A, B and C were isolated from the pyloric caeca of mackerel, and identified to be homogeneous with electrophoresis. The specific activity of the purified Enz. A, B and C was increased to 34, 53 and 37-fold over the crude enzyme solution, respectively. Yield of them was 1.6, 2.1 and $1.5\%$, respectively, and a combined yield was $5.2\%$.

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폐윤활유 정제기술

  • 박상도
    • Tribology and Lubricants
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    • v.10 no.2
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    • pp.20-29
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    • 1994
  • 우수한 기유와 첨가제들이 혼합된 양질의 윤활유라 할지라도 윤활유는 사용중에 차차 변질하여 그 성상이 저하하게 되는데 이와 같은 윤활유의 열화현상은 윤활유 자신이 일으키는 내부변화 즉, 화학변화와 외부적 요인에 의하여 생기는 윤활유의 오염 등에 기인하는 것으로 알려져 있다. 열화현상이 발생되면 폐윤활유는 주기적으로 교체하여야 하는데 소모성 물질이 아닌 윤활유는 국내에서 93년도 기준 년간 약 750,000 k1의 윤활유가 사용되어지고 있다. 윤활유 사용으로부터 발생된 폐윤활유는 첫째, 원유내의 윤활 성분이 10~15%인데 비하여 폐윤활유는 약 85% 이상의 윤활성분이 포함되어 있어 윤활기유의 회수율이 높으며 둘째, 폐윤활유내의 불순물은 윤활성분과는 물리화학적 성질이 달라 쉽게 분리될 수 있으며 셋째, 폐윤활유는 윤활유로서의 부적당한 물질은 이미 열화나 산화에 저거된 상태이므로 재정제가 용이하다는 장점이 있어 폐자원 재활용 측면에서 오래전 부너 관심의 대상이 되어왔다.