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Synthesis and Structure of the Layered Cathode Material $Li[Li_xMn_{1-x-y}Cr_y]O_2$ for Rechargeable Lithium Batteries (리튬2차전지용 양극 소재 $Li[Li_xMn_{1-x-y}Cr_y]O_2$의 합성 및 층상구조 연구)

  • 최진범;박종완;이승원
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.3
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    • pp.223-232
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    • 2003
  • The co-precipitation method is applied to synthesize the cathode material Li[L $i_{x}$M $n_{1-x-y}$C $r_{y}$ ] $O_2$ for lithium rechargeable batteries at $650^{\circ}C$ (CR650) and 8$50^{\circ}C$ (CR850), respectively. Rietveld indices indicate that $R_{wp}$ with respect to $R_{exp}$ ( $R_{wp}$/ $R_{exp}$) are 9.2%/10.1% for CR650 and 15.9%/9.76% for CR850, respectively. $R_{B}$ and S (GofF) shows 10.9%, 8.54% and 1.9, 1.6, respectively. Rietveld structure refinement reveals that layer structure of LiMn $O_2$ (R3m) coexists with lower symmetry of Li[L $i_{1}$3/M $n_{2}$3/] $O_2$ (C2/c) due to superlattice ordering of Li and Mn in metal-transition containing layers. Unit-cell parameters are calculated as a=2.8520(2)$\AA$, c=14.248(2)$\AA$, V=100.40(l)$\AA^3$ for CR650, and a=2.8504(1)$\AA$, c=14.2371(7)$\AA$, V=100.179(8)$\AA^3$ for CR850. Final chemistry is obtained as Li[L $i_{0.35}$M $n_{0.56}$C $r_{0.09}$] $O_2$ (CR650) and Li[L $i_{0.27}$M $n_{0.61}$C $r_{0.13}$] $O_2$ (CR850), respectively.y...y..vely.y...y..

Effective Geophysical Methods in Detecting Subsurface Caves: On the Case of Manjang Cave, Cheju Island (지하 동굴 탐지에 효율적인 지구물리탐사기법 연구: 제주도 만장굴을 대상으로)

  • Kwon, Byung-Doo;Lee, Heui-Soon;Lee, Gyu-Ho;Rim, Hyoung-Rea;Oh, Seok-Hoon
    • Journal of the Korean earth science society
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    • v.21 no.4
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    • pp.408-422
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    • 2000
  • Multiple geophysical methods were applied over the Manjang cave area in Cheju Island to compare and contrast the effectiveness of each method for exploration of underground cavities. The used methods are gravity, magnetic, electrical resistivity and GPR(Ground Pentrating Radar) survey, of which instruments are portable and operations are relatively economical. We have chosen seven survey lines and applied appropriate multiple surveys depending on the field conditions. In the case of magnetic method. two-dimensional grid-type surveys were carried out to cover the survey area. The geophysical survey results reveal the characteristic responses of each method relatively well. Among the applied methods, the electric resistivity methods appeared to be the most effective ones in detecting the Manjang Cave and surrounding miscellaneous cavities. Especially, on the inverted resistivity section obtained from the dipole-dipole array data, the two-dimensional distribution of high resistivity cavities are revealed well. The gravity and magnetic data are contaminated easily by various noises and do not show the definitive responses enough to locate and delineate the Manjang cave. But they provide useful information in verifying the dipole-dipole resistivity survey results. The grid-type 2-D magnetic survey data show the trend of cave development well, and it may be used as a reconnaissance regional survey for determining survey lines for further detailed explorations. The GPR data show very sensitive response to the various shallow volcanic structures such as thin spaces between lava flows and small cavities, so we cannot identify the response of the main cave. Although each geophysical method provides its own useful information, the integrated interpretation of multiple survey data is most effective for investigation of the underground caves.

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Establishment of Geospatial Schemes Based on Topo-Climatology for Farm-Specific Agrometeorological Information (농장맞춤형 농업기상정보 생산을 위한 소기후 모형 구축)

  • Kim, Dae-Jun;Kim, Soo-Ock;Kim, Jin-Hee;Yun, Eun-Jeong
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.21 no.3
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    • pp.146-157
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    • 2019
  • One of the most distinctive features of the South Korean rural environment is that the variation of weather or climate is large even within a small area due to complex terrains. The Geospatial Schemes based on Topo-Climatology (GSTP) was developed to simulate such variations effectively. In the present study, we reviewed the progress of the geospatial schemes for production of farm-scale agricultural weather data. Efforts have been made to improve the GSTP since 2000s. The schemes were used to provide climate information based on the current normal year and future climate scenarios at a landscape scale. The digital climate maps for the normal year include the maps of the monthly minimum temperature, maximum temperature, precipitation, and solar radiation in the past 30 years at 30 m or 270 m spatial resolution. Based on these digital climate maps, future climate change scenario maps were also produced at the high spatial resolution. These maps have been used for climate change impact assessment at the field scale by reprocessing them and transforming them into various forms. In the 2010s, the GSTP model was used to produce information for farm-specific weather conditions and weather forecast data on a landscape scale. The microclimate models of which the GSTP model consists have been improved to provide detailed weather condition data based on daily weather observation data in recent development. Using such daily data, the Early warning service for agrometeorological hazard has been developed to provide weather forecasts in real-time by processing a digital forecast and mid-term weather forecast data (KMA) at 30 m spatial resolution. Currently, daily minimum temperature, maximum temperature, precipitation, solar radiation quantity, and the duration of sunshine are forecasted as detailed weather conditions and forecast information. Moreover, based on farm-specific past-current-future weather information, growth information for various crops and agrometeorological disaster forecasts have been produced.

Gridded Expansion of Forest Flux Observations and Mapping of Daily CO2 Absorption by the Forests in Korea Using Numerical Weather Prediction Data and Satellite Images (국지예보모델과 위성영상을 이용한 극상림 플럭스 관측의 공간연속면 확장 및 우리나라 산림의 일일 탄소흡수능 격자자료 산출)

  • Kim, Gunah;Cho, Jaeil;Kang, Minseok;Lee, Bora;Kim, Eun-Sook;Choi, Chuluong;Lee, Hanlim;Lee, Taeyun;Lee, Yangwon
    • Korean Journal of Remote Sensing
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    • v.36 no.6_1
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    • pp.1449-1463
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    • 2020
  • As recent global warming and climate changes become more serious, the importance of CO2 absorption by forests is increasing to cope with the greenhouse gas issues. According to the UN Framework Convention on Climate Change, it is required to calculate national CO2 absorptions at the local level in a more scientific and rigorous manner. This paper presents the gridded expansion of forest flux observations and mapping of daily CO2 absorption by the forests in Korea using numerical weather prediction data and satellite images. To consider the sensitive daily changes of plant photosynthesis, we built a machine learning model to retrieve the daily RACA (reference amount of CO2 absorption) by referring to the climax forest in Gwangneung and adopted the NIFoS (National Institute of Forest Science) lookup table for the CO2 absorption by forest type and age to produce the daily AACA (actual amount of CO2 absorption) raster data with the spatial variation of the forests in Korea. In the experiment for the 1,095 days between Jan 1, 2013 and Dec 31, 2015, our RACA retrieval model showed high accuracy with a correlation coefficient of 0.948. To achieve the tier 3 daily statistics for AACA, long-term and detailed forest surveying should be combined with the model in the future.

Numerical Simulation of Normal Logging Measurements in the Proximity of Earth Surface (지표 부근에서의 노멀전기검층 수치 모델링)

  • Nam, Myung-Jin;Hwang, Se-Ho
    • Economic and Environmental Geology
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    • v.43 no.3
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    • pp.259-267
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    • 2010
  • Resistivity logging instruments were designed to measure electrical resistivity of formation, which can be directly interpreted to provide water-saturation profile. Short and long normal logging measurements are made under groundwater level. In some investigation sites, groundwater level reaches to a depth of a few meters. It has come to attention that the proximity of groundwater level might distort short and long normal logging readings, when the measurements are made near groundwater level, owing to the proximity of an insulating air. This study investigates the effects of the proximity of groundwater level (and also the proximity of earth surface) on the normal by simulating normal logging measurements near groundwater level. In the simulation, we consider all the details of real logging situation, i.e., the presence of wellbore, the tool mandrel with current and potential electrodes, and currentreturn and reference-potential electrodes. We also model the air to include the earth’'s surface in the simulation rather than the customary choice of imposing a boundary condition. To obtain apparent resistivity, we compute the voltage, i.e., potential difference between monitoring and reference electrodes. For the simulation, we use a twodimensional, goal-oriented and high-order self-adaptive hp finite element refinement strategy (h denotes the element size and p the polynomial order of approximation within each element) to obtain accurate simulation results. Numerical results indicate that distortion on the normal logging is greater when the reference potential electrode is closer to the borehole and distortions on long normal logging are larger than those on short normal logging.

The molten KOH/NaOH wet chemical etching of HVPE-grown GaN (HVPE로 성장된 GaN의 용융 KOH/NaOH 습식화학에칭)

  • Park, Jae Hwa;Hong, Yoon Pyo;Park, Cheol Woo;Kim, Hyun Mi;Oh, Dong Keun;Choi, Bong Geun;Lee, Seong Kuk;Shim, Kwang Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.4
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    • pp.135-139
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    • 2014
  • The hydride vapor phase epitaxy (HVPE) grown GaN samples to precisely measure the surface characteristics was applied to a molten KOH/NaOH wet chemical etching. The etching rate by molten KOH/NaOH wet chemical etching method was slower than that by conventional etching methods, such as phosphoric and sulfuric acid etching, which may be due to the formation of insoluble coating layer. Therefore, the molten KOH/NaOH wet chemical etching is a better efficient method for the evaluation of etch pits density. The grown GaN single crystals were characterized by using X-ray diffraction (XRD) and X-ray rocking curve (XRC). The etching characteristics and surface morphologies were studied by scanning electron microscopy (SEM). From etching results, the optimum etching condition that the etch pits were well independently separated in space and clearly showed their shape, was $410^{\circ}C$ and 25 min. The etch pits density obtained by molten KOH/NaOH wet chemical etching under optimum etching condition was around $2.45{\times}10^6cm^{-2}$, which is commercially an available materials.

An implementation of 2D/3D Complex Optical System and its Algorithm for High Speed, Precision Solder Paste Vision Inspection (솔더 페이스트의 고속, 고정밀 검사를 위한 이차원/삼차원 복합 광학계 및 알고리즘 구현)

  • 조상현;최흥문
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.41 no.3
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    • pp.139-146
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    • 2004
  • A 2D/3D complex optical system and its vision inspection algerian is proposed and implemented as a single probe system for high speed, precise vision inspection of the solder pastes. One pass un length labeling algorithm is proposed instead of the conventional two pass labeling algorithm for fast extraction of the 2D shape of the solder paste image from the recent line-scan camera as well as the conventional area-scan camera, and the optical probe path generation is also proposed for the efficient 2D/3D inspection. The Moire interferometry-based phase shift algerian and its optical system implementation is introduced, instead of the conventional laser slit-beam method, for the high precision 3D vision inspection. All of the time-critical algorithms are MMX SIMD parallel-coded for further speedup. The proposed system is implemented for simultaneous 2D/3D inspection of 10mm${\times}$10mm FOV with resolutions of 10 ${\mu}{\textrm}{m}$ for both x, y axis and 1 ${\mu}{\textrm}{m}$ for z axis. Experiments conducted on several nBs show that the 2D/3D inspection of an FOV, excluding an image capturing, results in high speed of about 0.011sec/0.01sec, respectively, after image capturing, with $\pm$1${\mu}{\textrm}{m}$ height accuracy.

Construction of Three Dimensional Soil Cadmium Pollution Map Using Geotechnical Information DB System (국토지반정보시스템을 이용한 3차원 토양오염지도 구축)

  • Hwang, Dae Young;Kang, In Joon;Jang, Yong Gu;Kim, Soo Kyum
    • Journal of Korean Society for Geospatial Information Science
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    • v.24 no.4
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    • pp.13-19
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    • 2016
  • This study presented the build-up of three-dimensional soil pollution map for precise analysis. To do this, survey on the existing pollutant region on Dongnae-gu, Busan that is the study subject, showed that it tended to produce 0.72 clusters. So, this study suggested to investigate center of $1km{\times}1km $ grid and, as the results of comparing the pollution map that input pollution figure values based on the actually investigation point showed precise results. And, it divided the standard of pollution into 5 levels in surface and underground space and the map was built up using IDW interpolation against the amount of polluted substance. The pollution of ground surface, flow of polluted substance, coefficient of permeability and ground water level that are 504 geotechnical informations were selected as the influential parameters in pollution analysis of underground space, and it calculated that to 0~20 points by dividing the characteristics. It enables the build-up of pollution map of ground surface-underground with depth that considers the characteristics of soil layers and it is considered that it is possible to analyze the general infiltration. And, it was considered that it enables more accurate forecast about influential analysis per depth and pollution of underground water.

Enhanced Recovery of Gravity Fields from Dense Altimeter Data

  • Kim, Jeong-Hee
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.14 no.2
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    • pp.127-139
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    • 1996
  • This paper presents a procedure to recover sea surface heights (SSH) and free-air (FA) gravity anomalies from dense satellite altimeter SSH data with enhanced accuracies over the full spectrum of the gravity field. A wavenumber correlation filtering (WCF) of co-linear SSH tracks is developed for the coherent signals of sub-surface geological masses. Orbital cross-over adjustments with bias parameters are applied to the filtered SSH data, which are then separated into two groups of ascending and descending tracks and gridded with tensioned splines. A directional sensitive filter (DSF) is developed to reduce residual errors in the orbital adjustments that appear as track patterned SSH. Finally, FA gravity anomalies can be obtained by the application of a gradient filter on a high resolution estimate of geoid undulations after subtracting dynamic sea surface topography (DSST) from the SSH. These procedures are applied to the Geosat Geodetic Mission (GM) data of the southern oceans in a test area of ca. $900km\;\times{1,200}\;km$ to resolve geoid undulations and FA gravity anomalies to wavelengths of-10 km and larger. Comparisons with gravity data from ship surveys, predictions by least squares collocation (LSC), and 2 versions of NOAA's predictions using vertical deflections illustrate the performance of this procedure for recovering all elements of the gravity spectrum. Statistics on differences between precise ship data and predicted FA gravity anomalies show a mean of 0.1 mgal, an RMS of 3.5 mgal, maximum differences of 10. 2 mgal and -18.6 mgal, and a correlation coefficient of 0.993 over four straight ship tracks of ca. 1,600 km where gravity changes over 150 mgals.

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Evaluation of Radiation effective dose by Naturally Radionuclides in the Soil of Busan (부산지역 토양 내 천연방사성핵종 분석 및 유효선량율 평가)

  • Kim, Jung-Hoon;Kim, Chang-Soo;Lim, Chang-Seon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3658-3666
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    • 2014
  • The presence of $^{238}U$, $^{232}Th$ and $^{40}K$, which are naturally residing radionuclides, in the ordinary soil of Busan, the 2nd largest city in Korea, was anlayzed and the residents' radiation exposure to ordinary soil was evaluated. Regarding the measurement methods, to conduct a detailed analysis of the naturally residing radionuclides in the soil of Busan, this study divided the 16 administrative districts into a lattice structure with 3 spots, and collected a total of 48 soil samples (July 2012 and April 2013). ICP-MS was used to analyze the concentration of the radioactivity of $^{238}U$ and $^{232}Th$ in the soil, and a HpGe detector, a gamma ray detector, was used to analyze the radioactivity of $^{40}K$. The measurement values of this study were compared with the concentration of radioactivity of East Asian regions. The concentration of $^{238}U$ nuclides in Korea was lower than the mean, whereas the concentration of $^{232}Th$ and $^{40}K$ nuclides was higher than the mean. The higher mean concentrations of $^{232}Th$ and $^{40}K$ than the mean were attributed to the many granite areas that contain a great deal of naturally occurring radionuclides.