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Growth and Photocurrent Properties of CuGaTe2 Single Crystal Thin Films by Hot Wall Epitaxy (Hot Wall Epitaxy (HWE) 방법에 의한 CuGaTe2 단결정 박막 성장과 광전류 특성)

  • 백승남;홍광준
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.158-158
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    • 2003
  • 수평 전기로에서 CuGaTe2 다결정을 합성하여 HWE 방법으로 CuGaTe2 단결정 박막을 반절연성 GaAs(100) 위에 성장하였다. CuGaTe2 단결정 박막은 증발원과 기판의 온도를 각각 67$0^{\circ}C$, 41$0^{\circ}C$로 성장하였다. 이때 단결정 박막의 결정성이 10K에서 측정한 광발광 스펙트럼은 954.5nm (1.2989eV) 근처에서 exciton emission 스펙트럼이 가장 강하게 나타났으며, 또한 이중결정 X-선 요동곡선(DCRC)의 반폭치(FWHM)도 139arcsec로 가장 작게 측정되어 최적 성장 조건임을 알 수 있었다. Hall 효과는 van der Paw방법에 의해 측정되었으며, 온도에 의존하는 운반자 농도와 이동도는 293K에서 각각 8.72$\times$$10^{23}$개/㎥, 3.42$\times$$10^{-2}$$m^2$/V.s였다. 상온에서 CuGaTe2 단결정 박막의 광흡수 특성으로부터 에너지 띠간격이 1.22 eV였다 Band edge에 해당하는 광전도도peak의 온도 의존성은 Varshni 관계식으로 설명되었으며, Varshni 관계식의 상수값은 Eg(0) = 1.3982 eV, $\alpha$= 4.27$\times$$10^{-4}$ eV/K, $\beta$= 265.5 K로 주어졌다. CuGaTe2 단결정 박막의 광전류 단파장대 봉우리들로부터 10K에서 측정된 $\Delta$cr (crystal Field splitting)은 0.0791eV, $\Delta$s.o (spin orbit coupling)는 0.2463eV였다. 10K에서 광발광 봉우리의 919.8nm (1.3479eV)는 free exciton(Ex), 954.5nm (1.2989eV)는 donor-bound exciton 인 I2(DO,X)와 959.5nm (1.2921eV)는 acceptor-bound exciton 인 I1(AO,X) 이고, 964.6nm(1.2853eV)는 donor-acceptor pair(DAP) 발광, 1341.9nm (0.9239eV)는 self activated(SA)에 기인하는 광발광 봉우리로 고찰되었다.

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Synthesis of free-standing ZnO/Zn core-shell micro-polyhedrons using thermal chemical vapor deposition (열화학기상증착법을 이용한 프리스탠딩 ZnO/Zn 코어셀 마이크로 다면체 구조물의 합성)

  • Choi, Min-Yeol;Park, Hyun-Kyu;Jeong, Soon-Wook;Kim, Sang-Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.4
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    • pp.155-159
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    • 2008
  • In this work, we report synthesis of free-standing ZnO/Zn core-shell micro-polyhedrons using metal Zn pellets as a source material by the thermal chemical vapor deposition process. Scanning and transmission electron microscopy measurements were introduced to investigate morphologies and structural properties of as-grown ZnO/Zn core-shell micro-polyhedrons. It was found that micro-polyhedrons were composed of inner single-crystalline metal Zn surrounded by single-crystalline ZnO nanorod arrays. The inner single crystalline metal Zn with micro-scale diameter has a hexagonal crystal structure. Diameter and height of ZnO nanorods covering the metal Zn surface are below 10 nm and 100 nm, respectively. It was also confirmed that c-axis oriented ZnO nanorods are single crystalline with a hexagonal crystal structure.

A Comparative Study on the Environmental Impacts by Concrete Strength Using End-point LCA methodology (피해산정형 전과정평가 기법을 적용한 콘크리트 압축강도별 환경영향 비교 분석 연구)

  • Kim, Sung-Hee;Tae, Sung-Ho;Chae, Chang-U
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.465-474
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    • 2014
  • This is a comparative study that shows the overall environmental impacts from concrete structures when different compressive strength of concrete applied to structural systems having the same reference flow with different durability. A total of 24 MPa, 40 MPa and 60 MPa cases is analyzed to define the characteristic using end-point perspective LCA methodology including the stages of production, construction, maintenance and disposal. As results, global warming, non-renewable energy and respiratory inorganics problems are the major issues for assessing environmental impacts of concrete products.

Pore Structure and Separation Properties of Thin Film Composite Forward Osmosis Membrane with Different Support Structures (지지층 구조가 다른 복합 정삼투막의 기공구조와 분리 특성)

  • Ahn, Soo-Hyun;Kim, In-Chul;Song, Doo-Hyun;Jegal, Jonggeon;Kwon, Young-Nam;Rhee, Hee-Woo
    • Membrane Journal
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    • v.23 no.3
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    • pp.251-256
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    • 2013
  • In this study, acetylated methyl cellulose (AMC) was successfully used as a support layer of thin film composite (TFC) forward osmosis (FO) membrane. A selective polyamide active layer, interfacially polymerized, was coated on top of various substrate layers. The structure and performance of the TFC FO membrane based on the AMC substrate were compared with those of TFC FO membranes with different polymeric support layers. The experimental results showed that the AMC FO membrane performance was better than other FO membranes due to its characteristic morphology and lower back diffusion rate of salts.

THE FORMAL ANALYSIS OF PANTHEON IN ROME IN RELATION TO THE SOLAR ANGLES (로마 판테온의 일조특성 연구)

  • Lim, Choong-Shin
    • Journal of architectural history
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    • v.7 no.4 s.17
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    • pp.191-198
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    • 1998
  • The form of Pantheon in Rome is graphically analyzed in relation to the angle of the Sun that varies through four seasons of the year. These are worked out in the Autocad drawing files for exactitude and efficiency. Some of the results suggest that the Pantheon is carefully designed to predict the equinoxes and the solstices.

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Real Time On-line Quality Assurance System for HDR Brachytherapy (고선량률 근접 방사선 치료를 위한 실시간 온-라인 정도 관리(QA) 시스템 개발)

  • Lee Su Jin;Lee Re Na;Yi Byang Yang;Lim Sang Waak;Choi Jin Ho
    • Progress in Medical Physics
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    • v.15 no.3
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    • pp.156-160
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    • 2004
  • An essential quality assurance (QA) procedure in high dose rate (HDR) remote after-loading brachytherapy is that of the verification of the Ir-192 HDR source positioning accuracy. A number of methods using mechanical rulers or autoradiograph and video cameras have been reported to check the positional error of the Ir-192 source. In this study, the feasibility of a CMOS (Complementary Metal Oxide Semiconductor) PC camera, with a fluorescent screen, was investigated. The agreement between the planned and measured dwell position was better than 1 mm and dwell times better than 0.4 sec. Our results indicate that the CMOS PC camera system could be used as a QA tool for the on-line determination of the source position and dwell time.

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Spinel$(MgAl_2O_4)$ single crystal growth by floating zone method (Floating zone 법에 의한 Spinel$(MgAl_2O_4)$단결정 성장)

  • Seung Min Kang;Byong Sik Jeon;Keun Ho Orr
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.3
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    • pp.325-335
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    • 1994
  • The spinel $MgO.Al_20_3$ single crystals were grown by FZ (floating zone) method. Its melting point is about, $2135^{\circ}C$ and is important to the process of the growth from the melt. There have been some reports of the growth by Czochralski and Verneuil method. However, this study is the first trial to the spinel crystal with the application of FZ method. In this study, $MgAl_2O_4$ spinel crystals were grown by using FZ method which uses the ellipsoidal mirror furnace having infrared halogen lamps as a heat source. With dopants of transition metal ions, it was possible to melt the feed rod which does not absorb the infrared rays due to the transparent properties to infrared ray of spinel itself and the red, green and blue colored spinel single crystals could be grown more easily. As a conclusion, the purpose of this study is to find the spinel single crystal growth mechanism with respect to th growth interfaces and molten zone stability and to characterize the state of growth resulting from the concavity to the melt of interfaces.

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The effect of cooling rate on the nuclei of OISF formation in Si single crystals (실리콘 단결정에서 산화적층결함의 핵생성에 미치는 냉각속도의 영향)

  • 하태석;김병국;김종관;윤종규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.360-367
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    • 1996
  • The OISF (Oxidation Induced Stacking Fault)is expected to affect the electrical properties in Si single crystals, and the nuclei of OISF are believed to be formed during the crystal growing process. Initial oxygen concentration, dopant type and its density, and cooling rate are regareded as major factors on OISF formation. In this study, the variations of OISF density under various cooling rate were investigated. Si single crystal was heated to $1400^{\circ}C$ in Ar ambient and cooled down to room temperature at different cooling rate, using horizontal tube furnace. After that, they were oxidized at $1150^{\circ}C$, and then, OISF was observed with optical microscope. The relation between oxide procipitates and OISF nucleation was investigated by FTIR analysis. As a result, it was found that there exists the intermediate cooling rate range in which OISF nucleation is highly enhanced. And also, it was found that OISF nucleation is closely related with silicon oxide procipitation in Si single crystals.

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Char Oxidation Characteristics of Ashless Coal in Drop Tube Furnace (DTF를 이용한 초청정 석탄 촤 산화 반응률 특성 연구)

  • Kim, Sang-In;Lee, Byoung-Hwa;Lim, Ho;Yu, Da-Yeon;Lee, Si-Hyun;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.7
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    • pp.675-681
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    • 2012
  • The char oxidation characteristics of ashless coal with a relatively low ash content and high heating value were experimentally investigated at several temperatures (from $900^{\circ}C$ to $1300^{\circ}C$), in various oxygen concentrations (from 10% to 30%) under atmospheric pressure in a drop tube furnace. The char reaction rate was calculated from the exhaust gas concentrations (CO, $CO_2$) measured by FT-IR, and the particle temperature was measured by the two-color method. In addition, the activation energy and pre-exponential factor of ashless coal char were also calculated based on the Arrhenius equation. The results show that higher temperature and oxygen concentration result in a higher reaction rate of ashless coal, and the activation energy of ashless coal char is similar to that of bituminous coal.

The moderating effect of 'Jung' in service recovery process (서비스 실패 후 회복과정에서 정(情)의 조절 역할)

  • Kim, Youn Hwan
    • Management & Information Systems Review
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    • v.33 no.3
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    • pp.59-76
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    • 2014
  • This research tries to present the role of Jung, which is well known as Koreans' traditional emotional attachment in service recovery process. Prior research on the service recovery have focused on relationship among perceived justice, recovery satisfaction and forgiveness. Especially perceived justice including distributive, procedural, and interactional justice has addressed as most important antecedents of recovery satisfaction. Although the pivotal role of emotional factors for successful service recovery has agreed by many researchers, relatively little attention has been paid to this issue. During the service recovery process, even if customer perceived recovery effort from service provider as justice one, they might feel displeasure or dissatisfaction. It means prior researches have underestimated the importance of emotional aspect, especially for Korean perspectives. In this study, we examined customer reactions to service failure and recovery process in restaurant service settings. Specifically, we focused on the moderating effect of 'Jung' on the paths between perceived justice and outcome variables such as forgiveness and recovery satisfaction.

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