• Title/Summary/Keyword: 접합류

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Qauntum Dot Sensitized Solar Cell Using Ag2S/CdS Co-sensitizer

  • Hwang, In-Seong;Yong, Gi-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.461.1-461.1
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    • 2014
  • 본 연구진에서는 기존에 Ag2S 양자점을 흡광층으로 활용하여 양자점 감응형 태양전지(QDSC)를 제작, 그 성능과 특징을 분석하여 발표한 바 있다. 기존 연구에서 제작된 Ag2S QDSC는 11 mA/cm2의 비교적 높은 광전류와 260 mV의 비교적 낮은 전압으로 인해 1.2%의 광전환효율 성능을 나타내는 것으로 보고되었다. 추후 연구로 진행된 본 결과에서는, 기존에 Single absorber로 사용된 Ag2S의 한계를 보완하기 위해 CdS를 도입하여 co-sensitization을 활용하였다. CdS는 약 2.3 eV의 밴드갭 에너지를 갖는 물질로, 1.1 eV의 밴드갭을 갖는 Ag2S에 비해 흡광 영역은 좁지만 그만큼 전자-정공 재결합을 억제할 수 있는 장점을 가지고 있다. 또한, 전도층으로 사용한 n-type 물질인 ZnO 나노선과의 밴드구조가 매우 적합하게 조화되어, ZnO/CdS/Ag2S 순서로 이종구조를 접합시켰을 때 세 물질의 Conduction band level과 Valence band level이 순차적으로 연결되는 cascade-shaped 밴드구조를 이루게 된다. 빛을 받아 Ag2S와 CdS에서 생성된 전자는 이 cascade 모양의 conduction band를 따라 순차적으로 ZnO로 잘 전달되게 되어, 효율 향상에 큰 도움을 주었다. 이런 장점들로 인해, CdS-Ag2S co-sensitized QDSC는 Ag2S QDSC에 비해 2배나 향상된 효율인 2.4%를 기록하였으며, 이는 IPCE spectrum 측정 등으로 근거가 뒷받침되었다.

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Developement of a PEFC electrodes under the high temperature and low humidified conditions (고온/저 가습 운전을 위한 고분자 전해질 연료전지용 전극 개발)

  • Ryu, Sung-Kwan;Choi, Young-Woo;Park, Jin-Soo;Yim, Sung-Dae;Yang, Tae-Hyun;Kim, Han-Sung;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.149-149
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    • 2009
  • Generally, Nafion ionomer is used in the polymer electrolyte fuel cell (PEFC) electrodes to achieve high power density. At the high temperature operation of PEFC, however, ionic conductivity of Nafion remarkably decreased due to the evaporation of water in Nafion polymer. Recently, many researchers have focused on using the Ionic Liquids(ILs) instead of water in Nafion polymer. ILs have intrinsic properties such as good electrochemical stability, high ionic conductivity, and non-flammability. Especially, ILs play a crucial role in proton conduction by the Grottuss mechanism and act as water in water-free Nafion polymer. However, it was found that the ILs was leached out of the polymer matrix easily. In this study, we prepared membrane electrode assemblies with various contents of ILs. The effect of ILs in the electrode of each designed was investigated by a cyclic voltammetry measurement and the cell performance obtained through a single cell test using H2/Air gases. Electrodes with different contents of ILs in catalyst layer were examined at high temperature and low humidified condition.

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Bending Die System Design for Metal Panel Processing (금속패널가공을 위한 벤딩 다이시스템 설계)

  • Kim, Woo-Ki;Kim, Seung-Kyeum;Choi, Kye-Kwang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.2
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    • pp.276-280
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    • 2008
  • The design technology to be developed in this study is technology related to the metal panel comer processing method of very high value-added, interior and exterior cladding material, in the architecture. This study is aimed at designing a Bending Die System that enables metal panel comer processing for the first time in Korea, by improving corrosion resistance (durability), weather resistance and elegances (design) for the connecting part of right angle cornering, where most serious problems occur in using metal steel plates of 2.5mm or thicker. This is used as a kind of metal ball and as architectural interior and exterior cladding material.

Fabrication of SMD Type PTC Thermistor with Multilayer Structure

  • Kim, Yong-Hyuk;Lee, Duck-Cuool
    • Journal of Sensor Science and Technology
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    • v.9 no.1
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    • pp.76-82
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    • 2000
  • PTC thermistors with multilayer structure were fabricated by internal electrode bonding technique in order to realize low resistance. MLPTC (Multilayer Positive Temperature Coefficient) possess various features, such as small size, low resistivity and large current. We describe the effect of additives on the PTC characteristics, voltage - current characteristics, temperature dependence of resistance and complex impedance spectra as a function of frequency range 100 Hz to 13MHz to determine grain boundary resistance. It was found that MLPTC thermistor has both highly nonlinear effects of temperature dependent resistance and voltage dependent current behaviors, which act as passive element with self-repair mechanisms. Decrease of room temperature resistance with increasing the number of layers was demonstrated to be a grain boundary effect. Switching characteristics of current were caused by heat capacity of PTC thermistor with multilayer structure. Switching times are lengthened by increasing the number of layers.

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Direct Bonding Characteristics of 2 inch 3C-SiC Wafers for MEMS in Hash Environments (극한환경 MEMS용 2 inch 3C-SiC 기판의 직접접합 특성)

  • Chung, Yun-Sik;Ryu, Ji-Goo;Kim, Kyu-Hyun;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.387-390
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    • 2002
  • SiC direct bonding technology is very attractive for both SiCOI(SiC-on-insulator) electric devices and SiC-MEMS(micro electro mechanical system) fields because of its application possibility in harsh environments. This paper presents pre-bonding techniques with variation of HF pre-treatment conditions for 2 inch SiC wafer direct bonding using PECVD(plasma enhanced chemical vapor deposition) oxide. The PECVD oxide was characterized by XPS(X-ray photoelectron spectrometer) and AFM(atomic force microscopy). The characteristics of the bonded sample were measured under different bonding conditions of HF concentration and an applied pressure. The bonding strength was evaluated by the tensile strength method. The bonded interface was analyzed by using IR camera and SEM(scanning electron microscope). Components existed in the interlayer were analyzed by using FT-IR(fourier transform infrared spectroscopy). The bonding strength was varied with HF pre-treatment conditions before the pre-bonding in the range of $5.3 kgf/cm^2$ to $15.5 kgf/cm^2$

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High Current MIG Welding of Al 5083 Alloy under Ar/He Mixed Gas Shielding (Ar/He 보호가스분위기에서 Al 5083 합금의 대전류 MIG 용접특성)

  • Choi, Young-Bae;Hwang, In-Sung;Kang, Mun-Jin;Kim, Dong-Cheol
    • Journal of Welding and Joining
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    • v.32 no.1
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    • pp.87-92
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    • 2014
  • Recently, use of thick Al 5083 plate has increased in production of LNG storage tank. In general, multi-pass welding has been used to achieve sufficient penetration in thick plate welding. High current welding which enables high deposition and deep penetration is preferred in thick plate welding because the increase of number of pass increases manufacturing cost and formation of weld defect. In this study, welding characteristics according to various Ar/He shielding gas composition was investigated in high current MIG welding. The bead-on-plate welding and V groove welding were conducted on Al 5083 alloy with a thickness of .25 mm. The effect of shielding gas composition on bead shape was evaluated and proper shielding gas composition was proposed. Also arc stability was examined under selected shielding gas composition. One side-one pass welding experiments were conducted for V groove specimen with a thickness of 25 mm. Mechanical properties and hardness profiles were measured for the V groove specimens.

Improvement of superconducting joint between NbTi filamentary wires (NbTi 초전도 선의 접합 조건 변화에 따른 임계전류 특성 향상 연구)

  • Ha, D.W.;Shim, K.D.;Jang, H.M.;Ha, H.S.;Oh, S.S.;Kwon, Y.K.;Ryu, K.S.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1521-1523
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    • 2000
  • NbTi/Cu superconducting wires were jointed inserting the NbTi filaments into Cu/NbTi sleeve and pressing it. When the NbTi filaments were inserted into Cu/NbTi sleeve additional NbTi filaments were inserted together to increase the numbers of filaments in the hole of sleeve. The thickness of sleeves and dimples were changed to get optimal factor for high Ic of joint Critical current of the joint with additional NbTi Filaments and 17mm thickness of dimple was 450 A at 4.2K, 0.5T.

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Manufacture of Bending die System for the Manufacturing of Metal Panel Coner (금속패널코너가공을 위한 벤딩 다이시스템 제작)

  • Kim, Woo-Ki;Kim, Seung-Kyeum;Choi, Kye-Kwang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1518-1522
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    • 2008
  • The design technology to be developed in this study is technology related to the metal panel corner processing method of very high value-added, interior and exterior cladding material, in the architecture. This study is aimed at designing a Bending Die System that enables metal panel corner processing for the first time in Korea, by improving corrosion resistance (durability), weather resistance and elegances (design) for the connecting part of right angle cornering, where most serious problems occur in using metal steel plates of 2.5mm or thicker. This is used as a kind of metal ball and as architectural interior and exterior cladding material.

Optimization of Fuzzy Controller for Constant Current of Inverter DC Resistance Spot Welding Using Genetic Algorithm (유전알고리즘을 이용한 인버터 DC 저항점용접에서의 정전류퍼지제어기 최적화)

  • Yu, Ji-Young;Yun, Sang-Man;Rhee, Se-Hun
    • Journal of Welding and Joining
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    • v.28 no.5
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    • pp.99-105
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    • 2010
  • Inverter DC resistance spot welding process has been very widely used for joining such as automotive body sheet metal. Because the lobe area of DC welding is larger than AC welding and DC welding has low electrode wear. So the use of Inverter DC resistance spot welding process has been further increased. And the application of high tensile steel is growing for light weight vehicle. To improve the weldability of high strength steel, the development of Inverter DC resistance spot welding system is more conducted. However, Inverter DC resistance spot welding system has a few problems. Current waveform is unstable and the expulsion has been occurred by characteristics of steel. In this study, inverter DC resistance spot welding system was made. And Fuzzy control algorithm was applied for constant current. The genetic algorithm was applied to optimize the fuzzy scaling factors, in order to optimize the fuzzy control.

Results of Surgical Management in Patients with Cardiac and Arterial Manifestations of Behcet's Syndrome (심장 및 동맥계를 침범한 베체트씨 증후군 환자의 수술 후 결과)

  • 원종윤;장병철;이도연;박상준
    • Journal of Chest Surgery
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    • v.35 no.1
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    • pp.36-42
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    • 2002
  • Background: To evaluate the efficiency of surgical treatment in patients with cardiac valvular and arterial involvement of Behcet's syndrome. Material and Method: 12 patients underwent surgical treatment due to the valvular heart diseases and the various arterial diseases associated with Behest's syndrome over 7 years; 6 with valvular heart disease, 1 with annuloaortic ectasia, 1 with ascending aortic aneurysm, 4 with pseudoaneurysms in abdominal aorta(n=2), carotid artery(n=1), and popliteal artery(n=1). All 12 patients had received valvular replacement(n=6) and the artificial(n=5) or autologous(n=1) graft interposition. We followed the results of these surgical treatments. Result: Operations were technically successful in all 12 patients and peri-operative complication was not demonstrated. However, 10 patients had recurrences; 6 with valvular dehiscence, 3 with pseudoaneurysm at anastostomosis site, and 1 with aorto-duodenal fistula. The duration of recurrence was 1 to 55 months(mean: 15.7$\pm$ 16.2 months). 7 patients underwent the second operation and among them, 4 patients showed repeated recurrences. Overall, 5 patients died 2 to 25 months after the operation(mean: 13.6 months), because of the bleeding at the anastomosis site Five patients did not present recurrence after the first(n=2) or the second operation(n=3) and their follow up duration was 5 to 60 months(mean: 45.8$\pm$41.7 months). Five patients received immune-suppressive therapy after the first(n=2) and second operation(n=3). Three did not shown recurrence for the 13, 29 and 33 months. Conclusion: Post-operative prognosis of arterial manifestation of Behcet's syndrome was not encouraging and if possible, other treatment strategy should be considered.