• Title/Summary/Keyword: 점도변화

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Effect of Propionic Acid Additive on Preparation of Phase Inversion Polysulfone Membrane (폴리설폰 상전환막의 제조에 있어 프로피오닉산 첨가제의 영향)

  • Han, Myeong-Jin;Choi, Seung-Rag;Park, So-Jin;Seo, Bum-Kyoung;Lee, Kune-Woo;Nam, Suk-Tae
    • Membrane Journal
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    • v.18 no.4
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    • pp.317-324
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    • 2008
  • Polysulfone membranes were prepared via the phase inversion process. With propionic acid as a nonsolvent additive, polysulfone casting solutions were solidified in an isopropanol bath. Propionic acid (PA) worked as a thermodynamic enhancer for phase separation and as a rheological suppressor for kinetic hindrance. Morphology of the prepared membranes significantly varied with propionic acid content in the casting solution. The dense skin layer, which was identified in the membrane prepared without PA, almost disappeared in the membrane prepared trom PA 10wt%. With 30wt% PA, the membrane revealed the morphological gradient from a nodular skin structure to a sponge-like substructure, including the finger-like cavity. Water permeability increased with PA content, and polyethylene glycol rejection decreased with the nonsolvent content.

Characteristics of Water-Based Magnetic Fluid Using Saturated Fatty Acids (포화지방산에 의한 수상자성유체의 분산특성)

  • Kim, Mahn;Oh, Jae-Hyun;Lee, Woo-Young
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.241-246
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    • 1993
  • The water-based magentic fluids were successfully prepared with the synthesized ultrafine magnetite using saturated with fatty acids($C_{9}~C_{18}$) and SDBS as surfactants. The dispersion index of water-based fluids was about 85 % when the amounts of lauric acid and SDBS for the 27 g of magnetite were more than $2.66{\times}10^{-2}mol$ and 5 g($7.17{\times}10^{-2}mol$) respectively. As the solid content increased from 0.05 g/cc to 0.4 g/cc, saturated magnetization of magnetic fluids at 5 kOe increased from 2.07 emu/g to 9.31 emu/g and its viscosity increased from 1.20 cp to 3.95 cp. The stable pH region in which the magnetic fluids prepared with lauric acid and SDBS was range of 3.1 to 11.1. It was found that the water-based magnetic fluids was well dispersed as the carbon length of fatty acid increased, but the amount of scum of the magnetic fluids increased.

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Change of Physicochemical Characteristics of Persimmon Vinegar by Vacuum Concentration (진공농축에 따른 감식초의 이화학적 특성 변화)

  • Lee, Boo-Yong;Yuk, Jin-Su
    • Korean Journal of Food Science and Technology
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    • v.31 no.4
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    • pp.1132-1136
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    • 1999
  • This study was performed to offer fundamental data for concentration of persimmon vinegar. The $5.4^{\circ}Bx$ raw persimmon vinegar was concentrated to $20^{\circ}Bx$, $30^{\circ}Bx$, $40^{\circ}Bx$, $50^{\circ}Bx$, $60^{\circ}Bx$ and $70^{\circ}Bx$ concentration by vacuum concentration at $55^{\circ}C$ and diluted to $5.4^{\circ}Bx$ solution with distilled water. The physicochemical properties such as color, viscosity, pH, acidity, organic acid content and free sugar content of various persimmon vinegar concentrates were examined. The recovery yield of water soluble solid to concentrates was 55.5% on $20^{\circ}Bx$ vacuum concentration. Color of $5.4^{\circ}Bx$ persimmon vinegar diluents from concentrates became more dark brown by vacuum concentration. Flow behavior of persimmon vinegar concentrates was pseudoplastic. As the concentration of persimmon vinegar concentrates increased, pH of $5.4^{\circ}Bx$ diluents increased and acidity as acetic acid decreased compared to original raw vinegar. Acetic acid, lactic acid and citric acid were detected, malic acid and oxalic acid were not detected in persimmon vinegar concentrate. Fructose and sucrose only were detected in persimmon vinegar concentrate.

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Place-based Policy and Urban Poverty: An Analysis of Employment Mismatch and Placeness of Regional Labor Market (장소기반 정책과 도시빈곤: 일자리 미스매치와 지역노동시장의 장소성 분석)

  • Lee, Wonho
    • Journal of the Korean Geographical Society
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    • v.51 no.1
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    • pp.41-56
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    • 2016
  • This study investigates the employment and spatial mismatch as a significant acting factor of deepening urban poverty and analyses the placeness of regional labor market that the more efficient place-based labor market intervention needs to take into account. The change of unemployment rate as a regional labor market outcome in metropolitan cities is determined by the dynamic interaction between disequilibrium of labor supply and demand and employment mismatch according to various labor market conditions and its process is certainly differentiated across the metropolitan regional labor markets. In addition, it is analyzed that during the employment suburbanization the spatial mismatch puts differentiated impacts on different labor groups through human capital requirements and industry-selective job opportunities. As a result, because this whole process works with its unique process within individual regional labor markets, in order to link between urban poverty and employment mismatch and to promote problem-solving labor market intervention, we need to develop place-based policy based on the placeness of regional labor marekt.

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Effect of Viscosity and Clogging on Grout Penetration Characteristics (점도 변화와 폐색 현상을 고려한 그라우트재의 침투 특성)

  • Kim, Jong-Sun;Choi, Yong-Ki;Park, Jong-Ho;Woo, Sang-Baik;Lee, In-Mo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.414-423
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    • 2006
  • Many construction projects adopt grouting technology to prevent the leakage of groundwater or to improve the shear strength of the ground. Recognition as a feasible field procedure dates back to 1925, Since then, developments and field use have increased rapidly. According to improvement of grout materials, theoretical study on grout penetration characteristics is demanded. Fluid of grout always tends to flow from higher hydraulic potential to lower and the motion of grout is also a function of formation permeability. Viscosity of grout is changed by chemical action while grout moves through pores. Due to the increment of viscosity, permeability is decreased. Permeability is also reduced by grout particle deposits to the soil aggregates. In this thesis, characteristics of new cement grout material that is developed recently is studied: injectable volume of new grout material is tested in two different sizes of sands, and the method to calculate injectable volume of grout is suggested with consideration of change in viscosity and clogging phenomena. The calculated values are compared with injection test results. Viscosity of new grout material is found to be an exponential function of time. And lumped parameter $\theta$ of new grout material to be used for assessing deposition characteristics is estimated by comparing deposit theory with injection test results considering different soil types and different injection pressure.

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Synthesis of Silica Aerogel and Thin Film Coating at Ambient (상입하에서의 실리카 에어로겔의 합성 및 박막코팅(I))

  • 양희선;최세영
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.188-194
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    • 1997
  • Wet gel with surface modification by TMCS was redispersed in EtOH and redispersed silica sol for coat-ing was prepared. After spin coating of redispersed sol was conducted on silicon substrate, processes of drying(8$0^{\circ}C$) and heat treatment(>25$0^{\circ}C$) were, followed at ambient pressure. The influence of heat treat-ment of properties of film was observed, changing temperature at heat treatment. The optimum redisp-ersion condition for stable silica sol was wet gel:EtOH=1g:110$m\ell$ and the concentration and viscosity of redispersed silica sol with average particle size of 30nm were 0.11 M, 2.0-2.2 cP respectively. Crack-free thin film with the refractive index of 1.14 and thickness of 400 nm was obtained through drying at 8$0^{\circ}C$ and subsequent heat treatment at 45$0^{\circ}C$ for 2 hrs respectively after spin coating of 1500rpm, 10 times.

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Seasonal Variation in Species Composition of Demersal Fish in the Coastal Water off Uljin and Hupo in the East Sea of Korea in 2002 (2002년 동해 울진과 후포 연안 저어류 종조성의 계절 변동)

  • Lee, Tae-Won
    • Korean Journal of Ichthyology
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    • v.23 no.3
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    • pp.187-197
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    • 2011
  • Fish species composition and size frequency distribution of major species were analyzed using seasonal samples collected by an otter trawl in the coastal water off Uljin and Hupo in 2002. Fish collected during the study were 20 species, 1,927 individuals and 53,969 g off Uljin, and 23 species, 2,762 individuals and 146,550 g off Hupo. Liparis tessellatus, Glyptocephalus stelleri and Cleisthenes pinetorum were predominated in abundance, and these 3 species were accounted for 70.9% in the number of individuals and 83.8% in biomass off Uljin, and 90.3% and 70.9% off Hupo, respectively. In the Korean coastal water of the East Sea, the migrating pelagic fish were predominated in catch by set net or gill net, and species composition varied greatly by season. Meanwhile, the fish collected by an otter trawl in the coastal water off Uljin and Hupo were dominated by the resident demersal fishes and did not show any clear seasonal trend in species composition. Collected G. stelleri and C. pinetorum were mainly composed of young fish, and size data as depth indicated that they moved into deeper shelf as they grew.

BLOOD VISCOSITY CHANGE IN ORAL SQUAMOUS CELL CARCINOMA XENOTRANSPLANTED NUDE MICE (구강편평세포암종 이식 누드마우스에서의 혈액 점도 변화)

  • Myoung, Hoon;Lee, Jong-Ho;Choung, Pill-Hoon;Kim, Myung-Jin
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.30 no.2
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    • pp.81-84
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    • 2004
  • It is well known that malignant tumor have hypoxic cell fraction, which is radio resistant and is one of the most important cause of local recurrence after radiotherapy. One of the causes of hypoxia in tumor is blood flow decrease due to increase in blood flow resistance and one of the causes of increased blood flow resistance could be attributed to the increase in blood viscosity. For the evaluation of the change of blood viscosity in oral cancer, experiments were carried out to test the change of blood viscosity among the normal control and xenografted oral cancer nude mice. Relative viscosity measured against distilled water was $3.30{\pm}0.14$ for normal control, and $3.67{\pm}0.62$ for tumor bearing mice at the first time of blood sampling in experimental period ($100mm^3$ $200mm^3$). There was no statistically significant difference between the control group and experimental group (p>0.05). However, as the tumor grew, significant difference of blood viscosity was detected at the third time of blood sampling (control group:$3.37{\pm}0.59$, and experimental group: $4.31{\pm}0.41\;300mm^3$

Diffusion Coefficient of Ag(I) ion in the Concentrated Nitric Acid Solution (고농도 질산용액에서 Ag(I) 이온의 확산계수 측정)

  • Park Sang Yoon;Choi Wang Kyu;Lee Kune Woo;Moon Jei Kwon;Oh Won Zin
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.93-97
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    • 1999
  • From the anodic peak currents of cyclic voltammograms for Ag(I)/Ag(II) couple obtained with the variation of nitric acid concentration, Ag(I) concentration and solution temperature at a Pt electrode in concentrated nitric acid solutions, the diffusion coefficients of Ag(I) ion were evaluated to estimate the limiting current density of Ag(II)-mediated electrochemical oxidation (MEO) process, which has been effectively used for the complete destruction of hazardous organic materials. The results showed that, due to the water decomposition reaction which occurred simultaneously with the Ag(I) ion oxidation, background subtractions for the cyclic voltammograms were required to estimate the correct peak currents. The empirical relationship for the diffusion coefficient of Ag(I) was suggested as a function of solution viscosity and temperature.

Effects of Cereal Powders on Rheological Properties in Kochujang (곡류분말 처리가 고추장의 물성학적 특성에 미치는 영향)

  • An Yeong-Soon;Hong Yeong-Pyo;Kim Hyong-Yol;Lee Keun-Bo;Lee Mi-Sook
    • Food Science and Preservation
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    • v.12 no.2
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    • pp.151-155
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    • 2005
  • General problems on the quality in circulation process of Kochujang are fluidity, separated water at upper layer, and color change to dark-brown. Rice powders, glutinous rice powder and gelatinized rice powder, gelatinized glutinous rice powder were applied for solving such problems to Kochujang. Relationship between blending ratio of com syrup and fluidity had a linear correlation. Water separation in Kochujang was prevented by addition of gelatinized cereal powders, and gelatinized glufinous rice powder was most effective. Optimal amount of gelatinized glutinous rice powder was $0.5\~1.0\%$ (w/w).