• Title/Summary/Keyword: 점도변화

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사출성형 공정 캐비티 내 압력 측정과 CAE 해석을 활용한 점도 함수 추정

  • Jeon, Kang-Il;Lim, Seung-Hyun;Noh, Seung-Kyu;Kim, Dong-Hak
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.305-308
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    • 2010
  • 본 연구에서는 사출 성형에서 Cavity내의 압력을 측정하여 사출 성형기에서의 설정한 변수 즉, 사출 압력에 따라 Cavity내의 압력이 사출 공정동안 어떠한 추이를 나타내는지 관찰하였다. 이를 CAE 해석과 비교 분석하여 결과에 따른 점도 함수와의 관계를 알아보았다. 우선 Cavity의 압력을 측정하기 위하여 Cavity 내에 압력센서를 설치하고, 이를 시간에 따른 압력측정 결과를 보기 위하여 압력센서 시스템을 제작 하였다. 실제 사출성형하면서 Cavity 내 압력을 측정하고 CAE 해석 결과의 압력 변화와 비교한다. 이때 일반적으로 CAE 해석과 실험결과가 일치하지 않으므로 새로운 점도 곡선을 추정하여 CAE 소프트웨어 D/B(Data Base) 파일에 입력하여 다시 해석하고 실험 결과와 비교하여 압력변화가 일치할 때까지 반복해서 수행한다. 이때 점도는 Power Law로 가정하여 D/B 파일에서 K와 n값을 조절할 수 있고 일반적으로 n값은 Base Resin과 동일하므로 K값의 변화만을 고려하여 압력변화를 해석한다.

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Viscosity Change of Polysaccharide, Methylan by Acids Content (다당류 메틸란의 산 성분 함량에 따른 점도의 변화)

  • Kim, Sang-Yong;Kim, Jung-Hoe;Oh, Deok-Kun
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1151-1157
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    • 1997
  • The chemical identities of purified polysaccharide, methylan, were analyzed by various chemical methods. The polysaccharide contained 79%(w/w) sugar, 6% protein, and 16% organic acids such as uronic acid, pyruvic acid, and acetic acid. With proceeding fermentation, the acids content in methylan increased from 10% at 34 hr to 17% at 72 hr, and the viscosity of methylan in the same concentration also increased. The correlation between viscosity and acid content in methylan was studied using chemically or biologically modified methylan. Methylan with a high content of pyruvic acid exhibited a high apparent and an intrinsic ·viscosity. When the pyruvic acid content of methylan with the same content of uronic acid was increased 1%, apparent viscosity and intrinsic viscosity increased 290 cp and 6 dL/g, respectively. Methylan with a high content of uronic acid exhibited a high apparent and an intrinsic viscosity. When the uronic acid content of methylan with the same content of pyruvic acid was increased 1%, apparent viscosity and intrinsic viscosity increased 85 cp and 1.5 dL/g, respectively. It was found that the increased viscosity of methylan resulted from the increased content of organic acids in methylan, and pyruvic acid was more an important factor contributed to the increase of methylan viscosity than uronic acid.

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Preparation and Rheological Characterization of Coal-Water Mixture (석탄-물 혼합연료의 제조와 유변학적 특성화)

  • 김도현
    • The Korean Journal of Rheology
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    • v.10 no.3
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    • pp.131-136
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    • 1998
  • 아역청탄을 이용하여 제조된 CWM(Coal-Water Mixture)연료의 유변학적 특성을 측 정함으로써 음이온 계면활성제 Temol-N, 안정제 Xanthan 및 전해질 등의 첨가제에 대한 성능을 평가하고 최적첨가조성을 결정하였다. 계면확성제의 흡착으로 인해 석탄입자는 음전 하를 띠게 되었고 표면에 전기이중층이 생성되었다. 전기 이중층의 전기적 반발력이 입자의 응집을 막았고 CWA 슬러리의 점도를 감소시켰다. 또한 Xanthan과 NaOH의 첨가로 인해 분산안정성 및 침강안정성이 향상되는 것을 관찰하였다. CWM에서 석탄입자가 차지하는 부 피비를 무게비로 전환하여 표현하고 분산계에서 입자의 부피비에 따른 점도변화를 예측하는 실험식인 Krieger-Dougherty 식과 Frankel-Acrivos 식에 적용하였다. 점도 실험값을 가지 고 식의 변수들을 결정해 본결과 CWM이 나타내는 점도의 석탄함량에 따른 변화를 위 식 들이 비교적 정확시 나타내 주는 것을 확인하였다.

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Relationship between Physical and Chemical Properties of Frying Vegetable Oils (가열산화에 의한 대두유와 면실유의 물리화학적 특성변화와 상관관계)

  • 이근태;박성민;황영길;강옥주
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.4
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    • pp.654-659
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    • 1994
  • To elucidate the relationship between physical and chemical properties of frying vegetable oils, soybean oil and cottonseed oil were heated in air temperatures from $160^{\circ}C\;to\;220^{\circ}C$ for 60 hours. Acid value, carbonyl value, iodine value, viscosity and content of polymer were remarkably changed as higher heating temperature and/or longer heating time. Correlation coefficient of viscosity to acid value was 0.9843 for soybean oil and 0.9819 for cottonseed oil. In case of viscosity and carbonyl value, viscosity also showed good relationship to carbonyl value as 0.9779 for soybean oil and 0.9797 for cottonseed oil. And correlation coefficient of viscosity to iodine value of soybean oil was 0.9852 and cottonseed oil was 0.9948.

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Rheological, Stability and Antiwear Properties of Water-in-Oil Emulsion Hydraulic Fluids (Water-in-oil 에멀젼 압축유의 유동성, 안정성 및 내마모성에 관한 연구)

  • Shim, Joosup;Cho, Wonoh
    • Tribology and Lubricants
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    • v.12 no.2
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    • pp.48-54
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    • 1996
  • 제철산업과 광산산업에서 난연성 압축유로써 Water-in-oil(W/O) 에멀젼의 사용이 점차 증가하고 있다. 이러한 관점에서, 기유의 점도, 물과 오일의 배합비율 및 음이온성 emulsifier의 농도 변화에 따른 W/O 에멀젼의 점도, 안정성 및 내마모성을 조사하였다. 에멀젼의 점도는 기유의 점도에 비례해서 증가하였으며 물의 배합비율에 따라 지수함수적으로 증가하였다. 에멀젼의 안정성은 에멀젼 점도와 대수함수 관계임을 보여주고 있다. 에멀젼 점도와 다른 요소와의 상관관계를 매우 복잡하며 이러한 상관관계를 해결하기 위해서는 더 많은 연구가 진행되어야 한다. 에멀젼의 점도는 에멀져의 내마모성에 거의 영향이 없으며 기유의 점도에 따라 영향을 받으며 물의 배합비가 너무 커지게 되면 마모에 심각한 나쁜 결과를 초래하였다.

Flow Behavior of Polystyrene and Poly(butyl methacrylate) Composite Particles Filled with Varying Concentrations of Carbon Black (다양한 농도의 카본블랙을 함유하는 폴리스티렌 및 폴리뷰틸메타크릴레이트 복합체 입자의 유동성)

  • Park, Moon-Soo
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.336-342
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    • 2009
  • We measured shear viscosity of polystyrene (PS) and poly(butyl methacrylate) (PBMA) particles, with a capillary rheometer, prepared by suspension polymerization with 1.0 wt% hydrophobic silica as a stabilizer by varying the initiator concentration at $75^{\circ}C$. PS particles with weight average molecular weight of 66,500 g/mol displayed a Newtonian behaior at low shear rates at $190^{\circ}C$. With increasing molecular weight, PS particles showed shear thinning over the entire range of shear rates. For PBMA particles, steady shear measurement was carried out at $170^{\circ}C$. PBMA particles with weight average molecular weight of 156,700 g/mol showed a Newtonian behaior only at low shear rates. PBMA particles also showed shear thinning with an increase in molecular weight and its pattern similar to that of PS. When carbon black was incorporated into PS and PBMA polymers, steady shear measurement was conducted at $170^{\circ}C$. An increase in carbon black concentration in PS and PBMA composite particles exhibited a progressive increase in shear viscosity. The increase in shear viscosity, however, was less pronounced compared to an increase as a function of molecular weight. Preparing PS composites containing carbon black by internal mixing resulted in an increase in shear viscosity. Its increase, however, was found to be less than that shown in PS composite particles. We speculate that this is caused by an enhanced dispersion of carbon black particles with an internal mixer. Yield behavior was not observed in any of the samples we selected in this experiment.

Property and Polymerization of Hi-solid PSA's using Seeded Polymerization (Seed 중합을 이용한 고고형분 수용성 점착제의 합성과 물성)

  • Jung, Young Sik;Min, Seong-Kee;Seul, Soo Duk
    • Journal of Adhesion and Interface
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    • v.10 no.4
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    • pp.174-181
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    • 2009
  • The viscosity for hi-solid pressure sensitive adhesive to improve water soluble low viscosity pressure sensitive adhesive polymerized using seeded polymerization. While seed binder polymerizing it produces an optimum polymerization condition, and acrylic acid and seed binder concentration changed were measurement of viscosity variation and adhesive power at the substrate (SUS420J) as flowing results. In adhesive polymerization, seed binder concentration 7 wt%/monomer was recovered 60% of solid content, 2,100 cps of low viscosity and clear adhesive film. When acrylic acid content was 4 wt%/monomer, it was turned excellent adhesive power and holding power.

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The Study on Properties of NEPE System Propellant to Size of RDX (RDX 입도에 따른 NEPE계 추진제 특성 연구)

  • Jang, Myungwook;Kim, Taekyu;Han, Haeji;Yun, Jaeho;Son, Hyunil
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.972-977
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    • 2017
  • The propellant tile and crack which account for the greatest proportion of solid rockets are profoundly affected by viscosity and mechanical properties of solid propellant. In this paper solid propellant with nitrate ester polyester(NEPE) system has been researched for the viscosity, mechanical properties and burning properties with size and mixing ratio of RDX. the viscosity of propellant was changed significantly depending on the size of RDX and mixing ratio, and mechanical properties of NEPE system propellant were also varied. Considering both lower viscosity and stable mechanical properties, the optimum size and mixing ratio of RDX can be identified as the main factors to the NEPE system propellant.

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Effect of V2O3 and CaO Concentrations on the Viscosity of 5-Component Petcoke Slag (V2O3와 CaO의 농도에 따른 5-성분계 석유코크스 슬래그의 점도 변화)

  • Yang, Yoonjung;Oh, Myongsook S.
    • Applied Chemistry for Engineering
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    • v.31 no.6
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    • pp.688-696
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    • 2020
  • Petroleum coke (petcoke) is widely used, next to coal, as a gasification feedstock. In gasification processes, the viscosity of the ash and the formation of crystalline phases must be understood to ensure the continuous removal of slag. This study investigates the effect of CaO and V2O3 on petcoke slag viscosity. The viscosity of the molten slag was measured in the temperature range of 1100~1600 ℃ while varying the concentration of each component. The crystalline phases formed in a cooled slag were examined. The most slag samples tested in this study exhibited crystalline slag behavior. The increased CaO concentration resulted in a lower viscosity and a lower Tcv. The viscosity behavior changed from the glassy to crystalline slag and also showed a higher Tcv as the concentration of V2O3 increases. Most slag samples showed different crystalline phases from top to bottom. Anorthites and Ca-V phases were observed in the top and middle section, while the bottom section mainly showed V2O3 and anorthite. The vanadium in the ash forms Ca-V and V-Fe phases and also remains in molten slag. A low melting Ca-V phase can contribute to lowering the viscosity.

Effect of Fluid Viscosity on Centrifugal Pump Performance (유체의 점성이 원심펌프 성능에 미치는 영향)

  • Kim, Noh-Hyeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.6
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    • pp.599-605
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    • 2013
  • The characteristics of centrifugal pump performance according to fluid viscosity change were studied experimentally. A small volute pump with low specific speed was tested by changing the viscosity of an aqueous solution of sugar and glycerin, which is considered a Newtonian fluid. After finishing the test, the total head, shaft horsepower, and pump efficiency were compared with those of a water pump. The results are summarized as follows: (1) when the fluid viscosity is increased, the shut-off head shows very little change but the total head decreases gradually as the flow increases, and this makes the H-Q curve leaning rapidly, and (2) when the fluid viscosity is increased, the shaft horsepower shows very little change at the shutoff condition; however, the shaft horsepower increases more rapidly with an increase in the flow and viscosity.