• Title/Summary/Keyword: 전해 염소수

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Cleaning and Storage Effect of Electrolyzed Water Manufactured by Various Electrolytic Diaphragm (격막 방식에 따라 제조한 전해수의 세척 및 보관 효과)

  • 김명호;정진웅;조영제
    • Food Science and Preservation
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    • v.11 no.2
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    • pp.160-169
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    • 2004
  • This study was carried out to investigate the efficacy of electrolyzed water manufactured with or without diaphragm on sterilization and preservation of cut-celery and shelled raw oyster. In cut-celery, total viable cell count and coliform group in the treatment of electrolyzed water were decreased to about 1/200∼1/1,000 level and about 1/100 level comparing non-treated ones. But moisture content, pH, hardness, vitamin C and residual chlorine content were showed a little difference among treatments up to 10 days at 10$^{\circ}C$. L and a color values were gradually increased in all treatments, and color differences($\Delta$E) were remarkable between treatment and untreatment sample. In overall acceptability, cut-celery treated with electrolyzed water showed somewhat higher score than that of other ones treated with tap water and 100 ppm NaClO solution until 5 days of storage. After 48 hours of storage, it was showed that VBN, total viable cell count and coliform count of shelled raw oyster treated with electrolyzed alkali water produced by non-diaphragm system are lower by about 3 mg%, 1∼2 log cycle and 2 log cycle respectively than that of ones treated with sea water. Total viable cell count of shelled raw oyster just after treatment was lower by about 1 log cycle than that of ones treated with sea water, and any significant increment was not found after 24∼48 hours of storage.

Electrochemical Behavior of Tin and Silver during the Electrorecycling of Pb-free Solder (Sn-Ag-Cu) Waste (폐무연솔더(Sn-Ag-Cu)의 전해재활용 시 주석과 은의 전기화학적 거동 연구)

  • Kim, Min-seuk;Lee, Jae-chun;Kim, Rina;Chung, Kyeong-woo
    • Resources Recycling
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    • v.31 no.3
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    • pp.61-72
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    • 2022
  • We investigated the electrochemical behavior of Sn (93.0 %)-Ag (4.06 %)-Cu (0.89 %) during electrolysis of Pb-free solder waste to recover tin and silver. A thin strip of the solder waste produced by high-temperature melting and casting was used as a working electrode to perform electrochemical analysis. During anodic polarization, the current peak of an active region decreased with an increase in the concentration of sulfuric acid used as an electrolyte. This resulted in the electro-dissolution of the working electrode in the electrolyte (1.0 molL-1 sulfuric acid) for a constant current study. The study revealed that the thickening of an anode slime layer at the working surface continuously increased the electrode potential of the working electrode. At 10 mAcm-2, the dissolution reaction continued for 25 h. By contrast, at 50 mAcm-2, a sharp increase in the electrode potential stopped the dissolution in 2.5 h. During dissolution, silver enrichment in the anode slime reached 94.3% in the 1 molL-1 sulfuric acid electrolyte containing a 0.3 molL-1 chlorine ion, which was 12.7% higher than that without chlorine addition. Moreover, the chlorine enhanced the stability of the dissolved tin ions in the electrolyte as well as the current efficiency of tin electro-deposition at the counter electrode.

Leaching of copper from waste PCBs with electro-generated chlorine -Analysis of experimental factors on the leaching by the factorial design- (전해생성염소(電解生成鹽素)에 의한 폐인쇄회로기판(廢印刷回路基板)으로부터 구리 침출(浸出) -실험계획법(實驗計劃法) 적용(適用)에 의한 침출(浸出) 영향인자(影響因子)의 분석(分析)-)

  • Kim, Eun-Young;Lee, Jae-Chun;Kim, Min-Seuk;Jung, Jin-Ki;Yoo, Kyoung-Keun
    • Resources Recycling
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    • v.17 no.6
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    • pp.24-33
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    • 2008
  • The leaching of Cu from waste PCBs was investigated with electro-generated chlorine as an oxidant. The leaching experiments were carried out according to the design of experiments to analyze quantitatively the effect of parameters on copper leaching. From the analysis of variance (ANOVA) it was suggested that the effective parameters were current density, temperature, concentration of HCl, and the interaction between the concentration of HCl and temperature. Especially, the effect of current density was analyzed to contribute to the interpretation of result for copper leaching up to 95.7%. A multiple regression model obtained from the analysis of effective parameters explained 99% of leaching results. From the model equation, it was found that the effect of HCl concentration on copper leaching increased with temperature.

Effect of Surface Sterilization on Quality of Vacuum Packaged Fresh-cut Deodeok (Codonopsis lanceolata) during Storage (표면살균수 처리 후 진공포장된 신선편이 더덕의 저장 중 품질특성 변화)

  • Choi, Duck-Joo;Lee, Yun-Jung;Kim, Youn-Kyeong;Kim, Mun-Ho;Choi, So-Rye;Cha, Hwan-Soo;Park, Hyung-Woo;Youn, Aye-Ree
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.18 no.1_2
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    • pp.39-44
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    • 2012
  • This study investigated the changes in the quality of minimally processed sliced Deodeok (Codonopsis lanceolata) during storage at $7^{\circ}C$ in relation to vacuum packing using PE film after the various surface washing treatments. The surface washing treatments resulted in approximately 1~2 log CFU/g reduction of microbial load in the early storage day. After 20 days, the weight loss rate, deterioration rate, hardness, color, total microorganism levels and the coliform count of deodeok washed by ultrasonic wave water was deteriorated rapidly like the control. When measured by the fresh-cut deodeok surface using the video microscope system, washing with chlorine water and electrolyzed water didn't seem to make perceivable quality deterioration during the 10 days at $7^{\circ}C$. The hardness and color maintenance of the product vacuum packaged using PE film after washing with electrolyzed water, was better than that of other treatments.

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The PWM Control Which used Microprocessor for Intensity Control of Acid Ion Water (산성이온수 농도제어를 위한 Microprocessor를 이용한 PWM 제어)

  • Kwon, Yunjung;Nam, Sangyep
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.7
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    • pp.269-274
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    • 2013
  • We are used with the alkaline ion water which an application field does to object for drinking water compare with the alkaline ion water which asked ion acid electrolysis so as to be very different. This is used with sterilization disinfection use by residual chlorine in case of strong acidity according to ph intensity, and in case of middle acidity use by washing and face washing, and mix with meal materials in case of weak acidity widely usable in cooking. Acid ion water generates as we electrolyze water. Chlorine gas and sodium hydroxide etc. was generated at electrolysis process, and we have toward sterilizing power. Derelicts such as chlorine, phosphorus, sulfur etc. are gathered from a negative ion, and we make acid ion water to + electrode direction in electrolysis. We used a diaphragm in order to disconnect too acid water and alkaline water. We implemented so that the acid water which it came down to three kinds of PWM voltage to PWM (pulse width modulation) control, and implementation method of ph intensity change authorized ph intensity between weak acidity to electrode in strong acidity as we used Microprocessor, and intensity was adjusted successively by PWM control was generated.

Bactericidal Effects of Food-borne Bacteria using Chlorine Dioxide and Electrolyzed Water (이산화염소수와 전해수를 이용한 식중독균의 살균효과)

  • Lee, Hye-Rin;Kim, Su-Jin;Bang, Woo-Suk
    • Journal of Food Hygiene and Safety
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    • v.37 no.4
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    • pp.232-237
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    • 2022
  • The present study investigated the bactericidal effects of chlorine dioxide (CD) and electrolyzed water (EW) on pathogenic bacteria, such as Bacillus cereus, Staphylococcus aureus, Salmonella Typhimurium, and Escherichia coli O157:H7, by treatment them with CD and EW, respectively, for 0, 2, 4, 6, 8, and 10 min. Additionally, the sensitivities of Gram-positive (B. cereus and S. aureus) and Gram-negative (S. Typhimurium and E. coli O157:H7) to CD and EW were compared, respectively. In CD, the D-values for B. cereus, S. aureus, S. Typhimurium, and E. coli O157:H7 were 1.85±0.64, 2.06±0.85, 2.26±0.89, and 2.59±0.40 min, respectively. In EW, the D-values for B. cereus, S. aureus, S. Typhimurium, and E. coli O157:H7 were 2.13±0.32, 1.64±0.64, 1.71±0.32, and 1.86±0.36 min, respectively. All strains decreased consistently for 10 min in both CD and EW. However, the D-values of each bacterial species did not differ significantly between CD and EW (P>0.05). When comparing the bactericidal effect of CD and EW, no difference in D-value was observed, even though the pH and available chlorine concentration of CD were significantly lower than those of EW. These data could be used for the application of CD and EW in the food industry, considering characteristics such as the selection of optimal disinfectants, determination of optimal concentrations, and sensitivity to disinfection targets.

A Study on Control Disinfection By-products in High Sodium Hypochlorite Generation (고농도 차아염소산나트륨 발생장치의 소독부산물 제어에 관한 연구)

  • Cho, Haejin;Shin, Hyunsoo;Ko, Sungho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.3
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    • pp.183-189
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    • 2017
  • Sodium hypochlorite used in water disinfection processes is generally in the production of chlorine to 0.8%. As the dose of chlorine increases, disinfection by-products (Chlorate) also increase simultaneously and exceed water quality standards. In this study, the electrolytic cell of a sodium hypochlorite generator (12% chlorine) was adjusted to control the production of the disinfection by-products. As a result, it was possible to reduce Chlorate concentrations by more than 95% by adjusting the pH of the electrolytic cell from 1.53 to 4.2 (normal pH of the electrolytic cell). As a low current is required to obtain these results, a 15% improvement in the efficiency of the positive electrode is also observed. For the development of High Sodium Hypochlorite Generation can be used in a safe sodium hypochlorite solution, which is expected to contribute to improvement in the safety of the disinfection process.

Experimental study of NOx reduction in marine diesel engines by using wet-type exhaust gas cleaning system (선박용 디젤엔진의 NOx를 저감하기 위한 습식 배기가스 처리기술 적용에 관한 실험적 연구)

  • Ryu, Younghyun;Kim, Taewoo;Kim, Jungsik;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.216-221
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    • 2017
  • Diesel engines have the highest brake thermal efficiency among internal combustion engines. Therefore, they are utilized in medium and large transportation vehicles requiring large amounts of power such as heavy trucks, ships, power generation systems, etc. However, diesel engines have a disadvantage of generating large quantities of nitrogen oxides during the combustion process. Therefore, the authors tried to reduce the amount of nitrogen oxides in marine diesel engines using a wet-type exhaust gas cleaning system utilizing the undivided electrolyzed seawater method. In this method, electrolyzed seawater in injected into the harmful gas discharge from the diesel engine using real seawater. The authors investigated the reduction of NO and NOx from the pH value, available chlorine concentration, and the temperature of electrolyzed seawater. The results of this experiment indicated that when the electrolyzed seawater is acidic, the NO oxidation rate in the oxidation tower is higher than that when the electrolyzed seawater has a neutral pH. Likewise, the NO oxidation rate increased with the increase in concentration of chlorine. Further, it was confirmed that the electrolyzed seawater temperature had no effect on the NO oxidation rate. Thus, the NOx exhaust emission value produced by the diesel engine was reduced by means of electrolyzed seawater treatment.

Formation Mechanism of Chlorate ($ClO_3\;^-$) by Electrochemical Process (전기화학적 공정에 의한 클로레이트의 생성메커니즘)

  • Baek, Ko-Woon;Jung, Yeon-Jung;Kang, Joon-Wun;Oh, Byung-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.627-634
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    • 2009
  • This study was done to find out the formation mechanism of chlorate by electrochemical process using chloride ion ($Cl^-$) as an electrolyte. Firstly, the effective factors such as pH and initial chloride concentration were figured out to see the formation property of chlorate during electrolysis. And the relation of free chlorine, and mixed oxidants such as OH radical and ozone with chlorate were estimated to concretize the formation mechanism. As a result, it was found that the major reaction of chlorate formation would be electrochemical reaction with free chlorine, and also the direct oxidation of chloride ion and the reaction by OH radical were participated in the formation of chlorate. Moreover, it was observed that formed chlorate was oxidized to perchlorate. Lastly, the optimum condition was recommended by comparing free chlorine with chlorate concentration during the electrochemical process with the different electrode separation.