• Title/Summary/Keyword: 전해물

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A Hermenutic Study of Material Language in Contemporary Metal-craft - Centerd on June Schwarcz′s Color works - (현대금속공예에 있어서 물질언어의 해석학적 분석연구 -June Schwarcz′s 색채 구조물을 중심으로 -)

  • 임옥수
    • Archives of design research
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    • v.14 no.3
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    • pp.197-210
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    • 2001
  • There are symbolicity and special meaning in the materials which are supposed to be used metalcraft from ancient to present. These are basical resources of hermeneutics and play a role as moaning elements. Generally, the precious Cold and Silver are mainly to be used with precious stone. But recently, ordinary materials like glass iron aluminum has begun to be used with them. Several artists are intentionally using them, and special skills which could be revealed by only the matherials are developing by them. In these skill, there are original material's texture and character of matter are looking like other matter. Well, special skills are adapted in these matters to magnify the possibility of expression, the originally codified meaning resources are disturbed. For example, The metal craft artist June Schwarcz is using the skills of electroforming, copper foiling, enameling, wire brush patina, fine wires fusing, etc. He is doing abstract forming and making various textures. And his works are very big size, and done by the skills of painting and sculpture. The outer form is very structural, special touches of the artists are heterogeneously mixed with the symbolic abstract expressionism color field. Further, there are mixed with Primitive original life atmosphere, Medieval ornamental aspect, Minimal, and Chaotic aspects. The meaning particles of these aspects are directly/indirectly joined but special skills and basic material languages are mixed together, the originally codified material language are disturbed. These disturbed material languages are becoming optically special effect and be illusion. It is making expressing way of tile metalcraft more fertile and be infinite.

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A Study on the Perception and Awareness of Native Local Foods - Centering around Gimhae, Gyeongnam Province - (향토음식에 대한 의식 및 인지도에 관한 연구 - 경남 김해지역을 중심으로 -)

  • Park, Kyong-Tae
    • Culinary science and hospitality research
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    • v.17 no.2
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    • pp.98-110
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    • 2011
  • This study aims to furnish the basic data in securing momentum for taking interest in inheriting and developing the native local foods in Gimhae by examining the perception and awareness of the native local foods among the local residents in Gimhae, Gyeongnam Province. As the results of this study, the definition of native local foods was surveyed as follows. Foods that have been handed down for generations by using local agricultural products as their ingredients; a local food restaurant was the most preferred place to eat native local foods; the most chosen reason why they should eat native local foods was 'good for health'; as for the necessity of inheriting and developing the native local foods, most of them agreed, and it was because they felt they should protect their food culture; and 'native local foods contests' were the best way to promote the native local foods. As the results of analyzing the awareness of 12 kinds of native local foods in Gimhae, there were significant differences in Kongnamul-bab, Minmul Jangeo-gui, Gajuk-jaban, Kongip-mulkimchi by gender, in Hobakogari-namul, Moomallaengi-jangachi, Kongip-mulgimchi by ages, and in Kongnamul-bab, Gajuk-jaban, Kongip-mulgimchi by the residential districts. Accordingly, in order to inherit and develop the native local foods which are the precious cultural assets in Gimhae, there should be continued opportunities and interest to promote them through the local festivals and events along with publicity activities for the native local foods.

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Electrochemical Properties of Using MnO2-HCS Composite for Supercapacitor (MnO2-HCS 복합체를 이용한 슈퍼커패시터의 전기화학적 특성)

  • Jin, En Mei;Jeong, Sang Mun
    • Clean Technology
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    • v.24 no.3
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    • pp.183-189
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    • 2018
  • Hollow carbon spheres (HCS) and carbon spheres (CS) were prepared by a hydrothermal reaction and they were introduced as a substrate for the deposition of $MnO_2$ nanoparticles. The $MnO_2$ nanoparticles were deposited on the carbon surface by a chemical redox deposition method. After deposition, the $MnO_2$ nanoparticles were uniformally distributed on the carbon surface in a slit-shape, and sparse $MnO_2$ slits appeared on the HCS surface. The $MnO_2-HCS$ showed an initial specific capacitance of $164.1F\;g^{-1}$ at scan rate of $20mv\;s^{-1}$, and after 1,000 cycles, the specific capacitance was maintained to $141.3F\;g^{-1}$. The capacity retention of $MnO_2-HCS$ and $MnO_2-CS$ were calculated to 86% and 78% in the cycle performance test up to 1,000 cycles, respectively. $MnO_2-HCS$ showed a good cycle stability due to the mesoporous hollow structure which can cause a faster diffusion of the electrolyte and can easily adsorb and desorb $Na^+$ ions on the surface of the electrode.

Fabrication and Property Evaluation of Tubular Segmented-in-Series Solid Oxide Fuel Cell (SOFC) (세그먼트 관형 SOFC의 제작 및 특성 평가)

  • Yun, Ui-Jin;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul;Han, Kyoo-Seung
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.562-566
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    • 2012
  • A novel design of tubular segmented-in-series(SIS) solid oxide fuel cell (SOFC) sub module was presented in this paper. The tubular ceramic support was fabricated by the extrusion technique. The NiO-YSZ anode and the yttria-stabilized zirconia (YSZ) electrolyte were deposited onto the ceramic support by dip coating method. After sintering at $1350^{\circ}C$ for 5 h, a dense and crack-free YSZ film was successfully fabricated. Also, the multi-layered cathode composed of LSM-YSZ composite, LSM and LSCF were coated onto the sintered ceramic support by dip coating method and sintered at $1150^{\circ}C$. The performance of the tubular SIS SOFC cell and sub module electrically connected by the Ag-glass interconnect was measured and analysed with different fuel flow and operating temperature.

Effect of Pressure on Hydration Number of Some Ions (몇 가지 이온의 水和數에 대한 壓力의 效果)

  • Jung-Ui Hwang;Jong-Jae Chung;Hag-Sung Kim
    • Journal of the Korean Chemical Society
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    • v.36 no.6
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    • pp.791-795
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    • 1992
  • The limiting equivalent conductances of LiCl, NaCl, KCl and KBr have been obtained in water using conductometric method from 1 to 2000 bars at $25^{\circ}C$. From the limiting equivalent ionic conductances (obtained using TATB[Tetraphenyl Arsonium Tetraphenyl Borate]method) of $Li^+$, $Na^+$, $K^+$, $Cl^-$, and $Br^-$ ions and viscosity of water at given pressure, their Stokes radii have been calculated. From the corrected radii caliberated by Nightingale method and the crystallographic radii at a given pressure, the volume of hydration-shell surrounding ion was calculated and hydration numbers of $Li^+$, $Na^+$, $K^+$, $Cl^-$, and $Br^-$ ions were obtained. From the experimental results, it was found that the hydration number of $Li^+$, $Na^+$, $K^+$, $Cl^-$, and $Br^-$ ions slightly decreased with increasing pressure. This trend may be explained by Horne's suggestion[Advances in High Pressure Research]. Comparing results of this study with those of Nakahara's, the hydration numbers of $K^+$ and $Cl^-$ ions were almost twice as large as those of Nakahara's[Rev. Phys. Chem. Japan, 42, 12 (1972)]. By comparing the present results with those of Kollman's [J. Am. Chem. Soc., 113, 2481 (1991)], the hydration number obtained by applying TATB method and Nightingale method may be inferred to be reasonable.

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Synthesis of Tridentate-Schiff Base Co(II) Complexes and Their Electrochemical Properties (세자리 Schiff Base Co(Ⅱ) 착물의 합성과 전기화학적 성질)

  • Chae, Hui Nam;Choe, Yong Guk
    • Journal of the Korean Chemical Society
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    • v.42 no.4
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    • pp.422-431
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    • 1998
  • Tridentate Schiff base ligands such as $SIPH_2,\;SIPCH_2,\;HNIPH_2,\;and\; HNIPCH_2$ were prepared by the reaction of salicylaldehyde and 2-hydroxy-l-naphthaldehyde with 2-aminophenol and 2-amino-p-cresol. The structures and properties of ligands and their Co(II) complexes were investigated by elemental analysis, $^1H$NMR, IR, UV-visible spectra, and thermogravimetric analysis. The molar ratio of Schiff base to the metal of complexes was found to be 1:1. Co(II) complexes were contemplated to be hexa-coordinated octahedral configuration containing three water molecules. The redox process of ligands and complexes in DMSO solution containing 0.1 M TBAP as a supporting electrolyte were investigated by cyclic voltammetry with glassy carbon electrode. The redox process of the tridentate Schiff base ligands was totally irreversible. The redox process of Co(II) complexes were irreversible and one electron processes by two steps in diffusion controlled reaction. The reduction potential of the Co(II) complexes was shifted to the positive direction in the order [Co(Ⅱ)$(HNIPC)(H_2O)_3$]>[Co(Ⅱ)$(HNIP)(H_2O)_3$]>[Co(II)$(SIPC)(H_2O)_3$]>[Co(Ⅱ)$(SIP)(H_2O)_3], and their dependence on ligands were not so high.

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Marine Blue-green Algae in Korea (II) (한국 해산 남조류 (II))

  • Yu, Sun-Ae;Chae, Seung-Mun;Lee, Gi-Wan
    • The Journal of Natural Sciences
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    • v.6 no.1
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    • pp.5-39
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    • 1993
  • The Blue-green algae collected from whole coasts of Korea were investigated morphotaxonomically in order to list up Korean marine Cyanophyta and clarify their taxnomic position. As a result, 36 species, 20 genus, 6 families belonging to 3 orders were identified. Among these, 14 species were recorded for the first time in Korea. They are Chroococcus minutus (K$\"{u}$tzing) N$\"{a}$geli, Merismopedia punctata Meyen, Microcystis ichtyoblabe K$\"{u}$zing, Dermocarpa leibleiniae (Reinsch) Born. et Thur., Hydrocoleum confluens (Setchell et Gardner) Drouet, Lyngbya sordida (Zanard.) Gomont, Phormidium forveolarum (Mont.) Gomont, Phormidium hansgieri Schmidle, Skujaella hildebrandtii (Gomont.) de Toni, Sphaeronema lithophila (Ercegovic) Umezaki, Spirulina tenerrima K$\"{u}$tzing, Hormothamnion enteromorphoides Grunow, Michrochaete aeruginea Batters, Michrochaete grisea Thuret ex Born. et flah.. Using the phase contrast microscope and the Nomarski interference micrope, we made photomicrographs of minute blue green algae. The cellular inclusions especially PHB(poly-$\SS$-hydroxy-butyrate) granules of the blue-green algae identified were investigated. The species clearly characteriged to have PHB granule were Lyngbya confervoides, L. semiplena, Phormidium corium, Sirocoleum kurzii, Hormothamnion enteromorphoides and Calothrix crustacea. These result would be fundamental data for estabilishing phylogenetic system of blue-green algae based on physio-biochemical characteristics in future.

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Effect of $H_O_2$ on the Corrosion Behavior of 304L Stainless Steel ($H_O_2$ 가 304L 스텐리스강의 부식거동에 미치는 영향)

  • Song, Taek-Ho;Kim, In-Sup;Park, Sung-Ki
    • Nuclear Engineering and Technology
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    • v.27 no.4
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    • pp.453-462
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    • 1995
  • In connection with the safe storage of high level nuclear waste, effect of $H_2O$$_2$ on the corrosion behavior of 304L stainless steel was examined. Open circuit potentials and polarization curves were measured with and without $H_2O$$_2$. The experimental results show that $H_2O$$_2$ increased corrosion potential and decreased pitting potential. The passive range, therefore, decreased as $H_2O$$_2$ concentration increased, indicating that pitting resistance was decreased by the existence of $H_2O$$_2$ in the electrolyte. These effect of $H_2O$$_2$ on corrosion of 304L stainless steel are considered to be similar to those of ${\gamma}$-irradiation. To compare the effects of $H_2O$$_2$ with those of $O_2$, cathodic and anodic polarization curves ore made in three types of electrolyte such as aerated, deaerated, and stirred electrolyte. The experimental results show that the effects of $H_2O$$_2$ on the corrosion behavior were tory similar to those of $O_2$ such as increase of corrosion potential, decrease of pitting resistance, and increase of repassivation potential. In acid and alkaline media, the corrosion potential shifts by $H_2O$$_2$ were restricted by the large current density of proton reduction and by the le Chatelier's principle respectively.y.

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Studies on the Determination Method of Hydrogen Peroxide in Foods (식품 중 과산화수소의 분석법에 관한 연구)

  • Lee, Tal-Soo;Lee, Young-Ja;Park, Jae-Seok;Kwon, Yong-Kwan;Hwang, Jung-Yeon;Lee, Ju-Yeun;Lee, Chul-Won
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.998-1001
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    • 2002
  • Micro-LC method for the quantitative determination of hydrogen peroxide in foods has been established. This method was carried out on cation-exchange resin gel column using distilled water as mobile phase with 50 mM sodium sulfate as electrolyte. The detection was performed with an electrochemical detector (ECD) at 0.6 voltage. Under this analytical condition, the recovery rates of hydrogen peroxide in tomato and lemon were 98.3 and 97.4%, respectively. Among 28 food types, hydrogen peroxide concentrations were 0.6, 0.5, 1.9, 0.9, 0.5, 0.6, 0.9, 0.8, and 0.4 ppm in banana, peach, orange, strawberry, pepper, onion, cucumber, burdock, and egg plant, respectively, Whereas none was detected in remaing 19 samples.

Development of Anion Exchange Membrane based on Crosslinked Poly(2,6-dimethyl-1,4-phenylene oxide) for Alkaline Fuel Cell Application (화학적 가교를 이용한 Poly(2,6-dimethyl-1,4-phenylene oxde)계 음이온 교환막의 제조 및 알칼리 연료전지용 특성평가)

  • Sung, Seounghwa;Lee, Boryeon;Choi, Ook;Kim, Tae-Hyun
    • Membrane Journal
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    • v.29 no.3
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    • pp.173-182
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    • 2019
  • Much research has been made for finding new and eco-friendly alternative sources of energy to solve the problems related with the pollution caused by emissions of greenhouse gases such as carbon dioxide as the use of fossil fuels increases worldwide. Among them, fuel cells draws particular interests as an eco-friendly energy generator because only water is obtained as a by-product. Anion exchange membrane-based alkaline fuel cell (AEMFC) that uses anion exchange membrane as an electrolyte is of increased interest recently because of its advantages in using low-cost metal catalyst unlike the PEMFC (potton exchange membrane fuel cell) due to the high-catalyst activity in alkaline conditions. The main properties required as an anion exchange membrane are high hydroxide conductivity and chemical stability at high pH. Recently we reported a chemically crosslinked poly(2-dimethyl-1,4-phenylene oxide) (PPO) by reacting PPO with N,N,N',N'-tetramethyl-1,6-hexanediamine as novel anion exchange membranes. In the current work, we further developed the same crosslinked polymer but having enhanced physicochemical properties, including higher conductivity, increased mechanical and dimensional stabilities by using the PPO with a higher molecular weight and also by increasing the crosslinking density. The obtained polymer membrane also showed a good cell performance.