• Title/Summary/Keyword: 전지구

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Electrochemical Properties of $Li_xV_3O_8$ Composite Cathode for All-solid state Rechargeable Battery (고체전지용 $Li_xV_3O_8$ Composite 정극의 전기화학적 특성)

  • 김종욱;성창호;구할본;박복기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.733-738
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    • 1998
  • 본 논문에서는 고체 리듐 전지를 개발하기 위하여 poly(ethylene oxide) [PEO] 에 $LiClO_4$, poly (vinylidene fluoride) [PVDF] 및 가소제로 propylene carbonate [PC] 와 ethylene carbonate[EC] 등을 혼합여 고분자 저해질을 제조하였다. 또한 고체 리듐 전지용 정극으로써 우수한 특성이 기대되는 $Li_xV_3O_8$을 졸-겔법에 의해 합성하여 $Li_xV_3O_8$SPE/Li cell 의 전기화학적 특성을 측정하였다. 고분자 matrix는 PEO와 PVDE를 혼합 사용한 결과 $PEO_4 PVDF_4LiCIO_4PC_5EC_5$ 고분자 전해질이 상온에서 $5.2 {\times} 10{-3}$ S/cm 의 높은 이온 전도도를 나타냈으며 리듐 이온 transference number는 0.3이었다. 졸-겔법에 의해 제조된 $Li_xV_3O_8$을 사용한 $Li_xV_3O_8$SPE/Li cell의 방전시 cell 저항이 방전 초기에는 비소한 증가를 하다가 방전 말기 전압인 2.0V에서 크게 증가하였다. $Li_xV_3O_8$ composite 정극의 첫 번째 방전 용량은 295㎃h/g이었으며 8번째 충방전 싸이클부터 방전 용량이 안정화 되었고 15번째 방전 용량도 212㎃h/g으로 고체 전지용 정극으로써 우수한 특성을 보였다.

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Spatial prioritization of permeable pavement considering multiple general circulation models: Mokgamcheon watershed (다수의 전지구모형을 고려한 투수성 포장시설의 우선지역 선정: 목감천 유역)

  • Song, Younghoon;Chung, Eun-Sung
    • Journal of Korea Water Resources Association
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    • v.52 no.12
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    • pp.1011-1023
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    • 2019
  • Rapid urbanization increases the risk of hydrologic disasters due to the increase of impervious areas in urban areas. Precipitation characteristics can be transformed due to the rise of global temperatures. Thus urban areas with the increased impervious areas are more exposed to hydrological disasters than ever before. Therefore, low impact development practices have been widely installed to rehabilitate the distorted hydrologic cycle in the urban area. This study used the Stormwater Management Model to analyze the water quantity and quality of the Mokgamcheon which had been severely urbanized, considering future climate scenarios presented by various general circulation models (GCMs). In addition the effectiveness of permeable pavement by 27 sub-watersheds was simulated in terms of water quantity and quality considering various GCMs and then the priorities of sub-watersheds were derived using an alternative valuation index which uses the pressure-state-response framework.

Effects of Full-Fat Soybeans and Linseed as Dietary Fat Sources on In Vitro Ruminal Disappearances of Dry Matter and C18-Unsaturated Fatty Acids and Fatty Acids Profile (지방원으로 전지대두와 아마종실의 첨가가 반추위내 건물과 C18계-불포화지방산의 조성과 소실율에 미치는 영향)

  • Lee, S.H.;Choi, N.J.;Maeng, W.J.
    • Journal of Animal Science and Technology
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    • v.45 no.3
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    • pp.443-454
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    • 2003
  • This study was conducted to investigate the effects of dietary full-fat soybeans and linseed as fat sources on in vitro ruminal disappearances of dry matter and unsaturated fatty acids and fatty acids profile. The full-fat soybeans and linseed were high in linoleic acid (C18:2n-6) and $\alpha$-linolenic acid (C18:3n-3), respectively. The incubation times were 0, 3, 6, 12, 24, 48 and 72 h. After each time of incubation, medium digesta was lyophilized for analyzing its DM and fatty acids contents. DM disappearance was significantly higher in linseed treatment compared to full-fat soybeans treatment on 6 h (p<0.01), 12 h (p<0.05) and 24 h (p<0.01), but cumulative gas production was not significantly different between both treatments. Stearic acid (C18:0) content in medium digesta was increased in both soybeans and linseed as a result of complete biohydrogenation with increased incubation time and C18:0 and C18:1 contents of full-fat soybeans were significantly higher than those of linseed (p<0.05). The content of C18:2 and C18:3 in digesta of each treatment were decreased by biohydrogenation as incubation time was increased. The content of C18:2 in full-fat soybeans was significantly higher than that of linseed (p<0.05) while the content of C18:3 in linseed was significantly higher than that of full-fat soybeans (p<0.001). Net C18:0 production was significantly higher in full-fat soybeans (332.24%) than linseed (133.16%) on 72 h. Disappearance of C18:1 was significantly lower in full-fat soybeans than linseed (p<0.05), especially full-fat soybeans showed negative (-) values on 3, 6, 12 and 24 h. The disappearance of C18:3 was significantly higher in linseed than full-fat soybeans (p<0.05). The disappearance of C18-unsaturated fatty acid was significantly higher in linseed than full-fat soybeans. In conclusion, polyunsaturated fatty acid (PUFA) in both full-fat soybeans and linseed were extensively biohydrogenated. In addition, biohydrogenation of PUFA was more completed to C18:0 in full-fat soybeans than linseed, reflecting dietary PUFA composition.

Intercomparison of the Global Ocean Reanalysis Data (전지구 해양 재분석 자료 비교 분석)

  • Chang, You-Soon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.20 no.2
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    • pp.102-118
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    • 2015
  • This study summarized the results of the international ocean reanalysis intercomparison project. We introduced the characteristics of various ocean reanalysis systems and analyzed the assimilated performance on the typical eight oceanic variables (heat content, steric height, sea level, surface heat fluxes, mixed layer depth, subsurface salinity, depth of $20^{\circ}C$ isotherm, sea ice). In general, ensemble means show better estimations than those of any individual ocean reanalysis, but it depends on analyzed regions and variables. Among the eight oceanic variables, salinity and sea ice variabilities have large spreads among models. The deep sea, Southern Ocean, and coastal regions including western boundary current commonly appear as the areas with largest uncertainty between different objective analyses and assimilation models. We expect that intercomparison project for the ocean assimilation models independently operated in Korea should be processed, which allows us to join relevant international programs in the near future.

The Verification for Extreme Hydrological Variables of HadGEM3-RA (HadGEM3-RA 자료의 극치수문변수에 대한 검증)

  • Sung, Jang-Hyun;Kang, Hyun-Suk;Park, Su-Hee;Cho, Chun-Ho;Kim, Young-Oh
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.122-122
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    • 2011
  • 수자원 분야에서 기후변화 관련 연구는 치수 측면 보다는 이수 측면에서 주로 이뤄지고 있다. 이는 홍수분석을 위한 시간 단위를 충족시켜주는 전지구 대기순환모형(Global Circulation Model: GCM)의 자료가 드물고, 시간 단위의 GCM 자료라 하더라도 극치값(extreme value) 표현에는 한계가 있기 때문이다. 이를 극복하기 위하여 과거 관측자료의 통계적 특성으로 극치자료의 편의(bias)를 보정하고 시간 단위로 분해하기도 한다. 하지만 이런 통계적 상세화(statistical downscaling)는 미래 기후는 과거자료와 통계적 차이가 유의하지 않음을 가정하고 있어, 미래 기후는 현재와 다를 것이라는 공감대에 는 적합하지 않다. 이와 같은 이유로 타당한 극치수문변수 결과를 얻기 위해서는 시간 단위의 고분해능(high resolution) GCM이나 지역기후모델(regional climate model)과 같은 고해상도의 미래 기후변화 자료가 필요하게 된다. 이에 국립기상연구소에서는 영국 기상청의 통합모델(UM)기반의 지역기후모델(HadGEM3)을 사용하여 50 km 및 12.5 km 격자 단위로 역학적 상세화(dynamic downscaling)를 수행하였다. 본 연구에서는 개발된 HadGEM3-RA 결과의 극치수문변수 검증을 위하여 한강유역의 관측 자료와 다양한 방법으로 비교하였다. 두 자료의 극치값을 GEV (Generalized Extreme Value) 분포에 적합(fitting)시켜 비초과확률별 극치사상과, 특정 임계값(threshold value) 이상의 극치사상 발생확률을 비교하였다. 검토 결과, HadGEM3-RA는 통계적 상세화로 구한 극치값 보다는 작았으나 기존의 지역 기후모델에 비하여 현실성 있는 극치값이 계산되었음을 확인하였다.

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