• Title/Summary/Keyword: 전도성 복합재료

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Preparation and Properties of Polystyrene/Graphene Nanofiller Nanocomposites via Latex Technology (라텍스 기법에 의한 폴리스티렌/그래핀 나노필러 나노복합재료의 제조 및 물성)

  • Yeom, Hyo Yeol;Na, Hyo Yeol;Chung, Dae-Won;Lee, Seong Jae
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.468-474
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    • 2015
  • Electrically conductive polymer nanocomposites were prepared by the inclusion of graphene-based nanofillers. Graphene oxide (GO) and reduced graphene oxide wrapped by poly(styrene sulfonate) (PSS-RGO) were used as nanofillers to make good dispersion with the aqueous dispersion of polystyrene (PS) particles. GO sheets were synthesized by the modified Hummers' method from graphite, and PSS-RGO sheets were prepared by the reduction of GO-dispersed PSS solution with hydrazine monohydrate. Morphology and properties of PS/GO and PS/PSS-RGO nanocomposites via latex technology were investigated. Both nanofillers showed well dispersed morphology in PS matrix. Rheological and electrical percolation thresholds were 0.28 and 0.51 wt% for GO, and 0.50 and 1.01 wt% for PSS-RGO respectively. It is speculated that PS/GO nanocomposites showed better conductivity than PS/PSS-RGO counterparts due to the partial recovery of GO by thermal reduction during molding.

Electromagnetic Shielding Polymer Composites with Segregated Structure for Automotive Part Application: A Review (자동차 부품 적용을 위한 Segregated structure를 갖는 전자파 차폐용 고분자 복합소재 연구동향)

  • Lee, Jinwoo;Suhr, Jonghwan
    • Composites Research
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    • v.35 no.4
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    • pp.223-231
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    • 2022
  • With the rapid growth of the future mobility market, a large number of electronic parts are being used in automobile, and the importance of electromagnetic interference (EMI) shielding in the automobile market is growing to minimize malfunctioning among the parts. Accordingly, conductive polymer composites (CPCs) are getting a lot of attention as EMI shielding materials for the automotive, but there are still challenges in CPCs like high content of conductive filler to achieve proper EMI shielding effectiveness, and poor mechanical properties. This paper introduces main methods to manufacture CPCs with segregated filler structure, which can significantly reduce the filler content, and analyzes EMI shielding performance of each manufacturing method.

폴리피롤/공중합폴리에스테르 전도성 복합필름의 전기전도성에 미치는 고분자 구조의 효과

  • 이성모;김길래;백두현
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.121-125
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    • 1998
  • 1977년 polyacetylene(PA)이 할로겐 도핑에 의해 금속에 필적하는 도전성을 나타낸다는 것이 발견된 이래 전도성 고분자는 전기 전도도 및 전자 상태를 자유롭게 제어 할 수 있다는 특징 때문에 2차 전지 및 연료 전지, 가스분리막, 우주 항공용 경량 도전재료, 대전방지제등의 넓은 응용분야를 가지며 현재에도 기초 연구 및 응용 연구의 양면에서 활기를 띠고 있다.(중략)

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Self-Diagnosis Properties of Fracture in Reinforced Concrete Intermixed with Conductive Materials (전도성 재료 혼입 철근콘크리트 구조체의 파괴예측 자기진단 특성)

  • Park, Seok-Kyun;Cho, Sung-Dong
    • Journal of the Korea Concrete Institute
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    • v.20 no.3
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    • pp.369-374
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    • 2008
  • Two types of conductive materials are selected and their applicable properties are investigated so as to give the capability of self-diagnosis of fracture in composite mortar, concrete and reinforced concrete. In this study, for giving selfdiagnosis capability, the powder of cokes and milled carbon fiber as conductive materials are selected and intermixed with mortar, concrete and reinforced concrete. After examining change in the value of electric resistance before and after the occurrence of cracks at each flexural load-stage in composite mortar, concrete or reinforced concrete, the relationships of each factors (electric resistance, crack and flexural load) are analyzed. As the results, it can be recognized that conductive materials with powder of cokes and milled carbon fiber can be applied for self-diagnosis of flexural fracture in composite mortar, concrete and reinforced concrete specimen.

Electrochemical performance of the flexible supercapacitor based on nanocarbon material/conductive polymer composite and all solid state electrolyte (탄소나노복합재료와 전고체 전해질 기반의 유연성 슈퍼커패시터의 전기화학적 특성 분석)

  • Kim, Chang Hyun;Kim, Yong Ryeol;Jeong, Hyeon Taek
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.200-207
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    • 2019
  • In this study, flexible supercapacitor based on the all solid state electrolyte with PVA (polyvinyl alcohol)-$H_3PO_4$, ionic liquid as a BMIMBF4 (1-buthyl-3-methylimidazolium tetrafluoroborate) and reduced graphene oxide/conductive polymer composite was fabricated and characterized electrochemical properties with function of its flexibility. In order to measure and compare that electrochemical performances (including cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge,after 0~100th bending test) of prepared flexible supercapacitor based on reduced graphene oxide/conducting polymer composite and all solid state electrolyte, we have conducted press machine with constant pressure ( 0.01/cm2) for $100^{th}$ bending test. As a result, specific capacitance of the flexible supercapacitor was 43.9 F/g which value decreased to 42.0 and 40.1 F/g after 50 and $100^{th}$ bending test, respectively. This result exhibited that decreased electrochemical property of the flexible supercapacitor effected on physical stress on the electrode after repeated bending test. In addition, we have measured that electrode surface morphology by SEM to prove its decreased electrochemical property of the flexible supercapacitor after prolonged bending test.

Composite Blade for Dicing of Wafer (웨이퍼 가공용 복합 블레이드)

  • Lee, Jeong-Ick
    • Proceedings of the KAIS Fall Conference
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    • 2008.05a
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    • pp.46-48
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    • 2008
  • 나노복합 블레이드가 반도체 웨이퍼 가공을 위한 마이크로급 나노장치나 그 이상의 나노급 구조체를 위해 사용되었다. 금속 블레이드는 실리콘 웨이퍼 가공을 위해 사용되어 왔다. 그러나, 최근 레진 복합 블레이드는 반도체나 핸드폰의 쿼츠 웨이퍼 가공에 사용된다. 유기 또는 비유기 재료 선정은 기계가공성, 전기 전도성, 강도, 연성 및 웨이퍼 저항을 가진 블레이드를 만드는데 중요하다. 고성능 응용의 증대 요구에 따라 개발된 고기술 비유기성 재료의 혼합은 낮은 가격에 고기능의 신뢰도를 필요로 한다. 나노 입자의 크기를 가진 레진 복합물의 마이크로 설계는 입자간 상호작용의 제어가 필요하다. 형상 제작 동안 마이크로 차원에 두께를 유지하기 위해서는 마이크로/나노급 제작을 위한 가공기술이 중요한 것 중의 하나이다. 본 연구에서는 핫 프레스 구조물이 원래 설계 기준과 두께 차이의 실험 접근법을 사용해 만들어졌다. 다른 습식 공정 기술은 차원의 허용치를 개선하기 위해 만들었다. 실험들과 해석들은 신뢰성 결과가 사용가능함을 보여주었다. 반도체 시장에 사용될 레진 복합 블레이드의 개선 효과가 논의되었다.

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Fabrication and Characteristics of Shielding Effects for the Complex Conductive Filler (복합 전도성 필러의 제작과 전자파 차폐 특성)

  • Park, Ju-Tae;Park, Jae-Sung;Do, Young-Soo
    • 전자공학회논문지 IE
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    • v.43 no.4
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    • pp.122-127
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    • 2006
  • A series of conductive filler were prepared with electroless plating method. Base conductive materials of the filler were nickel and copper. The cores were prepared with Nylon 6 and rayon in different aspect ratio. Also, various complexes were made with ABS resin and conductive filler with different filler feed ratio. The conductivity of the filler was measured with conductivity analyzer and the size distributions of fillers was measured with laser particle size analyzer. Electromagnetic wave shielding efficiency of each complex film was measured with flange circular coaxial transmission line sample holder within the 1MHz$\sim$1GHz bandwidth range. From this study, the conductivity of filers surpass that of other carbon films. It is available that the filler made of fibrous materials can be applied in plastic molding industry of electric appliances as a EMI filler.

Fabrication and Microstructure of Metal-Coated Carbon Nanofibers using Electroless Plating (무전해 도금을 이용한 금속 코팅된 탄소나노섬유의 제조 및 미세조직)

  • Park, Ki-Yeon;Yi, Sang-Bok;Kim, Jin-Bong;Lee, Jin-Woo;Lee, Sang-Kwan;Han, Jae-Hung
    • Composites Research
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    • v.20 no.5
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    • pp.43-48
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    • 2007
  • The absorption and the interference shielding of electromagnetic wave have been very important issues for commercial and military purposes. The stealth technique is one of the most typical applications of electromagnetic wave absorption technology. This study has started for the development of composite fillers containing dielectric and magnetic lossy materials. To improve the electromagnetic characteristics of conductive nano fillers, carbon nanofibers (CNFs) with nickel-phosphorous (Ni-P) or nickel-iron (Ni-Fe) have been fabricated by the electroless plating process. Observations by the electron microscopy (SEM/TEM) and element analyzer (EDS/ELLS) showed the uniform Ni-P and Ni-Fe coated CNFs. The compositions of the plating layers were about Ni-6wt%P and Ni-70wt%Fe, respectively. The average thicknesses of the plating layers were about $50\;{\sim}\;100\;nm$.