• Title/Summary/Keyword: 전극 전위

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A Study on the Application of Temporary Fence as a Ground Electrode (접지전극으로서의 가설울타리 활용방안에 관한 고찰)

  • Park, Sung-Yeol
    • Proceedings of the Korean Society of Disaster Information Conference
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    • 2023.11a
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    • pp.127-128
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    • 2023
  • 본 논문에서는 건설현장에 설치하는 가설울타리와 접지동봉을 매설하여 접지저항을 측정하였다. 접지저항을 측정한 결과 접지동봉은 10.8Ω이고, 가설울타리는 2.07 Ω이었으며, 이는 가설울타리가 접지전극으로 활용될 수 있음을 의미한다. 그러나, 가설울타리를 특별고압설비나 피뢰설비 등의 접지전극으로 활용할 때 가설울타리에 접지전류가 흐르게 되면 전위가 상승하고 접촉전압이나 보폭전압 등으로 인하여 감전사고가 발생할 수 있으므로, 가설울타리를 접지전극으로 활용하는 때는 신중해야 한다. 감전이나 화재 등의 위험이 없도록 안전조치를 한 상태에서 가설울타리를 접지전극으로 제한적으로 활용해야 할 것이다.

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Modeling of High-throughput Uranium Electrorefiner and Validation for Different Electrode Configuration (고효율 우라늄 전해정련장치 모델링 및 전극 구성에 대한 검증)

  • Kim, Young Min;Kim, Dae Young;Yoo, Bung Uk;Jang, Jun Hyuk;Lee, Sung Jai;Park, Sung Bin;Lee, Han soo;Lee, Jong Hyeon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.4
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    • pp.321-332
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    • 2017
  • In order to build a general model of a high-throughput uranium electrorefining process according to the electrode configuration, numerical analysis was conducted using the COMSOL Multiphysics V5.3 electrodeposition module with Ordinary Differential Equation (ODE) interfaces. The generated model was validated by comparing a current density-potential curve according to the distance between the anode and cathode and the electrode array, using a lab-scale (1kg U/day) multi-electrode electrorefiner made by the Korea Atomic Energy Research Institute (KAERI). The operating temperature was $500^{\circ}C$ and LiCl-KCl eutectic with 3.5wt% $UCl_3$ was used for molten salt. The efficiency of the uranium electrorefining apparatus was improved by lowering the cell potential as the distance between the electrodes decreased and the anode/cathode area ratio increased. This approach will be useful for constructing database for safety design of high throughput spent nuclear fuel electrorefiners.

The Usability of Zinc Electrode using Wireless Measuring System of Electric Potential (무선전위측정시스템에 사용하는 아연전극 활용성 검토)

  • Lee, Jong-Rark;Leem, Sa-Hawn;Kim, Sang-O
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2006.11a
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    • pp.177-180
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    • 2006
  • This study is to make a basic study if solid zinc (Zn) can be used for buried reference electrode, so we examined the adequacy of zinc as reference electrode by using zinc which showed regular electrode for buried period. The deference of electric potential if zinc electrode for corrosion factor such as soil resistivity or pH didn't show fixed trend and there was no clear trend on the change of measurement period. From field test, it is known that the natural electric potential difference of CSE electrode and zinc electrode is 1,100mV, but the electric potential of zinc electrode for CSE electrode in the natural soil and copying soil was 1,094~1,158mV. There was no fixed trend on the change of measurement period and electric potential difference of zinc electrode for corrosion factors such as soil resistivity or pH. Consequently, there was 40~60mV of electric potential difference in every copying soil during the experiment measurement.

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A Research about Transient Response at a Lightning Strike of Steel-Beam Building (건축물 구조체의 낙뢰 전위 분포 특성에 관한 연구)

  • Cho, D.H.;Lee, K.S.;Lee, K.G.;Ryu, C.H.
    • Proceedings of the KIEE Conference
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    • 2004.11d
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    • pp.122-126
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    • 2004
  • 직격뇌가 높은 건축물에 치거나 인접 건물로부터 뇌전류가 유입되었을 때 잘못된 피뢰설비로 인한 피해는 매우 심각한 실정이다. 낙뢰가 치는 순간에 반도체와 같은 민감한 전자부품을 사용하는 전자 및 통신기기는 뇌전류로 인한 전자기장의 영향으로 오동작이 발생하거나 부품의 손상을 입기가 쉽다. 본 논문에서는 건축물 구조체에 직격뇌가 유입되었을 때 건축물 구조체 및 건물 주위에 나타나는 전위분포특성을 연구하였다. 본 논문에서 30m 높이 건축물의 상부 모서리와 중앙부 그리고 건축물 하부 모서리와 중앙부로 뇌전류가 유입된다고 가정하여 건축물의 전계분포특성을 시뮬레이션하였으며, 뇌전류는 2중 지수함수형태로 모의된 20kA 임펄스 서지 전류를 주입하였다. 뇌서지 전류의 주파수 특성은 Fast Fourier Transform(FFT)을 이용하여 얻었으며, 얻어진 주파수 값을 이용하여 건축물 구조체와 인접지역의 Scalar Potentials과 Electric Fields의 특성을 시뮬레이션하였다. 또한 철골 빔 건축물의 철골 빔에 직접 뇌전류가 유입되는 경우와 건물 하부의 접지전극에 뇌전류가 유입되는 경우로 분리 하여 연구하였다. 그 결과 뇌전류의 유입경로가 건축물의 모서리부분 보다는 중심부에 위치될 때 전위 및 전계 크기가 작았으며 건축 철골구조물보다 건축물 하부에 접지전극이 설치될 때 더 낮은 전계 값을 갖는 것을 확인하였다.

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Relationship Analysis between Half Cell Potential and Open Circuit Potential Considering Temperature Condition (온도 영향을 고려한 RC 구조의 반 전위 및 OCP의 상관성 분석)

  • Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.124-132
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    • 2022
  • The corrosion potential in concrete varies greatly with exposure and concrete mix conditions. In this study, RC (Reinforcement Concrete) samples were prepared considering cover depth, chloride concentration, and W/C(water to cement) ratio as variables, and HCP(Half Cell Potential) was measured, which evaluated comparative potential between embedded steel and concrete surface. In addition, OCP(Open Circuit Potential) was measured using buried steel and CE(Counter Electrode). Agar and NaOH solution were used as ion exchange materials and Hg/HgO was used for RE(Reference Electrode), which was more sensitive to temperature than HCP. Among the influencing factors, the exposure period and chloride concentration had a relatively greater effect than cover depth and w/c ratio. Additionally, the entire measured HCP and OCP showed a clearly linear relationship with increasing cover depth and w/c ratio. Through multiple regression analysis, the relationship between HCP and OCP was quantified, and an improved correlation was obtained with temperature effect.

Determination of Electrode Potential in Micro Electrochemical Machining of Stainless Steel (스테인리스강의 미세 전해 가공 시 전극 전위의 선정)

  • Park B.J.;Chu C.N.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1281-1284
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    • 2005
  • In the micro electrochemical machining (ECM), unfavorable oxide/passive layer formation and overall corrosion of electrodes must be prevented. Generally, the stainless steel electrode corrodes, passivates or dissolves in the electrochemical cell according to the electrode potential. Therefore, the electrode must maintain stable potential. The stable electrode potentials of tool and workpiece were determined with the potentiodynamic polarization test and verified experimentally from the point of machining stability and machined surface quality.

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Determination of Electrode Potential in Micro Electrochemical Machining of Passive Metals (부동화 금속의 미세 전해 가공 시 전극 전위의 선정)

  • Nam Ho-Sung;Kim Bo-Hyun;Chu Chong-Nam;Park Byung-Jin
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.4 s.181
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    • pp.146-152
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    • 2006
  • In micro electrochemical machining (ECM), electrodes should be prevented from unfavorable oxide and Passive layer formation on the machined surface or overall corrosion of the entire surface. Generally, metal electrodes corrode, passivate or dissolve in the electrochemical cell according to the electrode potential. Therefore, each electrode must maintain its stable potential. Tn this paper, the stable electrode potentials of tool and workpiece were determined using the potentiodynamic polarization test and verified experimentally considering machining stability and surface quality. Stable workpiece electrode potentials of two different passive materials of 304 stainless steel and nickel were determined in the 0.1 M sulfuric acid. Experimental results show good machined surface and fast machining rate using the determined electrode potentials.

Characteristics of PEO and Electro Deposition Coating on Magnesium alloy

  • Nam, Seok-Hyeon;Lee, Jae-Eun;Na, Il-Chae;Jang, Chae-Min
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.187-187
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    • 2015
  • 마그네슘 합금은 지구상에 존재하는 가장 경량인 금속이며 비강도가 우수할 뿐만 아니라 진동 감쇠능과 절삭성 및 전자파 차폐성 등이 뛰어나 전자제품, 수송기기 부품, 주방제품 및 의료 분야 등 광범위한 분야에 이용이 크게 기대되고 있다. 그러나 마그네슘은 표준 전극 전위가 매우 낮은 활성 금속이기 때문에 쉽게 산화되며 표준 전극 전위가 높은 이종 금속과 접촉하면 먼저 부식되는 등 내식성이 현저히 낮아 그 사용범위에 제약을 받는다. 그러므로 마그네슘 금속을 사용하기 위해서는 내식성 및 기계적 특성을 향상시키는 표면처리가 필수적이다.

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A study on the oxidation characteristics of phenol on Pt anode (백금전극을 이용한 페놀의 산화특성에 관한 연구)

  • Kim, Hong-Soo;Nam, Jeong-Woo;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.1 no.1
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    • pp.44-51
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    • 1990
  • The electrochemical oxidation behavior of phenol on platinum anode had been investigated by cyclic voltammetric method. The initial oxidation potential of phenol was dependent on the pH in acid solution. But in basic solution, it was held 033-0.40V(vs. S.C.E.). The peak current was proportional to the concentration of phenol and the optimum concentration was found to be about 0.1N. The oxidation reaction of phenol was found to be irreversible and controlled by diffusion.

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Determination of Electrode Potential in Micro Electrochemical Machining of Nickel (니켈의 미세 전해 가공 시 전극 전위의 선정)

  • Nam H.S.;Park B.J.;Kim B.H.;Chu C.N.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.585-588
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    • 2005
  • The dissolution characteristic of metal shows the different tendency according to the applied electrical potential, the kind of electrolyte and pH value, etc. In the micro electrochemical machining (ECM), unfavorable oxide/passive layer formation and overall corrosion of electrodes must be prevented. The anodic polarization curve of nickel has distinct three dissolution regions, i.e. two active regions and the transpassive dissolution region. In this paper, the stable electrode potentials of workpiece and tool were determined in sulfuric acid and hydrochloric acid solution, respectively. In each solution, different machining property was shown and possible electrochemical reactions were discussed. On the basis of this experiment, the methodology to obtain the proper electrode potential was suggested.

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