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Influence of Activation Temperature on Surface and Adsorption Properties of PAN-based Activated Carbon Fibers/Phenolic Resin Matrix Composites (활성화 온도에 의한 PAN계 활성탄소섬유/페놀수지 복합재료의 표면 및 흡착특성)

  • 박수진;김기동;이재락
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.97-104
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    • 2000
  • PAN-based activated carbon fibers/phenolic resin matrix composites (ACFCs) were manufactured via molding process with oxidized carbon fabrics (plain-type) and phenolic resin (resole-type) compounded by 70 : 30 wt%. The green body (as molded) was submitted to carbonization (at 100$0^{\circ}C$) in an inert environment and activation (at 700, 800, 900 and 100$0^{\circ}C$) in a $CO_2$ environment. In this work, the influence of activation temperatures was investigated in surface properties, such as pH, acid- and base-values by titration method, and in adsorption properties, i.e., specific surface area and pore structures by BET-method of the composites. Also, the pressure drops of the specimens were calibrated by ASTM. As a result, the activation temperature influenced the surface property of ACFCs. When the activation temperature was higher than 90$0^{\circ}C$, the surface was gradually developed in basic nature. And, the evolutions of specific surface area, total pore volume and pore size distribution of ACFCs could be easily confirmed the dependence on the activation temperature. Among them, well-developed pore structure from adsorption characteristics was changed of the ACFCs activated at 90$0^{\circ}C$. Also, the pressure drop was slightly decreased with increasing the temperature due to increasing the burn-off with heat treatment temperature of ACFCs.

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Spatial Variability Analysis of Paddy Rice Yield in Field (필지내 벼 수량의 공간변이 해석)

  • 이충근;우메다미키오;정인규;성제훈;김상철;박우풍;이용범
    • Journal of Biosystems Engineering
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    • v.29 no.3
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    • pp.267-274
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    • 2004
  • Using geo-statistical method, yield data of different fields were analyzed to examine their field variability according to examining year, analysis method. Semivariogram and Kriged maps of geo-statistical analysis were used to examine their spatial dependence within a filed. The results obtained were as follows. 1) Descriptive statistical results of the yield showed that the yield and the difference of yield ranged from 100 to 946kg/10a and from 272 to 653kg/10a, respectively within a field. The coefficient of variation also ranged from 5.9 to 22.4 %. 2) More than 90% of yield data were placed between 350 to 850kg/10a. e results indicated that the gram mass flow sensor should have the measuring range from 0.34 to 0.82kg/s considering the yields when 4 rows head-feeding combine with 0.8 m/s of working speed was utilized. 3) A high spatial dependence was found within paddy field. The Q values ranged from 0.20 to 0.97, and the range of spatial dependence was from 6.9 to 53.3m. From this result, the rational sampling interval for yield investigation was estimated 6.9m. 4) Yields within a field between observation years showed considerable variability even if the field was evenly cultivated and managed. To apply precision agriculture in a paddy field, the field test should be continued to build a solid data-base including meteorological data, blight damage and insect damage.

SO2 Adsorption Characteristics of PAN-based Activated Carbon Fiber Impregnated with Palladium and Gold Nanoparticles (팔라듐과 금 나노입자를 첨착한 PAN계 활성탄소섬유의 SO2 흡착특성)

  • Lee, Jin-Jae;Jun, Moon-Gue;Kim, Young-Chai
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.467-474
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    • 2007
  • The palladium and gold nanoparticles containing PAN-based active carbon fiber (ACF) with a high specific surface area were prepared. Using the BET, TEM, FE-SEM, and XPS, their specific surface area and pore volume, pore structure, and the change in surface oxygen groups with time were analyzed and $SO_2$ adsorption performances were investigated. Because of the impregnating process, the micropore volume was mostly decreased from 95.5% to 30.5~43.7% compared with the total pore volume. And the change in surface oxygen groups with time was higher for the metal salt than the nanoparticles. Also, $SO_2$ breakthrough time of PAN-ACFs impregnated with Au nanoparticles and metal salts did not change compared with that of the non-impregnated PAN-ACF. But the PAN-ACF impregnated with Pd nanoparticles (100 ppm) showed good $SO_2$ adsorption performance as the breakthrough time of 880 sec. These results indicated that the $SO_2$ adsorption performance depended on the change in surface oxygen groups with time and the moderate impregnation of Pd nanoparticles on the PAN-ACF caused the increase in the $SO_2$ adsorption performance by a catalytic action.

Synthesis of Nanoporous NiO-SiO2 Pillared Clays and Surface Modification of the Pillaring Species (나노다공성 NiO-SiO2 가교화 점토의 합성 및 가교물질의 표면개질 연구)

  • Yoon, Joo-Young;Shim, Kwang-Bo;Moon, Ji-Woong;Oh, You-Keun
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.81-85
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    • 2004
  • Nanoporous materials with nanometer-sized pores, are of great interest in the various applications such as selective adsorbents, heterogeneous catalysts and catalyst supports because of their high porosity, surface area, and size selective adsorption properties. This study is aimed to prepare nanoporous catalytic materials on the basis of two-dimersional clay by pillaring of $SiO_2$ sol particles. $SiO_2$ Pillared Montmorillonite (Si-PILM) was prepared by ion exchanging the interlayer $Ni^{2+}$ ions of clay with $SiO_2$ nano-sized particles of which the surface was modified with nicked polyhydroxy cations sach as $Ni_4(OH)_4^{4+}$. Nano-sized $SiO_2$ particles were formed by the controlled hydrolysis of tetraethyl orthosilicate (TEOS). Upon pillaring of $Ni^+$-modified $SiO_2$ nano particles between the clay layers, the basal spacing was expanded largely to $45{\AA}$ and the extremely large specific surface area ($S_{BET}$) of $760m^2/g$ was obtained.

Characteristics of the Stored Samjangs with Different Doenjangs (원료된장을 달리하여 제조한 저장쌈장의 품질특성)

  • Kim, Hye-Lim;Lee, Taik-Soo;Noh, Bong-Soo;Park, Jung-Suk
    • Korean Journal of Food Science and Technology
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    • v.31 no.1
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    • pp.36-44
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    • 1999
  • Samjangs which were prepared using magjang, traditional doenjang, and mixture of traditional doenjang and magjang were stored. Characteristics of the stored samjangs were investigated. Maximum titratable acidity was shown in traditional doenjang after 30 day of storage. Total sugar in samjangs decreased while reducing sugar increased to $11.45{\sim}12.35%$ from $8.44{\sim}9.29%$ after 40 days. Amino type nitrogen predominantly increased to $337.3{\sim}381.1\;mg%$ after 40 days from $48{\sim}53\;mg%$ of initial period of preparation. Among the free amino acids the content of glutamic acid $(202.6{\sim}464.6\;mg/100g)$ was highest and others were not too much changed. Forty two components including 7 alcohols, 4 esters, 13 acids, 6 aldehydes, 5 phenols, 3 pyrazines and others were found in samjangs. Ethanol, acetic acid ethyl ester and 2-phenylethanol were found in all treatments and ethanol, acetic acid ethyl ester, phenylacetaldehyde, butanoic acid, acetic acid, 3-methyl butanoic acid and 2,4-hexadienoic acid might be major volatile components considering of high peak area. 2-Phenylethanol, butandioic acid ethyl ester, butanoic acid and 2-methyl-2-butenoic acid were higher than other components in samjang with magjang while ethanol, acetic acid, 2,4-hexadienoic acid were in samjang with traditional doenjang and 3-methyl butanoic acid, acetic acid ethyl ester and methyl pentanoic acid were in the mixed treatment.

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Effect of Nursery Period and Block Size on Growth and Yield of Paprika (파프리카 육묘기간 및 육묘블록의 크기가 생육과 수량에 미치는 영향)

  • Choi, Gyeong-Lee;Cho, Myeung-Whan;Cheong, Jae-Woan;Roh, Mi-Young;Rhee, Han-Cheol;Kang, Yun-Im
    • Journal of Bio-Environment Control
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    • v.20 no.4
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    • pp.263-268
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    • 2011
  • This study was carried out to investigate the effect of nursery period and block size on seedling quality and fruit yield of paprika (Capsicum annuum L. 'Cupra'). Seeds of paprika (Capsicum annuum L., Cupra) were sown in rockwool plugs. Seedlings were transferred and grown to the rockwool block different sizes: $5{\times}5$, $7.5{\times}7.5$ and $10{\times}10cm$ at sowing after 15 days. The plants were transplanted by 25, 30, 35, 40, 45 and 50 days we planted the seeds to the rockwool slabs. Seedling growth was not influenced by block size in the 25 day old plant, since then growed poorly with increasing nursery period in the $5{\times}5cm$ block size, plant height, stem diameter, fresh weight, dry weight have no difference from $10{\times}10cm$ and $7.5{\times}7.5cm$, but leaves and leaf area were higher $10{\times}10cm$ than the $7.5{\times}7.5cm$ block size. Growth of the paprika in field 80 days after sawing did not differ from nursery period and block size below 35 days old, but decreased with increasing nursery period and decreasing block size beyond 40 days old. Flowering did not differ from nursery period and block size below 35 days, but delayed with increasing nursery period and decreasing block size beyond 40 days old. The highest yield was obtained from 30 and 35 days old, and decreased with increasing nursery period and decreasing block size beyond 40 days old.

Effect of ionic Strength of Nutrient Solution on Growth and Yield in Cucumber(Cucumis sativus L.) (양액이온 농도 차이가 오이의 생육과 수량에 미치는 영향)

  • 권병선;정현희;신동영;김학진;임준택;현규환;신정식
    • Korean Journal of Plant Resources
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    • v.16 no.3
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    • pp.223-229
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    • 2003
  • This study was carried out to investigate the optimum ionic strength of nutrient solution were treated with a quarter, a half, three quarters, standard, one and half, and double ionic strength of balanced nutrient solution of Yamazaki solution recommended for cucumber plants. Plant height and number of loaves of growing period were rapidly increased in 1/2 ionic strength of nutrient solution. Growth characteristics of cucumber plant as affected by the different ionic strength of nutrient solution were not significant differences, however, in the growing period, plant height, stem length and leaf area were highest in 1/2 ionic strength of nutrient solution. Fruit yield of cucumber plant as affected by the different ionic strength of nutrient solution was not significant differences, however, fruit yield was highest in 1/2 ionic strength of the lowering ionic strength of nutrient solution. Nitrogen concentration was not significant differences, however, it was high corcentration in 1/2 ionic strength of nutrient solution. Growth and yield characteristic of cucumber as affected by 1/2 ionic strength of nutrient solution at 36 days transplanting analyzed correlation cofficient. Plant height showed positive correlated with number of plant and positive correlated with yield.

A study on simplification of SWMM for prime time of urban flood forecasting -a case study of Daerim basin- (도시홍수예보 골든타임확보를 위한 SWMM유출모형 단순화 연구 -대림배수분구를 중심으로-)

  • Lee, Jung-Hwan;Kim, Min-Seok;Yuk, Gi-Moon;Moon, Young-Il
    • Journal of Korea Water Resources Association
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    • v.51 no.1
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    • pp.81-88
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    • 2018
  • The rainfall-runoff model made of sewer networks in the urban area is vast and complex, making it unsuitable for real-time urban flood forecasting. Therefore, the rainfall-runoff model is constructed and simplified using the sewer network of Daerim baisn. The network simplification process was composed of 5 steps based on cumulative drainage area and all parameters of SWMM were calculated using weighted area. Also, in order to estimate the optimal simplification range of the sewage network, runoff and flood analysis was carried out by 5 simplification ranges. As a result, the number of nodes, conduits and the simulation time were constantly reduced to 50~90% according to the simplification ranges. The runoff results of simplified models show the same result before the simplification. In the 2D flood analysis, as the simplification range increases by cumulative drainage area, the number of overflow nodes significantly decreased and the positions were changed, but similar flooding pattern was appeared. However, in the case of more than 6 ha cumulative drainage area, some inundation areas could not be occurred because of deleted nodes from upstream. As a result of comparing flood area and flood depth, it was analyzed that the flood result based on simplification range of 1 ha cumulative drainage area is most similar to the analysis result before simplification. It is expected that this study can be used as reliable data suitable for real-time urban flood forecasting by simplifying sewer network considering SWMM parameters.

A Basic Study on the Development of Garlic Seeder (경운기 부착형 마늘 파종기 개발을 위한 기초연구)

  • Lim, Hack-Kyoo;Kim, Tae-Han
    • Current Research on Agriculture and Life Sciences
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    • v.22
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    • pp.19-27
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    • 2004
  • Cultivation area of garlics is 9% of all cultivation area of vegetables. The amount of annual demand is increased in 1,000~1,500ton. Also, the amount of demand per person has a tendency to increase as above 10kg. So, garlics has become important crops in agriculture. The purpose of this study is to acquire the basic information to design the garlic seeder attached power tiller. We used Working Model 3D program to design an automatic aligning device which is the most important part of the garlic seeder. The results are as follows; 1. The optimum depth of garlics seeding was shown as 3cm. 2. The garlic seed has to he discharged from the garlic seeder at intervals of 0.75sec in order to seed at intervals of seeds of 15cm. 3. The optimum design factors of the automatic aligning device were shown as cylinder diameter of 4cm, cylinder gap of 1cm, revolution of 36rpm and inclined angle of cylinder of $8.4^{\circ}$.

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A Study on Floating Waste Trace in Flood Control Dam Using the EFDC Model (EFDC 모델을 활용한 홍수조절용 댐의 부유쓰레기 유동 모의)

  • JANG, Suk-Hwan;OH, Kyung-Doo;OH, JiHwan;HAN, SuHee
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.336-336
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    • 2015
  • 일반적인 다목적댐은 홍수 발생 시 본댐으로 유입되는 부유쓰레기 및 잡목 등을 차단하기 위하여 댐 상류에 차단망을 설치하여 1차적으로 사전 방지하고, 홍수기 이후 선박으로 부유물을 수거하여 재활용, 소각 등으로 처리하는 시스템이다. 그러나 본 연구의 대상인 한탄강댐은 홍수조절용 댐으로서 수위 변화 폭이 매우 크고 정상 조건(비 홍수기)시는 대규모 홍수터가 드러나기 때문에 댐 유지관리 방법이 상이하며 한탄강 본류 구간은 하폭과 수심 등 하도의 불규칙성과 만곡부에서 유수의 흐름이 한쪽으로 쏠리는 편기 현상이 발생하는 등 복잡한 수리현상으로 인하여 부유쓰레기의 분포를 판단하기 어려운 지역이다. 따라서 본 연구에서는 부유쓰레기의 유동을 모의하기 위하여 HEC-HMS 모형과 $Vflo^{TM}$ 모형을 활용하여 본류와 지류의 빈도별 홍수량 분석을 실시하고, EFDC 3차원 동수역학 모형을 적용하여 홍수조절용지 내 부유쓰레기의 유입 경로 및 정체 구역을 분석하여 효과적인 쓰레기 처리 방안을 제시하고자 하였다. 분석 결과, 소규모 빈도 홍수(2년, 5년)의 경우 중 상류 지류의 부유쓰레기는 거의 유동하지 못하고 하도의 만곡의 영향을 받아 부분적으로 높은 밀도로 고착될 것으로 모의되며, 특히 본류와의 합류점 부근에 도달한 부유쓰레기는 유로 폭이 급확대되어 유속이 거의 없는 사수역 구간으로 변함에 따라 본류 배수위 영향으로 불규칙하게 맴돌다가 고착되는 것으로 모의되었다. 중규모 홍수(25년, 50년)의 경우, 상류부의 부유쓰레기의 분포는 소규모 홍수 시와 유사한 패턴을 보였으나 중류부에서 홍수파가 본류 하도를 월류하여 홍수터로 넓게 범람하는 지역에서는 소규모 홍수 시 본류 하도 양안에 분포하던 부유쓰레기가 홍수터 쪽으로 밀려가서 고착되는 경향을 보였다. 대규모 홍수(100년, 200년)의 경우, 댐과 인접한 분석 구간 하류부는 댐 배수위의 영향을 가장 크게 받으며 수심이 깊어 흐름이 가장 정체되는 구간으로 본류와 지류 모두 다량의 부유쓰레기가 분포할 것으로 분석되었다. 분석 구간 중류부는 홍수 규모가 증가함에 따라 넓은 홍수터로 침수범위가 급격하게 증가하며 이에 따라 부유쓰레기가 분포할 수 있는 면적이 크게 증가할 것으로 분석되었다. 또한 분석 구간 상류부는 협곡을 이루고 있어 홍수규모가 증가하더라도 침수범위와 부유쓰레기의 분포면적에 큰 변화가 없을 것으로 분석되었다. 본 연구 결과를 바탕으로 댐의 치수 문제가 발생하지 않도록 효과적으로 수거 처리 할 수 있는 부유쓰레기 적치장 및 차단 시설의 적정 설치 위치를 파악하였다.

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