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Characteristics of Electric Conductivity and Adhesion with Current Collector According to Composition of $LiMn_2O_4$ Cathode (망간산화물 정극의 합제조성에 따른 전자전도특성 및 집전체와의 접착특성)

  • Eom Seung-Wook;Doh Chil-Hoon;Moon Seong-In
    • Journal of the Korean Electrochemical Society
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    • v.4 no.1
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    • pp.1-5
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    • 2001
  • Composite ratio of $LiMn_2O_4$ in cathode was optimized as function of specific surface area. Binder has to be used as possible as little, and it should maintain adhesive property between cathode composite and current collector even though in electrolytes. For this purpose, We used 'Hot Roll Pressing' method, and it was effective. To prevent separation of cathode composite from current collector, PVDF(Polyvinylidenefluoride) has to be mixed more than $1.1\%$ in weight ratio to sum of surface area of lithium manganese oxide and conducting agents. Specific internal resistance was reduced as by increasing electrical conductivity of cathode. And Ratio of 2C rate discharge capacity to 0.2C rate discharge capacity was increased by $17\%$, as increasing electrical conductivity from 0.019 mS/cm to 0.036 mS/cm.

Generation of Fine Droplets in a Simple Microchannel (유체 소자를 이용한 미세 액적 생성)

  • Kim, Su-Dong;Kim, Young-Won;Yoo, Jung-Yul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.7
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    • pp.671-677
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    • 2010
  • In the present study, we designed a microfluidic platform for generating monodisperse droplets with diameters ranging from hundreds of nanometers to several micrometers. To generate fine droplets, T-junction and flow-focusing geometry are integrated into the microfluidic channel. Relatively large aqueous droplets are generated at the upstream T-junction and transported to the flow-focusing geometry, where each droplet is broken into smaller droplets of the desired size by the action of pressure and viscous stress. In this configuration, the flow rate of the inner fluid can be made very low, and the ratio of the inner- and outer-fluid flow rates in the flow-focusing region can be made very high. It has been shown that the present microfluidic device can generate droplets with diameters of approximately $1\;{\mu}m$ (standard deviation: <3%).

Gas Impermeability Enhancement of EFDM/Crosslinked IIR Blends (Crosslinked IIR의 블렌드비에 따른 EPDM의 내기체투과특성 향상)

  • Kim, Hyun-Jun;Jung, Il-Hyun;Hong, In-Kwon;Park, Jae-Woo
    • Elastomers and Composites
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    • v.33 no.3
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    • pp.193-200
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    • 1998
  • It is well known that EPDM(ethylene propylene diene monomer) rubber has inherently excellent resistance to the weathering, ozone, heat, cold and moisture, whereas crosslinked IIR (isobutylene isoprene divlnyl benzene terpolymer) shows proper resistance to the water and gas permeation. Various characteristics of EPDM blend with crosslinked IIR such as curing characteristics, mechanical properties, dispersion of minor component and gas impermeability were explored. The optimum curing time $(t_{90})$ examined with peroxide was decreased by adding small amount of crosslinked IIR to the EPDM rubber. Mechanical properties of blends such as tensile strength, hardness and elongation at break were enhanced by increasing EPDM content. These results might be explained with the affinity of carbon black to the EPDM rubber. On the other hand, the physical properties were not changed significantly after aging, and the increase of crosslinked IIR fraction caused the decrease of compression set to small rate. EPDM rubber shows different behavior with crosslinked IIR in oxygen permeability. By adding 30wt.% crosslinked IIR to the EPDM rubber, the resistance to the oxygen permeation was improved up to three times than that of pure EPDM rubber. Conclusively, EPDM blend containing 30wt.% crosslinked IIR might be commercially applied to the o-ring and electric parts because of its proper resistance to the weathering, ozone and oxygen permeability.

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Performance Test of Liquid Cooling Type Cold Plates for Robot Cooling (로봇 냉각을 위한 수냉식 냉각판의 성능 평가)

  • Lee, Suk-Won;Karng, Sarng-Woo;Hwang, Kyu-Dae;Kim, Seo-Young;Rhee, Gwang-Hoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.3
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    • pp.189-196
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    • 2008
  • The increase of system weight due to installation of cooling devices adds electrical and mechanical loads of humanoid robot, and in return, results in much heat. Therefore, the weight of cooling system is a critical issue for robot cooling. In this study, we propose non-metallic cold plates to deal with such problems. We compare thermal performances between one metallic cold plate and five different types of non-metallic cold plates. A metallic cold plate is totally made of copper. Five non-metallic PC(polycarbonate) cold plates, which are designed to reduce the overall weight of robot cooling system, are composed of a polycarbonate cover with different types of base plate. The overall heat transfer coefficients per unit mass and thermal resistances are obtained for the cold plates. The metallic cold plate shows the best thermal performance. It is interesting to note that the PC cold plate with an aluminum base plate with 18 channels shows the best overall heat transfer coefficient per unit mass. Most polycarbonate cold plates display fairly comparable thermal performance with more reduced system weight compared to the metallic cold plate.

Measurements of Turbulent Flow In a$6\times{6}$ Rod Bundle with Spacer Grids (지지격자를 갖는 $6\times{6}$ 봉다발에서의 난류유동 측정)

  • Yang, Sun-Kyu;Chung, Moon-Ki
    • Nuclear Engineering and Technology
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    • v.28 no.2
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    • pp.162-174
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    • 1996
  • The local hydraulic characteristics in a single phase flow of a 6$\times$6 rod bundle with neighboring different spacer grids were measured by using a LDV(Laser Doppler Velocimeter) system. 6$\times$6 rod bundle is formed by two 3$\times$6 rod bundles with different spacer grids. The objective of this study in a rod bundle is to investigate the thermal-hydraulic interactions between different spacer grids with different configurations and resistance. By using a LDV system, the velocity and turbulent intensity in axial and horizontal directions ore measured. Pressure drop measurements ore also performed to evaluate the loss coefficient for the spacer grid and the friction factor for rod bundles. Implications concerning thermal mining due to spacer grids were investigated based on the hydraulic test results. Swirl factor, which is assumed as a qualitative criteria for DNB(departure from nucleate boiling), was defined and estimated from the horizontal velocity result.

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Properties of ZnO Films on r-plane Sapphires Prepared by Ultrasonic Spray Pyrolysis (초음파(超音波) 분무(噴霧) 열분해법(熱分解法)으로 r-plane 사파이어 위에 증착(蒸着)된 ZnO 막(膜)의 특성(特性))

  • Ma, Tae-Young;Moon, Hyun-Yul;Lee, Soo-Chul
    • Journal of Sensor Science and Technology
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    • v.6 no.2
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    • pp.155-162
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    • 1997
  • Zinc oxide(ZnO) thin films were deposited on r-plane sapphires from a solution containing zinc acetate. The films were obtained in a hot wall reactor by the pyrolysis of an aerosol produced by an ultrasonic generator. The crystallinity, surface morphology and composition of the films have been studied using the x-ray diffraction method(XRD) scanning electron microscopy(SEM) and Auger electron spectroscopy (AES) respectively. The influences of the substrate temperature on the crystallinity of the films were studied. Strongly (110) oriented ZnO films were obtained at a substrate temperature of $350^{\circ}C$. The resistivity was increased to above $3{\times}10^{6}{\Omega}{\cdot}cm$ with copper doping and vapor oxidation.

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Reflow of copper film for the interconnection of the next generation semiconductor devices (차세대 반도체 소자의 배선을 위한 구리박막의 reflow)

  • 김동원;김갑중;권인호;이승윤;라사균;박종욱
    • Journal of the Korean Vacuum Society
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    • v.6 no.3
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    • pp.206-212
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    • 1997
  • The reflow characteristics of copper, which is expected to be used as interconnection materials in the next generation semiconductor devices, were investigated. Copper films were deposited on hole and trench patterns by metal organic chemical vapor deposition and annealed in nitrogen and oxygen ambient with the annealing temperatures ranging from $350^{\circ}C$ to $550^{\circ}C$. Copper films were not reflowed into the patterns upon the annealing in nitrogen ambient, but reflowed at the annealing temperature higher than $450^{\circ}C$ in oxygen ambient. It is considered that the reflow takes place as the heat generated by the oxidation of copper liquefies the copper film partly and the liquid copper fills the patterns for minimizing the surface energy and the potential energy. Upon the annealing in oxygen ambient, the copper oxide whose thickness was less than 300$\AA$ formed at the surface of an agglomerate and the resistivity of copper film increased drastically at an annealing temperature of $550^{\circ}C$ due to the copper agglomeration.

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Reliability assessment of mica high voltage capacitor through environmental test and accelerated life test (마이카 고전압 커패시터의 환경시험과 가속 수명시험을 통한 신뢰성 평가)

  • Park, Seong Hwan;Ham, Young Jae;Kim, Jeong Seok;Kim, Kyoung Hun;So, Seong Min;Jeon, Min Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.270-275
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    • 2019
  • Mica capacitor is being adopted for high voltage firing unit of guided weapon system because of its superior impact enduring property relative to ceramic capacitor. Reliability of localized mica high voltage capacitors was verified through environmental test like terminal strength test, humidity test, thermal shock test and accelerated life test for application to high voltage firing unit. Failure mode of mica capacitor is a decrease of insulation resistance and its final dielectric breakdown. Main constants of accelerated life model were derived experimentally and voltage constant and activation energy were 5.28 and 0.805 eV respectively. Lifetime of mica capacitor at normal use condition was calculated to be 38.5 years by acceleration factor, 496, and lifetime at accelerated condition and this long lifetime confirmed that mica high voltage capacitor could be applied for firing unit.

Preparation of Pt/porous Gold Electrode for CO Oxidation (CO 가스 산화를 위한 백금/다공성 골드 전극의 개발)

  • Shin, So-Hyang;Kim, He-Ro;Oh, Cheon-Seok;Ko, Jae-Wook;Kim, Young-Hun
    • Journal of the Korean Institute of Gas
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    • v.15 no.4
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    • pp.27-32
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    • 2011
  • Management of gas safety is becoming important with increasing use of gas facilities. U-safety system is being promoted as part of national management of gas, and thus real-time and in-situ gas sensor should be developed. Detection method for When the gas sensor is installed in gas conduit, explosion may be likely, because hydrocarbon gases is usually used the difference of thermal resistance between reference and working electrode. Therefore, it is required to detect the hydrocarbons, such as $CH_4$ and CO, at room temperature via electrochemically catalytic reaction. In this study, Pt nanoparticle was doped on the porous gold powder by electrolytic plating method, and then it was used as catalytic electrode for CO oxidation. For Pt/PAu electrode, approximately 21% of CO conversion was obtained. It is noted that Pt/PAu electrode could be used to react the oxidation of hydrocarbon gases at room temperature via applying of external voltage.

Dimming Control of the LED Luminaire Emergency Exit Sign Operation using a Hybrid Super Capacitor of DC-DC Convertor (하이브리드 슈퍼커패시터 DC-DC 컨버터를 이용한 LED 비상 유도등 동작 디밍 제어)

  • Hwang, Lark-Hoon;Kim, Jin-Sun;Na, Yong-Ju
    • Journal of Advanced Navigation Technology
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    • v.21 no.3
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    • pp.220-229
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    • 2017
  • In this paper, To take advantage a variety of DC power as the boost DC-DC converter design specifications through the inductor L and capacitor C through PSPICE to calculate the best estimate of the value. Boost DC-DC converter with a switch device using IRF840 and reverse recovery time Schottky diodes with excellent with constant current controller using D10SC6M and resistance can be configured to considering the Power LED Module was driven by the production. Converter's switching frequency is 50 kHz, the first Duty Rate was made to increase gradually depending on the value of the detection were, 10 % in the output voltage. As a result, the simulated Boost Power LED driver characteristics is in comparison with the design specifications, 5% or less as the error was approximated. Finally, when input 15 V were offered, a stable output 24 V were obtained. and Dimming Control through the adjustment of brightness and current consumption were possible.