• Title/Summary/Keyword: 재용출

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Study of the environmental assessment of heavy metals bearing slag utilization (중금속 함유 폐기물의 재사용을 위한 환경적 평가에 관한 연구)

  • Bae, Hae-Ryong;Gwon, Yeong-Bae;Moszkowicz Pierre
    • 연구논문집
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    • s.28
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    • pp.161-172
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    • 1998
  • In the recycling industry, the recuperation of zinc from Electric Arc Furnace dust by the Waelz process generates important quantities of slag. This slag presents good mechanical properties, and for the most siliceous slag. a high stability which would enable its use by total or partial substitution of certain granulates in civil engineering Our study (within the framwork of a European programme cofunded by the European Commission-DGXII) concerns the physico-chemical and mineralogical characterization and leaching behaviour of several types of Waelz slag. The leaching tests are regulatory tests and specific characterization tests of leaching behaviour. They take into account the influence of several main parameters of the valorization scenarios envisaged for the slag(e.g. pH, Redox potential, chemical nature of the leachant, type of contact-liquid/ solid etc.).

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PWR 불시정지시 냉각재화학 변화에 따른 화학제어 방향 도출

  • 성기웅;나정원;구제휴;성기방;강덕원;정홍호
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.10a
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    • pp.357-362
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    • 1997
  • PWR 원전 계획 예방정비 기간 중에는 Crud 제거를 위한 정지화학 제어가 수행되고 있으나, 불시정지시 화학제어에 대한 접근은 거의 전무하다. 이에, 정지시 냉각재화학 변화에 따른 Nickel Ferrite의 안정성에 대해 검토하고, 불시정지시 냉각재 화학제어의 방향을 도출하였다. 계획정지 화학제어가 가능한 불시정지시에는 Nickel Ferrite 용출 증대를 위한 조기 붕산화와 고농도 용존수소 (Fig. 1 참조) 유지 및 산성-산화 단계의 도입이, 적용이 불가능한 경우에는 Nickel Ferrite 용출 억제를 위한 붕산화 연기 및 용존수소의 저농도 유지가 타당할 것이다.

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Assessment of Ion Leaching and Recycling Potential of Steel Slag Mixed with Clay (점토와 혼합된 제강슬래그의 이온 용출 및 재활용 가능성 평가)

  • Hyeongjoo Kim;Hyeonki Lee;Taegew Ham;Sohee Jeong;Hyeongsoo Kim
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.5
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    • pp.39-47
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    • 2024
  • In this study, the environmental implications of electric arc furnace steel slag, commonly used in road construction and soil reinforcement, were examined. Experiments were conducted to assess the leaching of heavy metals based on particle size and to investigate ion leaching from specimens with varying mixtures of steel slag and clay. The official waste test revealed no detectable heavy metals in the sample items. However, when subjected to leaching experiments and analyzed using ICP-OES, certain heavy metals were found. The reaction of steel slag with water, facilitated by free CaO within the slag, was identified as the cause of leaching. Results showed that aluminum, exhibiting the highest leaching rate, displayed an inverse relationship with particle size. In mixed soil containing steel slag and clay, higher steel slag content resulted in increased aluminum leaching. Nonetheless, the quantity of leached aluminum was notably lower in mixed soil compared to pure steel slag. Furthermore, leaching of other heavy metals remained within acceptable limits. These findings suggest that recycling mixed soil of steel slag and clay for road construction or soil stabilization presents reduced environmental risks compared to using steel slag alone. Utilizing such mixtures could offer an environmentally sustainable and safe alternative.

The Injection Characteristics and Environmental Effects for Grouting Materials (지반주입재 종류별 주입특성 및 환경적 유해성에 관한 연구)

  • Chun, Byung-Sik;Lee, Jae-Young;Ha, Kwang-Hyun
    • Journal of the Korean GEO-environmental Society
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    • v.3 no.4
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    • pp.37-49
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    • 2002
  • In this study, it is performed that mix design of grouting materials which high strength, durability and environmentally safe materials for 2 types of suspension, solution grouting. The laboratory model tests such as permeation, solidification tests are performed to find injection effects by the injection pressure, soil condition. And environmental effects of the grouting materials is analyzed through the heavy-metal leaching tests. From the results, micro cement of suspension grouting superior permeation, solidification injection to Portland cement, and phosphoric acid and sodium hydrogen carbonate in solution grouting were similar to micro cement of suspension grouting. When compare to strength of grouted soils, micro cement of suspension grouting showed high compression strength to Portland cement. While, solution grouting showed very low compression strength comparing suspension grouting. Also, in the heavy-metal leaching tests results were satisfied with the environmental regulation standard for raw grouting materials and grouted soil by 7, 14, 28days curing.

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A Study on the Characteristics and Utilization of Ash from Sewage Sludge Incinerator (하수(下水)슬러지 소각재의 특성(特性) 평가(評價) 및 재활용(再活用)을 위한 기초연구(基礎硏究))

  • Lee, Hwa-Young
    • Resources Recycling
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    • v.17 no.3
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    • pp.3-9
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    • 2008
  • The measurement of physicochemical properties and chemical composition of SSA(sewage sludge ash) has been carried out and the preparation of lightweight material has also been performed using SSA for reuse as building or construction materials. For this aim, lightweight material has been prepared by forming the mixture of SSA, lightweight filler and inorganic binder followed by calcination at elevated temperature and characterized in terms of density and compressive strength. The pH of fly ash was found to be slightly alkaline, pH 8.69, due to the addition of caustic soda in order to neutralize the acidic gas while the pH of bottom ash was 6.48 Heavy metal leachability based on the standard leach test was also found to be below the detection limit for Cd, Cu, Pb, As and Cr of SSA. As far as the compressive strength of lightweight material was concerned, the compressive strength of lightweight material using fly ash was higher than that of lightweight material using bottom ash.

Characteristics of VOCs Adsorption of Brick Prepared by MSWI Fly Ash (소각재로 제조한 건축외장재의 VOCs 흡착 특성 평가)

  • Ban, Hyo-Jin;Jeong, Jae-A;Lee, Woo-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.857-861
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    • 2010
  • Recently photochemical smog has become a serious urban air pollution. And VOC is the major pollutant for it. With the advance of industrialization and urbanization, MSWI fly ash and sewage sludge and melting slag were generated. It is necessary to de-toxificate ashes, because they contain many toxic constituents and probably lead to contaminate the environment. The objective of this research was to prepare multi-functional brick which is able to remove VOCs in ambient air. The bricks were made of MSWI fly ash, sewage sludge and slag. The benzene adsorption experiment by brick was acted to evaluate its adsorptivity. And also photocatalyst material was coated to enhance its adsorptivity and the endurance on the brick. According to the result, the benzene showed 74~96%. The removal efficiency was increased and the breakpoint time was lengthened by coating a brick.

A Study on Lithium Leaching from the Fly Ash of Taean Electric Power Plant (태안화력발전소 비산재로부터 리튬용출연구)

  • Kim, Kang-Joo;Lee, Eun-Gyu;Lee, Jae-Cheol;Hwang, Soo-Yeon;Kim, Chang-Hyeon
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.117-122
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    • 2012
  • The leaching of Li from fly ashes was studied. The fly ash produced from the Taean electric power plant of the Korea Western Power Co., Ltd. was used for this study. The Li leaching was observed according to the changes in solid:solution ratio, solution types (seawater or deionized water), and the $CO_2$ condition in the atmosphere. The results showed that the Li concentrations in the solution increased continuously as the solid:solution ratio increased. The Li leaching per unit mass of fly ash was greater when the deionized water was used for the experiment and when the $CO_2$ dissolution is limited during the reaction because the precipitation of $CaCO_3$ is suppressed under those conditions. At high solid:solution ratio, $Mg^{2+}$, the ion preventing the Li extraction from seawater by adsorption, was effectively removed from the seawater.

Solvent Leaching Characteristics of Dark Brownish Pigment from Activated Charcoal used in Decolorization of Crude Polysaccharide from Auricularia auricula (흑목이 버섯 다당류의 탈색에 사용된 활성탄으로부터 흑갈색 색소의 용매 침출 특성)

  • Kim, Hyeon-Min;Hur, Won;Lee, Shin-Young
    • Food Engineering Progress
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    • v.13 no.4
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    • pp.262-268
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    • 2009
  • A dark brownish pigment in the crude polysaccharide from Auricularia auricula was adsorbed by activated charcoal. The leaching of the pigment adsorbed on activated charcoal and regeneration of activated charcoal used was investigated with eight kinds of solvents. The highest leaching capacity was obtained with the alkaline solution (KOH). The optimum volume of 1 M KOH solution per activated carbon was 45 mL/g, and the treatment for 10 min during single stage leaching was sufficient to achieve the leaching equilibrium. Second-order kinetic model provided the best fitting for the pigment leaching. The pigment leaching capacity of 88.9% was obtained by seven times of treatment with 1 M KOH solution at 25$^{\circ}C$, while at 95$^{\circ}C$, leaching capacity of 82.6% was achieved with single stage alone showing the significant increase of leaching capacity with increasing temperature. The regenerated activated charcoal was nearly as effective as fresh activated charcoal in pigment adsorption of crude polysaccharide from Auricularia auricula.