• Title/Summary/Keyword: 장기 내구성

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Studies on Endpoints of Toxicological Evaluation of Heavy Metals in Brachinella kugenumaensis (카드뮴과 구리에 노출된 풍년새우의 생태독성)

  • Park, Ki-Yun;Lee, Dong-Ju;Lee, Chang-Hoon;Won, Du-Hee;Lee, Won-Choel;Kwak, Inn-Sil
    • Environmental Analysis Health and Toxicology
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    • v.24 no.3
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    • pp.241-249
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    • 2009
  • Heavy metal contaminants on the aquatic environment are of interest because they can have severe effects on economy and public health. Recently, the studies for monitoring of heavy metals try to do on aquatic system to assess safety and health of ecosystem by heavy metals. Thus, biological responses were investigated on Korean fairy shrimp Branchinella kugenumaensis exposed to cadmium (Cd) or copper (Cu) for long-periods (30 days). The survival rate decreased significantly (p<0.05) on B. kugenumaensis exposed to Cd and Cu at all concentrations. Especially, the highest decrease was observed at the relatively high concentration of Cd and Cu (p<0.01) and the response by Cd exposure was at dose-dependent. The growth rates were also decreased significantly (p<0.05) on B. kugenumaensis exposed to Cd and Cu for at all concentrations. Then, the reproduction rate, numbering cyst, was decreased significantly (p<0.01) on B. kugenumaensis after Cd or Cu exposures. Long exposure of the relatively high concentration Cd and Cu can have severe effects on the reproduction, while exposures of Cd and Cu can not have effects on sex ratios of B. kugenumaensis. Additionally, asymmetric telson deformity was only observed after Cd exposure. Therefore, these results suggest that B. kugenumaensis is a sensitive bio-indicator of heavy metal exposure and these biological responses of B. kugenumaensis give important information for long-term monitoring on aquatic ecosystem.

Properties of Alkali-Activated Cement Mortar by Curing Method (양생 방법에 따른 알칼리활성 시멘트 모르타르의 특성)

  • Kim, Ji-Hoon;Lee, Jae-Kyu;Hyung, Won-Gil
    • Journal of the Korea Concrete Institute
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    • v.26 no.2
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    • pp.117-124
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    • 2014
  • Globally, there are environmental problems due to greenhouse gas emissions. $CO_2$ emissions rate of the cement industry is very high, but the continued demand of cement is needed in the future. In this study, in order to reduce the environmental impact of $CO_2$ emissions from cement production. The experiments were carried out for the development of non-sintered cement (have not undergone firing burning) by granulated ground blast furnace slag. In order to compare the characteristics by curing, an experiment was conducted by changing the curing conditions such as atmospheric steam curing, observe the mechanical properties for the measurement of flexural compressive strength by mortar, observe the chemical properties such as acid resistance, $Cl^-$ penetrate resistance and analyzed the mechanism of hydration by XRD, SEM experiments. From the experimental results, as compared with portland cement usually confirm the mechanical and chemical properties excellent, it is expected be possible to apply to the undersea, underwater and underground structures that require superior durability. In addition, based on the excellent compressive strength by steam curing, it is expected to be possible to utilize as a cement replacement material in the secondary product of concrete. In the future, to solve the problem through continued research, it will be expected to reduce the effect of environmental load and to be excellent economics.

Cyclicality of Inter-Industry Wage Gaps and Segmented Labor Market Hypotheses (산업간 임금격차의 경기변동상 변화 패턴과 분단노동시장 가설)

  • Shin, Donggyun
    • Journal of Labour Economics
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    • v.26 no.3
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    • pp.77-114
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    • 2003
  • Analyses of the special data sets constructed from the National Longitudinal Survey of Youth and the Panel Study of Income Dynamics reveal that, compared with an annual wage measure, survey week wages are significantly counter-cyclically biased due to selecting workers with strong labor market attachment. We also find that survey week wages are more counter-cyclically biased in high-wage industries than in low-wage industries, that is, inter-industry gaps of survey week wages are counter-cyclically biased. Unlike existing longitudinal studies, the current study concludes that real wages are much more procyclical in high-wage industries than in low-wage industries, which is attributed to our adoption of annual wages that is less subject to the selectivity bias. Our finding is consistent with the empirical regularity that real wages are much more procyclical for men than for women, as men are overrepresented in industries with greater real wage procyclicalities. Overall, current results do not support the predictions of segmented labor market theories for the cyclicality of real wages.

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Synthesis of Pd-decorated SiO2 layers with superhydrophobic and oleophilic micro-nano hierarchical (초소수성 및 친유성을 갖는 마이크로-나노 계층구조의 Pd 금속입자 기능화된 SiO2층 합성)

  • Kim, Jae-Hun;Lee, Jae-Hyeong;Kim, Jin-Yeong;Kim, Sang-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.67.2-67.2
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    • 2017
  • 본 연구에서는 $SiO_2$ 미세구조 상에 Pd 나노입자(NPs)를 증착하여, 불소화된 마이크로-나노 계층구조를 갖는 Pd-decorated $SiO_2$($Pd/SiO_2$)를 제작하였다. 마이크로 크기의 거칠기를 갖는 $SiO_2$ 층은 졸-겔 공정을 사용해서 제조된 용액을 전기분사함으로써 제조되었다. 이어서, 자외선(UV)을 이용한 광 환원법을 이용해 Pd 나노입자를 $SiO_2$ 층에 형성했다. 생성된 표면은 마이크로-나노의 계층구조 형태를 보여주었다. 해당 시편의 불소화 처리 후, 마이크로-나노의 계층구조 표면은 $170^{\circ}$ 이상의 물 접촉각(water contact angle; WCA) 및 $5^{\circ}$ 이하의 슬라이딩 각(sliding angle)을 보여줌으로써 물에 대해 탁월한 소수성을 나타내었다. 또한, 커피($CA=161^{\circ}$), 우유($CA=162^{\circ}$), 쥬스($CA=163^{\circ}$), 그리고 글리세롤($CA=165^{\circ}$)에 대해서도 우수한 소수 특성을 보여주었다. 또한, 이들 $Pd/SiO_2$ 층은 우수한 장기내구성 및 자외선 저항성을 보여주었다. 그리고 이어진 기름에 대한 접촉각 측정을 통해 해당 시편이 소유 특성이 아닌 친유 특성을 보여준다는 것을 확인할 수 있었고, 기름에 대한 CA는 약 ${\sim}10^{\circ}$로 매우 우수한 친유 특성을 나타내었다. 이와 같은 결과는 자체세정이 가능한 표면 및 지능형 물/기름 분리 시스템과 같은 스마트 장치에서 초소수성-친유성 특성을 갖는 계층구조의 $Pd/SiO_2$ 층을 사용할 가능성을 명확하게 보여준다고 판단된다.

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Low-costBacksheet Materials with Excellent Resistance to Chemical Degradation for Photovoltaic Modules (태양전지모듈용 고내구성 저가형 백시트)

  • Pyo, Se Youn;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.3
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    • pp.287-294
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    • 2015
  • Photovoltaic (PV) modules are environmentally friendly energy-conversion devices to generate electricity via the photovoltaic effect of semiconductors on solar energy. One of key elements in PV modules is "Backsheet," a multi-layered film to protect the devices from a variety of chemicals including water vapor. A representative Backsheet is composed of polyvinyl fluoride (PVF) and poly(ethylene terephthalate) (PET). PVF is relatively expensive, while showing excellent resistance to chemical attacks. Thus, it is necessary to develop alternatives which can lower its high production cost and guarantee lifetime applicable to practical PV modules at the same time. In this study, PET films with certain levels of crystallinity were utilized instead of PVF. Since it is well known that PET is suffering from trans-esterification and hydrolysis under a wide pH range, it is needed to understand decomposition behavior of the PET films under PV operation conditions. To evaluate their chemical decomposition behavior within a short period of times, accelerated decomposition test protocol is developed. Moreover, electrochemical long-term performances of the PV module employing the PET-based Backsheet are investigated to prove the efficacy of the proposed concept.

A Study on the Engineering Property and Durability of Recycled Concrete with Replacement Ratio of Recycled Fine Aggregate and Fly-ash (재생잔골재 및 플라이애시 대체율에 따른 재생콘크리트의 공학적 특성 및 내구성능에 관한 연구)

  • Kim, Moo-Han;Kim, Gyu-Yong;Kim, Jae-Whan;Cho, Bong-Suk;Kim, Young-Sun;Moon, Hyung-Jae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.89-97
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    • 2005
  • Recently, for the problem solution of demand and supply imbalance of fine aggregate due to the shortage of natural fine aggregate resource and the environment regulation on sea sand extraction in the construction field, the studies for the application of recycled fine aggregate using waste concrete are being progressed versatilely. On the other hand, the treatment of fly-ashes that of industrial by-product originated in the steam power plant is discussed by the continuous increasing of origination quantities. In the ease of using fly-ash, advantages are the improvement of workability, viscosity and long-time strength, and the reduction of hydration heat under the early ages, as the admixtures for concrete, but the studies for the application of fly-ash as recycled concrete admixtures are inadequacy. There fore, in this study, through investigating the properties of fresh, hardened and durability according to the replacement of recycled fine aggregate and fly-ash, it is intended to propose the fundamental data for structural application of recycled concrete using recycled fine aggregate and fly-ash. As the result of this study, they arc shown that the engineering properties and durability, in the case of replacement ratio 100% of recycled fine aggregate, arc similar to those of concrete using natural fine aggregate, so it is considered that recycled fine aggregate could be used as the fine aggregate for concrete. Also, the performances of recycled concrete are improved by replacing fly-ash.

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An Analysis of the Deep Geological Disposal Concepts Considering Spent Fuel Rods Consolidation (사용후핵연료봉 밀집을 고려한 심지층처분 개념 분석)

  • Lee, Jongyoul;Kim, Hyeona;Lee, Minsoo;Kim, Geonyoung;Choi, Heuijoo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.4
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    • pp.287-297
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    • 2014
  • For several decades, many countries operating nuclear power plants have been studying the various disposal alternatives to dispose of the spent nuclear fuel or high-level radioactive waste safely. In this paper, as a direct disposal of spent nuclear fuels for deep geological disposal concept, the rod consolidation from spent fuel assembly for the disposal efficiency was considered and analyzed. To do this, a concept of spent fuel rod consolidation was described and the related concepts of disposal canister and disposal system were reviewed. With these concepts, several thermal analyses were carried out to determine whether the most important requirement of the temperature limit for a buffer material was satisfiedin designing an engineered barrier of a deep geological disposal system. Based on the results of thermal analyses, the deposition hole distance, disposal tunnel spacing and heat release area of a disposal canister were reviewed. And the unit disposal areas for each case were calculated and the disposal efficiencies were evaluated. This evaluation showed that the rod consolidation of spent nuclear fuel had no advantages in terms of disposal efficiency. In addition, the cooling time of spent nuclear fuels from nuclear power plant were reviewed. It showed that the disposal efficiency for the consolidated spent fuel rods could be improved in the case that cooling time was 70 years or more. But, the integrity of fuels and other conditions due to the longer term storage before disposal should be analyzed.

Performance Based Evaluation of Concrete Strength and Freeze-Thaw Resistance from Wind Speed - Sunlight Exposure Time Effect (풍속과 일조시간에 따른 콘크리트의 강도 및 동결융해 저항성 성능중심평가)

  • Kim, Tae-Kyun;Choi, Seung-Jai;Choi, Ji-Hun;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.49-58
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    • 2017
  • The phenomena that we experience in everyday life such as snow, rain, wind, and temperature are referred to as weather, and the average state of atmospheric phenomena that occur over a long period of time in a specific region is referred to as climate. In addition, significant variation of climate compared to the average state is referred to as climate change. Concrete structures can have various problems when exposed to elements. Among the problems, the freeze-thaw problem due to extreme climatic factors such as heavy rain and snowfall has become a particularly significant issue recently. The concrete that has been subjected to repeated freeze-thaw rather than too high or low temperature shows serious degradation of durability, and the performance of structures with degraded performance is difficult to recover. Therefore, in this study, concrete durability performance with respect to freeze-thaw from curing conditions change due to wind speed and sunshine exposure time. Concrete freeze-thaw experiment are performed. using wind speed and sunlight exposure time. Also, performance based evaluation through the satisfaction curve based on the freeze-thaw test results are performed.

Evaluation of the Pull-out Resistance of the SMA Wire Connector (SMA 와이어를 이용한 연결재의 인발저항성능 평가)

  • Jung, Chi-Young;Woo, Tae-Ryeon;Lee, Jong-Han;Cheung, Jin-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.130-137
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    • 2019
  • Precast concrete (PC) structure is one of the type of the structures which is made in a facility prior to installing it to a construction field. The contact surfaces between two PC structures should be treated for obtaining enough binding force by inducing prestressing force. However, in the many cases, the contact surface causes the crack and leakage of water. These cracks and water leakage can cause the corrosion of the rebar, and the corrosion of the rebar can severely reduce the long-term durability. In this study, the SMA wire connector is suggested to solve the problem with the contact surfaces between two PC structures. The pull-out resistance of the suggested SMA wire connector is evaluated by conducting the tests to find the effect of the number of wires, shape of connector part, and shape memory effect. As a result of this study, the empirical formula is suggested to estimate the pull-out resistance related with the effects of the shape of the connector, shape memory effect, and the adhesive force. The validity between the estimated pull-out resistance and the measured value is confirmed.

A Study for Field Application of Environmental-friendly Waterproof Method for Riverbed (친환경 하상차수공법 현장 적용성에 관한 연구)

  • Park, Minchul;Kim, Seonggoo;Kwak, Nokyung;Shin, Hyohee;Lee, Song
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.1
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    • pp.71-80
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    • 2011
  • In period of rapid economic development, as doing river conservation work by using harmful materials environmental pollution has adversely effected humans, animals and plants frequently. For recovery of environmental pollution it needs a lot of time and cost. Therefore, in this study, in order to take an environment-friendly method which is also economical and durable both results of the laboratory model test and field test were compared and analyzed. According to the results of the laboratory model test, those methods such as concrete paving, asphalt paving, bentonite mat, stabilized soil method and mixed soil method have small amount of seepage, but on the other hand compaction soil, grassland and permeable materials have considerable amount of seepage. The results of field test show a similar tendency with laboratory test and have been satisfied to assess standard of domestic water permeability below $1.0{\times}10^{-7}cm/sec$ and unconfined compressive strength is also than 1.0MPa so it has been satisfied about standard. In conclusion, as compaction rate increased, as unconfined compression strength increased and coefficient of permeability decreased.