• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.488-495
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• 2017

In this study, we conducted the kinetic hydration modeling of OPC and the final product according to the substitution ratio of GGBS by using the geochemical code, GEMS, in order to calculate the thermodynamic equilibrium. The thermodynamic data was used by GEMS's 3rd party database, Cemdata18, and the cement hydration model, the Parrot & Killoh model was applied to simulate the hydration process. In OPC modeling, ion concentration of pore solution and hydration products by mass and volume were observed according to time. In the GGBS modeling, as the substitution rate increases, the amount of C-S-H, which contributes the long-term strength, increases, but the amount of Portlandite decreases, which leads to carbonation and steel corrosion. Therefore, it is necessary to establish prevention of some deterioration.

• Proceedings of the KSR Conference
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• 2007.11a
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• pp.1267-1272
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• 2007

In the case of the railway bridge, there are following the progress of works after the drainage method of a bridge surface - vibration proof rubber establishment, track gravel construction and rail construction etc. But these works are not enforced consecutively by the execution and economical reason. This is the reason of the long period of exposure after drainage execution. In many case, from the deterioration phenomenon by long term exposure of surface, there are a lot of occasions that do not keep primitive penetration depth waterproof primitive time. It is the most important that select the drainage method that have durability - it is not fallen in long-term exposure of surface. The major objective of this study is to deduce objective analysis result through examination about the Deterioration Restraining Agent method and to master KNOW-HOW of DRA drainage method. Through the study, minimize economical damage by frequent repair and reinforcement and present the reasonable standard of judgement fot drainage method of construction.

• Tunnel and Underground Space
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• v.14 no.1
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• pp.1-15
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• 2004

The development of high-performance shotcrete lining is essential in improving the long-term durability of tunnels and in introducing single-shell tunnelling methods, where shotcrete as well as rockbolts are used as permanent support members. In this paper, new and advanced admixtures to improve shotcrete performance are introduced. In addition, requirements for mechanical properties as well as test items for quality control of shotcrete are summarized. A case study on the application of the pneumatic pin penetration test which can estimate compressive strength of shotcrete more easily and quickly is also illustrated. Previous studies to analyze the behaviors of shotcrete lining by considering its transient hardening and to carry out the sensitivity analysis of the design parameters of shotcrete lining are discussed to give fundamental concepts on rock-support interactions. Representative single-shell tunnelling methods where high-performance shotcrete lining is applied as a permanent support are also introduced.

• International Journal of Highway Engineering
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• v.18 no.1
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• pp.63-72
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• 2016

PURPOSES : The use of roller-compacted concrete pavement (RCCP) is an environmentally friendly method of construction that utilizes the aggregate interlock effect by means of a hydration reaction and roller compacting, demonstrating a superb structural performance with a relatively small unit water content and unit cement content. However, even if an excellent structural performance was secured through a previous study, the verification research on the environmental load and long-term durability was conducted under unsatisfactory conditions. In order to secure longterm durability, the construction of an appropriate internal air-void structure is required. In this study, a method of improving the long-term durability of RCCP will be suggested by analyzing the internal air-void structure and relevant durability of roller-compacted concrete. METHODS : The method of improving the long-term durability involves measurements of the air content, air voids, and air-spacing factor in RCCP that experiences a change in terms of the kind of air-entraining agent and chemical admixture proportions. This test should be conducted on the basis of test criteria such as ASTM C 457, 672, and KS F 2456. RESULTS : Freezing, thawing, and scaling resistance tests of roller compacted concrete without a chemical admixture showed that it was weak. However, as a result of conducting air entraining (AE) with an AE agent, a large amount of air was distributed with a range of 2~3%, and an air void spacing factor ranging from 200 to $300{\mu}m$ (close to $250{\mu}m$) coming from PCA was secured. Accordingly, the freezing and thawing resistance was improved, with a relative dynamic elastic modulus of more than 80%, and the scaling resistance was improved under the appropriate AE agent content rate. CONCLUSIONS : The long-term durability of RCCP has a direct relationship with the air-void spacing factor, and it can be secured only by ensuring the air void spacing factor through air entraining with the inclusion of an AE agent.

• Membrane Journal
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• v.25 no.5
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• pp.385-390
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• 2015

To determine the pervaporation separation characteristics of IPA/water mixtures, PEI/PDMS hollow fiber membrane module commercialized by Airrane Co. was subjected to both lab and pilot tests. The flux of $0.52kg/m^2h$ and IPA concentration of 68.5% at $25^{\circ}C$ were obtained whereas the $1.368kg/m^2h$ and 61.2% were measured at $55^{\circ}C$. In order to realized the durability of the module, the long-term test (at $50^{\circ}C$) of 100 days has been conducted and as a result, the flux $1.03{\sim}1.15kg/m^2h$ and IPA concentration 61.8~62.5% were maintained with the initial values.

• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.20-24
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• 2022

In the process of long-term use of PEMFC (Proton Exchange Membrane Fuel Cells), chemical degradation of membrane electrode assembly (MEA) occurs due to corrosion of stack elements and contamination of supply gas. In this study, we investigated whether chemically degraded MEA can be recovered by acid washing. The performance was measured and compared in a PEMFC cell after contamination with iron ions and washing with an aqueous sulfuric acid solution. The performance was reduced by about 25% by 0.5 ppm iron ion contamination, and 97.1% performance recovery was possible by washing of 0.15 M sulfuric acid. The membrane resistance was increased due to iron ion contamination of the polymer membrane, and the ionic conductivity was restored by washing the iron ions from the membrane while minimizing the loss of the electrode catalyst by washing with a low-concentration sulfuric acid aqueous solution. The possibility of solving the decrease in durability caused by chemical contamination of PEMFC MEA by the acid washing was confirmed.

• Membrane Journal
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• v.32 no.6
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• pp.496-513
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• 2022

In this study, we sought to verify the applicability of anion exchange membrane water electrolysis system using FAA-3-50, Neosepta-ASE, Sustainion grade T, and Fujifilm type 10, which are commercial anion exchange membranes. The morphology of the commercial membranes and the elements on the surface were analyzed using SEM/EDX to confirm the distribution of functional groups included in the commercial membranes. In addition, mechanical strength and decomposition temperature were measured using UTM and TGA to check whether the driving conditions of the water electrolyte were satisfied. The ion exchange capacity and ion conductivity were measured to understand the performance of anion exchange membranes, and the alkaline resistance of each commercial membrane was checked and durability test was performed because they were driven in an alkaline environment. Finally, a membrane-electrode assembly was manufactured and a water electrolysis single cell test was performed to confirm cell performance at 60℃, 70℃, and 80℃. The long-term cell test was measured 20 cycles at other temperatures to compare water electrolysis performance.

• The Journal of the Korea institute of electronic communication sciences
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• v.18 no.3
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• pp.397-404
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• 2023

This paper designs a wind turbine test site based on international regulations for the certification of wind turbine prototypes. The maximum height of the meteorological mast installed at the test site is 140m, and power facilities capable of testing up to three wind turbines of 5MW or more are installed. The weather resources measured at the mast can be recorded and analyzed using a monitoring system. Wind turbine manufacturers can use this test site during the certification period, and the installed wind turbines can be used for continuous power generation projects. Therefore, this test site can provide fundamental data for measuring the long-term performance and durability of wind turbines, which can be used to improve models or develop new wind turbines.

• Journal of Korean Tunnelling and Underground Space Association
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• v.11 no.4
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• pp.387-394
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• 2009

The objective of this study is to evaluate the durability and deterioration of concrete lining in the seven conventional tunnels. These tunnels were constructed about 40~70 years ago, and closed about 10~40 years ago. The field investigation and various laboratory testings were performed for this study. It was observed from the visual, examinations that the concrete linings of 7 tunnels were severely deteriorated, such as, cracks, leakages, desquamation, and exploitations. The compressive strengths obtained from rebound hardness method and uniaxial compressive strength test on core specimens largely differed depending on the locations in the tunnel. The maximum compressive strength of concrete lining was greater about 2 times than the minimum compressive strength of concrete lining in the same tunnel. The results of micro-structural analysis showed that the substances deteriorating the concrete lining, such as ettringite and thaumasite, were detected in the concrete lining of tunnel.

• Membrane Journal
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• v.33 no.3
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• pp.127-136
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• 2023

In this study, the electrochemical performance of a 5-layer fuel cell stack using silica composite membranes as polymer electrolyte membranes was evaluated. It was observed that the flow rate of the fuel gases plays a crucial role in stack performance, particularly being mainly dependent on the flow rate of hydrogen. Increasing the flow rate of oxygen resulted in negligible changes in performance, whereas an increase in the flow rate of hydrogen demonstrated performance improvements. However, this led to an imbalance in the ratio of hydrogen to oxygen flow rates, causing significant degradation in stack performance and durability. A decline in stack performance was also observed over time due to the degradation of stack components. This phenomenon was consistently observed in individual unit cells. Based on these findings, it was emphasized that, in addition to optimizing the performance of each component during stack operation, it is important to optimize design and operating conditions for uniform flow rate control. Lastly, the developed silica composite membrane was assessed to have sufficient performance for application in actual fuel cell systems, exhibiting a performance of over 25 W based on maximum power.