• Solar Energy
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• v.11 no.3
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• pp.53-61
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• 1991

In this research, Octacosane($C_{28}H_{58}$) and Sodium Acetate Trihydrate($CH_3COONa{\cdot}3H_2O$) were selected as latent heat storage materials to store off-peak electricity or waste heat of an industrial plant. Experimental analyses were performed in terms of the variation of phase change temperature and latent heat, phase change stability for the long term utilization. The results were as follows. 1. The phase change temperatures of industrial grade Octacosane and Sodium Acetate Trihydrate were $60.7^{\circ}C$ and $57.4^{\circ}C$, the latent heat were 60.6kcal/kg and 51.1kcal/kg respectively. 2. The latent heat quantity of Octacosane was decreased with the increasing number of phase change cycles. It decreased from 60.6kcal/kg to 47.2kcal/kg upto 200 cycles and then no variation was observed after 200 cycles. 3. To prevent the supercooling of Sodium Acetate Trihydrate, the nucleating agent, Sodium Pyrophosphate Decahydrate of 3 wt% was added, and then the supercooling temperature (Tm-Tsc) was decreased from $25.7^{\circ}C$ to $1^{\circ}C$. The phase separation was disappeared by the addition of CMC-Na of 3 wt% as a thickener. It was found that the optimal quantity of nucleating agent and thickener was 4wt% considering the stability of SAT as a latent heat storage material. 4. The phase change temperature of Sodium Acetate Trihydrate($CH_3COONa{\cdot}3H_2O$) was adjusted from 57.4 to $46.2^{\circ}C$ by the addition of UREA. And then the latent heat quantity was decreased from 51.1 to 38.3kcal/kg. 5. When the heat storage capacities between the sensible and latent heat storage materials were analyzed and compared in heating process from 30 to $90^{\circ}C$, the heat storage capacity of Octacosane was 2.45 times larger than water and 12.5 times than granite at $60.7^{\circ}C$, and the heat storage capacity of Sodium Acetate Trihydrate was 2.53 times larger than water and 12.91 times than granite at $57.4^{\circ}C$.

• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 2001.04b
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• pp.31-33
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• 2001

잠열축열 그린하우스 난방 시스템의 난방특성을 분석하기 위하여 이에 대한 열평형 이론을 정립하고 수치해석에 의하여 컴퓨터 시뮬레이션 모델을 개발하고자 잠열축열 그린하우스 난방 시스템의 열저항 회로망을 구성하였다. 그리고 그린하우스의 피복재, 내부 공기, 토양표면, 잠열 축열재와의 열평형 방정식을 구성하였으며, Newton-Raphson반복법을 이용하여 수치해석을 하였고, 실험 분석을 통하여 수치해의 타당성을 검증하였다. 시뮬레이션 모델을 위하여 C언어를 사용하였으며, 겨울철 (11월-2월)의 기후 조건이 유사한 여러 날을 선정하여 온도, 태양강도, 상대습도, 토양 수분함량 등을 자료로 하여 모델링을 하였다. 여기에 사용된 토양 조건은 사양토로 건조한 상태를 유지하였다. 이상과 같은 분석에 의하여 그린하우스내 경시적 공기온도 변화와 열전달 현상의 실험치와 이론분석 결과가 잘 일치하고 있음을 알 수 있었다.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2011.06a
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• pp.207-207
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• 2011

본 논문은 공장 등에서 버려지는 중온온도영역($100{\sim}250^{\circ}C$)에서의 패열을 잠열축열 시스템에서 유용하게 사용을 목적으로 잠열축열재인 에리스리톨와 만니톨 그리고 이것들을 혼합한 혼합물에 대한 조사에 관한 것이다. 또한, 만니톨에 에리스리톨을 첨가하는 것에 의해 융해 응고온도가 조정의 가능성에 대해서도 조사한다. 이때 에리스리톨과 만니톨 그리고 이것들의 혼합물의 융점과 잠열량은 시차주사열량계(DSC)를 이용하여 측정되며, 시험관안에 상변화물질을 충전하여 융해 응고거동을 디지털 카메라를 이용하여 관찰 된다. DSC측정결과에서는 만니톨의 함유량이 50~60mass%에서는 3개의 융점, 70~90mass%에서는 2개의 융점을 나타내는 것을 확인할 수 있었다. 또한 시험관을 이용한 실험결과에서는 만니톨의 함유량에 따라서 각 각 다른 융해 응고거동이 일어나는 것을 확인할 수 있었다.

• Journal of the Korean Solar Energy Society
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• v.33 no.3
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• pp.9-16
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• 2013

In this research, the effect of a heating system, which is powered by direct solar energy accumulated in phase change material (PCM) as heat storage material installed on the floor surface, on the cooling load was studied. Cooling load of a test building designed for this research was measured with fan coil unit and factors affecting it were also estimated. Experiments were performed with and without PCM installed on the building floor to understand the effect of the PCM on the cooling load. Additionally, to confirm the experiments results, the prediction calculation formula by average outside temperature and integrated solar radiation was composed using multivariate regression model. The results suggested that the heating system with PCM on the floor surface has the potential to shift electric power peak by radiating heat, stored during the daytime in it, at night, not increasing the total cooling load much.

• Solar Energy
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• v.17 no.2
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• pp.67-74
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• 1997

Spherical shape of phase change material(PCM) has been prepared by using sodium acetate trihydrate as a latent heat storage medium. Gelatin was used as an effective thickener to prevent undesirable phase separation. Sodium pyrophosphate decahydrate was used as nucleator to decrease the degree of supercooling in the thickened phase change material. Spherical PCM particles of 3-3.5 mm in diameter continuously manufactured with molten PCM with those conditions. The particle size of PCM was not affected by the effluent velocity of molten PCM in range of 1.3-1.8 ml/min. DSC, SEM and XRD were also used to characterize the properties of PCM particles.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.522-526
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• 2010

Heat storage application techniques can be categorized into the sensible heat storage and the latent heat storage according to the method of heat storage. Heat storage is the way of saving remaining heat when heating and cooling loads are light, and then using it when the heating and cooling loads are heavy. Latent heat storage is defined as the method of saving heat by using substances which have high potential heat when phase change is in the range of a certain temperature and when heat storage space is small, compared to those of sensible heat storage and it is possible that absorption and emission of heat at a certain temperature. This study is conducted to save energy when either air-conditioning or heating is operated in a building. We have tried to find out the essential properties of matter and the optimum mixing rate about cement and gypsum for building materials, which have been widely used for proper phase change materials (PCM), when thermal environment property is applied. So we obtained the result of the cooling delay effect about 19% with heat storage mortar containing 3 wt% of PCM.

• Solar Energy
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• v.15 no.1
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• pp.13-28
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• 1995

In this study, the history of Korean traditional Ondol was investigated and the latent heat materials and bioceramics were selected to develop the latent heat storage-bioceramics Ondol system based on the Korean traditional Ondol(sensible heat storage type), and the thermal characteristics of Ondol were analyzed experimentally The results could be summarized as follows; 1. Korean traditional Ondol has been originated in "Whaduk" which had been utilized continuously for about $2{\times}10^6$ years from the Old Stone Age to the Bronze Age, and Korean traditional Ondol using in these days has been utilized for about 976 years from the Koryu Dynasty to the Modern Ages. 2. $Na_2SO_4{\cdot}10H_2O(SSD)$ was selected as latent heat material for the latent heat storage Ondol. 3. Ondol unit was filled with the latent heat material of 0.63 kg and the dimension of Ondol unit was $400mm{\times}400mm{\times}27mm(width{\t\imes}depth{\times}height)$. 4. The comfortable surface temperature($23{\sim}29^{\circ}C$) of the latent heat storage Ondol was lasted 5 hours at the room temperature of $16{\sim}18^{\circ}C$, whereas that of sensible heat storage Ondol was lasted only 1.0 hours in the same conditions. 5. For the thermal effect of bioceramics, the Ondol air temperature i.n case of bioceramics treatment on the pannel was higher than that of without bioceramics treatment.

• Solar Energy
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• v.15 no.2
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• pp.13-24
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• 1995

Korean traditional Ondol with the sensible heat storage medium has been for a long time used as residential heating system, in these days the concrete Ondol without the heat storage medium was realized as the heating system in the private houses and the apartments. This floor heating system is good for our health. But the concrete Ondol is not desirable for the energy saving and for the maintenance of comfortable room temperature because the heat storage medium is not employed in the concrete Ondol. And as the hot water circulating pipes are buried under the concrete floor, the concrete Ondol system has some kind of problems to be improved. Therefore the new type of Ondol system was developed in this study. And the new Ondol was consisted of latent heat storage material as heat storage medium with a great heat capacity and bioceramics as medium to maintain comfortable room temperature. In this study, the heat transfer characteristics of latent heat storage-bioceramic Ondol was analyzed theoretically.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.570-574
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• 2010

The main function of conventional insulation materials is only to block the heat transfer and reduce heat loss from the building. On the other hand, thermal storage materials can work as an energy saver by absorbing or emitting heat within a specific temperature range. Thermal storage materials for building can maintain a constant temperature by effectively regulating the cycle of indoor temperature. As a result, we can enhance the performance of a cooling and heating system efficiently. In this study, phase change materials (PCMs) were added as thermal storage materials into gypsum boards which are extensively used for building material and we found out the thermal environmental characteristics. In addition, we checked out some problems when applying the thermal storage materials to buildings. Finally, This study set out to examine the degree of environmental-friendly characteristics of thermal storage building materials by analyzing the amount of TVOC and HCHO contents with the possibility of pollutants emission.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.1
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• pp.17-25
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• 2013

Thermal storage technology used for indoor heating and cooling to maintain a constant temperature for a long period of time has an advantage of raising energy use efficiency. This, the phase changing material, which utilizes heat storage properties of the substances, capsulizes substances that melt at a constant temperature. This is applied to construction materials to block or save energy due to heat storage and heat protection during the process in which substances melt or freeze according to the indoor or outdoor temperature. The micro-encapsulation method is used to create thermal storage from phase changing material. This method can be broadly classified in 3 ways: chemical method, physical and chemical method and physical and mechanical method. In the physical and chemical method, a wet process using the micro-encapsulation process utilized. This process emulsifies the core material in a solvent then coats the monomer polymer on the wall of the emulsion to harden it. In this process, a surfactant is utilized to enhance the performance of the emulsion of the core material and the coating of the wall monomer. The performance of the micro-encapsulation, especially the coating thickness of the wall material and the uniformity of the coating, is largely dependent on the characteristics of the surfactant. This research compares the performance of the micro-capsules and heat storage for product according to molecular mass and concentration of the surfactant, SSMA (sulfonated styrene-maleic anhydride), when it comes to micro-encapsulation through interfacial polymerization, in which Dodecan-1 is transformed to melamin resin, a heat storage material using phase changing properties. In addition, the thickness of the micro-encapsulation wall material and residual melamine were reduced by adjusting the concentration of melamin resin microcapsules.