• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.132-132
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• 2012

압력 $10^{-9}$ Torr 이하의 초고진공(ultrahigh vacuum) 영역에서의 압력 측정에는 수 mA의 열전자로 잔류 가스를 이온화시켜 그 이온 전류를 측정하는 이온게이지를 주로 사용한다. 압력이 $10^{-12}$ Torr영역 이하인 극고진공(extreme high vacuum: XHV) 영역에 진입하면, ESD (electron stimulated desorption) 효과 등에 의한 이온 게이지 자체의 가스방출률이 커져 정확한 압력 측정이 곤란해 진다. 극고진공 영역에서 이온 게이지는 수 와트(W) 이상의 전력을 사용하여 수 mA의 열전자를 방출시키나, 신호인 이온 전류의 양은 1pA 이하이기 때문에 열전자에 의해 발생되는 백그라운드 전류에 묻혀 신호 전류가 측정되지 않는다고 할 수 있다. 100 nm 이하의 곡률을 가진 뾰족한 금속 탐침에 강한 전기장을 걸어주면 고체 내부의 전자가 터널링 효과에 의해 진공 중으로 방출되며, 이를 전계방출(Field Electron Emission) 효과라 부른다. 전계 방출 전류량은 탐침 표면의 일함수에 의존하며, 일함수가 클수록 지수함수 적으로 감소한다. 금속 표면에 진공 중의 잔류 가스가 부착하면 일함수가 증가한다. 가열에 의해 전계방출 탐침의 표면을 세정한 후에 전자 빔을 방출 시키면, 표면에 가스 분자가 흡착하여 방출 전류량은 점점 감소한다. 감소 속도는 압력에 비례하며, W(310) 탐침의 경우 $10^{-10}$ Torr 영역에서는 수분만에 최초 전류값의 1% 이하로 감소한다. 전계방출 전류의 감소속도가 압력에 비례하는 현상을 이용하여 압력을 측정하였다. Extractor Ionization Gauge 측정값 $5{\times}10^{-12}-3{\times}10^{-10}$ Torr의 범위에서 (111) 방향으로 정렬된 텅스텐 단결정 탐침을 사용하여 방출전류의 로그값을 시간의 함수로 semilog그래프를 그리면, 그래프는 직선을 그리며 그 기울기가 압력에 비례함을 알 수 있었다. 기울기 값과 게이지 측정값은 $10^{-11}{\sim}10^{-10}$ Torr 영역에서 거의 완벽한 비례관계를 보여주었으나, $10^{-12}$ Torr 영역에서 게이지 측정값은 기울기 값에서 추출한 압력치보다 높은 값을 보여주었으며, 이는 게이지 백그라운드 전류에 의한 차이라고 생각된다. W (310) 탐침의 방출전류는 그 감소속도가 W (111) 탐침과 마찬가지로 압력에 비례하였으나, 전류-시간 그래프는 가열 세정 직후에 전류가 거의 감소하지 않는 $2{\times}10^{-10}$ Torr에서 약 10분간 지속되는 '안정 영역'이 존재함을 보여주었다. '안정 영역'은 $10^{-11}$ Torr 영역에서는 수십분, $10^{-12}$ Torr 영역에서는 수시간 이상으로 증가하였다. 초-극고진공 영역에서의 잔류가스 주성분인 수소에서 물, 일산화탄소등의 가스로 바뀌면 '안정 영역'은 사라졌고, 이는 '안정 영역'이 수소 흡착에 의해서만 나타나는 고유 현상임을 말해준다.

• Journal of the Korean Society of Food Science and Nutrition
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• v.38 no.5
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• pp.601-604
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• 2009

This study was conducted to examine the effect of aqueous chlorine dioxide treatment as a washing method on removal of pesticide residues. Three pesticides of chlorpyrifos, diazinon, and metalaxyl, which are commonly used in vegetable crops, were treated with 10, 50, and 100 ppm of aqueous chlorine dioxide and decomposition of the pesticides was determined using gas chromatography. Three pesticides used in this study were decomposed by aqueous chlorine dioxide treatment and removal rate was proportional to treatment time as well as concentration of aqueous chlorine dioxide. In particular, 100 ppm of aqueous chlorine dioxide treatment decreased the pesticides efficiently. In addition, lettuce was treated by dipping in distilled water and 100 ppm aqueous chlorine dioxide, respectively, and was compared regarding removal efficiency of the pesticides. The results revealed that washing with 100 ppm aqueous chlorine dioxide for 10 min was the most effective for removing the pesticides. These results suggest that aqueous chlorine dioxide can be used as a washing method of fresh produce to remove the residual of pesticides.

• Journal of Food Hygiene and Safety
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• v.34 no.3
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• pp.227-234
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• 2019

An analytical method was developed for the determination of oxytetracycline in agricultural products using the QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) method by liquid chromatography-tandem mass spectrometry (LC-MS/MS). After the samples were extracted with methanol, the extracts were adjusted to pH 4 by formic acid and sodium chloride was added to remove water. Dispersive solid phase extraction (d-SPE) cleanup was carried out using $MgSO_4$ (anhydrous magnesium sulfate), PSA (primary secondary amine), $C_{18}$ (octadecyl) and GCB (graphitized carbon black). The analytes were quantified and confirmed with LC-MS/MS using ESI (electrospray ionization) in positive ion MRM (multiple reaction monitoring) mode. The matrix-matched calibration curves were constructed using six levels ($0.001{\sim}0.25{\mu}g/mL$) and coefficient of determination ($r^2$) was above 0.99. Recovery results at three concentrations (LOQ, $10{\times}LOQ$, and $50{\times}LOQ$, n=5) were from 80.0 to 108.2% with relative standard deviations (RSDs) less than of 11.4%. For inter-laboratory validation, the average recovery was in the range of 83.5~103.2% and the coefficient of variation (CV) was below 14.1%. All results satisfied the criteria ranges requested in the Codex guidelines (CAC/GL 40-1993, 2003) and the Food Safety Evaluation Department guidelines (2016). The proposed analytical method was accurate, effective and sensitive for oxytetracycline determination in agricultural commodities. This study could be useful for safety management of oxytetracycline residues in agricultural products.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.62-62
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• 2009

석탄화력발전소의 CO2배출량 감소와 고효율, 대용량화로 인해 초초임계압(USC:Ultra Super Critical) 화력발전소의 건설이 증가하고 있다. USC 발전소는 효율향상을 위한 증기온도와 압력의 상승 때문에 보일러 고온고압부에 기존의 소재에 비해 고온강도와 내산화성의 재료물성이 향상된 신소재 적용이 불가피하다. 특히 사용된 신소재 중에서 보일러 본체를 구성하는 수냉벽관(Water wall), 과열기와, 재열기용 튜브 및 후육부인 헤더와 배관재로 기존의 2.25Cr-1Mo강을 개량한 2.25Cr-1.6W계 내열강이 적용되고 있다. 2.25Cr-1.6W강은 SMI와 MHI가 공동개발한 소재로 1995년 튜브제품이, 1999년에 단조, 파이프재, 플레이트제품이 ASME code case로 등재되었고, 2009년 ASME code case 2199-4로 개정되어 사용 중이다. 이 소재는 2.25Cr-1Mo강에 고온강도 개선을 위해 석출강화효과가 있는 V과 Nb을 첨가하였고, 탄화물의 열적안정성과 고용강화효과 증대를 위해 W을 첨가하였다. 그리고 제작성과 용접성 및 재료의 인성 향상을 위해 B첨가와 C함량을 낮추었다. 합금성분의 첨가와 조정에 의해 고온강도는 개선되었지만, 보일러 설치 및 보수를 위한 용접과정에서 용접금속과 CGHAZ(Coarse Grain HAZ)에서 용접균열이 발생하였다. 대부분의 용접균열은 용접결함이나 고온 혹은 저온균열이 아닌 2.25Cr-1.6W계강의 강도 개선을 위해 첨가한 V과 Nb이 용접후열처리 도중 입내에 MX형태의 미세석출로 입내를 강화시킴으로서 발생한 재열균열 민감성 증대에 기인된 것으로 판단된다. 이에 본 연구에서 용접 및 후열처리 과정에서 용접금속과 HAZ에서 발생하는 용접금속의 응력분포를 전산해석을 통해 확인하고 실제 후육파이프 용접부에서 잔류응력을 측정해 비교하였다. 용접부 응력분포는 SYSWELD 프로그램을 사용해 해석을 수행하였고, 발전소 실배관재의 용접부 응력측정은 수평부 측정이 용이하도록 지그를 부착한 Potable 잔류응력측정기를 사용해 Hole Drilling Method(HDM)를 적용하여 잔류응력을 측정하였다. 해석 결과 CGHAZ부위의 잔류응력이 용접금속과 기타 부위에 비해 높은 응력분포를 나타냈으며, 이는 CGHAZ와 용접용융선 부근에서 균열이 발생하는 실제값과 일치하는 결과를 보였다. 실제 배관재 용접부에서 측정한 잔류응력값은 항복응력의 약 50% 이하 응력값을 나타냈다. 배관 구조에 기인한 시스템응력의 영향을 제거하기 위해 배관재 용접부를 중심으로 양끝단을 절단 후 용접부에서 측정한 응력은 항복응력 대비 25%수준의 낮은값을 보였다. 그러나 배관재가 장기간 고온환경에 노출되었고 용접금속 내부의 균열이 발생한 상태에서 측정하였기 때문에 용접잔류응력은 상당부분 해소되어 상대적으로 낮은 응력값이 얻어진 것으로 판단된다.

• Korean Journal of Environmental Agriculture
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• v.16 no.3
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• pp.255-258
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• 1997

In order to determine the removal efficiency of pesticide residues on apples by ultrasonic cleaner, apples(Fuji var.) were artificially treated by dipping in water solution of fenitrothion EC, chlorpyrifos EC and phenthoate EC. The treated apples were washed by the ultrasonic cleaner with water, 30% ethanol solution or 0.2% detergent solution, respectively. The removal efficiency of fenitrothion, chlorpyrifos and phent-hoate by ultrasonicated washing in water for 0.5min. was 39.2%, 32.0% and 50.4%, respectively, but there was a tendency to decrease the removal efficiency of the pesticide residues as the duration of ultrasonicated washing period is increased. The maximum removal efficiency of the pesticide residues washed in the detergent solution was observed by ultrasonicated washing the samples for 5min. and it was recorded as 33.5% ; fenitrothion, 30.1% ; chlorpyrifos and 48.3% ; phenthoate, respectively. However it's appeared that the longer the ultrasonicated washing period in 30% ethanol solution the more pesticides from the apples were removed and the maximum removal efficiency of the pesticides was recorded as 66.2%(fenitrothion ; washed for 15min.), 41.7%(chlorpyrifos ; washed for 10min.), 74.2%(phenthoate ; washed for 10min.).

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.100-100
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• 2009

This paper is concerned with numerical analyses of residual stresses in welds and material's susceptibility to stress corrosion cracking (SCC) for the primary piping system in nuclear power plants: Both the dissimilar metal weld (DMW) for stainless steel to low alloy steel joints and the similar metal weld (SMW) for forged stainless steel to cast stainless steel joints are considered. Thermal elasto-plastic analyses using the finite element method (FEM) are performed to predict residual stresses generated in fabrication welding and its related processes for both the DMW and SMW, including effects of quenching for cast stainless steel piping, machining of the DMW root, and grinding of the SMW root. As a result, the effect of quenching should be included in the evaluation of residual stresses in the SMW for the cast stainless steel piping. It is deemed that residual stresses in both the DMW and SMW would not affect the SCC susceptibility of the welds providing that the welding processes are completed without any weld repair on the inside wall of the joint. However, the grinding process if performed on the safe-end to piping weld, would produce a high level of residual stresses in the inner surface region and thus a stress improvement process (e.g. buffing) should be considered to reduce susceptibilities to SCC.

• Korean Journal of Food Science and Technology
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• v.40 no.3
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• pp.265-270
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• 2008

This study examined the effects of treating green tea leaves with ozonated water by evaluating pesticide residue levels and catechin content. The pesticide residue levels of tea leaves treated with carbendazim, captain, diazinon, fenthim, dichlorvos, and chlorpyrifos ranged from 43.2 to 48.2 ppm. For leaves treated by soaking or watering with tap water, or with 0.25 ppm of ozone water for 30 min. Pesticide residue levels were reduced by 24.0-30.2%, 30.3-33.6%, 52.4-70.5%, and 65.5-80.2%, respectively. No major differences in catechin content were observed in the leaves according to the soaking and rinsing treatments using ozonated or tap water.

• Journal of Applied Biological Chemistry
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• v.63 no.1
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• pp.51-60
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• 2020

This study was conducted to investigate changes in pesticide residues in eggplant and lettuce during washing and cooking processes after application with azoxystrobin. Eggplant was processed with running washing, steaming, and stir-frying, and lettuce was processed with soaking washing, running washing, soaking and running washing, ultrasonic cleaning, and blanching. The limit of quantitation of GC analysis of azoxystrobin was 0.01 mg/kg and the recovery rate was 84.7-109.5%. The azoxystrobin processing factors (PFs) and reduction rates in eggplant and lettuce were calculated and the results were as follows. In the case of eggplant, the azoxystrobin PF and reduction rate of running washing were 0.29 and 71.1%, respectively, those of steaming were 0.32 and 68.0%, respectively, and those of stir-frying were 0.24 and 75.7%, respectively. In the case of lettuce, the azoxystrobin PF and reduction rate of soaking washing were 0.25, 75.3%, those of running washing were 0.61 and 38.9%, respectively, those of soaking and running washing were 0.32, 68.0%, those of ultrasonic cleaning were 0.47 and 53.1%, respectively, and those of blanching were 0.26 and 73.6%, respectively. It could be identified that pesticide residues in eggplant and lettuce can be effectively reduced through washing and cooking processes and that most of pesticide residues were removed when cooking processes were undergone after washing. Therefore, azoxystrobin PFs after washing and processing can be provided as basic data for risk assessment.

• Journal of the Korean Magnetics Society
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• v.14 no.4
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• pp.143-148
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• 2004

Effects of residual flux density M$_{res}$ and number of inspection on the detection voltage and flux density B of the gas pipeline were investigated in MFL inspection, which is widely used for the non-destructive inspection in a gas pipeline. A simulation equipment composed of the magnetizer and iron ring attached on an aluminum disc was constructed instead of a huge gas pipeline facility. With this system. the iron ring could be perfectly demagnetized and signals from the bolt screw stuck on the disc could be clearly detected so that the effects of M$_{res}$S and the inspection number on the detection voltage and B of iron ring were effectively investigated. With increasing the number of inspection, M$_{res}$, B of the iron ring and the detection voltage decreased and then kept at constant values while final M$_{res}$ increased with increasing initial M$_{res}$. If inspection condition were kept unchanged, the detection voltage was proportional to the last M$_{res}$ of the iron ring instead of B. This was probably due to magnetic hysteresis of the iron ring inherited from magnetic domain so that consideration on the magnetic hysteresis was inevitable in the analysis of MFL signal from defects of a gas pipeline. A new inspection scheme using the magnetizer with reversed magnetization in the subsequent inspection was proposed from the result that a high detection voltage could be obtained in the first inspection of gas pipeline with positive M$_{res}$.

• Journal of Food Hygiene and Safety
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• v.25 no.4
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• pp.346-353
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• 2010

This study was conducted to determine cleaning effects of environmental-friendly washing detergent on milking installation in dairy farms. Milking machine, cooling machine and milking liner were washed by alkaline detergent and acid detergent for first three weeks and alkaline detergent and environmental~friendly detergent for next three weeks and the results get through microorganism and physico-chemistry analysis at the five district dairy farms different from environment. E-coli, coliform, fecal coliform, staphylococcus aureus, fecal streptococcus, prsudomonas aeruginosa and yersinia were not found in all of the dairy farms, and total colony counts were no difference compared with chemical detergent. The water for washing exceeded the determining acceptable level of nitrate nitrogen in the Anseong, Onyang and Cheonan and the remaining substance of washed water was also high levels. The cause of the result was that the level of nitrate nitrogen of water is basically high. Therefore, this study indicated that washing effect is no differences between environmental-friendly detergent and chemical detergent by washing for milking machine and cooling machine. Above all, producing high quality milk is to manage the water quality as well as using detergent.