• Title/Summary/Keyword: 잔류특성

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열무 중 살충제의 잔류농약 분해 특성 연구

  • 김준형;서혜영;최근영;정양모;박순연;김관수;최택열;손길선;김경수
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.10a
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    • pp.150.1-150
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    • 2003
  • 열무의 안전한 생산을 위한 생산단계에서의 각 농약 잔류량 변화 추이와 최종 소비단계에서의 농산물 안전성 평가자료로 활용하기 위하여 실제 시험포장에 열무를 파종한 후 수확 10일 전에 4 종(diazinon, endosulfan, cypermethrin, cyhalothrin)의 살충제를 각 성분별로 안전사용 기준에 따라 기준량 및 배량의 처리구에 직접 살포하여 열무의 포장상태에서의 잔류량 감소(생물학적 반감기) 변화를 조사하였다. 각 농약별로 2 수준 농도의 표준물질을 첨가하여 실험한 결과 평균회수율은 diazinon 98.7∼99.9%, endosulfan 97.6∼98.5%, cypermethrin 98.3∼99.6%, cyhalothrin 98.4∼99.1%이였고, 검출한계는 diazinon 및 cypermethrin은 0.04 mg/kg, endosulfan은 0.012 mg/kg, cyhalothrin은 0.01 mg/kg 이었다. 약제 살포 후 분해속도가 빠른 성분은 diazinon > endosulfan > cypermethrin >cyhalothrin 순이었다. 작물체(열무)내에서 시간의 경과에 따른 잔류량의 변화를 1차 반응으로 표현하여 농약 4종의 살포농도별 생물학적 반감기를 산출한 결과, 기준량 살포의 경우 diazinon 0.9일, endosulfan 2.0일, cypermethrin 2.2일, cyhalothrin 2.5일 그리고 배량 살포의 경우에는 diazinon 1.1일, endosulfan 2.0일, cypermethrin 2.1일, cyhalothrin 2.2일로 나타났다. 안전한 농산물 생산을 위한 열무 중 약제 살포 후 수확일은 잔류허용기준(MRL)을 적용시킬 경우 기준량으로 볼 때 diazinon은 6일 후, endosulfan은 10일 후에 수확하는 것이 바람직한 것으로 나타났으며 합성 피레스로이드계인 cypermethrin과 cyhalothrin은 농약살포 후 2 시간 후에 농약 잔류량이 잔류허용기준 미만으로 나타났다.

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Investigation into Variations of Welding Residual Stresses and Redistribution Behaviors for Different Repair Welding Widths (보수용접부 폭에 따른 용접잔류응력의 변화 및 재분배 거동 평가)

  • Park, Chi-Yong;Lee, Hwee-Sueng;Huh, Nam-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.2
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    • pp.177-184
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    • 2014
  • In this study, we investigated the variations in welding residual stresses in dissimilar metal butt weld due to width of repair welding and re-distribution behaviors resulting from similar metal welding (SMW) and mechanical loading. To this end, detailed two-dimensional axi-symmetric finite element (FE) analyses were performed considering five different repair welding widths. Based on the FE results, we first evaluated the welding residual stress distributions in repair welding. We then investigated the re-distribution behaviors of the residual stresses due to SMW and mechanical loads. It is revealed that large tensile welding residual stresses take place in the inner surface and that its distribution is affected, provided repair welding width is larger than certain value. The welding residual stresses resulting from repair welding are remarkably reduced due to SMW and mechanical loading, regardless of the width of the repair welding.

AE Characteristics on the Damage Behavior of TiNi/A16061 Shape Memory Alloy Composites at High Temperature (TiNi/A16061 형상기억복합재료의 고온에서의 손상거동에 대한 AE 특성)

  • Lee, Jin-Kyung;Park, Young-Chul;Ku, Hoo-Taek
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.1
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    • pp.45-52
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    • 2002
  • It has been known that tensile residual stresses occurring by the thermal expansion coefficient mismatch between fiber and matrix is a cause of the weak strength of metal matrix composites(MMCs). In order to solve this problem, TiNi alloy fiber was used as a reinforced material in TiNi/A16001 shape memory alloy composite in this study. TiNi alloy fiber improves the tensile strength of the composite by causing compressive residual stress in matrix on the basis of its shape memory effect. Pre-strain was imposed to generate the compressive residual stresses inside the TiNi/A16001 shape memory alloy composites. AE technique was used to quantify the microscopic damage behavior of the composite at high temperature. The effect of applied pre-strains on the AE behavior was also evaluated.

A Residual Ionospheric Error Model for Single Frequency GNSS Users in the Korean Region (한국지역에서의 단일주파수 GNSS 사용자를 위한 전리층 잔류 오차 모델 개발)

  • Yoon, Moonseok;Ahn, Jongsun;Joo, Jung -Min
    • Journal of Advanced Navigation Technology
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    • v.25 no.3
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    • pp.194-202
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    • 2021
  • Ionosphere, one of the largest error sources, can pose potentially harmful threat to single-frequency GNSS (global navigation satellite system) user even after applying ionospheric corrections to their GNSS measurements. To quantitatively assess ionospheric impacts on the satellite navigation-based applications using simulation, the standard deviation of residual ionospheric errors is needed. Thus, in this paper, we determine conservative statistical quantity that covers typical residual ionospheric errors for nominal days. Extensive data-processing computes TEC (total electron content) estimates from GNSS measurements collected from the Korean reference station networks. We use Klobuchar model as a correction to calculate residual ionospheric errors from TEC (total electron content) estimate. Finally, an exponential delay model for residual ionospheric errors is presented as a function of local time and satellite elevation angle.

Residue Patterns of Azoxystrobin and Cyenopyrafen In Grape between Rainshield and Plastic House Conditions (비가림과 시설 재배조건시 포도 중 Azoxystrobin과 Cyenopyrafen의 잔류 특성)

  • Lee, Cho-Rong;Hong, Ji-Hyung;Lim, Jong-Sung;Lee, Kyu-Seung
    • The Korean Journal of Pesticide Science
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    • v.15 no.2
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    • pp.97-103
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    • 2011
  • The residual patterns of azoxystrobin and cyenopyrafen were investigated to compare the differences between rainshield and plastic house conditions of the grapes. Initial residue concentrations of azoxystrobin were $0.54\;mg{\cdot}kg^{-1}$ under rainshield condition and $0.9\;mg{\cdot}kg^{-1}$ under plastic house condition. And cyenopyrafen was 0.55 and $0.64\;mg{\cdot}kg^{-1}$ respectively. Biological half-life of azoxystrobin was calculated as 13.28 days under rainshield and 15.58 days under plastic house condition. And cyneopyrafen was 7.99 and 12.65 days, respectively. In comparison with two different cultivation conditions, pesticides in/on the grape were decomposed more faster under plastic house than rain shield conditions.

Study on Thermal Residual stresses and Transmission Characteristics in Loop Type Frequency Selective Surface Embedded Composite Structures (루프 종류의 FSS가 결합된 복합재료 구조의 잔류응력과 전파 투과 특성)

  • Park, Kyoung-Mi;Hwang, In-Han;Chun, Heoung-Jae;Hong, Ic-Pyo;Park, Yong-Bae;Kim, Yoon-Jae
    • Composites Research
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    • v.26 no.5
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    • pp.279-288
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    • 2013
  • In this paper, the delamination and deformed FSS caused by residual stresses in the Loop type FSS embedded composites and the transmission characteristic changes due to deformation of FSS by residual stresses were studied. FSS may have different electromagnetic characteristics depending on the type of element, design variables, and array. Therefore, design variables of square loop FSS embedded composites structures were determined to obtain the transmission characteristic for X-band (8~12 GHz). Then the design variables of other types of loops (triangular loop and circular loop) were determined based on the dimensions of square loop. Thereafter, the residual stresses and transmission characteristics of FSS embedded composite structures with various single and double loop FSS's, and stacking sequence of composite laminates were compared.

Characteristics of Shear Behavior According to State of Particle Bonding and Crushing (입자 결합 및 파쇄 형태에 따른 전단거동 특성)

  • Jeong, Sun-Ah;Kim, Eun-Kyung;Lee, Seok-Won
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.2
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    • pp.1-12
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    • 2011
  • In order to analyze the influence of particle bonding and crushing on the characteristics of shear behavior, especially residual shear behavior of granular soil, ring shear test was simulated by using DEM(Discrete Element Method)-based software program PFC(Particle Flow Code). Total four models including two non-crushing models and two crushing models were created in this study by using clump or cluster model built in PFC. The applicability of Lobo-crushing model proposed by Lobo-Guerrero and Vallejo(2005) was investigated. In addition, the results of ring shear test were analyzed and compared with those of direct shear test. The results showed that the modelling of ring shear test should be conducted to investigate the residual shear behavior. The Lobo-crushing model cannot be applied to investigate the residual shear strength. Finally, it can be concluded that the numerical models excluding Lobo-crushing model suggested in this study can be used extensively for other studies concerning the residual shear behavior of granular soil including soil crushing.

금속중간층을 이용한 나노결정질 다이아몬드 박막 코팅

  • Na, Bong-Gwon;Myeong, Jae-U;Gang, Chan-Hyeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.99-99
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    • 2013
  • 나노결정질 다이아몬드(Nanocrystalline Diamond: NCD) 박막은 고경도와 낮은 마찰계수를 가지고 있어 초경합금이나 고속도강과 같은 절삭공구 위에 코팅하여 공구의 성능 향상을 도모하려는 노력이 있어 왔다. 그러나 NCD 박막의 잔류응력이 크고, 초경합금과 철계 금속에 NCD가 증착되지 않는다는 문제점이 있다. 따라서 잔류응력 완화와 다이아몬드 핵생성을 위하여 제3의 중간층 재료가 필요하다. 본 연구에서는 W과 Ti을 중간층으로 하여 초경합금(WC-Co)과 고속도강(SKH51)에 NCD 박막을 코팅하고 기계적 특성을 비교하였다. 초경합금 또는 고속도강기판 위에 W 또는 Ti 중간층을 DC magnetron sputter를 이용해 각 1 ${\mu}m$의 두께로 증착하고 그 위에 MPCVD (Microwave Plasma Chemical Vapor Deposition)를 이용해 NCD 박막을 2${\mu}m$의 두께로 코팅하였다. FESEM을 이용하여 표면과 단면의 형상을 관찰하였고, XRD와 Raman spectroscopy를 통해 NCD 박막의 결정성을 확인하였다. 그리고 tribology test를 실시하여 코팅된 박막의 내마모성을 비교하였으며, Rockwell C indentation test를 이용하여 밀착력을 비교하였다. 초경합금에 적용 시, W이 Ti보다 중간층으로서 더 우수한 것으로 나타났으며 이는 열팽창계수 차이에 의한 잔류응력의 차이에 의한 것으로 여겨진다. 중간층 두께에 따른 박막의 기계적 특성 변화를 알아보기 위해 W 중간층의 두께를 1, 2, 4 ${\mu}m$로 변화를 주었다. 중간층 두께가 2 ${\mu}m$ 이상일 때 박막의 밀착력이 증가되는 것으로 나타났다. 고속도강 위에 같은 방법으로 1 ${\mu}m$의 W 또는 Ti 중간층 위에 2 ${\mu}m$의 NCD 박막을 코팅한 시편들은 초경합금에 코팅한 것과 달리 두 시편 모두 낮은 밀착력을 나타내었다. 열팽창계수 차이에 의한 잔류응력을 완화하기 위해 고속도강에 W/Ti 복합박막을 중간층으로 Ti, W순으로 각각 1 ${\mu}m$ 두께로 증착 후 그 위에 NCD 박막을 2 ${\mu}m$ 두께로 코팅 한 후 특성을 비교하였다. Ti/W 복합 중간층 위에 코팅된 NCD 박막의 밀착력이 W 혹은 Ti 단일 중간층에 코팅된 박막에 비해 우수한 것으로 나타났다. 그러나 실제 공구에 적용하기에는 박막의 밀착력 개선이 요구되며 이를 위해서 더 연구가 필요하다.

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Comparison Study on the Residual Excess Pore Water Pressure Observed in seabed (해저지반에서 계측된 잔류과잉간극수압에 대한 비교 연구)

  • Yang, Soonbo
    • Journal of Navigation and Port Research
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    • v.37 no.2
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    • pp.173-179
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    • 2013
  • The interaction among wave, seabed and marine structure is an important issue in coastal engineering as well as geotechnical engineering. Understanding variations of stresses and pore water pressures generated in seabed induced by waves is important for civil engineers who have to design the foundation for various marine structures and verify the instability of seabed. In the matters on seabed instability, particularly, in the case of wave-induced liquefaction of seabed, it is turned out there are two different mechanisms through previous studies. These are caused by the transient or oscillatory nature and the residual or progressive nature of excess pore water pressure generated in seabed, respectively. In this study, it is analyzed dynamic characteristics of soils sampled in seabed around the port of Kochi, Japan, through the dynamic triaxial tests and the residual excess pore water pressure in the seabed induced by seepage force of wave. In addition, the calculated residual excess pore water pressures were compared with the field data observed in the port of Kochi.

Residue Patterns of Indoxacarb and Thiamethoxam in Chinese Cabbage(Brassica campestris L.) Grown under Greenhouse Conditions and Their Estimated Daily Intake (비닐하우스 재배 얼갈이배추 중 Indoxacarb와 Thiamethoxam의 잔류특성 및 식이섭취량)

  • Lee, Eun-Young;Kim, Dae-Kyu;Park, In-Young;Noh, Hyun-Ho;Park, Young-Soon;Kim, Tae-Hwa;Jin, Chung-Woo;Kim, Kwang-Ill;Yun, Sang-Soon;Oh, Sang-Kyun;Kyung, Kee-Sung
    • Korean Journal of Environmental Agriculture
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    • v.27 no.1
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    • pp.92-98
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    • 2008
  • This experiment was carried out to investigate the residue patterns of two insecticides, indoxcarb and thiamethoxam, commonly used for Chinese cabbage, under greenhouse conditions. The pesticides were sprayed onto Chinese cabbage at the recommended dose and double of the recommended dose 10 days before the prearranged harvest and then sampling was done at 0.17, 1, 2, 3, 4, 5, 6, 8, 10, and 12 days after spraying. The amounts of their residues in the crop were analyzed with an HPLC. The limit of detection(LOD) of both indoxacarb and thiamethoxam was 0.01 mg $kg^{-1}$ and mean recoveries of indoxacarb and thiamethoxam were from 97.91 to 104.36% and from 97.07 to 105.49%, respectively. Half-lives of indoxacarb and thiamethoxam were 3.4 and 2.3 days at the recommended dose and 3.3 and 3.5 days at the doubled dose, respectively. The ratios of the EDI to ADI by intake the crop harvested 10 days after spraying were less than 4% of their ADIs.