• Title/Summary/Keyword: 자유 에너지

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Estimation of Activation Energy for the Free Radical Polymerization by Using Isoconversional Analysis (등전환 분석(Isoconversional Analysis)를 이용한 자유라디칼 중합의 활성화 에너지 계산)

  • Chung, I.
    • Elastomers and Composites
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    • v.39 no.4
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    • pp.281-285
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    • 2004
  • In this paper, the simple way to evaluate the value of the activation energy for the overall rate of free radical polymerization by using DSC thermograms was studied using free radical polymerization or butylacrylate as a model. Activation ehergies were determined at heating rates of 1, 2, 5, and $10^{\circ}C/min$ by applying the multiple scanning-rate methods of Kissinger, Osawa, and half-width methods as well as the single rate method of Barrett. The value of the overall activation energy measured was closely matched with the values calculated from individual data. This work also demonstrated that the use of the isoconversional method was a simple and effective way to estimate the activation energy for the overall free radical polymerization.

Power Conditioning System for Single Phase Linear Generation System of Free Piston Engine (자유 피스톤 엔진용 단상 선형 발전시스템을 위한 전력제어시스템)

  • Kwak, Bongwoo;Kim, Jonghoon;Kim, Myungbok
    • Proceedings of the KIPE Conference
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    • 2017.07a
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    • pp.431-432
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    • 2017
  • 본 논문은 자유 피스톤 엔진에 적용되는 단상 선형발전기용 전력제어시스템에 관한 연구이다. 자유 피스톤 엔진 선형발전시스템은 피스톤의 움직임을 구속하는 기구가 없기 때문에 기계적 마찰 손실이 적고 상사점 도달 시간이 짧아 에너지 효율측면에서 기존의 피스톤 엔진보다 유리한 기술이다. 하지만, 자유 피스톤 엔진의 경우 초기 기동 할 수 있는 동력원이 필요하며, 단상 선형 발전기의 경우 짧은 스트로크 및 낮은 속도로 인해 인덕턴스가 크게 설계 되어, 높은 인덕턴스로 인한 전류의 위상 지연으로 역률이 낮아지게 되고, 응답성이 떨어지는 문제점을 가지고 있다. 이러한 문제점을 해결하기 위해 본 논문에서는 역률 보상 및 응답성을 높일 수 있는 자유피스톤 엔진용 단상선형발진기용 전력제어시스템을 제안한다.

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A Study on the Effect of Si Surface on Diamond Film Growth by AES (Diamond 박막 성장에 미치는 Si 표면 영향의 AES에 의한 연구)

  • Lee, Cheol-Ro;Sin, Yong-Hyeon;Im, Jae-Yeong;Jeong, Gwang-Hwa;Cheon, Byeong-Seon
    • Journal of the Korean Vacuum Society
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    • v.2 no.2
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    • pp.199-208
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    • 1993
  • The effect of nucleation free energy related to Si surface states on diamond film growth behavior has been studied. Ar first, the three kinds of diamond thin films (A, B, C) were deposited on various Si substrates (A-Si, B-Si, C-Si) whose surfaces were polished with 1 ${\mu}m$ diamond paste, 6 ${\mu}m$ Al_2O_3$ powder and 12 ${\mu}m$ Al_2O_3$ powder respectively. And then, relative nucleation free energy calculated is ${\Delta}G_{A-Si}<{\Delta}G_{B-Si}<{\Delta}G_{C-Si}$. Although there are some difference in grain size, shape and nucleated size, the thin films on A-Si and B-Si were diamond including a small amount of DLC which was confirmed by AES, SEM, XRD, and RHEED. Namely, the diamonds of films (B) were not nucleated in scratches but in dents and larger in grain size compare with the film (C) of which diamond sere nucleated not only scratches but also dents. And, the sphere diamond which is not general shape was grown on C-Si. After all, the sphere was turned out to be the diamond including much graphite as a result of the AES in situ depth profiling. Consequently, the diamond shape and quality grown on Si were Changed from the crystal which the (100) and (110) planes were predominent to the crystal in which (111) plane was predominent, and newt to sphere shape diamond including much graphite according as the nucleation free energy increases.

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The Research of Vibration Power Generation with Two Degree of Freedom Using Ocean Wave (파도를 이용한 2자유도 파력진동발전시스템에 대한 연구)

  • Han, Ki-Bong;Lee, Hyoung-Woo
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.8
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    • pp.1028-1034
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    • 2011
  • This paper have been studied that ocean wave power vibration generation system with two D.O.F.(degree of freedom) consists of buoy and vibration generation system with two D.O.F. for using efficiency of ocean wave energy. It selected main frequencies ${\omega}_1$, ${\omega}_2$ in frequency with ocean wave and it fitted them to the natural frequencies of vibration system with two D.O.F. in the vibrational power generation system. Then each the relative velocity of between the winding coil and the permanent magnet is faster than the velocity of ocean wave up and down motion by resonance phenomenon. Also the ocean wave power generation with two D.O.F. obtained the more electric energy then the ocean wave power generation with one D.O.F. by coupling effect for two D.O.F. vibration system. Therefore ocean wave power vibration generation system with two degree of freedom that is proposed in this paper has merits which not only using more energy in the ocean wave but also obtaining more electronic energy.

Prediction of Wave Energy Absorption Efficiency and Wave Loads of a Three-Dimensional Bottom-Mounted OWC Wave Power Device (착저식 OWC 파력발전장치의 파에너지 흡수효율 및 파랑하중 계산)

  • Hong, Do-Chun;Hong, Key-Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.1
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    • pp.47-52
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    • 2010
  • The wave energy absorption efficiency and the first-order and the time-mean second-order wave loads of a three-dimensional bottom-mounted oscillating water column (OWC) chamber structure are studied. The potential problem is solved by making use of a hybrid Green integral equation associated with the finite-waterdepth free-surface Green function outside a twin chamber and the Rankine Green function inside taking account of the fluctuating air pressure inside the chamber. Numerical results of the primary wave energy converting efficiency and the oscillating and steady wave loads of a three-dimensional bottom-mounted OWC pilot plant have been presented.

파력발전용 수력터빈 성능시험을 위한 파랑수조의 유동장 수치해석

  • Jo, Yeong-Jin;Choe, Yeong-Do;Kim, Yu-Taek;Lee, Yeong-Ho
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2007.12a
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    • pp.357-359
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    • 2007
  • 해양에너지원 중에서 파랑은 모든 해역에 폭넓게 분포하므로 가용에너지원이 풍부하고 에너지를 회수하기 위한 장치를 설치할 수 있는 해역 또한 광범위하며 반도의 지형을 지닌 우리나라의 연안 해역에 대규모로 활용이 가능한 에너지 자원중 하나이다. 본 연구는 새로운 방식인 파력발전용 횡류형터빈인 케이슨 내장형 횡류터빈을 개발하기에 앞서 파랑수조의 왕복운동을 CFD해석을 통하여 구현하는 것이다.

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Design of Room Reverberation Filter by Using 5 DOF Reverberation Model (5자유도 잔향 모델을 이용한 실내 잔향 필터 설계)

  • Kim Sohee;Kim Yang-Hann
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.227-230
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    • 1999
  • 잔향에 대한 인간의 주관적인 지각을 잔향기 설계에 객관적인 수치로써 반영하는 방법으로, 5 자유도 잔향 모델이 제안된 바 있다[1]. 5자유도 잔향 모델은 잔향에 대한 다섯 개의 객관적인 평가량들을 이용하여 시간에 따른 음 에너지 감쇠 곡선을 근사화한 것이다. 즉 5 자유도 잔향 모델을 이용하여 청취자가 원하는 특성을 갖는 잔향을 객관적으로 묘사할 수 있고, 이는 잔향을 합성할 때 잔향 필터의 설계 기준이 된다. 그러나 이 모델로부터 만들 수 있는 잔향 필터의 개수는 실로 무한하고, 그 중에는 인간이 듣기에 부자연스러운 합성음을 만들어 내는 경우도 있다. 즉 자연스러운 잔향을 만들기 위해서는 잔향 모델 외에도 부가적인 잔향 설계 기준이 필요하다. 시간, 주파수 영역에서 대표적인 특성을 갖는 몇 종류의 원음에 대한 청음실험을 통해, 필요한 잔향 설계 기준을 제시한다.

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Numerical Analysis on Nonlinear Sloshing Problem using Finite Element Method (유한 요소법을 이용한 비선형 슬러싱 문제 해석)

  • Kyoung Jo-Hyun;Kim Jang-Whan;Cho Seok-Kyu;Bai Kwang-June
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.4
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    • pp.216-223
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    • 2004
  • A nonlinear sloshing problem is numerically simulated. During excessive sloshing the sloshinginduced impact load can cause a critical damage on the tank structure. A three-dimensional free-surface flow in a tank is formulated in the scope of potential flow theory. The exact nonlinear free-surface condition is satisfied numerically. A finite-element method based on Hamiltons principle is employed as a numerical scheme. The problem is treated as an initial-value problem. The computations are made through an iterative method at each time step. The hydrodynamic loading on the pillar in the tank is computed.

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