• Journal of the Society of Cosmetic Scientists of Korea
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• v.22 no.1
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• pp.70-83
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• 1996

자외선 차단제는 화장품 원료 중 주요 자극원의 하나이다. 그러나 자오선 차단제를 고분자로 만들 경우 피부에 도포 되었을 때 경피흡수가 불가능 하여 피부 자극 문제를 해결할 수 있다. 이에 본 연구에서는 PVBC와 alkylhydroxycinnamate를 반응시켜 고분자 자외선 차단제를 합성하였다, PVBC는 benzylic chloride를 가지고 있는 고분자로서 이 작용기는 친핵성 치환반응이 용이하므로 side chain modification이 가능하다. PVBC와 alkyl hydroxycinnamate의 반응에서 반응성은 alkyl hydroxycinnamate의 크기와 반응에 첨가된 촉매의 종류에 영향을 받는다. 효율이 낮은 촉매를 사용할 경우에는 alkyl hydroxycinnamate의 크기가 작을수록 반응수율이 높았으며, 높은 효율을 갖는 촉매를 사용할 경우에는 alkyl hydroxycinnamate의 종류에 관계없이 반응수율은 100%였다. 실험에 사용한 PVBC는 평균 분자량이 55,000이었으며, 고분자의 구조와 분자량은 NMR과 GPC로 확인하였다. 고분자 자외선 차단제의 자외선 흡수 능력은 OMC에 비해 65 - 94% 였으며, caprylic/capric triglyceride에 좋은 용해도를 보여주었다.

• Proceedings of the KAIS Fall Conference
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• 2010.11b
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• pp.1005-1009
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• 2010

자외선을 막아주고 피부에 안정한 자외선 차단성을 갖는 고분자 미립자를 키틴 및 키토산 미립자에 p-amino benzoic acid(PABA), parsol MCX, parsol 1789를 공유결합시키거나 캡슐화시켜 제조하였다. 자외선 차단성을 갖는 고분자 미립자의 자외선 차단성은 우수하였다. 그리고 피부에 대한 안정성과 독성을 in vivo로 평가한 결과 기존의 화학 자외선 흡수제 보다 안정하였다.

• Journal of the Korea Convergence Society
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• v.9 no.4
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• pp.93-98
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• 2018

This study was wanted to confirm ability for UV blocking according to its material. The lenses materials were Acryl, CR-39, NK-55, and MR-8. It was grouped: Group A consisting of anti-scratch hard coated lenses and anti-refractive multi coated lenses, Group B added UV blocking coating on the group A, and Group C consisting of only UV blocking lenses. The results measured UV transmittance, On the UV-A wavelength, Group A showed the UV transmittance of 7.726%, 0.043%, 0.007%, and 0.007% respectively. Group B showed 0.038%, 0.037%, 0.007%, and 0.007%, respectively. The UV-blocking performance of CR-39 has been greatly improved. Group C has shown the best UV blocking function; only 0.005% and 0.004% of UV transmittances.(1.60 and 1.67 index of refraction respectively). For the low power of lenses and sunglasses, the CR-39 lens is the most used. Therefore, to UV blocking from the lens, new materials or UV absorbers or UV coating technology and development of Converged Technologies are required.

• Korean Journal of Environmental Biology
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• v.20 no.3
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• pp.205-215
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• 2002

Effects of artificial and solar W-B radiation on five rhodophytes (Curdiea racovitzae, Gigaytina skottsbergii, Mazzaella obovata, Myriogramme manginii, Palmaria decipiens) from Antarctica have been investigated using PAM fluorescence in laboratory and in the field. Laboratory studies showed that there were significant differences in the UV sensitivity between different species, and that the differences appeared to be correlated with the depth of collection of the specimens. It was apparent from the observations that the samples such as M. manginii and P. decipiens collected from 20-30 m depths were move sensitive to W-B radiation compared with those collected from shallower depths, The present study confirmed that an acclimation to the surrounding light regime could be an important factor to determine the UV-sensitivity of a species or individuals and that PAM measurements are rapid and non-destructive methods to evaluate UV influences. From field studies on M. manginii and P. decipiens it was observed that both plants exhibited changes in the effective quantum yield, with the minimum values nt noon followed by n recovery in the evening. Photoinhibition occurred in these species could therefore be accounted for by so- called dynamic photoinhibition. It seems likely that this protective mechanism may contribute to survival of the species in shallow water where they may encounter intense solar radiation. The presence or absence of the W- B component under solar radiation differently affected the photosynthetic recovery process, and the rate of recovery was much stoney in UV- present than in W- absent conditions. Functional role of W- B appears to delay the recovery of photosynthesis in the studied macroalgae. Differential sensitivity to UV-B recognised between M. manginii and P. decipiens seemed to correspond well with the amount of UV-absorbing substances (UVAS) contained in the respective species. Higher tolerance to solar radiation by the latter species may be due to the higher amount of UVAS. There were variations of UVAS concentrations in algal thalli depending on the season and depth of collection.

• Proceedings of the Korean Society for Emotion and Sensibility Conference
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• 2001.11a
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• pp.245-250
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• 2001

화장품 사용 시 소비자가 가장 중요하게 느끼는 요인은 효과와 촉감이라고 볼 수 있다. 특히 반복적인 사용을 위해서 쾌적한 촉감은 필수 조건이다. 그런데, 촉감은 사용하는 사람 자신의 감각에 의존하는 것이므로, 이러한 화장품의 촉감을 포함하는 성능을 평가하기 위해서 사람에 의한 최종평가는 필수적인 단계이다. 따라서, 여러 특성의 강도를 측정하는 분석형 관능평가와 소비자의 선호도를 조사하는 기호형 관능평가의 필요성이 요구되며, 두 결과를 종합적으로 고려하는 것이 바람직할 것이다. 우리는 훈련된 전문패널에 의해 다양한 자외선차단 크림과 로션들에 대한 분석형 관능평가를 실시하였다. 그 결과, 자외선차단 제품의 관능속성 평가의 주요인은 잔여감 요인과 발림성 요인으로 나타났으며, 이 결과에 따라 제품들을 2차원 공간 상에 위치하였다. 이 중 몇 제품을 선택하여 20대 후반 여성소비자를 대상으로 기호형 관능평가를 실시하였다. 평상시 실제 화장단계에서 인지되는 자외선차단제품에 대한 용어들은 촉촉함 및 도포균일성 요인/흡수속도 요인의 두가지 요인으로 분류되었다. 이상적인 자외선차단제품의 사용감은 너무 촉촉하지도 매트하지도 않으면서, 흡수속도는 빠르고 화장밀림이나 번들거림이 적은 사용감을 나타내는 특성쪽으로 나타났다.

• Electric Engineers Magazine
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• v.233 no.2
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• pp.11-16
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• 2002

많은 사람들이 썬탠을 즐기며 건강해 보일것이라고 생각한다. 하지만 태양 광선을 많이 쬐면 건강에 해롭다는 것에 관심이 모아지고 있다. 태양 광선은 자외선 영역 안에서 어느정도 약간 포함되어 있는 파장을 가진 빛을 많이 포함하며 자외선을 과도하게 흡수하면 화상을 가져올 수 있기 때문에 주의를 요해야 한다.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.31 no.1 s.49
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• pp.65-71
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• 2005

A silsesquioxane precursor that contains p-methoxycinnamoyl group was synthesized to produce UV absorbing spherical polysilsesquioxane (PSQ) spheres with diameters of 10nm to a few ${\mu}m$ under different conditions. A dispersion of $10wt\%$ in Vaseline of these PSQ spheres with diameters of approximately $0.6{\mu}m$ showed SPF values of 5.7 and the identical dispersion did not turn white when applied to human hands. These UV absorbing PSQ spheres showed higher boosting effect of sun protection factor (SPF) than the well known UV blocking octyl methoxycinnamate (OMC). The results indicated that the PSQ spheres with p-methoxycinnamoyl group should be useful as the ingredients in UV screening functional cosmetics without causing allergies and whitening.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.37 no.2
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• pp.137-141
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• 2011

Sunscreen is divided into the organic agent of UV absorption and inorganic agent of reflection. These are evaluated by sun protection factor (SPF) in-vivo test requiring high cost and time, while in-vitro tests are adopted commonly because of short test time, easy result collection. Generally, test method of SPF use SPF 290a by UV-vis spectrometer. The evaluate by SPF 290 has low reproducibility. Although analysis using UV-vis spectrometer has high reproducibility, it is hard to separated results of transmission, adsorption, and reflection. In this study, suggested method of elipsometer has some merit such as high reproducibility, easy separation of transmission/adsorption/re- flection, analysis using various incident angle. We tested the validity of elipsometer for SPF measurement, using commercially available sun-block (SPF 50).

• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.279-283
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• 2022

UV-vis spectroscopy is one of the powerful tools for measuring the concentrations of reactant and products during a chemical reaction. However, there is an limitation of using the technique when the reaction undergoes in high concentration and high temperature. Color analysis using camera images can provide the identical results with UV-vis analysis with regardless of the sample concentration and temperature. The catalytic reduction reaction of resazurin to resorufin was investigated using the color analysis with the color spaces such as CIE L^*a^*b^*. Moreover, the color analysis enabled the independent analysis of two different material's concentrations without the deconvolution of overlapped wavelengths unlike the case of using UV-vis spectroscopy.

• Proceedings of the Korean Fiber Society Conference
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• 1999.10a
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• pp.227-230
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• 1999