• Title/Summary/Keyword: 자성 입자

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Water Quality and Cyanobacterial Anatoxin-a Concentration in Daechung Reservoir (대청호의 수질과 남조류 독소 Anatoxin-A 농도의 관계)

  • Joung, Seong-Hyun;Kim, Jee-Hwan;Ahn, Chi-Yong;Choi, Shin-Sok;Kim, Hee-Sik;Oh, Hee-Mock
    • Korean Journal of Ecology and Environment
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    • v.35 no.4 s.100
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    • pp.257-265
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    • 2002
  • The current study was performed to elucidate the relationship between the anatoxin -a produced by cyanobacteria and aquatic environmental factors, Algal and water samples were collected from the Daechung Reservoir from June to November 2001. The physical factors of the water quality were measured in sifu, while the biological and chemical factors were examined in the laboratory. The concentrations of anatoxin-a in the algal and water samples were analyzed by HPLC using a fluorescence detector, and ranged from $0.61-8.68\;{\mu}g/g$ dw in the algal samples and $0.01-0.08\;{\mu}g/L$ in the water samples. The suggested maximum concentration of anatoxin-a for safe drinking water is $1\;{\mu}g/L$. The concentrations of anatoxin-a in the algal and water samples were highest in July. The relationships between tile aquatic environmental factors and the anatoxin-a concentration were also analyzed to identify the crucial elements for toxin production. The anatoxin-a concentrations in the algal samples exhibited a high correlation with nitrate, the TN/TP ratio, TDN (P<0.05), and TPN/TPP ratio (P<0.01), whereas the anatoxin-a concentrations in the water samples were highly related to the water temperature, conductivity (P<0.01) , pH, phycocyanin, and phycocyanin/chlorophyll a ratio (P<0.05).

Electrical and Magnetic Properties of Magnetite Powder during a Verwey Transition (Verwey 전이와 마그네타이트의 전기적 및 자기적 특성)

  • Yoon, Sunghyun
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1302-1307
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    • 2018
  • The crystallographic, electrical and magnetic behaviors of magnetite powder in the vicinity of its Verwey transition were investigated in this study. Magnetite was prepared by synthesizing a nanoparticle precursor and then annealing it at $800^{\circ}C$ for 1 h under a dynamic vacuum. Crystallographic and morphology analyses were done by using scanning electron microscope (SEM) and X-ray diffraction (XRD). The electrical and the magnetic properties were examined by using $M{\ddot{o}}ssbauer$ spectroscopy, vibrating sample magnetometer (VSM) and resistivity measurement. Both the magnetic moment and the resistivity showed discontinuous changes at the Verwey transition temperature ($T_V$). The temperature dependence of magnetic anisotropy constant showed a monotonic decrease with increasing temperature, with slight dip near $T_V$. $M{\ddot{o}}ssbauer$ spectra showed the superposition of two sextets, one from the tetrahedral (A) and the other from the octahedral (B) sites. The results revealed that identical charge states existed in the B site at temperatures both above and below $T_V$. A coordination crossover resulted in a transition from an inverse to a normal spinel at or close to $T_V$.

Prediction of Propylene/Propane Separation Behavior of Na-type Faujasite Zeolite Membrane by Using Gravimetric Adsorption (중량식흡착 거동에 기초한 Na형 Faujasite 제올라이트 분리막의 프로필렌/프로페인 분리 거동 예측 연구)

  • Hwang, Juyeon;Min, Hae-Hyun;Park, You-In;Chang, Jong-San;Park, Yong-Ki;Cho, Churl-Hee;Han, Moon-Hee
    • Membrane Journal
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    • v.28 no.6
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    • pp.432-443
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    • 2018
  • In this study, propylene/propane separation behavior of Na-type faujasite zeolite membranes is predicted by observing gravimetric adsorptions of propylene and propane on zeolite 13X. The gravimetric adsorptions were measured by using a magnetic suspension balance (MSB) at temperatures of 323, 343, 363 K and a pressure range of 0.02-1 bar. The pressure was increased at 0.1 bar intervals. As adsorption temperature increased, adsorptions of propylene and propane decreased and propylene/propane adsorption selectivity increased. Also, the diffusion coefficients of propylene and propane were increased as the adsorption temperature increased, following the Arrhenius equation. The maximum propylene/propane diffusion selectivity was 0.9753 at 323 K. The perm-selectivity was calculated from the adsorption data of zeolite 13X and compared with the perm-selectivity measured in the single gas permeation experiment for the Na-type faujasite zeolite membrane. The maximum values for the calculated and measured perm-selectivities were observed at a temperature of 323 K. It could be concluded that the prediction of propylene/propane separation of surface diffusion-based membrane by using gravimetric adsorption data is reasonable. Therefore, it is expected that this prediction method can be applied to the screening of adsorption-based microporous membrane for propylene/propane separation.

The Effect of Chemical Composition and Sintering Temperature on the Experiment of Physical Properties of Ni-Zn Ferrite (Ni-Zn Ferrite의 조성성분 및 소결온도에 따른 물리적 특성의 실험적 연구)

  • Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.16 no.5
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    • pp.255-260
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    • 2006
  • The basic composition of Ni-Zn ferrite was $(Ni_{0.35}Cu_{0.2}Zn_{0.45})_{1.02}(Fe_2O_3)_{0.98}$ (group A) and $(Ni_{0.4}Cu_{0.2}Zn_{0.4})_{1.02}(Fe_2O_3)_{0.98}$(group B) with additional 0.1 mol% $CaCO_3$ and 0.03 mol% $V_2O_5$. For high permeability and acceleration of grain growth, $CaCO_3$ and $V_2O_5$ was added. The mixture of the law materials was calcinated at $600^{\circ}C$ for 2 hours and then milled. The compacts of toroidal type were sintered at different temperature ($1,050^{\circ}C,\;1,070^{\circ}C,\;1,100^{\circ}C$) for 2 hours in air followed by an air cooling. Then, effects of various composition and sintering temperatures on the microstructure and physical properties such as density, resistivity, magnetic induction, coercive force, initial permeability, quality factor, and curie temperature of the Ni-Zn ferrite were investigated. The density of the Ni-Zn ferrite was $4.90{\sim}5.10g/cm^3$, resistivity revealed $10^8{\sim}10^{12}{\Omega}-cm$. The average grain size increased with the increase of sintering temperatures. The magnetic properties obtained from the aforementioned Ni-Zn ferrite specimens were 4,000 gauss for the maximum induction, 0.25 oersted for the coercive force, 2,997 for the initial permeability, 208 for the quality factor, and $202^{\circ}C$ for the curie temperature. The physical properties indicated that the specimens could be utilized as the core of microwave communication and high permeability deflection yoke of high permeability.