• Title/Summary/Keyword: 자성 안정성

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Urea Conversion via Enzymes Immobilized on Magnetic Microparticles (자성 미세입자에 고정된 효소를 통한 요소 전환)

  • Yeseul Park;Jieun Kwon;Seungjun Jung;Hyukjin Cho;Gounhanul Shin;Gangik Cho;Jin-Won Park;Kyung-Hyuk Lee
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.407-411
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    • 2023
  • The urease is covalently immobilized on the surface of the magnetic particles to catalyze the conversion of urea to bicarbonate anion. The conversion was confirmed qualitatively using high-pressure liquid chromatography and UV/Vis spectrometry, and analyzed quantitatively with cyclic voltammetry. The amount of conversion with respect to time was measured and analyzed by the reaction rate equation to calculate a reaction rate constant of 0.0474 min-1. In the 1 to 3 cycles, a conversion percentage of over 90% was found, and it was possible to reuse the urease 8 times up to the percentage of 50%. It was also observed that the stability evaluated for storage for 30 days was maintained. As a result of this study, it can be seen that the urease covalently immobilized on the scaffold can be used for urea removal for the purpose of producing ultrapure water.

The Parallel Recovery Method for High Availability in Shared-Nothing Spatial Database Cluster (비공유 공간 데이터베이스 클러스터에서 고가용성을 위한 병렬 회복 기법)

  • You, Byeong-Seob;Jang, Yong-Il;Lee, Sun-Jo;Bae, Hae-Young
    • Proceedings of the Korea Information Processing Society Conference
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    • 2003.11c
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    • pp.1529-1532
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    • 2003
  • 최근 인터넷과 모바일 시스템이 급속히 발달함에 따라 이를 통하여 지리정보와 같은 공간데이터를 제공하는 서비스가 증가하였다. 이는 대용량 데이터에 대한 관리 및 빠른 처리와 급증하는 사용자에 대한 높은 동시처리량 및 높은 안정성을 요구하였고, 이를 해결하기 위하여 비공유 공간 데이터베이스 클러스터가 개발되었다. 비공유 공간 데이터베이스 클러스터는 고가용성을 위한 구조로서 문제가 발생할 경우 다른 백업노드가 대신하여 서비스를 지속시킨다. 그러나 기존의 비공유 공간 데이터베이스 클러스터는 클러스터 구성에 대한 회복을 위하여 로그를 계속 유지하므로 로그를 남기기 위해 보통의 질의처리 성능이 저하되었으며 로그 유지를 위한 비용이 증가하였다. 또한 노드단위의 로그를 갖기 때문에 클러스터 구성에 대한 회복이 직렬적으로 이루어져 고가용성을 위한 빠른 회복이 불가능 하였다. 따라서 본 논문에서는 비공유 공간 데이터베이스 클러스터에서 고가용성을 위한 병렬 회복 기법을 제안한다. 이를 위해 클러스터 구성에 대한 회복을 위한 클러스터 로그를 정의한다. 정의된 클러스터 로그는 마스터 테이블이 존재하는 노드에서 그룹내 다른 노드가 정지된 것을 감지할 때 남기기 시작한다. 정지된 노드는 자체회복을 마친 후 클러스터 구성에 대한 회복을 하는 단계에서 존재하는 복제본 테이블 각각에 대한 클러스터 로그를 병렬적으로 받아 회복을 한다. 따라서 정지된 노드가 발생할 경우에만 클러스터 로그를 남기므로 보통의 질의처리의 성능 저하가 없고 클러스터 로그 유지 비용이 적으며, 클러스터 구성에 대한 회복시 테이블단위의 병렬적인 회복으로 대용량 데이터인 공간데이터에 대해 빠르게 회복할 수 있어 가용성을 향상시킨다.들을 문법으로 작성하였으며, PGS를 통해 생성된 어휘 정보를 가지고 스캐너를 구성하였으며, 파싱테이블을 가지고 파서를 설계하였다. 파서의 출력으로 AST가 생성되면 번역기는 AST를 탐색하면서 의미적으로 동등한 MSIL 코드를 생성하도록 시스템을 컴파일러 기법을 이용하여 모듈별로 구성하였다.적용하였다.n rate compared with conventional face recognition algorithms. 아니라 실내에서도 발생하고 있었다. 정량한 8개 화합물 각각과 총 휘발성 유기화합물의 스피어만 상관계수는 벤젠을 제외하고는 모두 유의하였다. 이중 톨루엔과 크실렌은 총 휘발성 유기화합물과 좋은 상관성 (톨루엔 0.76, 크실렌, 0.87)을 나타내었다. 이 연구는 톨루엔과 크실렌이 총 휘발성 유기화합물의 좋은 지표를 사용될 있고, 톨루엔, 에틸벤젠, 크실렌 등 많은 휘발성 유기화합물의 발생원은 실외뿐 아니라 실내에도 있음을 나타내고 있다.>10)의 $[^{18}F]F_2$를 얻었다. 결론: $^{18}O(p,n)^{18}F$ 핵반응을 이용하여 친전자성 방사성동위원소 $[^{18}F]F_2$를 생산하였다. 표적 챔버는 알루미늄으로 제작하였으며 본 연구에서 연구된 $[^{18}F]F_2$가스는 친핵성 치환반응으로 방사성동위원소를 도입하기 어려운 다양한 방사성의 약품개발에 유용하게 이용될 수 있을 것이다.었으나 움직임 보정 후 영상을 이용하여 비교한 경우, 결합능 변화가 선조체 영역에서 국한되어 나타나며 그 유의성이 움직임 보정 전에 비하여 낮음을 알 수 있었다. 결론: 뇌활성화 과제 수행시에 동반되는

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Development of Irreversible Micro-size Ferromagnetic Structures by Hydrogenation and Electron-beam Lithography (수소화 및 전자빔 사진식각 기술에 의한 비가역적 마이크로 크기의 강자성 구조체 개발)

  • Yun Eui-Jung
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.1 s.343
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    • pp.7-12
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    • 2006
  • In this study, we developed irreversible and stable micro-size ferromagnetic structures utilizing hydrogenation and electron-beam lithography processes. The compositionally modulated (CM) Fe-Zr thin films that had average compositions $Fe_XZr_{100-x}$ with $x=65-85\%$ modulation periods of similar to 1 nm, and total thicknesses of similar to 100 m were prepared. The magnetic properties of CM Fe-Zr thin films were measured using a SQUID magnetometer, VSM and B-H loop tracer. After hydrogenation, the CM films exhibited larger magnetic moment increases than similar homogeneous alloy films for all compositions and かey showed largest increase in $Fe_{80}Zr_{20}$ composition. After aging in air at $300^{\circ}K$ the hydrogenated $Fe_{80}Zr_{20}$ CM films showed much larger magnetic moment increases, indicating that they relax to a stable, irreversible, soft magnetic state. The selective hydrogenation through electron-beam lithographed windows were performed after the circle shaped windows were prepared on $Fe_{80}Zr_{20}$ CM films by electron beam lithography. The hydrogenation through electron-beam resist and W lithographic techniques give a $49\%$ magnetic moment increase. This method can be applied to nano scale structures.

Tunneling Magnetoresistive Properties of Reactively Sputtered $Fe/Al_2O_3/Co$ Trilayer Junctions ($Fe/Al_2O_3/Co$ 자기 터널링 접합 제작 및 자기수송현상에 관한 연구)

  • 최서윤;김효진;조영목;주웅길
    • Journal of the Korean Magnetics Society
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    • v.8 no.1
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    • pp.27-33
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    • 1998
  • We have investigated tunneling magnetoresistance (TMR) properties of Fe/$Al_2O_3$/Co magnetic trilayer junctions sputtered on single-crystal Si (001) substrates. $Al_2O_3$ layers with thicknesses of 50~200 $\AA$ were deposited directly on the bottom ferromagnetic layer by a reactive rf sputtering. For comparsion, we prepared Pt/$Al_2O_3$/Pt tunnel junctions whose current-voltage (I-V) characteristics measured at 300 K indicated that reactively sputtered $Al_2O_3$ is a particularly good material for thin insulating barriers and allows us to form pinhole-free tunnel barriers. The magnetic tunnel junctions exhibit changes of tunnel resistance of about 0.1% at 300 K with an applied magnetic field and it was found that most junctions with Co as a top electrode have rather good I-V and TMR characteristics compared to those with Fe as a electrode. These results were discussed in relation to interfacial on the basis of those for Pt/$Al_2O_3$/Pt.

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Purification and Characteriztion of an Antifungal Antibiotic from Bacillus megaterium KL 39, a Biocontrol Agent of Red-Papper Phytophtora Blight Disease. (고추역병균 Phytophthora capsici를 방제하는 길항균주 Bacillus megaterium KL39의 선발과 길항물질)

  • 정희경;김상달
    • Microbiology and Biotechnology Letters
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    • v.31 no.3
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    • pp.235-241
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    • 2003
  • For the biological control of Phytophthora blight of red-pepper caused by Phytophthora capsici, an antibiotic-producing plant growth promoting rhizobacteria (PGPR) Bacillus sp. KL 39 was selected from a local soil of Kyongbuk, Korea. The strain KL 39 was identified as Bacillus megaterium by various cultural, biochemical test and API and Microlog system. B. megaterium KL 39 could produce the highest antifungal antibiotic after 40 h of incubation under the optimal medium which was 0.4% fructose, 0.3% yeast extract, and 5 mM KCl at 30 C with initial pH 8.0. The antifungal antibiotic KL 39 was purified by Diaion HP-20 column, silica gel column, Sephadex LH-20 column, and HPLC. Its RF value was confirmed 0.32 by thin-layer chromatography with Ethanol:Ammonia:Water = 8:1:1. The crude antibiotic KL39 was active against a broad range of plant pathogenic fungi, Rhizoctonia solani, Pyricularia oryzae, Monilinia fructicola, Botrytis cinenea, Alteranria kikuchiana, Fusarium oxysporum and Fusarium solani. The purified antifungal antibiotic KL39 had a powerful biocontrol activity against red-pepper phytophthora blight disease with in vivo pot test as well as the strain B. megaterium KL 39.

Exchange coupling field of NiFe/IrMn/CoFe trilayer depending on Mn composition (3중박막 NiFe/IrMn/CoFe에서 Mn 함유량에 의존하는 교환결합세기)

  • 김보경;이진용;함상희;김순섭;이상석;황도근;김선욱;이장로
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.130-131
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    • 2003
  • The magnetic and thermal properties of NiFe/IrMn/CoFe with Mn additions have been studied. As grown CoFe pinned-layers with IrMn-Mn have dominantly larger exchange biasing field( $H_{ex}$) and blocking temperature( $T_{b}$) than when pure I $r_{22}$M $n_{78}$ is used. The magnetic properties improve, $H_{ex}$ and $T_{b}$ improve with 77-78 vol% Mn, but drop considerably with more Mn additions, losing magnetic properties of theb NiFe/IrMn/CoFe with addition 0.6 vol % Mn. The average x-ray diffraction peak ratios fcc (111)CoFe of (111)IrM $n_3$ textures for the Mn inserted total vol of 75, 77, and 79 vol% were about 1.4, 0.8, and 0.6, respectively. For the sample without Mn inserted layer, the $H_{ex}$ between I $r_{22}$M $n_{78}$ and CoFe layers is almost nothing. For two multilayer as-grown samples with ultra-thin Mn layers of 77 vol % and 79 vol %, the $H_{ex}$s are 250 Oe and 150 Oe, respectively. In case of IrMn with 77.5 vol% Mn, the $H_{ex}$ was 444 Oe up to 30$0^{\circ}C$ endured of 363 Oe at 40$0^{\circ}C$, respectively. Mn additions improve the magnetic properties and thermal stabilities of NiFe/IrMn/CoFe. Those increase the $H_{ex}$ and $T_{b}$. In applications where higher $H_{ex}$ and $T_{b}$ are accept, proper concentrations of Mn can be used.n can be used.be used.

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Evaluation of the Curvature Reliability of Polymer Flexible Meta Electronic Devices based on Variations of the Electrical Properties (전기적 특성 변화를 통한 고분자 유연메타 전자소자의 곡률 안정성 평가)

  • Kwak, Ji-Youn;Jeong, Ji-Young;Ju, Jeong-A;Kwon, Ye-Pil;Kim, Si-Hoon;Choi, Doo-Sun;Je, Tae-Jin;Han, Jun Sae;Jeon, Eun-chae
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.268-276
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    • 2021
  • As wireless communication devices become more common, interests in how to control the electromagnetic waves generated from the devices are increasing. One of the most commonly used electromagnetic wave control materials is magnetic one, but due to the features that make the product heavy and thick when applied to the product, it is difficult to use them in curved electronic devices. Therefore, a polymer flexible meta electronic device has been presented to sort out the problem, which is thin and can have various curvatures. However, it requires an additional evaluation of curvature reliability. In this study, we developed a method to predict electromagnetic wave control characteristics through the resistance/length of the conductive ink line patterns of polymer flexible meta electronic devices, which is inversely proportional to the electromagnetic wave control characteristics. As the radius of curvature decreased, the resistance/length increased, and there was little variations with the duration times of curvature. We also found that both permanent and recoverable changes along with the removal of curvature were occurred when the curvature was applied, and that the cause of these changes was newly created vertical cracks in the conductive ink line pattern due to the tensile stress applied by applying curvature.

Trends in Rapid Detection Methods for Marine Organism-derived Toxins (해양 생물 유래 독소의 나노 기술 기반 신속 진단법 개발 동향)

  • Park, Chan Yeong;Kweon, So Yeon;Moon, Sunhee;Kim, Min Woo;Ha, Sang-Do;Park, Jong Pil;Park, Tae Jung
    • Journal of Food Hygiene and Safety
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    • v.35 no.4
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    • pp.291-303
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    • 2020
  • Marine organism-derived toxins have negative effects not only on human health but also in aquaculture, fisheries, and marine ecosystems. However, traditional analytical methods are insufficient in preventing this threat. In this paper, we reviewed new rapid methods of toxin detection, which have been improved by adopting diverse types of nanomaterials and technologies. Moreover, we herein describe the main strategies for toxin detection and their related sensing performance. Notably, to popularize and commercialize these newly developed technologies, simplifying the process of pre-treating real samples real samples is very important. As part of these efforts, numerous studies have reported pretreatment methods based on the antibody-immobilized magnetic nanoparticles, and some cases have applied nanoparticles to enhance the sensing performance by utilizing the intrinsic catalytic activity. Furthermore, some reports have introduced fluorescent nanoparticles, such as quantum dots, to represent the lower detection limits of conventional enzyme-based colorimetric methods and lateral flow assays. Some studies using electrochemical measurements based on aptamer-nanoparticle complexes have also been announced. In addition, as the response to new toxins generated by changes in the marine environment is still lacking, further research on diagnostic and detection is also greatly needed for these kinds of marine toxins and their derivatives.

K-DEV: A Borehole Deviation Logging Probe Applicable to Steel-cased Holes (철재 케이싱이 설치된 시추공에서도 적용가능한 공곡검층기 K-DEV)

  • Yoonho, Song;Yeonguk, Jo;Seungdo, Kim;Tae Jong, Lee;Myungsun, Kim;In-Hwa, Park;Heuisoon, Lee
    • Geophysics and Geophysical Exploration
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    • v.25 no.4
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    • pp.167-176
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    • 2022
  • We designed a borehole deviation survey tool applicable for steel-cased holes, K-DEV, and developed a prototype for a depth of 500 m aiming to development of own equipment required to secure deep subsurface characterization technologies. K-DEV is equipped with sensors that provide digital output with verified high performance; moreover, it is also compatible with logging winch systems used in Korea. The K-DEV prototype has a nonmagnetic stainless steel housing with an outer diameter of 48.3 mm, which has been tested in the laboratory for water resistance up to 20 MPa and for durability by running into a 1-km deep borehole. We confirmed the operational stability and data repeatability of the prototype by constantly logging up and down to the depth of 600 m. A high-precision micro-electro-mechanical system (MEMS) gyroscope was used for the K-DEV prototype as the gyro sensor, which is crucial for azimuth determination in cased holes. Additionally, we devised an accurate trajectory survey algorithm by employing Unscented Kalman filtering and data fusion for optimization. The borehole test with K-DEV and a commercial logging tool produced sufficiently similar results. Furthermore, the issue of error accumulation due to drift over time of the MEMS gyro was successfully overcome by compensating with stationary measurements for the same attitude at the wellhead before and after logging, as demonstrated by the nearly identical result to the open hole. We believe that the methodology of K-DEV development and operational stability, as well as the data reliability of the prototype, were confirmed through these test applications.

An Explicit Dynamic Memory Management Scheme in Java Run-Time Environment (자바 실행시간 환경에서 명시적인 동적 메모리 관리 기법)

  • 배수강;이승룡;전태웅
    • Journal of KIISE:Software and Applications
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    • v.30 no.1_2
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    • pp.58-72
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    • 2003
  • The objects generated by the keyword new in Java are automatically managed by the garbage collector Inside Java Virtual Machine (JVM) not like using the keywords free or delete in C or C++ programming environments. This provides a means of freedom of memory management burden to the application programmers. The garbage collector however. inherently has its own run time execution overhead. Thus it causes the performance degradation of JVM significantly. In order to mitigate the execution burden of a garbage collector, we propose a novel way of dynamic memory management scheme in Java environment. In the proposed method, the application programmers can explicitly manage the objects In a simple way, which in consequence the run-time overhead can be reduced while the garbage collector is under processing. In order to accomplish this, Java application firstly calls the APIs that arc implemented by native Jana, and then calls the subroutines depending on the JVM, which in turn support to keep the portability characteristic Java has. In this way, we can not only sustain the stability in execution environments. but also improve performance of garbage collector by simply calling the APIs. Our simulation study show that the proposed scheme improves the execution time of the garbage collector from 10.07 percent to 52.24 percent working on Mark-and-Sweep algorithm.