• Title/Summary/Keyword: 자발발화

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Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of n-Heptane (탄화수소계 연료의 축소반응모텔과 노말-헵탄(n-Heptane)의 자발화 현상)

  • 여진구
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.1
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    • pp.76-83
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    • 2002
  • Mathematically and chemically simplified reaction scheme for n(heptane that simulates autoignitions of the end gases in spark ignition engines has been developed and studied computationally. The five(equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius pre-exponential constants, A, and heats of reaction for stoichiometric nheptane/air has all been optimized. Comparisons between computed and experimental autoignition delay times have validated the present simplified reaction scheme. The influences of heat loss and concentration of chain carrier at the beginning of compression upon autoignition delay times have been computationally investigated.

Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of Gasoline with Different Octane Numbers (탄화수소계 연료의 축소반응모델과 가솔린연료의 옥탄가 변화에 따른 자발화 지연시간)

  • 여진구
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.3
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    • pp.13-19
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    • 2003
  • Mathematically simplified reaction scheme that simulates autoignitions of the end gases in spark ignition engines has been studied computationally. The five equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius preexponential constants, A, and heats of reaction for stoichiometric n-heptane/air, iso-octane/air, and their mixtures have all been optimised. The optimisation has been guided by Morley's correlation of the ratio of chain branching to linear termination rates with octane number. Comparisons between computed and experimental autoignition delay times have validated the Present simplified reaction scheme and the influences of octane number upon autoignition delay times have been computationally investigated. It has been found that both cool flame and high temperature direct reactions can have an effect on autoignition delay times.

고온/고압 산화제 과잉 환경에 적합한 재질 및 코팅 조사

  • Yu, Jae-Han;Ha, Seong-Eop;Mun, Il-Yun;Lee, Su-Yong
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.149.1-149.1
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    • 2012
  • 고성능 다단연소싸이클 엔진은 산화제과잉 예연소기를 사용한다. 예연소기 후류에 위치한 배관 및 연소기 헤드 등은 고온/고압 산화제 과잉 환경에 놓이게 되며, 운용 조건에서는 국부적으로 온도를 상승시키는 외부 발화제에 의하여 녹는점보다 낮은 온도에서 재질이 발화될 수 있다. 따라서, 이러한 환경에 적합한 재질 및 코팅은 내산화성, 내인화성 및 자발화성도 중요하나, 외부 발화제에 의한 내발화성이 가장 중요한 특성이 된다. 여기서는 이러한 환경에 적합하며 지상 시험용 노즐 및 배관에 적용될 수 있는 재질 및 코팅에 대하여 조사한다. 러시아는 이미 이러한 환경에 적합한 재질 및 코팅들을 개발하여 RD-170, 180에 적용 중이다. 그러나 미국은 최근에 이러한 연구를 시작한 것으로 추정된다. 따라서 자료 접근이 가능한 범위에서 러시아의 재질 및 코팅을 조사하며, 미국 자료에서는 산소 시스템 안전 등과 같이 간접적인 자료들을 통하여 대체가 가능한 후보 재질 및 코팅을 조사한다. 다단연소싸이클 연소시험 배관에 적용할 수 있는 방법은 다음과 같다. 코팅 없이 Monel K500을 사용하거나, OFHC 혹은 Ni 라이너에 고강도 외피를 사용하는 방법이 있으나, 두 방법 모두 재질의 가격 및 수급, 라이너 적용 방법 등이 어려울 수 있다. 국내에서 산화제과잉 가스 환경에서 적용할 수 있는 법랑을 개발하거나 수급이 용이한 법랑을 찾아 오스테나이트 스테인리스강에 적용하는 방법이 있다. 이 방법은 외부 발화제에 대한 내발화성을 증가시키는 경제적이고 용이한 방법으로 판단된다.

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Linguistic Features of Spontaneous Speech Production in Normal Aging, Alzheimer's Disease (정상 노인과 알츠하이머성 치매 환자의 자발화 산출에서의 언어적 특징)

  • Kim, Jung Wan
    • 한국노년학
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    • v.32 no.3
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    • pp.747-758
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    • 2012
  • Detecting probable Alzheimer's disease (AD) at an early stage is crucial in slowing the progression of the disease and initiating drug therapy for more effective symptom management. Therefore, this study aimed to identify linguistic features that allow us to distinguish between patients with AD and normal controls. This paper reports on characteristics of spontaneous speech in subjects in three stages of AD (questionable, mild, moderate) compared with education- and age-matched normal controls. Four components of speech were measured in Korean native speakers with AD and normal aging: speech tempo, hesitation (measured in seconds), rate of articulation errors, and rate of grammatical errors. The results revealed significant differences in most of these speech components among the four groups, including significant differences between normal controls and the questionable AD group in the areas of speech tempo and rate of grammatical errors. Phonological? articulatory ability was preserved in questionable AD, and grammatical ability was preserved in questionable and mild AD. Subjects with moderate AD were severely impaired in grammatical ability. Prospective assessments of spontaneous speech skills using a dialogue and picture-description task are useful in detecting the subtle, spontaneous speech impairments that AD causes even in its early stage.

Relation among Mother's Interaction Behavior, Mother's Language Input and Children's MLU: A Comparison between Multicultural- and Korean-Families (어머니의 상호작용행동 및 언어입력과 영·유아의 언어발달과의 관계: 다문화가정과 일반가정의 비교)

  • Park, Hye-Won;Lee, Kuk-Hee;Cho, Jeung-Ryeul
    • Korean Journal of Human Ecology
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    • v.21 no.3
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    • pp.439-451
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    • 2012
  • Maternal interaction behavior, language input and children's language of 34 multicultural families were compared with those of ordinary families. MLU's of multicultural mothers and their children were shorter than those of ordinary Korean mothers and children. Positive maternal interaction behaviors of multicultural mothers were significantly lower than those of ordinary mothers. Correlational analyses revealed that there were positive correlations among maternal interaction behaviors, mother's MLU and children' MLU in multicultural families. However, there were no such correlations in ordinary families. Findings suggest language education and support for multicultural mothers be an effective policy for their children's language development.

Complex Sentence Development of Korean-Chinese Bilingual Children (한국어-중국어 이중 언어 아동의 한국어 발달 : 복문발달을 중심으로)

  • Lee, Kwee-Ok;Lee, Hae-Ryoun
    • Korean Journal of Child Studies
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    • v.29 no.5
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    • pp.1-12
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    • 2008
  • This study investigated the development of complex sentences in the early utterances of Korean-Chinese children. The subjects were 47(20 2-year-old, 15 3-year-old, and 12 4-year-old) Korean-Chinese children living in China. Each child's spontaneous natural speech during interaction with his/her caregiver was videotaped for about 30 minutes and analyzed for Korean complex sentences using Kim's(2000) categories and Korean Computerized Language Analysis 2.0(2000). Results showed that older children were higher in Mean Length of Utterance and in number and frequency of word types than younger children. The language development of bilingual children was delayed compared with monolingual children but the developmental sequence between bilingual and monolingual children was similar.

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노출평가를 위한 TLV 근거 - PHOSPHORUS(YELLOW)

  • Kim, Chi-Nyeon
    • 월간산업보건
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    • s.380
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    • pp.8-15
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    • 2019
  • 황색인(Yellow phosphorus)에 대한 직업적 노출기준 TLV-TWA는 0.1 mg/㎥(0.02ppm)으로 권고하였다. 이 수준은 보고된 간경변증을 포함하여 호흡기 자극, 급성 중독인 전해질 불균형, 심근 붕괴 및 신장 피질 괴사의 가능성을 최소화하기 위한 것이다. 그러나 제한된 자료로 인중독성괴저(phossy jaw)와 같은 만성적 영향에 대한 보호 한계 수준을 설정하기에는 불확실하다. 입자 상태의 인(phosphorus)에 대한 노출은 예상되지만 증기압 수준을 감안할 때 증기에 대한 직업적 노출의 유해성을 내포하고 있다. 황색인은 가장 독성이 강한 무기 물질 중에 하나이다. 또한, 결정체 고체(crystalline solid)는 30℃ 이상의 온도에서 공기 중에 자발적으로 발화될 수 있으며, 독성이 높은 흄도 방출될 수 있다.

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Exploring a Teacher's Argumentation-Specific Pedagogical Content Knowledge Identified through Collaborative Reflection and Teaching Practice for Science Argumentation (협력적 성찰과 과학 논변수업 실행에서 드러난 교사의 논변특이적 PCK 탐색)

  • Kim, Suna;Lee, Shinyoung;Kim, Heui-Baik
    • Journal of The Korean Association For Science Education
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    • v.35 no.6
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    • pp.1019-1030
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    • 2015
  • This study examined the development of a teacher's teaching practice and identified argumentation-specific pedagogical content knowledge (PCK) and the influence of the argumentation-specific PCK on teaching practice in an argumentation classroom. The teacher has a Ph.D degree in science education, a 19-year teaching career, and no experience in instructing in an argumentation classroom. The developed program consists of nine lessons regarding photosynthesis for 7th graders. The teacher participated in a collaborative reflection with researchers after each lesson once a week and five times in total, which lasted for thirty minutes. All of the lessons were video- and audio-recorded and the transcript of lessons and collaborative reflection, pre- and post-survey related to argumentation, and researchers' journals were analyzed. Analysis of the data showed that the teacher emphasized group interaction showing utterances of listening, evaluating arguments, counter-arguing/debating, and reflecting on argument process after the fourth lesson although the teacher focused on individual argumentation showing utterances of talking, knowing meaning of argument, and justifying with evidence in the first three lessons. Also, the argumentation-specific PCK, which was identified with the understanding of students, nature of argumentation and argumentation task strategy, also influenced the development of teaching practice. The teacher comprehended the students' challenges in argumentation, developed her understanding of the nature of argumentation from an individual plane to social plane, and demonstrated a deep understanding of the task strategy by voluntarily joining in modifying the argumentation tasks.

Development and Application of the Scientific Inquiry Tasks for Small Group Argumentation (소집단의 논변활동을 위한 과학 탐구 과제의 개발과 적용)

  • Yun, Sun-Mi;Kim, Heui-Baik
    • Journal of The Korean Association For Science Education
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    • v.31 no.5
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    • pp.694-708
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    • 2011
  • In this study, we developed tasks including cognitive scaffolding for students to explain scientific phenomena using valid evidences in science classroom and sought to investigate how tasks influence the development of small group scientific argumentation. Heterogeneous small groups in gender and achievement were organized in one classroom and the tasks were applied to the class. Students were asked to write down their own ideas, share individual ideas, and then choose the most plausible opinion in a group. One group was chosen for investigating the effect of tasks on the development of small group argumentation through the analysis of discourse transcripts of the group in 10 lessons, students' semi-structured interview, field note, and students' pre- and post argument tests. The discrepant argument examples were included in the tasks for students to refute an argument presenting evidences. Moreover, comparing opinion within the group and persuading others were included in the tasks to prompt small group argumentation. As a result, students' post-argument test grades were increased than pre-test grades, and they argued involving evidences and reasoning. The high level of arguments has appeared with high ratio of advanced utterances and lengthening of reasoning chain as lessons went on. Students had elaborate claims involving valid evidences and reasoning by reflective and critical thinking while discussing about the tasks. In addition, tasks which could have various warrants based on the data led to students' spontaneous participation. Therefore, this study has significance in understanding the context of developing small group argumentation, providing information about teaching and learning context prompting students to construct arguments in science inquiry lessons in middle school.