• Title/Summary/Keyword: 입자미세화

Search Result 403, Processing Time 0.035 seconds

Physical, Morphological, and Chemical Analysis of Fly Ash Generated from the Coal Fired Power Plant (석탄 화력발전소에서 발생되는 석탄회 특성과 형성 분석에 관한 연구)

  • 이정언;이재근
    • Journal of Energy Engineering
    • /
    • v.7 no.1
    • /
    • pp.146-156
    • /
    • 1998
  • Fly ash produced in coal combustion is a fine-grained material consisting mostly of spherical, glassy, and porous particles. A physical, morphological, and chemical characteristic of fly ash has been analyzed. This study may contribute to the data base of domestic fly ash, the improvement of combustion efficiency, ash recycling and ash collection in the electrostatic precipitator. The physical property of fly ash is determined using a particle counter for the measurement of ash size distribution and gravimeter. Morphological characteristic of fly ash is performed using a scanning electron micrograph and an optical microscope. The chemical components of fly ash are determined using an inductively coupled plasma emission spectrometry (ICP). The distribution of fly ash size was ranged from 15 to 25 $\mu$m in mass median diameter. Exposure conditions of flue gas temperature and duration within the combustion zone of the boiler played an important role on the morphological properties of the fly ash such as shape, relative opacity, coloration, cenosphere and plerosphere. The spherical fly ash might be generated at the condition of complete combustion. The size of fly ash was found to be increased the with particle-particle interaction of agglomeration and coagulation. Fly ash consisted of $SiO_2\;Al_2O_3\;and\;Fe_2O_3$ with 85% and carbon with 3~10% of total mass.

  • PDF

Charactericstics of Glass-Ceramic having High Efficiency Diffuse Reflectance and Fabrication of Laser Cavity (MAS계 결정화유리를 이용한 레이저 여기용 공진기의 제작 및 특성분석)

  • Park, Yong-Bae;Byun, Woo-Bong;Kim, Yo-Hee
    • Proceedings of the KIEE Conference
    • /
    • 2002.07c
    • /
    • pp.1559-1561
    • /
    • 2002
  • 적외선 확산반사형 결정화유리를 응용한 레이저 여기용 공진기를 제작하여 미세구조 분석 및 레이저 여기 효율특성을 조사하였다. 출발물질로는 Cordierite를 주결정상으로 하는 MAS(MgO, $Al_2O_3$, $SiO_2$) 3성분계 조성에 결정화 유도용 조핵제로 $TiO_2$를 첨가하였으며, 형성된 유리 용융물을 흑연제 몰드에 부어 공진기를 제조하였다. 용융물 중 일부를 2단계 열처리를 행하여 상분석을 실시한 결과 Cordierite($2MgO{\cdot}2Al_2O_3{\cdot}5SiO_2$)와 Rutile($TiO_2$)이 주결정상으로 관찰되었으며, 열처리 온도를 변화시켜 생성된 입자의 크기에 따른 확산반사율간의 관계를 조사한 결과, $1100{\sim}1200nm$에서 열처리된 시편의 경우 $500{\sim}2200nm$의 영역에서 95% 이상의 확산반사율을 나타내었다. 대표적인 고체레이저인 Nd:YAG의 경우, $700{\sim}900nm$ 파장이 주흡수대이며, 이를 결정화유리로 제조된 공진기의 레이저 효율특성실험에 이용하였다. 수냉 및 단일 펄스의 조건에서 $1.7{\sim}1.9%$의 효율을 나타내었다.

  • PDF

Low-Temperature Microencapsulation of Sesame Oil Using Fluidized Bed Granulation (Fluidized bed granulation을 이용한 참기름의 저온 미세캡슐화)

  • Jeong, Chan-Min;Lee, Min-Kyung;Lee, Hyun-Ah;Park, Ji-Yong
    • Korean Journal of Food Science and Technology
    • /
    • v.41 no.1
    • /
    • pp.27-31
    • /
    • 2009
  • Top spray-drying method is frequently utilized for flavor encapsulation, but the top spray-dried products frequently suffer from high losses of volatile flavor as the result of a high processing temperature (150-$300^{\circ}C$). In an effort to solve these problems, a low-temperature fluidized-bed granulating method was utilized to encapsulate the flavor. For the encapsulation of sesame oil, oil-in-water emulsions of sesame oil and a mixture of maltodextrin, modified starch, gum arabic, and gellan gum were bottom-sprayed at milder temperatures (70-$100^{\circ}C$) using a fluidized-bed granulator. Sesame oil extracts from microcapsules were obtained via a simultaneous distillation/extraction technique, and the retention of volatile flavor compounds was analyzed via a gas chromatography-mass spectrometry. The retention of volatile flavors of sesame oil per se, spray-dried and fluidized-bed granulated microcapsules after 3-day-storage at $37^{\circ}C$ were 0.8%, 37.2%, and 42.0%, respectively. In addition, the low-temperature fluidized-bed granulation showed higher encapsulation yield and sensory preferences for the application of commercial products (beef rice porridge), as compared to spray drying.

Enhancing maintenance performance of tunnel drainage using vibration from polyvinylidene fluoride(PVDF) film (압전필름의 진동을 활용한 터널배수재 유지관리 성능 개선)

  • Xin, Zhen-Hua;Moon, Jun-Ho;Song, Young-Karb;Kim, Young-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.16 no.1
    • /
    • pp.822-826
    • /
    • 2015
  • This study investigated the possible use of vibration from polyvinylidene fluoride(PVDF) film to enhance the performance of the deteriorated tunnel drainage due to physical/chemical clogging of the fine particles through a series of laboratory experiments. The test program was consisted of two different experiments, fundamental investigation and drainage model test. In the fundamental investigation, flow of clay slurry mixed with 50% water (freshwater and brine) on PVDF film with various frequencies was examined. In the model tests, slurry clogging to the woven fiber attached to drainage pipe and its reduction by vibration was investigated. Results of the experiment show that vibration from PVDF film enhances the drain performance significantly. Based upon the investigation, it gives an essential data that are needed for a potential use of hybrid drainage system with PVDF.

The Effect of Mechanical Grinding on the Magnetic Properties of Nd-Fe-B Ingots (분쇄처리가 Nd-Fe-B계 ingot의 자기적 특성에 미치는 영향)

  • Hwang, Yeon;Kim, Taek-Soo;Lee, Hyo-Sook
    • Korean Journal of Materials Research
    • /
    • v.8 no.11
    • /
    • pp.1038-1042
    • /
    • 1998
  • Mechanical grinding and subsequent annealing were applied to the $Nd_5Pr_7Fe_{82}B_6$ and $Nd_{12}Fe_{82}B_6$ ingots, and the crystal structure and magnetic properties were investigated. After 330 hours milling, the particles with $2~3\mu\textrm{m}$average size were identified to be composed of very fine crystallites judging from the x-ray diffraction patterns. The intrinsic coercivity of 18.36 ~ 18.79 kOe and the maximum energy product of 8.32-8.38 MGOe were obtained by the annealing of the milled powders at $600^{\circ}C$ for 2 hours. Annealing at a higher temperature resulted in the improved magnetic properties. However it was revealed that the control of the micro-crystallites formed during the grinding process was more important to get an optimized magnetic properties than the annealing condition.

  • PDF

Validation of the emission inventory of volatile organic compounds in Seoul (서울의 휘발성유기화합물 배출량 자료 검증)

  • Kim, Yong Pyo
    • Particle and aerosol research
    • /
    • v.5 no.3
    • /
    • pp.139-148
    • /
    • 2009
  • In Seoul, the largest emission source for volatile organic compounds (VOCs) based on the emission inventory is solvent usage followed by vehicular exhaust. However, according to a CMB modeling result by Na and Kim (2007), vehicular exhaust was the largest emission source followed by solvent usage. Detailed analyses on the validity of the CMB model result were carried out and it was suggested that the existing emission inventory for VOCs might be underestimating vehicular emission. Scientific considerations that should be considered for the effective control strategy against VOCs are discussed.

  • PDF

Preparation of Monodispersed Polystyrene Latex Spheres (PLS) as Artificial Dusts (인공 먼지로서 단분산 Polystyrene Latex Spheres (PLS)의 제조)

  • Kim, Ok Hee;Ryu, Dong Wan;Sung, Dong Chan;Moon, Hee
    • Applied Chemistry for Engineering
    • /
    • v.23 no.1
    • /
    • pp.59-64
    • /
    • 2012
  • Polystyrene latex spheres (PLS) were prepared as artificial dusts by the emulsion polymerization with potassium persulfate (KPS) and sodium dodecyl sulfonate (SDS) as an initiator and a stabilizer, respectively. The reaction temperature and the concentration of the initiator and stabilizer were chosen as variables to control the PLS particle size. As temperature increased, the particle size decreased considerably. Furthermore, the PLS particle size and their size distributions can be controlled minutely by adjusting the concentrations of KPS and SDS. It is confirmed that the PLS prepared in this work is monodispersed with the coefficient of variance less than 7% and are in the range of 0.1~0.5 ${\mu}m$, which are good for using as artificial dusts.

Attrition Characteristics of Korean Antracite Ash in Fluidized Bed Combustors (유동층 연소로에서 국내탄 회재의 마모 특성)

  • Lee, See Hoon;Kim, Sang Done;Kim, Jae Sung;Lee, Jong Min
    • Applied Chemistry for Engineering
    • /
    • v.17 no.5
    • /
    • pp.547-551
    • /
    • 2006
  • In the reactor following the American standard test method (ASTM) D5757-95 and lab-scale fluidized bed combustor, the attrition characteristics of sand and ash of Korean anthracite were investigated. The attrition characteristics, such as particle size distribution of fly ash, attrition rate, and attrition ratio etc, were studied with variation of gas velocities. The particle attrition of ash was more active than sand which was generally used as a fluidized material and also the attrition index of ash taken by ASTM D5757-95 was 5 times higher than that of sand. The formation of fine particles continuously occurred due to particle attrition with increasing gas velocities. The following equation has been suggested for attrition rate of ash. $$\frac{dW}{dt}=-3.18{\times}10^{-7}(U-U_{mf})W$$.

A Study on the magnetic properties of Mn-Zn Ferrite (Mn-Zn Ferrite의 자기적 특성에 관한 연구)

  • Kim Do-Hwan;Choi Young-Ji;Kwon Oh-Heung
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2006.05a
    • /
    • pp.898-901
    • /
    • 2006
  • In this paper, effect of ceramic processing was investigated on the magnetic properties of low loss Mn-Zn ferrite. High frequency characteristics, high saturated magnetic flux density and high magnetic permeability and low magnetism loss are required for the development of Mn-Zn ferrite, which is parts in the communication. therefore, in order to improve Mn-Zn ferrite with a high frequency , it is important to have a minimal change of particles and to control the eddy current loss caused by high resistance of the stratum of particles and to reduce the hysteresis loss by uniform change of detailed structure. In this paper, we added $V_2O_5\;and\;CaCo_3$ to Mn-Zn Ferrite to achieve a high efficiency, low loss core material. The compositions are MnO : ZnO : $Fe_2O_3$ = 21 : 10 : 69 mol%. They were sintered at $1250^{\circ}C$ for Three hours. Initial permeability was measured at 0.1MHz. At 50mT, Power loss was measured by temperature changing at 100kHz.

  • PDF

Fabrication of Double-layered Porous Materials (이중 기공구조를 갖는 다공질체의 제조)

  • Yun, Jung-Yeul;Kim, Hai-Doo;Park, Chun-Hong
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.10
    • /
    • pp.919-927
    • /
    • 2002
  • In order to fabricate double-layered porous materials powders of different particle sizes were pressed stepwise. Ford's equation which predicts the fired density with the change in pressed density was employed in order to adjust the difference in sintering shrinkage of the green body with double-layered porous structure. Double-layered porous materials were characterized by investigating microstructures and permeability. SEM micrographs showed the distinct difference in pore sizes of double-layered porous material. Permeability of single-layered porous material increased by increasing the starting particle sizes and porosity as well. Permeability of the double-layered porous material depends largely on the layer of small pore diameter.