• Journal of Marine Life Science
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• v.5 no.1
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• pp.25-33
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• 2020

The Asan Bay, which has semi-diurnal tide with macro-tidal range, is affected by both freshwater discharge from the sluice gates in the sea dikes and tidal seawater inputs from the Yellow sea. Understanding water quality change in response to tides is important since tides can impact the short-term variations in physical and chemical water properties as well as the response of biological properties. The diel variations in water quality were seasonally investigated at 2 hour intervals from a fixed station in the Asan Bay. In the results, water temperature and salinity consistently fluctuated in phase or out of phase with tidal height. Especially salinity was positively correlated with tidal height. The concentrations of total suspended solids were higher in the bottom water than in the surface and fluctuated greatly over the tidal cycle recording higher values at low tide than at high tide. Nitrite+nitrate levels also fluctuated out of phase with tidal height and correlated negatively with tidal height. Other nutrients also showed a similar pattern. The pattern was distinct in July when freshwater was discharged before the field sampling. The concentrations of organic materials, total nitrogen and total phosphorus greatly fluctuated over the tidal cycle and were generally out of phase with tidal height. Most materials except particulate organic forms were correlated with salinity indicating that freshwater inputs were sources for the materials similarly to the dissolved inorganic nutrients. The results suggest that water quality (except dissolved oxygen and pH) and nutrients including organic materials was largely affected by tides in the Asan Bay.

• Journal of the Korean Society of Marine Environment & Safety
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• v.23 no.7
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• pp.885-892
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• 2017

We estimated the limiting nutrient and DIP limiting history based on alkaline phosphatase (APase) activity during the spring of 2017 in the Southern Sea, Korea. In the frontal area, concentration of dissolved inorganic phosphorus (DIP), dissolved inorganic nitrogen (DIN): DIP ratio and Chlorophyll a (Chl-a) were < $0.2{\mu}M$, 23.2 and $2.2{\mu}g/L$, respectively, indicating high productivity despite DIP limiting. The relationship between APase and DIP indicates that the study area had limited DIP because of a strongly reverse correlation (r= -0.81; P<0.001). Relationship between APase and Chl-a (r=0.61, p<0.001) also indicated that APase may have been induced by phytoplankton (ca. 60 %) and bacteria (ca. 40 %). In DIP limiting history in this study area, frontal area and non-frontal areas might have induced long-term DIP limitation and the recent relief from DIP-limitation, respectively, based on distributions of dissolved APase and particulate APase. Thus, these results suggest that by measuring the enzyme that hydrolyzes organic matter such as APase in frontal area, it is possible to estimate temporal and spatial characteristics of limiting nutrient, thereby improving our understanding of biogeochemistry cycles.

• Journal of radiological science and technology
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• v.44 no.4
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• pp.359-365
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• 2021

A heavy particle accelerator is a device that accelerates particles using high energy and is used in various fields such as medical and industrial fields as well as research. However, secondary neutrons and particle fragments are generated by the high-energy particle beam, and among them, the neutrons do not have an electric charge and directly interact with the nucleus to cause radiation of the material. Quantitative evaluation of the radioactive material produced in this way is necessary, but there are many difficulties in actual measurement during or after operation. Therefore, this study compared and evaluated the generated radioactive material in the concrete shield for protons and carbon ions of specific energy by using the simulation code FLUKA. For the evaluation of each energy of proton beam and carbon ion, the reliability of the source term was secured within 2% of the relative error with the data of the NASA Space Radiation Laboratory(NSRL), which is an internationally standardized data. In the evaluation, carbon ions exhibited higher neutron flux than protons. Afterwards, in the evaluation of radioactive materials under actual operating conditions for disposal, a large amount of short-lived beta-decay nuclides occurred immediately after the operation was terminated, and in the case of protons with a high beam speed, more radioactive products were generated than carbon ions. At this time, radionuclides of ⁴⁴Sc, ³H and ²²Na were observed at a high rate. In addition, as the cooling time elapsed, the ratio of long-lived nuclides increased. For nonparticulate radionuclides, ³H, ²²Na, and for particulate radionuclides, ⁴⁴Ti, ⁵⁵Fe, ⁶⁰Co, ¹⁵²Eu, and ¹⁵⁴Eu nuclides showed a high ratio. In this study, it is judged that it is possible to use the particle accelerator as basic data for facility maintenance, repair and dismantling through the prediction of radioactive materials in concrete according to the cooling time after operation and termination of operation.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.519-524
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• 2022

Domestic building finishing materials are being evaluated according to KS F 2271 standards according to the notification of the Ministry of Land, Infrastructure and Transport, and this test is evaluated using laboratory animals. In this study, experiments were conducted on highly combustible organic insulation materials such as EPS, urethane, and phenolic foam. The purpose of this study was to analyze the cause of the behavioral suspension of the experimental mice by measuring the average behavioral suspension time of the mice caused by the harmful gas generated when these three types of insulation materials were burned. FTIR analysis and smoke density experiment were performed as a cause analysis method for the behavioral suspension of mice, and the experimental results were analyzed by dividing the causes of behavioral suspension into suffocation by particulate matter and toxic inhalation by gaseous substances. As a result of the test, urethane was evaluated as the most harmful insulation material, and as a result of FTIR analysis and smoke density test as a cause analysis for the gas toxicity test results, it is judged that the behavioral stop of the rats by suffocation is higher than the effect of toxic inhalation. This study is a basic study on the cause analysis of harmful gases, and it will be necessary to prepare the toxicity basis and analyze various materials and gases.

• Journal of the Korean Geotechnical Society
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• v.25 no.5
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• pp.75-86
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• 2009

Salt, one of the most common soluble materials in engineering soil, may have an effect on mechanical behaviors of soils under its cementation process. In order to investigate this natural phenomenon, non-soluble material by using glass beads is mixed with salt electrolyte and cemented by using oven to evaporate water. Three different sizes of glass bead particles, 0.26, 0.5, and 1.29 mm, with different salt concentration, 0, 0.1, 0.2, 0.5, 1.0, and 2.0M, are explored by using P- and S-waves, excited by bender elements and piezo disk elemets, respectively. The velocities of the P-wave and S-wave of the particulate medium cemented by salt show three stages with the degree of saturation: 1) S-wave velocities increase while P-wave velocities reduce with degree of saturation changing from 100% to 90%; 2) Both velocities are stable with degree of saturation varying from 90% to 10%; 3) The velocities change enormously when the specimens are nearly dry with degree of saturation from 10% to 0%. Besides, the resonance frequencies of S-wave show similar stages to the S-wave velocities. This study demonstrates meaningful trends of elastic wave characteristics of geo-materials according to the cementation of dissolved salt.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.14 no.1
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• pp.56-62
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• 2009

Stable carbon isotope analysis was used to investigate the autotrophic carbon sources supporting fisheries in three coastal bay systems of the southern coast of Korea. Carbon isotope ratios (${\delta}^{13}C$) of 31 fish species were analysed and compared with those of a range of potential primary food sources [e.g., seagrass (Zostera marina), seagrass epiphytes, benthic microalgae, macroalgae, marine particulate organic matter (marine POM), marsh plant (Phragmites australis) and terrestrial POM]. ${\delta}^{13}C$ values (range, -16.2${\sim}$-8.3‰) of fishes from the coastal embayment systems were overlapped with those of seagrass (-8.3${\pm}$1.9‰), seagrass epiphytes (-12.4${\pm}$0.6‰), benthic microalgae (-15.4${\pm}$1.6‰) and macroalgae (-16.0${\pm}$1.8‰). In addition, fishes (-12.9${\pm}$1.5‰) from the study area had distinctly higher ${\delta}^{13}C$ values compared to those collected in offshore sites (-17.3${\pm}$0.8‰) of the southern sea of Korea and Nakdong River (-23.2${\pm}$1.6‰). This result indicates that carbon supporting fish communities of these coastal bay systems is mainly derived from the local benthic producers.

• Journal of The Korean Association For Science Education
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• v.26 no.3
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• pp.367-375
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• 2006

This study investigated the effects of varying visuals in drawing and writing as methods to assist students in connecting and integrating multiple external representations provided in learning the particulate nature of matter. Seventh graders (N=233) at a coed middle school were assigned to control, static drawing (SO), dynamic drawing (DD), static writing (SW), and dynamic writing (DW) groups. The students were taught about "Boyle's Law" and "Charles's Law" for two class periods. Two-way ANCOVA results revealed that the scores of a conception test for the two drawing (SD, DD) groups and the two writing (SW, DW) groups were significantly higher than those for the control group. Within the writing groups, students of lower spatial visualization ability in the DW group scored significantly higher than those in the SW group. However, no significant differences were found in the scores of the conception test for the two drawing (SD, DD) groups regardless of students' visualization ability. Researchers also found that most students in both DD and DW groups had respectively positive perceptions of dynamic visuals in drawing or writing.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.29 no.1
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• pp.1-13
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• 2024

The southwestern part of the East Sea is known to have a high primary productivity compared to those in the northern and eastern parts, which is attributed to nutrients supplies either by Tsushima Warm Current or by coastal upwelling. However, research on the biological pump in this area is limited. We developed machine learning models to estimate net community production (NCP), a measure of biological pump, with high spatial and time scales of 4 km and 8 days, respectively. The models were fed with the input parameters of sea surface temperature, chlorophyll-a, mixed layer depths, and photosynthetically active radiation and trained with observed NCP derived from high resolution measurements of surface O₂/Ar. The root mean square error between the predicted values by the best performing machine model and the observed NCP was 6 mmol O₂ m^-2 d^-1, corresponding to 15% of the average of observed NCP. The NCP in the central part of the Ulleung Basin was highest in March at 49 mmol O₂ m^-2 d^-1 and lowest in June and July at 18 mmol O₂ m^-2 d^-1. These seasonal variations were similar to the vertical nitrate flux based on the ³He gas exchange rate and to the particulate organic carbon flux estimated by the ²³⁴Th disequilibrium method. To expand this method, which produces NCP estimate for spring and summer, to autumn and winter, it is necessary to devise a way to correct bias in NCP by the entrainment of subsurface waters during the seasons.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.5
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• pp.443-454
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• 2010

Phthalate compounds are widely used as plasticizers in polyvinyl chlororide (PVC) resins and other industrial consumer products, and some of them are known to be endocrine disruptors. In Korea, a number of studies have been carried out for the measurement of phthalates in consumer products and drinking water. However, no data are available for those compounds in the ambient air where the general public are routinely exposed. In this study, we evaluated sampling and analytical methods for the determination of phthalates in the ambient atmosphere. A wide range of phthalates compounds were included in the target analytes, which are dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), butyl benzyl phthalate (BBP), di(2-ethylhexyl) phthalate (DEHP), and di-n-octyl phthalate (DOP). Most of samples were collected using a high volume sampler with a PUF/XAD-2 column/quartz fiber filter and then analyzed by GC/MS. Some of samples were simultaneously collected on XAD-2 using a low-volume sampler, together with high-volume samples. The analytical method applied in this study showed good repeatability and linearity. Quantitative detection limits were estimated from 0.60 to 17.84 ng/$m^3$ in air, depending on individual compounds. The field measurements were carried out at 3 sites located in Sihwa- Banwall industrial areas and a suburban area from January 2007 to November 2007. From the field experiments, DEHP, DMP and DBP appeared to be the most abundant compounds in the ambient air. It was also found that DMP, DEP and DBP were mainly distributed in the vapor phase, while BBP, DEHP and DOP were predominantly associated with the particulate phase. The concentrations of DEHP and DMP in the industrial areas ranged from 45.7 to 1,012.7 ng/$m^3$ and from 7.7 to 375.1 ng/$m^3$, respectively. Overall, the high-volume sampling method was demonstrated to be superior to the low-volume method for the determination of phthalates in the ambient atmosphere.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.34 no.4
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• pp.291-298
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• 2001

Seawater, sediment and biota in the Kwangyang Bay were analyzed by gas chromatography/quartz furnace atomic absorption spectroscopy (GC-QFAAS) to investigate concentrations and distribution pattern of butyltin compounds (TBT, DBT, MBT) during February, April and July, 1996, Marine biota analyzed were Tapes japcnicus and Crassostrea gigas. The concentrations of tributyltin (TBT) in seawater were in the range of ND-15.7 ng/L for the surface and ND-68.5 ng/L for the bottom. The highest concentration of TBT in seawater was detected in April for the both, surface and bottom water. The maximum value of $TBT_{(bottom)}/TBT_{(surface)}$, 3.6 in April showed the increased input of TBT from the surface water in April compared to February (2.1) and July (0.9). The concentrations of TBT in the sediment were in the range of ND-8.5 ng/g dry wt. The highest concentration of TBT in the sediment was measured in July, This result seems to attributed to the removal of TBT from water column via sorption onto particulate matters to the relatively undisturbed underlying sediment and increased input of TBT by increased fluxes of detritus of marine plankton after spring bloom, in July. The mean values of partitioning coefficient ($K_d$) of TBT between seawater and sediment were $3.0\times10^3$(February), $7.4\times10^3$(April) and $9.4\times10^3$(July). The concentrations of TBT in biosamples were in the range of ND-93.30 ng/g dru wt. (T. japonicus) and ND-138.53 ng/g dry wt. (C. gigas). The seasonal variation of TBT contents in biota was remarkable. The $K_d$ (biological concentration factor) was $7-41\times10^3$ for T. japonicus. and $5-34\times10^3$ for C. gigas. The measured TBT concentrations in seawater in the study area was sufficient to cause the imposex of shellfish and to retard the growth of aquatic organisms including oyster upon chronic exposure.