• Title/Summary/Keyword: 입계확산

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Oxidation Behavior and Magnetic Properties of Nd-Fe-B Based Melt-Spun Ribbons (Nd-Fe-B계 급냉리본의 산화거동과 자기적 특성)

  • Jo, Beom-Rae;Kim, Jin-Gu;Song, Jin-Tae;Gang, Gi-Won
    • Korean Journal of Materials Research
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    • v.5 no.4
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    • pp.483-489
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    • 1995
  • Nd-(Fe, Co)-B합금에 Ni, Al, Ti등을 복합치환하여 그에 따른 산화거동과 자기적 성질의 변화를 조사하였다. 이들 리본의 산호거동은 parabolic한 거동을 나타내고 있으며, Ni 첨가시 매우 낮은 산화량을 나타내었다. 또한 산화된 리본은 Nd-rich상의 우선적 산화에 의해 표면에 요철이 관찰되었으며 Ni 첨가시 그러한 요철은 많이 줄어들었다. 표면의 산화층은 Nd산화물이었고, 이는 입계에 있는 Nd-rich상이 산화되고 이것이 확산 통로로 작용하였다고 생각된다. 산화가 진행됨에 따라 입계상에 의한 domain wall pinning이 약해져 자기특성이 저하하였다. 그러나 Ni 첨가시 이러한 산화거동이 크게 억제되었으며 Ni의 첨가는 Nd-rich상의 산화저항성을 증가시킴으로써 리본의 산화를 억제해 자기특성의 저하를 억제하였다.

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Dislocation Density Propagation adjacent to the Low Angle Grain Boundaries of Polycrystalline Materials (다결정 미세입자 소각입계면에서의 전위밀도 확산)

  • Ma, Jeong-Beom
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.5
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    • pp.618-622
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    • 2011
  • Specialized large-scale computational finite-element and molecular dynamic models have been used in order to understand and predict how dislocation density emission and contact stress field due to nanoindentation affect inelastic deformation evolution scales that span the molecular to the continuum level in ductile crystalline systems. Dislocation density distributions and local stress fields have been obtained for different crystalline slip-system and grain-boundary orientations. The interrelated effects of grain-boundary interfaces and orientations, dislocation density evolution and crystalline structure on indentation inelastic regions have been investigated.

1773K 에서 dopant 첨가에 따른 (U,Ce)$O_2$ 의 크립거동

  • 나상호;김시형;정창용;김한수;이영우
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.181-185
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    • 1998
  • 모의 혼합산화물인 (U,Ce)O$_2$ 에 dopant 인 Li$_2$O 와 SiO$_2$ 를 첨가한 소결체의 압축크립변형거동을 수소분위기, 온도 1773K 에서 응력(10-120MPa)을 변화시켜 조사하였다. Dopant 를 첨가할 경우 정상상태 크립변형속도는 첨가하지 않은 경우보다 크게 증가하는 것으로 나타났다. 증가한 원인으로는 Li$_2$O 를 첨가한 경우 우라늄 확산계수의 증가에 기인되며, SiO$_2$ 를 첨가한 경우에는 SiO$_2$ 가 glassy phase 로 입계에 위치하여 입계이동이 용이하게 되어 정상상태 크립변형속도가 증가한 것으로 사료된다. 또한 저응력구간에서 (U,Ce)O$_2$ 의 크립활성화에너지는 109.6 kcal/mol 로 $UO_2$ 의 크립활성화에너지(94.2kca1/mol)보다 더 크게 나타났다.

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The Role of Grain Boundary Diffusion in the Activated Sintering of Tungsten Powder (텅스텐 활성소결에서 입계확산의 역할)

  • 이재성
    • Journal of Powder Materials
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    • v.1 no.1
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    • pp.79-84
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    • 1994
  • The mechanism of activated sintering of tungsten powder was discussed in terms of diffusion and segregation of activator atoms at W grain boundaries. Shrinkage behaviours of W-0.2wt.% Ni, W-0.2wt.% Cu or pure W powder compacts during sintering at low temperatures of 900~ $1200^{\circ}C$ were investigated. It was found that the Cu additive inhibits sintering process causing lower densification than pure W compact while remarkable shrinkage occurred in the Ni added W powder. Such contrary effect was explained by comparing self diffusion processes along Ni or Cu segregated W boundaries in which Ni segregants enhance but Cu atoms retard the migration of W atoms at W boundaries.

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A Boundary Diffusion Creep Model for the Plastic Deformation of Grain Boundary Phase of Nanocrystalline Materials (나노재료 입계상의 소성변형에 대한 입계확산크립 모델)

  • 김형섭;오승탁;이재성
    • Transactions of Materials Processing
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    • v.10 no.5
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    • pp.383-388
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    • 2001
  • In describing the plastic deformation behaviour of ultrafine-grained materials, a phase mixture model in which a polycrystalline material is regarded as a mixture of a crystalline phase and a grain boundary phase has been successful. The deformation mechanism for the grain boundary phase, which is necessary for applying the phase mixture model to polycrystalline materials, is modelled as a diffusional flow of matter along the grain boundary. A constitutive equation for the boundary diffusion creep of the boundary phase was proposed, in which the strain rate is proportional to (stress/grain siz $e^{2}$). The upper limit of the stress of the boundary phase was set to equal to the strength to the amorphous phase. The proposed model can explain the strain rate and grain size dependence of the strength of the grain boundary phase. Successful applications of the model compared with published experimental data are described.

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입계기공의 확산성장 모델을 이용한 고온 기기의 크립균열전파 해석 (2)

  • Jeon, Jae-Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.4
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    • pp.1186-1193
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    • 1996
  • The analytic solution of the stress field at creep crack in the presence of grain boundary caviation is to be obtained by solving the governing equation which was derived through the previous paper. The complex integral technique is used to slove the singular integral equation. under the help of the information about stress behaviors at the ends of integral region know by numerical solution. The resultant stress disstribution obtained shows the relaxed crack-tip singularity of $r^{1/2+\theta}$ due to the intervention of cavitation effect, otherwise, it should assumed to be $r^{1/2}$ singularity of linear elastic fracture mechanics with no cavitation.

Distribution Behavior of Solute Element in Al-Mg-Zn Alloy Continuous Cast Billet During Homogenization Treatment (Al-Mg-Zn계 알루미늄 합금 연주 빌렛 균질화처리과정 중 용질원소 거동변화)

  • Myoung-Gyun Kim
    • Journal of Korea Foundry Society
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    • v.43 no.6
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    • pp.286-293
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    • 2023
  • In this study, we investigated the microstructural evolution of Al-Mg-Zn aluminum alloy billet during homogenization treatment using OM, SEM, EDS and DSC. There were numerous phases found, such as; AlMgZn, AlMgFe, and AlMgZnSi phases, in the grain of the cast billet. After 6 hours homogenization treatment, Zn was mostly dissolved, whereas, Mg and Si were only partly dissolved. Accordingly, only AlMgFe and AlMgSi remained. After 18 hours, all of the leftover Mg and Si were dissolved, leaving only AlMgFe, which was also found after 24 hours. The results of the alloy design program, JMatPro showed that Mg dissloved more rapidly than Zn. According to the homogenization kinetic equation, Mg and Zn are completely dissolved within 1.9 and 3.5 hours, respectively.