• Polymer(Korea)
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• v.28 no.1
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• pp.51-58
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• 2004

The molecular cluster model for the homogeneous bubble nucleation rather than the classical nucleation theory was extended to predict the bubble nucleation events in elastomers(cross-linked polymers), polymers and polymer which are dissolved in the organic solvent. The classical theory assumes the formation of the critical bubble while the molecular cluster model assumes the critical cluster as for the initiation of the bubble nucleation. For the bubble nucleation in elastomers and polymers, the strain energy overcome by a critical bubble was also considered. The calculation results for the number of bubbles nucleated in elastormers and polymer solutions, which are about 10$\^$8/∼10$\^$12/ bubbles/㎤ are in good agreement with observed ones.

• Journal of Korea Foundry Society
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• v.23 no.3
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• pp.147-152
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• 2003

질소 용해도가 낮은 ${\delta}$상으로 응고가 시작되는 16Cr-3Ni 계 스테인리스강의 응고시 질소기포 형성에 미치는 질소 함량과 냉각속도의 영향이 조사되었으며 이를 기반으로 질소 기포 결함이 발생하는 임계 질소 함량을 예측하는 방법을 제시하였다. 질소함량의 증가는 질소 기포 결함을 증가시켰으며, 냉각속도의 증가는 질소기포결함의 형성을 다소 억제 할 수 있는 것으로 조사되었다. 실험적으로 구한 Fe-16Cr-3Ni-9Mn 합금의 임계 질소 함량은 0.19wt%였으며, 임계 질소 압력은 평형응고로 가정한 경우 1.27atm, Scheil 응고로 가정한 경우에는 1.23atm으로 계산되었다. 질소 용해도를 증가시킬 수 있는 Mn 함량의 변화에 따른 임계 질소 함량의 변화를 예측하기 위하여 계산된 임계 질소 압력을 Fe-16Cr-3Ni-11Mn 합금에 적용하였으며 이를 통해 얻은 임계 질소 함량은 평형응고로 가정한 경우 0.25wt%, Scheil 응고로 가정한 경우에는 0.24wt% 로 예측되었다. 예측 결과의 타당성을 확인하기 위하여 Fe-16Cr-3Ni-11Mn 합금의 실험 결과와 비교하였으며, 일치하는 결과가 얻어졌다.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.05a
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• pp.329-334
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• 1997

기포막 제한 및 기포 군집 이론에 의한 해석적 접근을 통해 축방향 출력분포가 임계열속에 미치는 영향을 파악하고, 이를 근거로 임계열속 발생지점에서의 엔탈피 변화를 고려하여 축방향 출력분포에 따른 임계열속 예측치 보정 모델을 개발하였다. 제안된 모델의 검증을 위해 cosine 형태의 축방향 출력분포를 갖는 임계열속 측정치와 비교하였으며, 그 결과 제안된 모델은 측정치에 대해 평균 1.0072, 표준편차 9.98%의 예측 성능을 나타냈다.

• Nuclear Engineering and Technology
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• v.27 no.6
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• pp.918-931
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• 1995

임계열속을 예측하는 기존의 여러 방법중 임계열속 발생 역학구조에 근거한 이론적 접근 방법은 여러 유동형태(Flow pattern)별로 연구되고 있으며, 대표적으로 환상유동에서의 LFD(Liquid Film Dryout) 이론, 기포류에서의 BBLD(Bubble Boundary Layer Dryout) 흑은 LNID(Local Nucleation Initiated Dryout)이론 등이 제시되고 있다. 본 논문에서는 일반적으로 원자로 조건에 서 적용될 수 있는 LFD이론과 BBLD 이론에 대하여 대표적인 모델들을 소개하고 특성을 검토하였다. 특히 BBLD 이론중에서 기포군집 (Bubble coalescence) 모델과 층류막 드라이 아웃(Sublayer dryout) 모델에 대해서는 원형관에서의 임계열속 시험자료를 사용하여 각 모델의 예측 성능 및 특성을 평가하였다. 평가 결과, 기포군집 모형인 Weisman 모델의 예측성능이 가장 우수했으며 아울러 층류막 드라이아웃 모델인 Katto 모델과 Mudawwar 모델은 구성 인자중 기포군속도와 층류막 두께와의 관계가 보다 정확히 모형화되야 할 것으로 판단된다.

• Clean Technology
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• v.17 no.1
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• pp.19-24
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• 2011

The bubble point pressures of binary mixtures of carbon dioxide ($CO_2$) and N,N-dimethylformamide (DMF) were measured by using a high-pressure experimental apparatus equipped with a variable-volume view cell, at various $CO_2$ compositions in the range of temperatures above the critical temperature of $CO_2$ and below the critical temperature of DMF. The experimental bubble point pressure data were correlated with the Peng-Robinson equation of state (PR-EOS) to estimate the corresponding dew point compositions at equilibrium with the bubble point compositions. The experimentally measured bubble point pressures gave good agreement with those calculated by the PR-EOS. The variable-volume view cell equipment was verified to be an easy and quick way to measure the bubble point pressures of high-pressure compressible fluid mixtures.

• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.94-98
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• 2009

The bubble point pressures of dimethyl carbonate and carbon dioxide mixtures were measured by using a high-pressure experimental apparatus equipped with a variable-volume view cell, at various $CO_2$ compositions in the range of temperatures above the critical temperature of $CO_2$ and below the critical temperature of dimethyl carbonate. The experimental bubble point pressure data were correlated with the Peng-Robinson equation of state (PR-EOS) to estimate the corresponding dew point compositions at equilibrium with the bubble point compositions. The experimentally measured bubble point pressures gave good agreement with those calculated by the PR-EOS. The variable-volume view cell equipment was verified to be an easy and quick way to measure the bubble point pressures of high-pressure compressible fluid mixtures.

• Proceedings of the Korean Nuclear Society Conference
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• 2001.10a
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• pp.74.1-74
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• 2001

• Applied Chemistry for Engineering
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• v.30 no.1
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• pp.102-107
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• 2019

Anionic surfactants were synthesized by using an sarcosine, taurine and fatty alcohol with varying the carbon chain length. The structure of synthesized surfactants was confirmed by $^1H$ NMR analysis. The critical micelle concentration of the synthetic anionic surfactant was $10^{-2}{\sim}10^{-4}mol/L$ and the surface tension value at the critical micelle concentration was between 21 and 39 mN/m. It was confirmed by the Ross-Miles method that the synthetic surfactant with the carbon chain of 12 showed a good foaming power and stability. In addition, the surfactant using the sacosine was found to have a good affinity in soybean oil while that using taurine in benzene. The physical properties of synthesized surfactants were determined by measuring the critical micelle concentration, foaming power and emulsifying stability.

• Nuclear Engineering and Technology
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• v.27 no.4
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• pp.503-517
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• 1995

A mechanistic model for forced convective transition boiling has been developed to predict transition boiling heat flux realistically. This model is based on a postulated multi­stage boiling process occurring during the passage time of an elongated vapor blanket specified at a critical heat flux condition. Between the departure from nucleate boiling (DNB) and the departure from film boiling (DFB) points, the boiling heat transfer is established through three boiling stages, namely, the macrolayer evaporation and dryout governed by nucleate boiling in a thin liquid film and the unstable film boiling. The total heat transfer rate during the transition boiling is the sum of the heat transfer rates after the DNB weighted by the time fractions of each stage, which are defined as the ratio of each stage duration to the vapor blanket passage time. The model predictions are compared with some available experimental transition boiling data. From these comparisons, it can be seen that the transition boiling heat fluxes including the maximum heat flux and the minimum film boiling heat flux are nil predicted at low qualities/high pressures near 10 bar.

• Resources Recycling
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• v.29 no.6
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• pp.104-113
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• 2020

Bubble size in froth flotation has long been recognized as a key factor which affects the bubble residence time, the bubble surface area flux (Sb) and the carrying rate (Cr). This paper presents method of bubble size measurement, relationship between operating variables and gas dispersion properties in flotation column. Using high speed camera and image analysis system, bubble size has been directly measured as a function of operating parameters (e.g., superficial gas rate (Jg), superficial wash water rate (Jw), frother concentration) in flotation column. Relationship compared to measured and estimated bubble size was obtained within error ranges of ±15~20% and mean bubble size was 0.718mm. From this system the empirical relationship to control the bubble size and distribution has been developed under operating conditions such as Jg of 0.65~1.3cm/s, Jw of 0.13~0.52cm/s and frother concentration of 60~200ppm. Surface tension and bubble size decreased as frother concentration increased. It seemed that critical coalescence concentration (CCC) of bubbles was 200ppm so that surface tension was the lowest (49.24mN/m) at frother concentration of 200ppm. Bubble size tend to increase when superficial gas rate (Jg) decreases and superficial wash water rate Jw and frother concentration increase. Gas holdup is proportional to superficial gas rate as well as frother concentration and superficial wash water rate (at the fixed superficial gas rate).