• Journal of the Korean Chemical Society
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• v.59 no.4
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• pp.271-279
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• 2015

The critical micelle concentration (CMC), the counter ion binding constant (B) and the aggregation number (N^* ) for the mixed micellization of sodium dodecanoate and sodium n-octanoate as two anionic surfactants have been investigated by means of electric conductivity and light scattering. As its experimental results are found to be deviated from ideal mixed model, thus two different kinds of regular solution models such as Rubingh and Motomura are used for interpreting our experimental data. The stability of the mixed micelles has been confirmed from the negative values of the standard Gibbs energy of mixed micellization ΔG^micel,0 over all compositions and the measured values of ΔG^micel,0 agreed with the theoretical ones within the experimental error.

• Polymer(Korea)
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• v.38 no.6
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• pp.767-773
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• 2014

Rheological and electrical properties of polystyrene (PS)/carbon nanotube (CNT) nanocomposites via coagulated precipitation were investigated. Chemical modification and surfactant wrapping of CNT to improve the dispersion of CNTs may reduce the intrinsic properties of pristine CNT. To avoid this problem, PS and CNTs were dissolved and dispersed in dimethylformamide and then PS/CNT nanocomposites were prepared by the coagulated precipitation of CNT-dispersed PS solution in water. The coagulated precipitation method was highly effective enhancing the electrical conductivity of nanocomposites. Furthermore, the effect of adding poly(styrene-co-divinylbenzene) crosslinked particles to PS matrix on the rheological and electrical properties was investigated. With the addition of the crosslinked particles, the electrical percolation threshold of CNT reduced to 0.25 wt% and electrical conductivity increased further. It is speculated that CNTs in the volume occupied by crosslinked particles helped electrical pathway formation.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.39 no.4
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• pp.269-275
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• 2003

In this paper, We examined auditory threshold and critical ratio of amberjack seriola dumerili, in the Jeju Island coastal waters, to find out hearing ability of the fish. The auditory threshold level, critical ratio and hearing index of amberjack were determinded by conditioning method using a sound coupled with electric shock in the condition of ambient noise or white noise in an experimental water tank. The audio-signals of pure tone and electric shock were from 80 HZ to 800 Hz and DC 7 V, respectively. Values for the critical ratios were calculated in terms of the masked thresholds using the noise projected to stable spectrum levels at all measurement frequencies of background noise. Masking noises were in the spectrum level range of 65 dB∼75 dB $(re 1{\mu}Pa\sqrt{Hz})$. The auditory thresholds of amberjack within the test the frequencies were most sensitive at 300HZ as 94.5 dB. The critical ratios of fishes ranged from 36.4 to 52.8 dB. The noise spectrum level that started masking was about 58∼72 dB within frequencies.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.24 no.5
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• pp.345-355
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• 1991

In order to effectively utilize the by-products of sea-food, the utilization of enzyme-modified flounder(Limanda aspera) skin gelatin as an emulsifier was investigated. In the experiment, the gelatin was extracted from the flounder skin with the heat-treatment at $60^{\circ}C$ and in pH 5.0 for 3 hrs with four volumes of distilled water and emulsifiers were enzymatically modified L-leucine alkyl esters$(L-leucine-OC_n$ : n= 2, 4, 6, 8 and 10) to the gelatin$(EMFSG-C_2,\;EMFSG-C_4,\;EMFSG-C_6,\;EMFSG-C_8,\;EMFSG-C_{10})$ for improving the functional properties such as emulsifying activity, emulsifying viscosity, whippability, electric conductivity, critical micelle concentration and interface tension, etc. Also, the functional properties of the L-leucine alkyl ester modified gelatins were compared with those of Tween-60 as reference. Molecular weights of the enzymatically modified flounder skin gelatin(EMFSG) were 20.5kDa. in $EMFSG-C_2.\;19.5 kDa.\;in\;EMFSG-C_4\;and\;16.5kDa.\;in\;EMFSG-C_6,\;EMFSG-C_8$ and $EMFSG-C_{10}$. respectively. Emulsifying activity and emulsifying viscosity in the modified gelatins were risen with increase of carbon number of the introduced L-leucine alkyl esters. Among the modified gelatins, $EMFSG-C_6$ exhibited the highest emulsifying stability and foaming stability, whereas $EMFSG-C_8$ showed the highest whippability. The electric conductivities of the all $EMFSG-C_n$ were linearly risen to critical micelle concentration(CMC) , therefore $EMFSG-C_{10}$ exhibited the lowest CMC value and interface tension, and dense particles in the microscopic observation. In conclusion, the best quality in functional properties was assured on $EMFSG-C_{10}$.

• Electrical & Electronic Materials
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• v.8 no.1
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• pp.6-12
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• 1995

High Tc superconducting YBa$_{2}$Cu$_{3}$$O_{7-x}$ thin films were prepared on various substrates by off-axis rf magnetron sputtering method to examine the substrate effects on the film structure and its R-T characteristics. The SEM analysis showed that the surface morphology of the grown YBa$_{2}$Cu$_{3}$O.sub 7-x/, film has different characteristic structure with different substrate used. The film on (100) SrTiO$_{3}$ substrate has critical current density of 3*10$^{5}$ A/cm$^{2}$ at 77K under zero magnetic field. The X-ray diffraction measurements revealed that the films on (100) SrTiO$_{3}$ substrate have mixed a-axis and c-axis normal to the substrate surface and the films on (100) MgO and ZrO$_{2}$/sapphire substrates have c-axis normal orientation to the substrate surface. However, YBa$_{2}$Cu$_{3}$$O_{7-x}$ films on (100) sapphire substrates showed no preferential orientation.ion.

• 대한공업교육학회지
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• v.33 no.2
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• pp.300-311
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• 2008

This study investigates the natural convection of air(Pr=0.7) between two walls having a small- wave- number sinusoidal temperature distributions with a phase difference. The wave number and the phase difference of wall temperatures are k=0.5 and ㄱ/2, respectively. In the conduction-dominated regime at small Rayleigh number, two slightly inclined cells are formed over one wave length. At higher Rayleigh number, however, multicellular convection occurs in thermally unstable region. A spatial symmetry is intermittently broken in the transient period at the Rayleigh number near the critical value. The steady-state flows always satisfy the spatial symmetry. A steep increase of Nusselt number occurs near the Rayleigh number at which transition of flow pattern occurs.

• Composites Research
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• v.17 no.5
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• pp.61-67
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• 2004

This paper reports the electrical conductivity and the stress-strain behavior of silver particle-filled silicone composite pastes for electromagnetic interference (EMI) shielding gasket materials. The percolation threshold (critical concentration) of the composite paste obtained by incorporating irregular sphere-shaped silver particles and room temperature vulcanizing (RTV) silicone resin was determined from the electrical conductivity result. At about 28 vol% Beading of untreated silver particles, the percolation phenomenon occurred and at this critical concentration, the volumetric resistivity, the tensile strength, and the elongation of the pastes were investigated. This work also suggests that the stress-strain characteristics of a composite paste filled with metal particles above the percolation threshold may be effectively improved by properly selecting a coupling agent.

• Electrical & Electronic Materials
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• v.6 no.4
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• pp.330-338
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• 1993

Channel의 폭과 길이가 15 x 15.mu.m, 15 x 1.5.mu.m, 1.9 x 1.7.mu.m인 비휘발성 SNOSFET EEPROM 기억소자를 CMOS 1 Mbit 설계규칙에 의하여 제작하고 체널크기에 따른 $I_{D}$- $V_{G}$특성 및 스위칭 특성을 조사하여 비교하였다. 게아트에 전압을 인가하여 질화막에 전하를 주입시키거나 소거시킨 후 특성을 측정한 결과, 드레인전류가 적게 흐르는 저전도상태와 전류가 많이 흐르는 고전도상태로 되는 것을 확인하였다. 15 x 15.mu.m의 소자는 전형적인 long channel특성을 나타냈으며 15 x 1.5.mu.m, 1.9 x 1.7.mu.m는 short channel특성을 보였다. $I_{D}$- $V_{G}$ 특성에서 소자들의 임계 문턱전압은 저전도상태에서 $V_{W}$=+34V, $t_{W}$=50sec의 전압에서 나타났으며 메모리 윈도우 폭은 15 x 15.mu.m, 15 x 1.5.mu.m, 1.9 x 1.7.mu.m의 소자에서 각각 6.4V, 7.4V, 3.5V였다. 스위칭 특성조사에서 소자들은 모두 논리스윙에 필요한 3.5V 메모리 윈도우를 얻을 수 있었으며 논리회로설계에 적절한 정논리 전도특성을 가졌다.특성을 가졌다.다.다.

• Proceedings of the KIEE Conference
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• 2005.07b
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• pp.1285-1287
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• 2005

고온초전도 선재 중에서 YBCO 박막을 금속테이프에 증착하여 제조되는 coated conductor는 높은 자기장에서도 임계전류밀도의 감소가 크지 않아 고자장용 초전도 자석을 제조하는데 많이 활용될 것으로 기대되고 있다. coated conductor를 고자장용 초전도 자석제작에 활용하기 위해서는 긴 길이의 도체를 제조하는 것과 함께, 도체의 접합기술이 필요하다. 이는 초전도 자석을 영구전류모드로 운전하기 위해서는 도체의 접촉저항이 충분히 적어야 하기 때문이다. 그러나 박막형 coated conductor는 아직 긴 길이의 선재제조기술이 확립되어 있지 않고, 또 박막형 coated conductor의 형태와 사용되는 제조기술이 본질적으로 초전도 접합을 형성시키기에 매우 어려워서 아직 까지 초전도 접합에 대한 연구결과가 발표되지 않고 있으며, 접합 특성을 측정하는 기술도 개발되지 않았다. 본 연구에서는 coated conductor의 접합특성을 측정하기 위한 기본적인 시험방법을 제안하고, 전도성 금속접합재를 이용한 접합시료를 제작하여 그 특성을 평가한 결과를 발표한다.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.1311-1312
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• 2007

본 논문에서는 YBCO coated conductor(CC) 의 접합연구와 접합된 선재의 응용을 위한 특성연구를 수행하였다. 최근에 지속적으로 연구 개발되어 본격적으로 응용이 시작되는 CC는 기본적으로 높은 인덱스 값과 자기장에 대한 임계전류의 균일성 등 다른 고온초전도에 비해 좋은 특성을 갖고 있으며 따라서 미래의 초전도 기기에 광범위하게 사용될 것으로 예상된다. CC와 같은 초전도 선재가 초전도 기기에 적용되는 경우 대부분 초전도 선재와 초전도 사이의 접합, 초전도 선재와 상전도체 사이의 접합 등의 접합들이 존재하게 된다. 접합을 위해서는 접합 땜납이 들어가게 되고 이 부분에서 저항이 발생하게 되어 손실이 발생하게 된다. 이러한 손실은 저항이 '0'이어서 손실이 적다는 초전도기기의 장점을 떨어뜨리는 요인이 될 수 있다. 따라서 CC의 접합 특성을 연구 하는 것은 초전도 기기의 성능향상에 도움을 줄 수도 있는 요인이 될 수 있다. 이 논문에서는 구리 안정화층, YBCO 층, 완충층과 기판층으로 이루어진 YBCO CC 선재를 이용하여 두 가지의 접합 방법을 이용하여 접합특성을 연구하였다.