• Title/Summary/Keyword: 인장와(印章瓦)

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Synthesis of Multifunctional AN-co-(MMA/IA) Fibrous ion-exchanger by Hydrolysis and Adsorption Properties for Trace Transition Elements (가수분해에 의한 AN-co-(MMA(IA) 다관능성 섬유이온교환체의 합성 및 미랑 전이금속 흡착특성)

  • 황택성;이선아;황계순
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.765-773
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    • 2001
  • In In order to remove harmful trace elements such as $Co^{2+}$, $Ni^{2+}$ , $Cr_2O_7\;^{2-}$ from water, we synthesized AN-co-(MMA/IA) according to various mole ratio of monomers and spun by wet-spinning. And multi-functional PAN ion exchangers were prepared by hydrolysis. We observed structure, degree of functionalization, ion exchange capacity, distribution coefficient and mechanical properties for ion exchanger. Anion exchange capacity decreased in 4.5 ~ 4.2 meq/g with increasing of IA content and cation exchange capacity increased in 1.8 ~ 2.2 meq/g. Tensile strength of the ion exchanger increased up to 0.008 mol% IA content and appeared maximum value by 216$kg/cm^2$Distribution coefficient for AN-co-(MMA/IA) ion exchanger appeared maximum value for Co(II), Ni(II) in pH 5-6 range and for Cr(III) in pH 3-4 range. And the adsorption capacity was in the order of Cr(III) > Co(II) > Ni(II) for multicomponent in continuous process.

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Effect of Tension, Compression Lamination and Number of Lamination on the Flexural Properties of Platanus occidentalis L. Laminated Beam (인장(引張) 및 압축부재(壓縮部材)와 적층수(積層數)가 플라타너스 집성재(集成材)의 휨성질(性質)에 미치는 영향(影響))

  • Oh, Se-Chang;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.14 no.2
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    • pp.3-12
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    • 1986
  • The aim of this study is to determine the flexural properties(Modulus of Rupture, Modulus of Elasticity) of Platanus occidentalis L. laminated beams fabricated with 1, 3, 5, 8, 15 lamination and Tension, Compression lamination. The results were as follows: 1. MOR increased with increasing number of lamination in 3, 5, 8, 15-beam and Tension lamination beam. MOR of Compression lamination beam was lower than that of 3-beam, MOR of vertical beam not having Tension or compression lamination was lower than that of horizontal beam, but MOR of vertical beam with tension or compression lamination was same or slightly higher than that of horizontal beam. 2. The allowable working stress showed the same tendency. This stress increased with increasing number of lamination. This value of Tension lamination beam was higher than that of compression lamination beam. 3. MOE of all laminated beams was higher than that of solid beam and Tension lamination beam was higher than that of 3-beam. MOE of Tension lamination beam was higher than that of Compression lamination beam. MOE of all vertical beam was higher than that of horizontal beam except for T-2, T-5, C-3. 4. Most beam failures appeared to begin in tension. These tension failures were classified into Splintering tension, Cross-grained tension, Simple tension, Brittle tension. All test beam failures could be classified into three categories. 1) Tension failure 2) Compression failure 3) Horizontal shear failure.

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Reinforcing Polymer Nanofibers Through Incorporation of Multi-walled Carbon Nanotubes (전기방사법을 이용한 고분자 나노섬유의 합성과 다중벽 탄소나노튜브의 혼합을 통한 물리적 강도 향상)

  • Lee, Mi-Hyun;Song, Woo-Seok;Kim, Yoo-Seok;Jang, Sung-Won;Choi, Won-Chel;Park, Chong-Yun
    • Journal of the Korean Vacuum Society
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    • v.21 no.1
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    • pp.41-47
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    • 2012
  • Multi-walled carbon nanotubes (MWCNTs) incorporated polyacrylonitrile (PAN) and poly (methyl methacrylate) (PMMA) nanofibers were synthesized using electronspinning method. Effects of polymer concentration and applied voltage on the synthesis of PAN and PMMA nanofibers were systematically investigated. The structural characterization of PAN/MWCNTs and PMMA/MWCNTs composited nanofibers synthesized as a function of the MWCNTs concentration was performed by scanning electron microscopy and transmission electron microscopy. 5 wt% MWCNTs incorporated PAN and PMMA electrospun nanofiber exhibit best strength and stiffness.

Study on the PVdF Nanofibers and Graphene Oxide Hybrid Membrane (PVdF 나노섬유와 Graphene Oxide 하이브리드막에 관한 연구)

  • Jung, Hyemin;Chen, Weidong;Yang, Woo Seok;Byun, Hongsik
    • Membrane Journal
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    • v.23 no.3
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    • pp.204-210
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    • 2013
  • Recently, many applications with grapheneoxide (GO) have been reported. But GO membrane for water treatment has not been developed. In this study we prepared polyvinylidene difluoride (PVdF) nanofiber/GO hybrid membrane (FG) for the microfiltration application. The PVdF substrate membrane was prepared by using the electrospinning method with a solution of PVdF in N,N-dimethylacetamide (DMAc) and acetone. GO sheets used in this study were prepared by modified Hummer's method. The PVdF/GO hybrid membrane was finally prepared by spraying the GO solution dispersed in ethanol on the PVdF nanofiber. The successfully prepared FG was thoroughly examined by SEM, Raman, contact angle, porometer and UTM, and water-flux was measured with designed cell (Dead-End Cell). From the contact angle results, it was found that the surface of FG membrane was reformed by hydrophilic property and the water permeability was increased about 2.5 times than that of the nascent PVdF membrane, indicating the possible alternative of the commercial MF membrane.

Synthesis and Physical Properties of Ophthalmic Copolymer Containing 4-fluorostyrene (4-Fluorostyrene을 포함하는 안의료용 고분자 합성 및 물리적 특성)

  • Kim, Tae-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.54 no.3
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    • pp.317-322
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    • 2010
  • This study used 4-fluorostyrene with the cross-linker EGDMA (ethylene glycol dimethacrylate), HEMA (2-hydroxyethyl methacrylate) and the initiator AIBN (azobisisobutyronitrile) for copolymerization. Measurement of the physical properties of the copolymerized polymer showed that the water content was 19.98 ~ 31.08%, refractive index 1.443 ~ 1.475, visible transmittance 87 ~ 93% and tensile strength 0.246 ~ 0.311 kgf while the contact angle showed a distribution between $54.14^{\circ}$ and $66.95^{\circ}$. Therefore, the ophthalmic material produced using 4-fluorostyrene satisfied the basic physical properties required for contact lenses and also showed an increase in wettability and refractive index while having no significant change in water content with relation to styrene. Based on the results of this study, the produced copolymer is suitable for use as a material to high refractive index and wettability contact lenses.

Mechanical Properties of Steel Fiber Reinforced Concrete Using Waste Glass (폐유리를 혼입한 강섬유보강 콘크리트의 역학적 특성)

  • 박승범;이봉춘
    • Journal of the Korea Concrete Institute
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    • v.14 no.6
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    • pp.1032-1039
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    • 2002
  • Since recycling waste glass as a material for concrete has a great advantage environmentally and economically, the US, Japan and other countries have started recycling waste glass widely and accumulating the technology of manufacturing equipment and its construction. However, there is no practical data on the mechanical property of concrete using waste glass. In this study, the mechanical property of the steel fiber reinforced concrete using waste glass was analyzed in terms of waste glass content(20vo1. %, 40vo1. % as a part of fine aggregate) and steel fiber content(0.5~ 1.5vol.%). The results of this study are as follows : The workability of the concrete including steel fiber and waste glass decreases, as the inclusion rate of waste glass and steel fiber increases. The tensile strength, flexural strength and flexural toughness of the concrete including waste glass increase considerably, as the inclusion rate of steel fiber increases. From the results, the appropriate inclusion rate of steel fiber and waste glass is thought to be 1.0vol. % and 20vo1. %, respectively.

Experiment of Flexural Behavior of Reinforced Concrete Beams with High Volume Fly Ash (하이 볼륨 플라이애쉬 철근콘크리트 보의 휨거동 실험)

  • Yoo, Sung-Won;Lee, Hyung-Jib
    • Journal of the Korea Concrete Institute
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    • v.26 no.3
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    • pp.323-329
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    • 2014
  • It is known that the best way to recycle fly ash is to use in concrete. It is impossible to bury in the ground this fly ash recently, so it is trying to use high volume fly ash concrete. Nevertheless, recent main research topics are focused in the part of material only, however, it is necessary to perform the researches about elasticity modulus, stress-strain relationship and structural behavior. Therefore, in this paper, 18 test members were manufactured with 3 test variables, namely fly ash replacement ratio 0, 35, 50%, concrete compressive strength 20, 40, 60 MPa and 2 tensile steel ratio. 18 test members were tested for flexural behavior. From the test results, there were no differences between 35, 50% high volume fly ash cement concrete and ordinary concrete without fly ash(FA=0%).

Prediction of Time-Dependant Strain of Reinforced Concrete Beams Externally Bonded with FRP (FRP가 외부 부착된 철근콘크리트보의 시간의존적 변형률 예측)

  • Kim, Sung-Hu;Han, Kyoung-Bong;Kim, Kwang-Soo;Kim, Jun-Won;Lee, In-Ju;Park, Sun-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.253-256
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    • 2008
  • Although researches on the beams strengthened with Fiber reinforced Polymers (FRPs) have recently been conducted around the world, there are few researches on the beams with FRPs under a sustained load. This paper presents the behavior of the beams with Carbon Fiber Reinforced Polymers (CFRP) and Glass Fiber Reinforced Polymers (GFRP) under a sustained load during 300 days. Strains of steel and FRP reinforcement were measured in order to investigate the behavior of the beams. Additionally, Adjusted Effective Modulus Method (AEMM) and Ghali and Farve's method were used to predict increase in the stress and strain caused by creep and shrinkage. Through the experiment, it was found that the beam with CFRP is more effective than the beam with GFRP in terms of flexural strengthening. Compared with analytical results, it was indicated that strains of tension steels were overestimated, whereas strains of compression steels were underestimated.

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Mechanical Characteristics of Asphalt Stabilized Soil (아스팔트 안정처리토의 역학적 특성 연구)

  • 박태순;최필호
    • Journal of the Korean Geotechnical Society
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    • v.19 no.5
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    • pp.189-197
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    • 2003
  • The treatment and hauling of surplus soils which occur from construction activity are costly and have been demanding a reasonable recycling method. This study presents laboratory test results regarding the mechanistic properties of asphalt stabilized soils. The foamed asphalt equipment which generates the asphalt bubble was used to mix the soil. The marshall stability, indirect tensile test, resilient modulus, creep test and triaxial test(UU) were conducted to find out the performance of the asphalt stabilized soil. The test results were compared with the samples that fabricated in different conditions(the samples without asphalt and the reinforced samples using 2% cement). The inclusion of the asphalt in the soil has improved the marshall stability, resilient modulus and moisture susceptibility, and the addition of the 2% cement has even more increased these properties. The amount of the fines and the optimum moisture contents for mixing affects the mechanistic properties and important parameters for mix design.

Fundamental Study for Vertical Fracturing Pressure of Impervious Soil (불투수성(不透水性) 지반(地盤)에서의 종할열주입압(縱割裂注入壓)에 관한 기초적(基礎的) 연구(硏究))

  • Chun, Byung Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.6 no.3
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    • pp.43-51
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    • 1986
  • Triaxial compression tests were performed with control of vertical stress, confined pressure(${\sigma}_H$), and injection velocity by means of impervious soil samples with a different grain size, density and grout density. By measuring pore water pressure at the time of vertical fracturing around the bore-hole, relationships between main factors are described, and the factors are pore water pressure, confined pressure, vertical fracturing injection pressure(${\sigma}$) and the tension strength(${\sigma}_t$). The hydraulic fracturing of soft clay was occurred at the pressure which was less than the pressure obtained by the theory of elasticity. It was found that the above result was the influence of pore water pressure due to injection pressure($U_a$) and pore water pressure due to confined pressure($U_i$). Therefore, the vertical injection pressure at the time of fracturing needs to be changed as follows. $${\sigma}=2{\cdot}{{\sigma}_H}-(U_a+U_i)+{\sigma}_t$$.

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