• Title/Summary/Keyword: 인장경화

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Effects of Silicone Polymer Blends on Physical Properties of Dental Polyvinylsiloxane Impression Materials (실리콘폴리머의 혼합사용이 폴리비닐실록산 치과용 인상재의 물성에 미치는 영향)

  • Lim, Chang-Ha;Kim, Min-Kang;Kim, Young-Chul;Park, Nam-Cook;Song, Ho-Jun;Park, Yeong-Joon
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.76-83
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    • 2009
  • The purpose of this study was to investigate the effects of combined use of several types of silicone polymers on the physical properties of the dental polyvinylsiloxane impression materials (PVS). Four types of silicone prepolymers having different molecular weight and vinyl group position, and two types of cross-linkers having differently located silyl hydride functional groups were used in various combinations for the formulation. The samples containing bimodal or trimodal prepolymers showed higher tensile strength, elongation at break, and elastic deformation than those containing only one type of prepolymer. The samples using CR210 cross-linker which has side- and terminal-silyl hydride groups showed higher elastic deformation and elongation at break than those using CR101 cross-liker which has side-only silyl hydride group. High vinyl content prepolymer having side vinyl group delayed setting even though it enhanced tensile strength. Further studies are needed to clarify the specific role of this component on setting time and to find appropriate controlling methods for making improved PVS with optimum workability.

Mechanical Property and Thermal Stability of Epoxy Composites Containing Poly(ether sulfone) (폴리에테르설폰이 도입된 에폭시 복합재의 열 안정성 및 기계적 특성)

  • Lee, Si-Eun;Park, Mi-Seon;Jeong, Euigyung;Lee, Man Young;Lee, Min-Kyung;Lee, Young-Seak
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.426-432
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    • 2015
  • Poly(ether sulfone) (PES) embedded diglycidylether of bisphenol-A (DGEBA) epoxy composites were fabricated for improving its mechanical properties and thermal stability. The mechanical properties such as tensile, flexural and impact strength of the composites changed significantly with the introduction of PES. The value of the fracture toughness of this composite also was increased remarkably about 24%. Thermal stability of PES/epoxy composites also improved 12%, which was calculated with integral procedural decomposition temperature (IPDT). From the differential scanning calorimeter (DSC) result, the curing temperature and curing heat decreased according to the increase of PES contents. These were attributed to the good distribution and the formation of the semi-interpenetrating polymer networks (semi-IPNs) composed of the epoxy network and linear PES.

On the Derivation of Material Constants Associated with Dynamic Behavior of Heat Formed Plates (열성형 판 부재의 동적거동에 관련된 재료상수 산출에 관한 연구)

  • Lee, Joo-Sung;Lim, Hyung-Kyun
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.29 no.2
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    • pp.105-114
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    • 2016
  • When impact load is applied to a plate structure, a common phenomenon that occurs in structures is plastic deformation accompanied by a large strain and eventually it will experience a fracture accordingly. In this study, for the rational design against accidental limit state, the plastic material constants of steel plate which is formed by line heating and by cold bending procedure have been defined through the numerical simulation for the high speed tension test. The usefulness of the material constants included in Cowper-Symonds model and Johnson-Cook model with the assumption that strain rate can be neglected when strain rate is less than the intermediate speed is verified through comparing the present numerical results with those in references. This paper ends with describing the future study.

Engineering Properties of HPFRCC Including Both Organic and Inoranic Fibers (유·무기 섬유를 복합사용한 HPFRCC의 공학적 특성)

  • Lee, Jong Tae;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.6
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    • pp.615-620
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    • 2015
  • The high performance fiber reinforced cementitious composite (HPFRCC) controls the cracking development of the structure by inducing micro-cracking and strain hardening behavior after the initial cracking under the tensile conditions. Although, in Korea, the research about manufacturing the single-fiber reinforced cementitious composite or the mechanical properties of hardened status has been conducted, the research to apply the HPFRCC with multi-fiber is not sufficient. Hence, in this research, considering the workability and economic aspect for practical applications, the engineering properties of HPFRCC with combined long steel fiber (SL) and long organic fiber (OL) are evaluated such as workability and strength. As a result of evaluating the engineering properties of HPFRCC, the most favorable performance was obtained when the mixture contained 1.5% of combined SL and OL.

Effects of low molecular weight Diols as Chain Extender on the Mechanical Properties of HTPB Urethane Elastomers (저분자량 디올이 체인 연장제로서 HTPB 우레탄 탄성 중합체의 기계적 성질에 미치는 영향)

  • Myong Pyo Hong;Man Gyoon No;Yong Joon Kim
    • Journal of the Korean Chemical Society
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    • v.27 no.1
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    • pp.58-65
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    • 1983
  • The mechanical properties (tensile strength, 100% modulus and hardness) of the urethane elastomers prepared from hydroxyl terminated polybutadiene (HTPB), several low molecular weight diols (ethylene glycol, 1, 3-propane diol, 1,4-butane diol, 1,5-pentane diol and 1,6-hexane diol) and two kinds of diisocyanates(TDI: toluene diisocyanate, IPDI: isophorone diisomechanical properties were enhanced for the increases of the concentrations of the urethane group, as predicted. In case of TDI, when the mechanical properties of the elastomers were plotted patterns were observed, which can be explained by hydrogen bondings depending on the number of the methylene carbons. But the mechanical properties of the elastomers derived from IPDI had decreasing curves against the number of methylene carbons in low molecular weight diols, without the characteristic zigzag patterns.

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Characteristics of EGW Welding Consumables for EH47-TM Steels (선급 EH47-TM용 EGW 용접재료의 특성)

  • An, Young-Ho;Han, Il-Wook
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.69-69
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    • 2010
  • 최근 컨테이너 선박의 초대형화로 극후물 고장력 강재인 항복응력 460MPa급 고장력강인 EH47이 개발되었다. 두께 80mm의 극후물 용접에서 용접생산성 향상을 위하여 EGW/FCAW로 양면 용접이 검토되고, 입열량은 최대 300kJ/cm의 대입열 용접이 요구된다. 이를 위해서는 강재 및 용접재료 모두 300kJ/cm 용접부 성능이 선급 규격을 만족하여야 함은 물론 마지막 조립단계에서 적용되기 때문에 용접재료의 용접작업성도 매우 크게 요구되고 있다. 먼저 대입열 용접금속에서 요구되는 저온 충격인성($vE_{-20^{\circ}C}{\geq}57J$)을 만족하기 위하여는 용접금속의 미세조직 제어가 필요하며, 특히 조대한 입계페라이트 생성을 억제하고 미세한 입내 페라이트를 균일 분포하는 것이 중요하지만, 이를 위해 용접금속의 소입성이 지나치게 높이면 경화조직인 베이나이트 분율이 증가하여 오히려 용접금속 저온 충격인성을 저하시키므로, 적절한 용접금속의 성분 제어가 중요하다. 한편 용접부는 선급에서 요구하는 최소 강도인 570MPa를 만족하기 위하여 용접금속의 소성구속 현상을 활용하여 용접부 인장강도를 확보 할 수 있음을 확인했다. 이를 위해서는 용접금속의 적정한 경화도 확보가 필요하였다. 전술한 바와 같이 대입열 용접금속 저온 충격인성 확보와 용접부 강도 측면을 고려하여 용접금속 최적의 탄소당량 범위를 제시코자 하였다. 한편 용접재료의 용접작업성은 EGW용접의 용적이행 현상은 자유비행이행으로 이루어지고 있으며 특성상 용접중 용적과 용융지 사이에 많은 순간단락 현상을 동반하고 있으며, 슬래그 유동이 불안정하면 아크 꺼짐 현상도 관찰되고 있다. 따라서, 현장용접시 원할한 용접작업성을 확보할 수 있는 평가 기준으로써 아크 전류 및 전압의 변동 정도를 설정하고, 용접재료의 용접작업성 확보 기준을 제시코자 하였다.

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Influence of Molecular Weight and Structure on the Physical Properties of the Vinylester Resin (비닐에스테르 수지의 구조 및 분자량이 물성에 미치는 영향)

  • Hong, Suk-Pyo;Choi, Sang-Goo;You, Kil-Sang
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.318-326
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    • 1992
  • Vinylester resin was synthesized by reacting epoxy resin with MAA(methacrylic acid) at a equivalent ratio of 1.1/1.0 in the presence of N,N dimethyl benzylamine. Low molecular weight epoxy(DER 331) was used together with higher molecular weight epoxy(DER 662, DER 664) and a novolac epoxy(DEN 439), and the amount of DER 331 was not over 50% of the total epoxy components. Viscosity, cure time and mechanical properties of the vinylester resin were profoundly influenced by the quantity of reacted MAA, and the structure and molecular weight of the epoxy resin. Tensile and flexural strength appeared to be the greatest when DER 331 fraction was 30~40%.

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Creep Behavior of Plastics Used in Automobile Instrument Panels (자동차 인스트루먼트 패널에 사용되는 플라스틱의 크리프 거동)

  • Kim, Young-Sam;Jeon, Chi-Hoon;Tumur-Ochir, Erdenebat;Yum, Young-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.12
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    • pp.1549-1556
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    • 2011
  • Tensile and creep tests were performed at various temperatures to investigate the mechanical properties of plastics used in automotive instrument panels. Mechanical properties such as Young's modulus and Poisson's ratios changed markedly with the test temperature. Three-point bending creep tests were performed for three kinds of plastics under four loading conditions. Coefficients in the time-hardening power law creep equation were obtained from the experiment, and the creep behavior was represented by a simple expression. The results of finite element creep analysis showed good agreement with the experimental results, while the difference between the numerical and experimental results increased with the load.

An Experimental Study on the Mechanical Properties of Steel Fiber Reinforced Fly Ash.Polyester Resin Composites (강섬유 보강 플라이애쉬.폴리에스터 수지복합체의 역학적 특성에 관한 실험적 연구)

  • 박승범;조영찬
    • Magazine of the Korea Concrete Institute
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    • v.5 no.4
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    • pp.156-166
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    • 1993
  • The results of an experimental study on the manufacture and the mechanical properties of steel fiber reinforced polyester resin composites utilizing industrial waste products(fly ash) are presented in this paper. The composites using steel fiber, fly ash, unsaturated polyester resin, styrene monomer, catalyst (cobalt octate) and accelerator(methyl ethyl ketone peroxide), fine and coarse aggreates were prepared using various mixing conditions. As the test results show. the mechanical and physical properties, such as the compressive, tensile and flexural strengths, and the setting shrinkage of fly ash$\cdot$polyester resin composites were improved considerably by increasing the fly ash-binder ratio. And the workability of steel fiber reinforced fly ash$\cdot$polyester resin composites was reduced with increasing the fly ash-binder ratio and steel fiber content. Also, the compressive, flexural strength and toughness of the composites were remarkably increased by increasing steel fiber content.

Undrained Behavior of Clay-Sand Mixtures under Triaxial Loading

  • Shin, Joon-Ho;Jeong, Sang-Seom
    • Journal of the Korean Geotechnical Society
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    • v.15 no.3
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    • pp.71-81
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    • 1999
  • A study on the undrained behavior of isotropically consolidated clay-sand mixtures was carried out using the automated triaxial testing apparatus. Overconsolidated ratio, effective mean pressure and clay content( up to 20% bentonite) were the factors varied in the experimental investigation. Undrained behavior(strength and pore water pressure generation during shear in triaxial loading) depends upon overconsolidation ratio, confining pressure and clay content. Significant changes in undrained compression characteristics occurred at around 20% of clay contents in the sand. The test results were analyzed and their behaviors were interpreted within the framework of plasticity constitutive model for clay-sand mixtures. Possible physical bases for the proposed forms are discussed. Validation of the applied model using the laboratory results is also given.

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