• Title/Summary/Keyword: 인산부산석고

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The stabilization of heavy metals by calcium sulfoaluminate (Calcium sulfoaluminate에 의한 중금속 고용화)

  • You, Kwang-Suk;Han, Gi-Chun;Um, Nam-Il;Cho, Kye-Hong;Ahn, Ji-Whan
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.330-334
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    • 2005
  • 본 연구에서는 유해 중금속을 다량 함유하고 있는 산업폐기물의 고화 처리에 사용되는 칼슘설포알루미네이트(4CaO $3Al_2O_3\;SO_4$ 이후부터 CSA로 기입)의 제조를 위해 철강부산물인 압연 슬러지를 활용하여 그 특성에 대해 조사하였다. 본 연구에서는 철강 부산물인 압연슬러지 외에 석회석 미분물, 인산부산 석고를 혼합하여 칼슘알루미네이트 상을 합성하였다. 합성 결과 소성온도 $1250^{\circ}C$에서부터 CSA가 합성되었고, 이와 함께 칼슘실리케이트$(2CaO\;SiO_2)$와 칼슘알루미노페라이트($4CaO\;Al_2O_3\;Fe_2O_3$)도 함께 합성되었다. CSA 합성에 미치는 중금속 영향을 관찰한 결과 원료의 중금속이 CSA 합성 온도를 낮추는 효과가 있는 것으로 나타났다. CSA를 이용한 철강산업 폐기물의 중금속 고용 처리 연구에서도 본 실험에서 합성된 CSA가 폐기물의 중금속 고화 처리에 효과가 있는 것으로 나타났다.

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Evaluation on Feasibility of Industrial By-products for Development of Mono-Layer Landfill Cover System (산업부산물을 이용한 단층형 매립지 복토시스템 개발을 위한 적용 타당성 평가)

  • Kim, Soon-Oh;Kim, Pil-Joo;Yu, Chan
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1075-1086
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    • 2008
  • In order to investigate the applicability and suitability of the industrial by-products to apply mono-layer cover system for non-sanitary landfill sites, 6 different industrial by-products, such as construction waste, bottom ash, gypsum, blast furnace and steel manufacture slags, and stone powder sludge, were evaluated. Various physicochemical and hydrodynamic properties of the industrial byproducts were investigated. The environmental safety was monitored using batch and long-term leaching tests as well. In addition, the flexibility of plants was observed by cultivating them in the industrial by-products. The results for physicochemical properties indicate that most of the materials considered appeared to be suitable for landfill cover. Particularly, the concentration levels of hazardous elements regulated by the Korean Law for Waste Management did not exceed the regulatory limits in all target materials. In addition, the concentrations of regulated elements for the Korean Soil Conservation Law were examined below the regulatory limits in most of materials considered, except for the stone powder sludge. The results of batch and long-term experiments showed bottom ash and construction waste were the most suitable materials for landfill cover among the industrial by-products considered. The results of plant studies indicate that the bottom ash among industrial by-products considered was most effective in developing vegetation on landfill site, showing fast germination and large growth index. At the final covering system made of mixture of soil and bottom ash, the optimum application rate of farmyard manure was observed to be 40-50 Mg/ha.

A Basic Study on the Radiological Characteristics and Disposal Methods of NORM Wastes (공정부산물의 방사선적 특성과 처분방안에 관한 기본 연구)

  • Jeong, Jongtae;Baik, Min-Hoon;Park, Chung-Kyun;Park, Tae-Jin;Ko, Nak-Youl;Yoon, Ki Hoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.3
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    • pp.217-233
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    • 2014
  • Securing the radiological safety is a prerequisite for the safe management of the naturally occurring radioactive materials (NORM) which cannot be reused. This becomes a crucial focus of our R&D efforts upon the implementation of the Act on Protective Action Guidelines against Radiation in the Natural Environment. To secure the safety, the establishment of technical bases and procedures for securing radiological safety related to the disposal of NORM is required. Thus, it is necessary to analyze the characteristics, to collect the data, to have the radiological safety assessment methodologies and tools, to investigate disposal methods and facilities, and to study the effects of the input data on the safety for the NORM wastes. Here, we assess the environmental impact of the NORM waste disposal with respect to the major domestic and foreign NORM characteristics. The data associated with major industries are collected/analyzed and the status of disposal facilities and methodologies relevant to the NORM wastes is investigated. We also suggest the conceptual design concept of a landfill disposal facility and the management plan with respect to the major NORM wastes characteristics. The radionuclide pathways are identified for the atmospheric transport and leachate release and the environmental impact assessment methodology for the NORM waste disposal is established using a relevant code. The assessment and analysis on the exposure doses and excessive cancer risks for the NORM waste disposal are performed using the characteristics of the representative domestic NORM wastes including flying ash, phosphor gypsum, and redmud. The results show that the exposure dose and the excessive cancer risks are very low to consider any radiation effects. This study will contribute to development in the areas of the regulatory technology for securing radiological safety relevant to NORM waste disposal and to the implementation technology for the Act.