• Journal of the Korean Chemical Society
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• v.51 no.4
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• pp.331-338
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• 2007

A rapid, simple and sensitive spectrophotometric method was developed for the determination of cobalt(II) using 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone (HMBATSC) as a analytical reagent. The metal ion in aqueous medium forms a brown coloured complex with HMBATSC at pH 6.0. The complex has two absorption maxima at 375 nm and 390 nm. At 375 nm, the reagent shows considerable absorbance, while at 390 nm the reagent does not shows appreciable absorbance. Hence, analytical studies were carried out at 390 nm. Beer's law is obeyed in the range of 0.059-2.357 μg ml-1 of Co(II). The molar absorptivity and Sandall's sensitivity of the method are 2.74×104 l mol-1 cm-1 and 0.0024 μg cm-2 respectively. The interference of various diverse ions has been studied. The complex has 1:2 [Co(II)- HMBATSC] stoichiometry. A method for the determination of cobalt(II) by second order derivative spectrophotometry has also been proposed. The proposed methods were applied for the determination of cobalt(II) in alloy steels, vitamin B12 and in some biological samples.

• Journal of the Korean Geotechnical Society
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• v.15 no.1
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• pp.161-173
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• 1999

Settlement analysis based on oedometer test results with or without Skempton-Bjerrum's modification method ( widely used for practical purposes when estimating consolidation settlements of soft clay deposits) has shortcomings that it cannot simulate real stress states and deformation behaviors of soils in case that in-situ loading and deformation conditions are not 1-dimensional. In this study, the stress path method, reflecting various probable stress paths, was employed to normally - consolidated kaolinite samples by using automated triaxial testing device which can control stress paths automatically. From this experimental study, elastic, consolidation, secondary compression and pore pressure development - dissipation behaviors under various stress paths were analyzed and deformation characteristics of soft clays, which can be the basis of rational estimation of settlements, were studied. Also by comparing results of stress path tests with those of 1-dimensional consolidation tests, limitations and problems of conventional methods were clarified.

• The Journal of Korean Academy of Prosthodontics
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• v.38 no.5
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• pp.675-694
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• 2000

The purpose of this study was to investigate the displacement of and the stress distribution on the prosthesis, abutment, and its supporting tissues under functional load, and the effect of alteration in root length of 2nd abutment. The 3-dimensional finite element method was used and the finite element models were prepared in which the abutments of left mandibular 5 unit axed partial denture were canine, the 1st pre-molar and the 2nd molar, and the root lengths of canines were as follows. Model I : Root length of canine was 2mm longer than the 1st premolar Model II : Root length of canine was 2mm shorter than the 1st premolar Static compressive force of 300N was applied to connector between 2nd premolar & 1st molar, and then von Mises stress, displacement and reaction force were obtained. The results were as follows : 1. In fixed partial denture, prosthesis under load on pontic was rotated around mesio-distal long axis of it from longual side to buccal, and simultaneously bended in buccal and gingival direction with mesial end deformed in gingival direction and distolingual end in occlusal. 2. Clinical crowns of abutments were bended in the same directions with those in which prosthesis deforms. Due to that, roots of anterior abutments were twisted in counterclockwise with concentration of shear stress on distal or distobuccal sides of their cervices, and that of posterior was in clockwise with concentration of shear stress on mesiobuccal side of it in the same level with anterior abutments. 3. In case that root length of the 2nd abutment was longer than that of the 1st abutment, its displacement and reaction force which means the force tooth exerts on the surrounding periodontal tissues were smaller but shear stress on itself was larger than in the case root length of 2nd abutment was shorter.

• Journal of the Korean Electrochemical Society
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• v.20 no.2
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• pp.41-48
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• 2017

Herein, we have fabricated an ultrathin aluminum oxide ($Al_2O_3$) coated PP separator by using a RF sputter deposition process. Approximately 20 nm thickness coating layer on the bare PP separator was formed at the power of 55 W for 2 minutes without thermal damage. Whereas only permeability of the coated separator was degraded slightly, other properties such as thermal stability, uptake amount of liquid electrolyte, and ionic conductivity were improved comparing to the bare PP separator. As a result, an only 20-nm-thick $Al_2O_3$ coating layer could improve the rate capability compared with a bare PP separator under a high current density.

• Journal of Hydrogen and New Energy
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• v.28 no.2
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• pp.156-165
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• 2017

This study quantitatively assessed the environmental impacts of fuel cell (FC) systems by performing life cycle assessment (LCA) and analyzed their energy efficiencies based on energy return on investment (EROI) and electrical energy stored on investment (ESOI). Molten carbonate fuel cell (MCFC) system and polymer electrolyte membrane fuel cell (PEMFC) system were selected as the fuel cell systems. Five different paths to produce hydrogen ($H_2$) as fuel such as natural gas steam reforming (NGSR), centralized naptha SR (NSR(C)), NSR station (NSR(S)), liquified petroleum gas SR (LPGSR), water electrolysis (WE) were each applied to the FCs. The environmental impacts and the energy efficiencies of the FCs were compared with rechargeable batteries such as $LiFePO_4$ (LFP) and Nickel-metal hydride (Ni-MH). The LCA results show that MCFC_NSR(C) and PEMFC_NSR(C) have the lowest global warming potential (GWP) with 6.23E-02 kg $CO_2$ eq./MJ electricity and 6.84E-02 kg $CO_2$ eq./MJ electricity, respectively. For the impact category of abiotic resource depletion potential (ADP), MCFC_NGSR(S) and PEMFC_NGSR(S) show the lowest impacts of 7.42E-01 g Sb eq./MJ electricity and 7.19E-01 g Sb eq./MJ electricity, respectively. And, the energy efficiencies of the FCs are higher than those of the rechargeable batteries except for the case of hydrogen produced by WE.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.5
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• pp.1947-1955
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• 2013

The purpose of this paper is to present an photoelasticity technique for measuring the displacement and stress distribution in particle assembly subjected to shallow foundation loading. Photoelastic measurement technique was employed to visualize the force transmission of a particle assembly. A model assembly bounded by a steel frame was built by stacking bi-dimensional circular particles made of polycarbonate elastomer. Each particle was coated by a thin photoelastic sheet so that the force transmission represented by bright light stripes can be visualized. In a contacted particle, both magnitude and orientation of principal stress difference can also be measured via the photoelasticity technique. The different distributions of the contact stresses at the initial loading and near the failure were quantitatively compared. The photoelastic patterns and displacement fields observed in the pre-failure state disappears immediately after the buckling of confined force chains.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.10
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• pp.1019-1023
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• 2012

In this research, a novel direct-aluminum-heating-induced crystallization method was developed for the purpose of application to solar cells. By applying a constant current of 3 A to an aluminum thin film, a 200-nm-thick amorphous silicon (a-Si) thin film with a size of $1cm{\times}1cm$ can be crystallized into a polycrystalline silicon (poly-Si) thin film within a few tens of seconds. The Raman spectrum analysis shows a peak of 520 $cm^{-1}$, which verifies the presence of poly-Si. After removing the aluminum layer, the poly-Si thin film was found to be porous. SIMS analysis showed that the porous poly-Si thin film was heavily p-doped with a doping concentration of $10^{21}cm^{-3}$. Thermal imaging shows that the crystallization from a-Si to poly-Si occurred at a temperature of around 820 K.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.121-125
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• 2013

In this work, we prepared the carbon paper from chopped carbon fibers using a gas diffusion matrix in polymer electrolyte membrane fuel cells by wet processing. The process of making carbon paper using wet processing is consisted of the three steps involving the dispersion of chopped carbon fibers, the preparation of the carbon fiber web, the impregnating of phenol resin. This work was focused on finding the optimal surfactant to make the carbon paper with 2D orientation of carbon fibers by investigating the dispersion state of carbon fibers in different dispersion solutions. Furthermore, the effect of phenol resin and carbon black contents on properties of electric conductivity was analyzed. As a result, it is confirmed that the carbon fiber was well dispersed when using sodium dodecyl sulfate as a surfactant, and the carbon paper with 8 wt% of phenol and 5 wt% of carbon black contents showed the most excellent electrical property.

• Korean Journal of Food Science and Technology
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• v.26 no.6
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• pp.655-658
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• 1994

This study was designed to investigate the suitability of oxidation matters and physico-chemical characteristics as a quality evaluation for the extent of rancidity development in fats and oils undergoing thermal oxidation. The results showed that acid value rapidly increased during heating time. Soybean oil, especially revealed a faster increase than palm oil and palm olein. Anisidine value and conjugated diene value also increased. Especially, soybean oil increased more rapidly than palm oil and palm olein. Active oxygen method stability was good in the ranks of palm oil, palm olein and soybean oil. Primary oxidation matter (POM) and secondary oxidation matter (SOM) were surveyed as an evaluation method for the extent of rancidity development in fats and oils. POM and SOM showed a sharp increase during the thermal oxidation period.

• The Korean Journal of Pesticide Science
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• v.14 no.4
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• pp.415-420
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• 2010

This study investigated effects of different sound frequencies on development and insecticide susceptibility of the green peach aphid, Myzus persicae. Under a constant sound intensity (95 dB), different frequency (0-5,000 Hz) sounds were treated on entire developmental period of the aphids. With increase of sound frequencies, nymphal to adult development of the aphids showed significant retardation and the females exhibited a significant decrease in fecundity. The greatest disrupting effects were induced by treatment of 5,000 Hz, which also caused marked change in protein expression of the aphids analysed by two dimensional electrophoresis. Sound frequencies above 2,000 Hz significantly increased susceptibility of the aphids against imidacloprid. This study clearly suggest that there is a stress sound, which can be sensed by M. persicae and induces its physiological alteration.