• Title/Summary/Keyword: 이중극

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Development of ZnS/SiO2 Double Overlayers for the Enhanced Photovoltaic Properties of Quantum Dot-Sensitized Solar Cells (양자점 감응 태양전지의 광전 특성 향상을 위한 ZnS/SiO2 이중 오버레이어 개발)

  • SONG, INCHEUL;JUNG, SUNG-MOK;SEO, JOO-WON;KIM, JAE-YUP
    • Journal of Hydrogen and New Energy
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    • v.32 no.6
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    • pp.656-662
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    • 2021
  • For the high efficiencies of quantum dot-sensitized solar cells (QDSCs), it is important to control the severe electron recombination at the interface of photoanode/electrolyte. In this work, we optimize the surface passivation process of ZnS/SiO2 double overlayers for the enhanced photovoltaic performances of QDSCs. The overlayers of zinc sulfide (ZnS) and SiO2 are coated on the surface of QD-sensitized photoanode by successive ionic layer adsorption and reaction (SILAR) method, and sol-gel reaction, respectively. In particular, for the sol-gel reaction of SiO2, the influences of temperature of precursor solution are investigated. By application of SiO2 overlayers on the ZnS-coated photoanode, the conversion efficiency of QDSCs is increased from 5.04% to 7.35%. The impedance analysis reveals that the electron recombination at the interface of photoanode/electrolyte is obviously reduced by the SiO2 overlayers.

Study on the Visual Cells in the Retina of Macropodus ocellatus (Pisces, Osphronemidae) Freshwater Fish from Korea (한국산 담수어류 버들붕어, Macropodus ocellatus (Pisces, Osphronemidae) 망막의 시각세포에 관한 연구)

  • Kim, Jae Goo;Park, Jong Yong
    • Korean Journal of Ichthyology
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    • v.29 no.3
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    • pp.218-223
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    • 2017
  • Using both light and scanning electron microscopies, it was investigated on the visual cells as well as the eyes of Macropodus ocellatus (Pisces, Osphronemidae). This species had a circular lens and yellowish cornea. The eyes had $3.5{\pm}0.2mm$ which is $31.1{\pm}3.0%$ in a percentage of eye diameter relative to head length. The retina ($158.2{\pm}10.6{\mu}m$) was built of several layers, including the visual cell layer which consists of three types of cells: single cons ($27.8{\pm}1.6{\mu}m$) and equal double cone ($33.9{\pm}3.7{\mu}m$), and large rods ($57.3{\pm}1.3{\mu}m$). The visual cell layer then was classified into the correct pattern. All visual cells were clearly distinguished from two parts (inner and outer segments). The elongated rod cells were extend to the bottom of the retinal pigment epithelium. In scanning electron microscopy, the outer segment links to inner segment by so-called calyceal piles. The M. ocellatus single and double cones appearance form a flower-petal arrangement, which is a regular mosaic pattern that contains quadrilateral units by four double cones surrounding a single cone.

Flexural and Shear Behavior of Reinforced Dual Concrete Beam (철근 이중 콘크리트 보의 휨 및 전단 거동)

  • Park Tae-Hyo;Park Jae-Min;Kim Hee-Dae
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.401-409
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    • 2005
  • In this study, reinforced dual concrete beam (RDC beam) composed of steel fiber reinforced concrete (SFRC) in the tension part and normal strength concrete (NSC) in the compression and remaining part is proposed. It is the epochal structural system that improves the overall structural performances of beam by partially superseding the steel fiber reinforced concrete in the lower tension part of conventional reinforced concrete beam (RC beam). Flexural and shear tests are performed to prove the structural excellence of RDC beam in comparison with RC beam. An analytical method is proposed to understand the flexrual behavior and is compared to experimental results. And for shear behavior, experimental results are compared to empirical equations predicting the ultimate shear strength of full-depth fiber reinforced concrete beam to examine the behavior of RDC beam under shear. From this studies, it is proved that RDC beam has more superior structural performance than RC beam, and the analytical method for flexural behavior agrees well with experimental results, and the partial-depth fiber reinforcements have no noticeable effect on ultimate shear strength but it is considerably effective to control and prevent evolutions of crack.

Preparation of Al2O3-coated TiO2 Electrode for Recombination Blocking of Photoelectron in Dye-Sensitized Solar Cells (염료감응형 태양전지의 광전자 재결합 방지를 위한 Al2O3 코팅 TiO2 전극 제조)

  • Hwang, Kyung-Jun;Yoo, Seung-Joon;Jung, Sung-Hoon;Kim, Sun-Il;Lee, Jae-Wook
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.162-168
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    • 2010
  • To increase the energy conversion efficiency of dye sensitized solar cells (DSSCs), it has been widely studied how to effectively transferred the electron generated from the adsorbed dye to the $TiO_{2}$ electrode for avoiding the recombination of injected electrons and iodide ions ($I^-/I_3^-$). For the blocking of the recombination, in this study, $Al_2O_3$-coated $TiO_{2}$ electrode was prepared and applied for DSSCs. In especial, the optimal preparation conditions of $Al_2O_3$ coated onto $TiO_{2}$ porous film was proposed for higher energy conversion efficiency. As a result, the solar cells fabricated from $Al_2O_3$-coated (i.e., particle size of bohemite sol : 100 nm) $TiO_{2}$ electrodes showed superior conversion efficiency (9.0%) compared to the bare $TiO_{2}$ electrodes (7.5%).

Ginseng Saponins Enhance Maxi $Ca^{2+}-activated\;K^+$ Currents of the Rabbit Coronary Artery Smooth Muscle Cells

  • Chunl Induk;Kim Nak-Doo
    • Journal of Ginseng Research
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    • v.23 no.4
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    • pp.230-234
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    • 1999
  • Potassium channels play an important role in regulating vascular smooth muscle tone. Four types of $K^+$ channels areknown to be expressed in vascular smooth muscle cells, and maxi $Ca^{2+}-activated\;K^+$ channel $(BK_{Ca})$ is a dominant type of $K^+$ channels in these cells. Because total ginseng saponins and ginsenoside $Rg_3$ cause vasodilation with unclear mechanisms, we hypothesized that total ginseng saponins and ginsenoside $Rg_3$ induce vasodilation via activation of maxi $Ca^{2+}-activated\;K+$ channels. Whole-cell BKe. currents were voltage-dependent with half maximum activation at -14 mV, and the currents were sensitive to nanomolar ChTX and millimolar TEA. External application of total ginseng saponins increased the anlplitude of the whole-cell BKe. current in a concentration-dependent manner. Single-channel analysis indicates that total ginseng saponins caused the channel opening for a longer period of time. Ginsenoside $Rg_3$ increased the amplitude of whole-cell $K_{Ca}$ currents without affecting voltage dependence of the currents and increased single-channel open time. Hence, the results suggest that ginseng saponin-induced vasodilation may be due to activation of $K_{Ca}$.

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Visual Cells in the Retina of Iksookimia longicorpa (Pisces; Cobitidae) of Korea (한국산 미꾸리과 어류 왕종개 Iksookimia longicorpa 망막의 시각세포)

  • Kim, Jae Goo;Park, Jong Young
    • Korean Journal of Ichthyology
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    • v.27 no.4
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    • pp.257-262
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    • 2015
  • The visual cells in the retina of Iksookimia longicorpa (Pisces, Cobitidae) were investigated by light and scanning electron microscopes. The retina ($216.42{\pm}13.36{\mu}m$) has several layers, and the visual cell layer consists of unequal double cones and large rods. In a double cone, two members are unequal such that one cone is longer than the other (long element $26.42{\pm}1.7{\mu}m$, short element $16.82{\pm}1.1{\mu}m$). The cones form a row mosaic pattern in which the partners of double cones are linearly oriented with a large rod. The visual cells observed have an outer segment (hematophilic), inner segment (eosinophilic). In scanning electron microscopy, the outer segment links to inner segment by so-called calyceal piles (calyceal processes) of membrane discs surrounded by double membranes.

Study on Temperature Dependence of Molecular Structure in Stearic Acid LB Films Using FTIR-RAS (FTIR-RA 분광법을 이용한 스테아르산 단분자막에서 분자구조의 온도의존성 고찰)

  • Kim, Dong Won;Park, Sang Rae;Umemura Junjo;Takeda Satoshi;Hasegawa Takeshi;Takenaka Tohru;Lee Hai Won
    • Journal of the Korean Chemical Society
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    • v.37 no.6
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    • pp.570-576
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    • 1993
  • 1-, 3-, 9-, and 21-Monolayer Langmuir-Blodgett(LB) films of stearic acid were deposited on silver-coated glass slides at the surface pressure of 30 mN/m. Fourier transform infrared(FTIR) reflection-absorption spectra (RAS) of these LB films were recorded at various temperatures from 31 to $72^{\circ}C.$ The spectra at $31^{\circ}C$ exhibited characteristic features of highly perpendicular orientation of the hydrocarbon chain. In the 1-monolayer LB film, the C=O stretching band was not observed, presumably due to the image dipole effect on the silver surface. In the 1-and 3-monolayer LB films, the trans isomer of stearic acid was prominent, but the cis isomer was dominant in the 21-monolayer LB film. FTIR-RAS measurements at an elevated temperature indicated that the chain melting temperature increases and approached to the bulk melting point with increasing the number of monolayer, except for the 1-monolayer LB film which has a higher melting temperature than the 3-monolayer film due to the strong interaction with the silver substrate.

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3D Printing-Based Ultrafast Mixing and Injecting Systems for Time-Resolved Serial Femtosecond Crystallography (시간 분해 직렬 펨토초 결정학을 위한 3차원 프린팅 기반의 초고속 믹싱 및 인젝팅 시스템)

  • Ji, Inseo;Kang, Jeon-Woong;Kim, Taeyung;Kang, Min Seo;Kwon, Sun Beom;Hong, Jiwoo
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.300-307
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    • 2022
  • Time-resolved serial femtosecond crystallography (TR-SFX) is a powerful technique for determining temporal variations in the structural properties of biomacromolecules on ultra-short time scales without causing structure damage by employing femtosecond X-ray laser pulses generated by an X-ray free electron laser (XFEL). The mixing rate of reactants and biomolecule samples, as well as the hit rate between crystal samples and x-ray pulses, are critical factors determining TR-SFX performance, such as accurate image acquisition and efficient sample consumption. We here develop two distinct sample delivery systems that enable ultra-fast mixing and on-demand droplet injecting via pneumatic application with a square pulse signal. The first strategy relies on inertial mixing, which is caused by the high-speed collision and subsequent coalescence of droplets ejected through a double nozzle, while the second relies on on-demand pneumatic jetting embedded with a 3D-printed micromixer. First, the colliding behaviors of the droplets ejected through the double nozzle, as well as the inertial mixing within the coalesced droplets, are investigated experimentally and numerically. The mixing performance of the pneumatic jetting system with an integrated micromixer is then evaluated by using similar approaches. The sample delivery system devised in this work is very valuable for three-dimensional biomolecular structure analysis, which is critical for elucidating the mechanisms by which certain proteins cause disease, as well as searching for antibody drugs and new drug candidates.

An Analysis of Three Port Ring Resonator for the Balun-BPF Characteristics (Balun-BPF 특성 구현을 위한 3-단자 링-공진기의 해석)

  • Kang, Seong-Jun;Park, Ung-Hee;Hwang, Hee-Yong
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.4
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    • pp.436-441
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    • 2008
  • In this paper, we derived the Y-parameter of the recently reported Balun-BPF with a dual mode ring resonator by using the network analysis method. Using the derived Y-parameter we verified that the Balun-BPF structure satisfy the balun conditions. In order to design the Balun-BPF with arbitrary characteristics using the standard BPF design method with ease we derived the immittance slope parameters of the dual mode ring resonator with a load. The notch frequencies are also predicted. By designing with the proposed equations, simulating with a circuit simulator, fabricated and measured a Balun-BPF we confirmed the validation of the equations. The measured data shows bandwidth of 71 MHz and insertion loss of 0.92 dB at the center frequency of 2.46 GHz. It shows the phase imbalance of $174{\sim}181$ degree and the magnitude imbalance within 0.5 dB.

Studies on Intestinal Trematodes in Korea XVI. Infection Status of Loaches with the Metacercariae of Echinostoma hortense (한국의 장흡충에 관한 연구 XVI. 미꾸리의 호르텐스극일흡충 피낭유충 감량상황)

  • 제종일;홍성종
    • Parasites, Hosts and Diseases
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    • v.23 no.1
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    • pp.18-23
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    • 1985
  • The infection stasus of the loaches, Misgurnus anguillicaudatus, with the metacercariae of Echinostoma hortense, was studied in Korea. A total of 154 loaches purchased at 4 local markets (Seoul, Kimhae, Naju-gun and Kangjin-gun) were examined their infection rate as well as the density and location of the metacercariae in the fish body. The results are as follows: 1. The loaches carrying the metacerariae of E. hortense were 64 (41.6%) in total number and the metacercarial density ranged 1-29 per infected loach with an average value of 8.1. The highest infection rate and metacercarial density were obtained from the loaches purchased at Kangjin-gun, Jeonranam-do. 2. The metacercariae of E. hortense were chiefly distributed in the distal intestinal wall and the adjacent mesentery, the perianal tissues, and the head and gill of the loaches examined. From the results, it is concluded that the loach is one of the important second intermediate hosts of E. hortense in Korea, and their infection rate and metacercarial density are considerably high.

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