• Title/Summary/Keyword: 이원혼합물

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Volatile Flavor Compounds from Raw Mugwort Leaves and Parched Mugwort Tea (생쑥과 덖음쑥차의 향기성분)

  • 김영숙;이종호;김무남;이원구;김정옥
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.2
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    • pp.261-267
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    • 1994
  • Parched mugwort tea was manufactured from mugwort (Artemisia asicatica nakai) leaves by traditional green tea preparation method. Volatile flavor compounds were collected by Tenax GC and they separated on DB-5 capillary column ($60m\;\times\;0.25mm$ i.d.) Fifty eight compounds were isolated and identified by GC-MS from the volatiles. Eleven compounds incucluding benzaldehyde, pinene, myrcene, cineole, 2-phrrolidinonoe, camphor, thujong, 1-acetylpiperidine, caryophyllene, coumarin, and farnesol among the compounds identified were considered as important compounds contributing mugwort-like flavor to the parched mugwort tea. The mixture of these eleven authentic compounds could reproduce aroma of mugwort leaves harvested in April. As results, the concentrations of these eleven flavor compounds in parched mugwort tea may indicate the strength of mugwort-like aroma of the tea.

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Phase Cooperation Between Mo-V-O and Metal Oxide in Selective Oxidation of Acrolein (아크롤레인 선택 산화반응에서 Mo-V-O와 금속산화물의 상간협동)

  • Park, D.W.;Na, S.E.;Kim, K.H.;Lee, W.H.;Chung, J.S.
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.327-336
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    • 1994
  • The synergistic effects in mechanical mixture catalysts of Mo-V-O and metal oxide were investigated for the selective oxidation of acrolein. The metal oxides used are $SnO_2$, ${\alpha}-Sb_2O_4$, $WO_3$, ${\alpha}-Al_2O_3$, CuO, $MnO_2$, $Cu_2O$, MgO, CoO, and ZnO. Mechanical mixtures of Mo-V-O plus $SnO_2$ or ${\alpha}-Sb_2O_4$ had resulted in higher conversion of acrolein and higher yield of acrylic acid than Mo-V-O. The origin of the synergy is attributed to the cooperation of Mo-V-O and $SnO_2$ or ${\alpha}-Sb_2O_4$, in which $SnO_2$ or ${\alpha}-Sb_2O_4$ forms dissociated oxygens at their oxygen vacancies and transports them to Mo-V-O. $Cu_2O$, MgO, CuO, and $MnO_2$, increased conversion of acrolein but decreased yield of acrylic acid. CoO and ZnO inhibited the catalytic performance of Mo-V-O. The different role of these metal oxides is explained in terms of their oxidation-reduction properties.

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The Effects of Chemistry Class Using Computer-Based Science Inquiry Program on Positive Experiences about Science, Science Core Competency, and Academic Achievement (컴퓨터 기반 과학 탐구 프로그램을 활용한 화학 수업이 과학 긍정경험, 과학과 핵심역량 및 학업성취도에 미치는 영향)

  • Kim, Sungki;Kim, Hyunjung
    • Journal of the Korean Chemical Society
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    • v.66 no.2
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    • pp.107-123
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    • 2022
  • The purpose of this study is to investigate the effects of learning using computer-based science inquiry program. To this end, the three lessons computer-based science inquiry were developed in domain of material's properties. The developed program was put into K middle school located in Seoul and the effects were verified. For the experimental group, the three lessons computer-based science inquiry related to the separation of mixture were introduced, and for the comparison group, the contents presented in the textbook were introduced as a teacher-centered teaching method. To verify the effects of the program, 2-way ANCOVA was performed on positive experiences about science and science core competency, and 2-way ANOVA was performed on academic achievement. As a result of the study, there were significant differences between the two groups in positive experiernces about science and scientific core competencies and academic achievement (p<.05), and group*gender interaction effect was only significant in academic achievement (p<.05). From the results of this study, we could see the possibility of using a computer-based science inquiry program as a chemistry teaching method that enables sustainable scientific inquiry.

Phosphate Adsorption on Metal-Impregnated Activated Carbon (금속담지 활성탄의 인산염 흡착특성)

  • Hwang, Min-Jin;Hwang, Yu Sik;Lee, Wontae
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.11
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    • pp.642-648
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    • 2015
  • Oak wood based activated carbon was modified with surface impregnation of $Fe^{3+}$ and $Al^{3+}$ metal ions mixture for enhancements of phosphate adsorption capacity in aqueous solution. The phosphate adsorption capacity of the prepared metal impregnated carbon (MC) was about 8 times higher than that of the original activated carbon (OC). Adsorption equilibrium capacities of the phosphate increased with increasing system temperature. The adsorption equilibrium isotherm of phosphate on the prepared MC could be represented by the Langmuir equation. Thermodynamic parameters also indicated that adsorption system was spontaneous and endothermic reaction. The internal diffusion coefficient was measured to analyze the adsorption behavior and kinetic rate. To determine the internal diffusion coefficient, pore diffusion model (PDM) was employed and the result was in good agreement with experimental data.

The Effect of Reciprocal Peer Tutoring Strategy for Inducing Structured Students' Interaction in Middle School Science Instruction (중학교 과학 수업에서 학생들의 구조화된 상호작용을 유도하기 위한 상호동료교수 전략의 효과)

  • Noh, Tae-Hee;Kim, So-Yeon;Kim, Kyung-Sun
    • Journal of The Korean Association For Science Education
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    • v.25 no.4
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    • pp.465-471
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    • 2005
  • In this study, the effects of reciprocal peer tutoring strategy on science achievement, science learning motivation, and self-esteem were investigated. Three classes of eighth graders (N=94) at a coed middle school were sampled for the study. They were divided into the comparison group, the cooperative learning (CL) group, and the reciprocal peer tutoring (RPT) group. Students were taught about the separation of mixtures for 13 class hours. Mid-term science examination scores were used as a blocking variable. The two-way ANCOVA results revealed that there were no significant differences among the three groups in the science achievement test, although the scores of the RPT group were higher than those of the comparison group. In all the subtests of the science learning motivation questionnaire, the scores of the RPT group were significantly higher than those of the comparison group. The scores of the RPT group were significantly higher than those of the other groups especially in the confidence part of the science learning motivation questionnaire. In the self-esteem test, the low achievers in the RPT group scored significantly higher than those in the CL group.

Dispersion and property evaluation of nanocomposites by aspect ratio of MWCNT (다중벽 탄소나노튜브 형상비에 따른 나노복합재료 분산 및 물성 평가)

  • Jang, Jung-Hoon;Yi, Jin-Woo;Lee, Won-Oh;Lee, Hak-Gu;Um, Moon-Kwang;Kim, Jin-Bong;Byun, Joon-Hyung
    • Composites Research
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    • v.23 no.3
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    • pp.58-63
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    • 2010
  • Tensile and flexural properties and electrical conductivity of MWCNT/epoxy composites with different aspect ratios of MWCNTs were compared. The MWCNT/epoxy mixtures were prepared by mechanical dispersion methods using a homomixer and a three-roll mill, and then composite samples were fabricated by compression molding process. The fractured surfaces of the samples were observed by SEM in order to evaluate the degree of dispersion of MWCNTs. The addition of MWCNTs into epoxy resin improved its tensile strength by 7.0% while its flexural strength increased slightly as compared with the one without MWCNTs. In the case of MWCNTs having highest aspect ratio, the mechanical properties of the composites were decreased. When the contents of CM-95 MWCNTs were varied, maximum of tensile and flexural strengths occurred at 1wt% and 0.5wt%, respectively. From the higher contents than these, tensile and flexural strengths of the composites decreased. Electrical conductivities of in-plane and thought-the-thickness directions of MWCNT/epoxy composites were measured using a two-point probe method. They increased with the increase of the aspect ratios and concentrations of MWCNTs in the epoxy matrix.

Effects of Water-extract Mixture of Scutellariae baicalensis GEORGI, Acarus gramineus SOLAND and Gastrodia elata BLUME on Cultured Rat Cortical Neurons and Enhancement of Learning and Memory Power (황금(黃芩), 석창포(石菖蒲), 천마(天麻) 물추출액 혼합물이 배양한 흰쥐 대뇌신경세포의 활성과 학습능력 증진 효능)

  • Bae, Chul-Hwan;Jung, Hyun-Jung;Jung, Seung-Hyun;Moon, Il-Soo;Lee, Won-Chul;Sin, Gil-Jo
    • Journal of Life Science
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    • v.19 no.6
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    • pp.756-764
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    • 2009
  • Scutellariae baicalensis GEORGt Acorus gramineus SOLAND and Gastrodia elata BLUME are traditional medicines used in the treatment of incipient stoke. In this study we investigated their effects on various aspects of neuronal differentiation in single or composite forms. Water-extracts of these medicines showed neuroprotective effects on cultured rat cortical neurons in normoxia and hypoxia. To understand the mechanism for neuroprotection we carried out various cell biological assays. They stimulated initial differentiation of neuronal development (transition from stage 1 to 2), and increased the number of spines and the length and number of dendritic processes. These effects were best manifested in the experimental group, which were given a mixture of the three kinds of extracts (p<0.01). To assess improvement of brain functions we carried out Morris water-maze tests for the mice that were fed on these extracts instead of water for 4 weeks. The experimental groups, especially those which were given the mixture of the three kinds of extract, showed significant (p<0.01) enhancement in memory as early as one day after the learning trial. These results indicate that these three kinds of extracts have synergistic effects on neuronal protection and improvement of brain functions.

The Effects of Cooperative and Individualistic Learning Strategies by the Level of Achievement (학습자의 성취 수준에 따른 협동학습과 개별학습의 효과)

  • Lim, Hee-Jun;Choi, Kyoung-Sook;Noh, Tae-Hee
    • Journal of The Korean Association For Science Education
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    • v.19 no.1
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    • pp.137-145
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    • 1999
  • This study investigated the influences of the cooperative and the individualistic learning strategies on the academic achievement and the attitudes toward science instruction and science by the level of achievement. These two learning strategies endowed students with the responsibility of learning and emphasized student-centered learning which included higher order thinking activities. Cooperative learning group students studied the tasks through small group discussion, and individualistic learning group students solved the same ones individually. In the traditional group. teacher-centered expository lesson was used. The subjects of this study were 7th graders of coed middle school, and were taught about separation of mixture for 10 class periods. Two-way ANCOVA results revealed that the test scores of academic achievement for cooperative learning group were significantly higher than those of individualistic and traditional learning groups. The attitudes toward science instruction and science were also more positive in cooperative learning group than the others. No interactions between the treatment and the level of previous achievement indicated that the cooperative learning strategy was effective regardless of the level of achievement.

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Physical Properties of Polymer Impregnated Concrete Prepared using Microwave Radiation (Microwave Radiation을 이용하여 제조된 고분자 함침 콘크리트의 물리적 특성)

  • Ku, Du Hyun;Park, Jung Soon;Park, Heon Young;Hur, Myung Jun;Lee, Won Mook
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.345-350
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    • 2008
  • Polymer Impregnated Concrete (PIC) prepared from Ordinary Portland Cement Concrete (OPC) has excellent mechanical properties as well as physico-chemical properties. For the manufacturing of PIC, drying process of basis concrete (precast concrete), impregnation process with evacuation system and ultrasonic vibration system, polymerization process of monomers are essential. Modified microwave reactor using magnetron was used for polymerization of styrene/MMA (1 : 1) impregnated in pore volume of basis concrete. From the experimental results, the degree of polymerization increased up to 30% and more homogeneous PIC was prepared as compared to the conventional thermal method. Also the mechanical strengths increased more than 400% ($800{\sim}1200kg_f/cm^2$) and the resistance for corrosion to acids was improved up to 25%. AIBN and BPO as initiators for polymerization were used at the concentration less than 1%. Optimum conditions for polymerization were obtained at the frequency of microwave of 400 W and 2450 MHz, and optimum reaction temperature was $120^{\circ}C$ at an atmospheric pressure.

THE EFFECT OF SEVERAL ROOT-END FILLING MATERIALS ON MG63 OSTEOBLAST-LIKE CELLS (수종의 치근단역충전 재료가 MG63 osteoblast-like cells에 미치는 영향)

  • Lee, Jeong-Ho;Shon, Won-Jun;Lee, Woo-Cheol;Baek, Seung-Ho
    • Restorative Dentistry and Endodontics
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    • v.35 no.3
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    • pp.222-228
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    • 2010
  • The purpose of this study was to compare mineral trioxide aggregate (MTA; Dentsply, Tulsa Dental, Tulsa, OK, USA), which is widely used as root-end filling material, with DiaRoot BioAggregate (DB; Innovative BioCaramix Inc, Vancouver, BC, Canada), newly developed product, by using MG63 osteoblast-like cells. MTA, DB, and Intermediate Restorative Material (IRM; Dentsply Caulk, Milford, DE, USA) were used for root-end filling material while tissue culture plastic was used for control group. Each material was mixed and, the mixtures were left to set for 24 hours. MG63 cells were seeded to each group and then they were cultured for attachment for 4 hours. Following the attachment of cells to the root-end filling material, early cellular response was observed. After another 12 hours'culture, the level of attachment between cells and material was observed and in order to identify the effect of each material to bone formation, transforming growth factor beta1 ($TGF{\beta}1$) and osteocalin (OC) were estimated by using enzyme-linked immunosorbent assay (ELISA), and the amount of alkaline phosphatase (ALP) was also measured. The data were analyzed using one-way ANOVA. As a result, only at OC and the number of cells which were attached to materials, there was no statistical difference between MTA and DB. At other items, there was statistically significant difference in all groups. Although DB has not shown exactly the same cellular response like that of MTA, the number of attached cells shows that biocompatibility of the material and OC indicates bone formation rate. Therefore, if DB is used for root end filling material, it is expected to lead to similar results to MTA.