• Title/Summary/Keyword: 이온 채널

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Characteristics of silver ion-exchanged glass waveguides at 633nm and $1.5{\mu}m$ (은 이온 교환법으로 만든 유리 도자로의 633nm와 $1.5{\mu}m$에서의 특성 연구)

  • 유건호
    • Korean Journal of Optics and Photonics
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    • v.3 no.3
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    • pp.198-202
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    • 1992
  • Silver ion-exchanged glass waveguide with its large surface index difference and shallow depth is suitable to be used for the hybrid integration of semiconductor device and glass waveguide using the semiconductor film grafting technique. We report characteristics of the planar and channel glass waveguides exchanged in the diluted silver nitrate melt in the visible and infrared spectral region. Especially, we determined the fabrication parameters for single-mode channel waveguide at 1.5.$\mu$m, an important wavelength in the optical communication. Directional couplers with several different configurations were fabricated, and their 3 dB coupling length was determined as a function of wavelenGh and polarization.

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Simulation Design of MHEMT Power Devices with High Breakdown Voltages (고항복전압 MHEMT 전력소자 설계)

  • Son, Myung-Sik
    • Journal of the Korean Vacuum Society
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    • v.22 no.6
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    • pp.335-340
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    • 2013
  • This paper is for the simulation design to enhance the breakdown voltage of MHEMTs with an InP-etchstop layer. Gate-recess and channel structures has been simulated and analyzed for the breakdown of the MHEMT devices. The fully removed recess structure at the drain side of MHEMT shows that the breakdown voltage enhances from 2 V to almost 4 V as the saturation current at gate voltage of 0 V is reduced from 90 mA to 60 mA at drain voltage of 2 V. This is because the electron-captured negatively fixed charges at the drain-side interface between the InAlAs barrier and the $Si_3N_4$ passivation layers deplete the InGaAs channel layer more and thus decreases the electron current passing the channel layer and thus the impact ionization in the channel become smaller. In addition, the replaced InGaAs/InP composite channel with the same thickness in the same asymmetrically recessed structure increases the breakdown voltage to 5 V due to the smaller impact ionization and mobility of the InP layer at high drain voltage.

나노전기동역학 수치 해석적 연구 동향

  • Bae, Ju-Yeol;Kim, Tae-Seong
    • Journal of the KSME
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    • v.57 no.10
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    • pp.38-42
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    • 2017
  • 이 글에서는 나노 스케일의 채널이 갖는 특성으로부터 기인하는 이온 및 물질의 전달현상을 이해하기 위한 수치 해석적 연구를 소개하고자 한다.

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pH Sensitive Graphene Field-Effect Transistor(FET) (pH에 민감한 그래핀 전계효과 트랜지스터(FET))

  • Park, Woo Hwan;Song, Kwang Soup
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.2
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    • pp.117-122
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    • 2016
  • Recently, the detection of pH with real-time and in vivo has been focal pointed in the environmental or medical fields. In this work, we developed the pH sensor using graphene sheet. Graphene has high biocompatibility. We fabricated flexible solution-gated field-effect transistors (SGFETs) on graphene sheet transferred on the polyethylene terephthalate (PET) substrate to detect pH in electrolyte solution. The gate length was $500{\mu}m$ and the gate width was 8 mm. We evaluated the current-voltage (I-V) transfer characteristics of graphene SGFETs in pH solution. The drain-source current ($I_{DS}$) and the gate-source voltage ($V_{GS}$) curves of graphene SGFETs were depended on pH value. The Dirac point of graphene SGFETs linearly shifted to the positive direction about 19.32 mV/pH depending on the pH value in electrolyte solution.

Effect of Force-field Types on the Proton Diffusivity Calculation in Molecular Dynamics (MD) Simulation (분자동역학 전산모사에서 force-field의 종류가 수소이온 확산도 계산에 미치는 영향)

  • Lee, Ji Hyun;Park, Chi Hoon
    • Membrane Journal
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    • v.27 no.4
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    • pp.358-366
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    • 2017
  • The most important factor in the performances of polymer electrolyte membranes for fuel cells is how fast hydrogen ions can be transported along the water channel formed inside the electrolyte membrane. Since the morphology of the water channel and the diffusivity of the protons are very important factors for the proton transport behavior, various molecular dynamics simulation studies are being carried out to clarify this. The force-field is an important variable parameterizing the movement and interaction of each atom in molecular dynamics simulation. In this study, proton diffusivities of the 3D models of polymer electrolyte membranes were calculated in order to analyze the effects of various types of force-fields on the molecular simulation. It has been found that the charge value determining the non-bonding interaction plays a very important role in the formation of the water channel morphology, and the COMPASS force-field can calculate the accurate proton diffusion behavior. Accordingly, for molecular dynamics simulation of polymer electrolyte membranes, the proper selection of the force-field is very important due to its great effect on the proton diffusion as well as the final molecular structure.

Effect of Nafion Chain Length on Proton Transport as a Binder Material (수소이온 전달 특성에 미치는 바인더로 활용 가능한 나피온의 주쇄 길이의 영향)

  • Kang, Hoseong;Park, Chi Hoon
    • Membrane Journal
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    • v.30 no.1
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    • pp.57-65
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    • 2020
  • The purpose of this study was to compare the water channel morphology and the proton conductivity by changing the number of repeating units of the polymer backbone of PEMs, and to present a criterion for selecting an appropriate polymer model for MD simulation. In the model with the shortest polymer main chain, the movement of the main chain and the sulfonic acid group was observed to be large, but no change in the water channel morphology was found. In addition, due to the nature of the proton transport ability that is most affected by the water channel morphology, the proton conductivity did not show a significant correlation with the length of the polymer backbone. These results provide important information, particularly for the preparation of ionomers for binders. In general, a low molecular weight polymer electrolyte material is used for a binder ionomer. Since the movement of the main chain/sulfonic acid group is improved, it can play a role of enclosing the catalyst layer well. However, there is no change in its proton conducting performance. In conclusion, the preparation of ionomers for binders will require molecular weight and structure design with a focus on physical properties rather than proton transfer performance.

Analysis of Subthreshold Current Deviation for Channel Doping of Double Gate MOSFET (이중게이트 MOSFET의 채널도핑에 다른 문턱전압이하 전류 변화 분석)

  • Jung, Hakkee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.6
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    • pp.1409-1413
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    • 2013
  • This paper analyzed the change of subthreshold current for channel doping concentration of double gate(DG) MOSFET. Poisson's equation had been used to analyze the potential distribution in channel, and Gaussian function had been used as carrier distribution. The potential distribution was obtained as the analytical function of channel dimension, using the boundary condition. The subthreshold current had been analyzed for channel doping concentration, and projected range and standard projected deviation of Gaussian function. Since this analytical potential model was verified in the previous papers, we used this model to analyze the subthreshold current. As a result, we know the subthreshold current was influenced on parameters of Gaussian function and channel doping concentration for DGMOSFET.

Molecular Dynamics Study to Investigate Ion Selectivity of Functionalized Carbon Nanotube Membranes (기능화된 탄소나노튜브 멤브레인의 이온 선택성에 관한 분자동역학 연구)

  • Suk, Myung Eun
    • Membrane Journal
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    • v.28 no.6
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    • pp.388-394
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    • 2018
  • Carbon nanotube (CNT) based membranes are promising candidates for separation membranes by showing high water transport rate and ion rejection rate according to their radii. The ion selectivity is an important factor to discover the full potential of CNT membranes, and it is affected by the functionalization of CNTs. With multivalent/size ion mixtures, the ion selectivity is affected by not only ion-functional groups interaction but also ion-ion interactions and ion size exclusion in a complex manner. In this study, molecular dynamics simulations are performed to study the ion selectivity of functionalized carbon nanotubes when multivalent/size ions are contained. The permeation energy barriers are calculated by plotting potential of mean force profiles, and various factors, such as CNT size and partial charges, affecting ion selectivity are investigated. The results presented here will be useful for designing CNT membranes for ion separation, biomimetic ion channels, etc.

Three Dimensional Computational Study on Performance and Transport Characteristics of PEMFC by Flow Direction (유동방향 변화에 따른 고분자 전해질 연료전지의 성능 및 전달특성에 대한 3차원 수치해석적 연구)

  • Lee, Pil-Hyong;Han, Sang-Seok;Hwang, Sang-Soon
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.51-58
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    • 2008
  • Many researches for effects of different flow configurations on performance of Proton Exchange Membrane Fuel Cell have extensively been done but the effects of flow direction at the same flow channel shape should be considered for optimal operation of fuel cell as well. In this paper a numerical computational methode for simulating entire reactive flow fields including anode and cathode flow has been developed and the effects of different flow direction at parallel flow was studied. Pressure drop along the flow channel and density distribution of reactant and products and water transport, ion conductivity across the membrane and I-V performance are compared in terms of flow directions(co-flow or counter-flow) using above numerical simulation method. The results show that the performance under counter-flow condition is superior to that under co-flow condition due to higher reactant and water transport resulting to higher ion conductivity of membrane.

Synthetic Strategies for High Performance Hydrocarbon Polymer Electrolyte Membranes (PEMs) for Fuel Cells (고성능 탄화수소계 고분자 전해질막의 합성 전략)

  • Lee, So Young;Kim, Hyoung-Juhn;Nam, Sang Yong;Park, Chi Hoon
    • Membrane Journal
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    • v.26 no.1
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    • pp.1-13
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    • 2016
  • Fuel cells are regarded as a representative energy source expected to replace fossil fuels particularly used in internal combustion engines. One of the most important components is polymer electrolyte membranes (PEMs) acting as a proton conducting barrier to prevent fuel gas crossover. Since water channels act as proton pathways through PEMs, many researchers have been focused on the 'good phase-separation of hydrophilic moiety' which ensures high water retention under low humidity enough to keep the water channel for good proton conduction. Here, we summarized the strategies which have been adopted to synthesize sulfonated PEMs having high proton conductivities even under low humidified conditions, and hope this review will be helpful to design high performance hydrocarbon PEMs.