• Journal of Korean Society of Environmental Engineers
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• v.34 no.3
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• pp.162-167
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• 2012

The removal of orthophosphate ions from aqueous solutions by the anion exchange resin in the form of $Cl^-$ ion was investigated to elucidate the ion exchange mechanism which depends on the forms of orhthophoshate ions. In addition, the effects of alkalinity and other common anions were studied. The results showed that the orhthophosphate ions with the oxidation state of 2 and 3 ($HPO{_4}^{2-}$ and $PO{_4}^{3-}$) were effectively removed by the anion exchange resin, whereas the part of the $H_2PO_4{^-}$ ion passed through the ion exchange column. This suggested that the affinity of $H_2PO_4{^-}$ to the ion exchange resin was comparable with that of $Cl^-$ ion. In all cases, the effluent pHs have shown to be much lower than the calculated values, indicating that more $Cl^-$ ions than the orthophosphate equivalents in the influent were eluded. As the alkalinity increases, the decrease in pH was minimized. When the alkalinity was 100 mg/L ($CaCO_3$) or greater, 100 mg/L orthophosphate ions including $H_2PO_4{^-}$ were completely removed. The common anions such as $SO{_4}^{2-}$ and $NO_3{^-}$ were also removed by the anion exchange resin, and thus decreased the ion exchange capacity for the removal of orthophosphate.

• Korean Journal of Soil Science and Fertilizer
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• v.33 no.2
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• pp.100-108
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• 2000

High sodium contents in food-waste compost(FWC) is the greatest limitation to recycle it to arable lands in Korea. The effects of the FWC application to paddy soil on the growth of rice plants, cationic balance in plants, and the sodicity of soil have been studied in pot trials. The effects of FWC application were compared with those of NaCl compound and swine manure compost(SMC) application. $Na_2O$ contents of FWC were high as 2.2%. Immediately after transplanting, rice plants in three treatments showed severe wilting in the order of 40Mg FWC $ha^{-1}$ > NPK+900kg $NaClha^{-1}$ > 20Mg FWC $ha^{-1}$. The high EC value and volatile acid contents of soil solution were regarded as the cause of severe wilting of young rice plants. Increase of NaCl application rate upto $900kgha^{-1}$ showed no significant reduction of dry matter yield at harvesting stage. Regardless of application rates FWC reduced the dry matter yield at harvesting stage, while SMC increased it with increase of application rates upto $40Mgha^{-1}$. In NPK+NaCl and FWC treatments, Na contents and equivalent ratio in plants increased linearly with increase of Na application rates. Between Na and K equivalent ratio negative correlation with high significance was shown. In contrast to much difference of Na, K, and Na/K equivalent ratio among treatments, little difference of Na+K indicated the physiological substitution of Na for K in rice plants. Na use efficiency in NPK+NaCl and FWC treatments showed 12-22%.

• Analytical Science and Technology
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• v.10 no.1
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• pp.31-34
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• 1997

Barium titanyl oxalate which is a precursor of barium titanate has been precipitated at pH 4~5 by a rapid addition of aqueous titanyl oxalate solution to artificial environmental water samples containing equivalent weight of $Ba^{2+}$ ions. Quantitative recoveries of $Cd^{2+}$ and $Pb^{2+}$ from the water samples has been confirmed and found to be usable as a possible method of preconcentration for their determination.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.4
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• pp.353-359
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• 1996

Micro plot study was conducted to elucidate the behavior of nitrogen derived from animal manure in soil and to obtain the fundamental information on animal waste management. Soils used in this experiment were sandy loam and loam. Soil water samplers (1m length ceramic cup tube) were installed at 90cm depth of soil to collect the percolate. Fresh and fermented pig manure were applied at the rate of 0, 50, 100 ton per ha. Maize was grown to evaluate the effect of crop on nitrogen behavior through soil profile. Concentration of nitrate nitrogen in percolate increased by application of pig manure. This trend was more obvious at the loam with fermented pig manure than sandy loam with fresh pig manure treatment. The concentration of nitrate nitrogen was lower under the maize cultivation than bare soil condition by 64.6-68.9%. Concentration of Ca, Mg and Na of soil and percolate increased as nitrate nitrogen concentration increased. The equivalent ratio of cation to nitrate nitrogen of percolate was increased by application of pig manure. This result showed that canon leaching was accompanied by nitrate nitrogen. Concentration of nitrate nitrogen of subsurface soil was increased by pig manure application.

• Applied Chemistry for Engineering
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• v.16 no.1
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• pp.123-130
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• 2005

Zeolite X adsorbents with large surface area were prepared for using oxygen PSA adsorbent. Selective adsorption performance of nitrogen on the synthesized zeolite X adsorbent was improved by the cation exchange of adsorbent. The zeolite X which had over $650m^2/g$ surface area was synthesized at the conditions of $SiO_2\;:\;Na_2O\;:\;H_2O\;:\;Al_2O_3$ = 2.5 : 3.5 : 150 : 1 mole ratio, $98^{\circ}C$ temperature and 18 h synthesized time in 50 L reactor. The metal ions Li, Ag, Ca, Br, Sr, etc. were investigated for ion exchange with zeolite X. Ag ion was showed the highest ion exchange rate among these metal ions and all metal ions were exchanged with Na ion at equivalent rate. Compared with the NaX adsorbent, the ion exchanged zeolite X adsorbent remarkably improved its adsorption performance of nitrogen at the conditions of $10{\sim}40^{\circ}C$ temperature and 0~9 atm pressure. At an equilibrium pressure under 0.5 atm, adsorption performance of nitrogen on the ion exchanged zeolite adsorbent increased in the order of Ag > Li > Ca > Sr> Ba > K, whereas at an equilibrium pressure over 1 atm showed in the order of Li > Ag > Ca > Sr > Ba > K. Nitrogen/oxygen separation factor of Li ion exchanged zeolite X adsorbent was 13.023 at the partial pressure of nitrogen/oxygen gas mixture similar to air and $20^{\circ}C$ adsorption temperature.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.4
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• pp.197-203
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• 2015

Particulate matter (PM) has emitted in many regions of the world and is causing many health-related problems. Thus reasonable politics and solutions are needed to reduce PM in Seoul. Further it is required to clearly explain the major portions of chemical components contained in $PM_{10}$ to figure out the characteristics of $PM_{10}$, and to develop effective reduction measures in order to decrease the adverse effects of $PM_{10}$. $PM_{10}$ samples were collected in Seoul and analyzed their ions to examine the physical and chemical characteristics of ionic species. Since hydrogen ion ($H^+$) and carbonate ion (${CO_3}^{2-}$)) cannot be analyzed by Ion chromatography (IC), concentrations of $H^+$ and ${CO_3}^{2-}$ were initially estimated by pH and equivalent differences between anions and cations in this study. Starting from the study findings, good combination results for compositional patterns between anions and cations were obtained by applying a mathematical modelling technique that was based on the mass balance principle. The ions in $PM_{10}$ were combined with $H^+$, ${CO_3}^{2-}$, and supplement for $NO_3{^-}$, $Cl^-$ formed such compounds $NH_4Cl$, $NH_4NO_3$, $CaSO_4$, $(NH_4)_2SO_4$, $NaNO_3$, NaCl, $Na_2CO_3$, and $(NH_4)_2CO_3$ in the study area.

• Resources Recycling
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• v.30 no.6
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• pp.61-67
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• 2021

This work investigated the cementation of iridium from iridium-containing hydrochloric acid leachate. Zinc powder was used as the reducing agent, and the effects of the stoichiometric ratio of Zn/Ir, initial Ir concentration, initial pH, reaction time, and ultrasound irradiation on iridium recovery were investigated. When only the stirrer was used for cementation, the iridium recovery increased with the addition amount of zinc, and the recovery of about 70% at 40 times the stoichiometric ratio of Zn/Ir. In contrast, when employing ultrasonic irradiation with stirring, the recovery of iridium decreased at 20 times or less the stoichiometric amount of zinc. The recovery of iridium increased at 40 times the stoichiometric ratio of Zn/Ir. This result may be due to the ionization of zinc and re-dissolution of iridium during the ultrasound irradiation treatment. When a combination of ultrasonic irradiation and stirring was used for cementation, the iridium recovery increased by more than 27% compared to that when using only the stirrer. It was possible to recover 99% of iridium under the following conditions: reaction time, 60 min; initial pH, 0.01; volume of leachate, 100 mL; 1770 ppm Ir, 40 times the stoichiometric ratio of Zn/Ir.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.474-479
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• 2012

Possibility of the selective removal of $Ca^{2+}$ ions from a mixed solution of $Na^{+}$ and $Ca^{2+}$ ions using membrane capacitive deionization (MCDI) was investigated. Adsorption equilibrium experiments were conducted to determine the selectivity of the CMX cation-exchange membrane toward $Ca^{2+}$ ions. In addition, desalination experiments for a mixed solution (5 meq/L NaCl + 2 meq/L $CaCl_{2}$) were performed using an MCDI cell. The adsorption equilibrium of CMX membrane showed that the equivalent fraction of $Ca^{2+}$ ions in the solution and the CMX membrane were 28.6 and 87.2%, respectively, which indicates the CMX membrane's high selectivity toward $Ca^{2+}$ ions. Desalination experiments were performed by applying a constant current to the MCDI cell until the cell potential reached 1.0 V. The amount of ions adsorbed did not significantly change as the applied current was changed. However, the equivalent fractions of $Ca^{2+}$ ions among the adsorbed ions were inversely proportional to the applied currents: 81.4, 78.4, 77.0, and 74.5% at 200, 300, 500, and $700\;A/m^{2}$ of applied current density, respectively. This result is attributed to the increased fraction of $Ca^{2+}$ ions adsorbed by the CMX membrane at lower applied current densities.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.399-402
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• 2006

현재까지 연료전지 전해질 막으로는 Nafion으로 잘 알려져 있는 perfluorosulfonic acid(PFSA)막이 주를 이루고 있다. 이 막들은 $80^{\circ}C$ 이하의 낮은 온도의 연료전지에서 가장 좋은 성능을 보인다. PFSA 막들은 탄소-불소로 이루어진 사슬의 특성상 산화, 환원의 조건에서도 뛰어난 안정성을 보이며 이온 전도도가 0.1S/cm 이상으로 기존에 알려진 전해질 막들 중 가장 우수한 성능을 나타낸다. 하지만 연료전지의 작동온도가 $100^{\circ}C$ 이상의 높은 온도에서 는 막에 존재하던 수분이 제거되면서 수소이온 전도도가 떨어지며 기계적 물성도 떨어지는 문제점을나타낸다. $100^{\circ}C$ 이상의 온도에서 연료전지를 작동시키면 양쪽의 전극에서 일어나는 촉매반응의 속도가 향상되며, 물의 끓는점 이상에서 작동되므로, 전지 내에서 다양한 상을 고려하지 않고 기화된 물만을 고려하여 설계를 할 수가 있다. 따라서 최근 이러한 고온/저가습 운전을 위 한 전해질 막의 개발을 위해 기존의 Nafion 막에 전도성 무기 입자를 도입하는 연구들이 활발히 진행되고 있다. 본 연구에서는 전도성 무기 입자로서 $ZrO_2$나노입자를 합성하고, 이를 상용 10 wt.% Nafion 용액에 분산하여 solution casting 방법을 통해 $61{\mu}m$ 두께의 유기-무기 복합막을 제조하였다. 제조한 유기-무기 복합막의 성능 평가를 위하여 함수율, 이온 전도도, 당량무게 및 단위 전지를 이용한 전류-전압 곡선을 측정하여 상용 Nafion 112 막과 비교해 보았다. $ZrO_2$ 입자는 전도성이며 동시에 친수성을 나타내기 때문에 상용 막에 비하여 함수율 및 수소이온 전도도가 우수하게 나타났다. 복합막의 이러한 물성은 $100^{\circ}C$이상의 고온에서 전해질 막 내의 물 관리를 용이하게 한다. 단위 전지 운전 온도 $130^{\circ}C$, 상대습도 37%의 운전 조건에서도 상당히 우수한 전지 성능을 보임에 따라 고온/저가습 조건에서 상용 Nafion 112 막보다 우수한 막 특성을 나타냄을 확인하였다.

• Journal of the Korean Society of Combustion
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• v.4 no.2
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• pp.35-41
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• 1999

The purpose of this study is to establish the flame structure and NOx emission characteristics of the swirl flow coaxial diffusion combustion in the model gas turbine combustor. The mean temperature, ion currents and NOx emission measurement technique showed the effect of equivalence ratio into flame length and flame stability. As a result of this study, NOx emission was increased by increasing the equivalence ratio, and the peak value of the NOx was appeared near the flame front.