• Journal of Bio-Environment Control
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• v.19 no.2
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• pp.70-76
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• 2010

To investigate the ground water quality status for paprika hydroponics for export, its pH, EC (electrical conductivity) and inorganic ion concentrations were analyzed in Gangwan-do (27 samples), Gyeonsangnam-do (77 samples) and Jeollanam-do (54 samples) from November 2008 to September 2009. The average values of several components in ground water were as follows; 7.20 (6.57~7.54) in pH, 0.31 (0.05~0.49) $dS{\cdot}m^{-1}$ in EC, 97.81 (35.37~161.11) in $HCO_3$, 5.68 (0.45~15.48) in T-N, 0.67 (0.15~0.70) in P, 2.53 (0.59~6.70) in K, 35.68 (4.15~80.70) in Ca, 7.35 (1.46~14.87) in Mg, 17.89 (3.31~34.82) in Na, 0.01 (0~0.05) in Fe, 0.09 (0~0.51) in Mn, 0.06 (0~0.07) in Zn, and 0.03 (0~0.10) $mg{\cdot}L^{-1}$ in Cu, respectively. The values of pH, EC, $HCO_3$, Ca, Mg and Na in ground water were different depending on areas and farms. Frequency rates were 92.6% of pH 5.0~8.0, 89.3% of EC < 0.5 $dS{\cdot}m^{-1}$, 69.5% of $HCO_3$ < 100, 97.5% of Na < 30, 88.5% of Ca < 40, 97.5% of Mg < 20, 90.1% of Fe < 0.05, 99.6% of Mn < 0.6, and 98.3% of Zn < 0.5 $mg{\cdot}L^{-1}$, respectively, which can be used for nutrient fertilizers in hydroponics. The percentage of suitable water quality was 46.3% as 70 sites among the all analyzed ions. The pH value showed high significance of correlations with EC, Mg, $HCO_3$, Na, and Fe. Also the EC value showed high positive significance with T-N, K, Ca, Mg, $HCO_3$, Na and Mn.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.4
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• pp.642-648
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• 2012

To evaluate the water quality in Juksancheon constructed wetlands for treating non-point source pollution, the removal rates of nutrients in water and the total amounts of T-N and T-P uptakes by water plants were investigated. Chemical characteristics of T-N and T-P in sediment were investigated. The concentrations of BOD (Biochemical Oxygen Demand), COD (Chemical Oxygen Demand), SS (Suspended Solids), T-N and T-P in inflow were 0.07~1.47, 0.60~2.65, 0.50~4.60, 1.38~6.26 and $0.08{\sim}0.32mg\;L^{-1}$, respectively. The removal rates of BOD, COD, SS, T-N, and T-P were -10, 51, 66, -3 and 5%, respectively. The maximum amount of T-N uptake by water plants in August was $368.7mg\;plant^{-1}$ in the $2^{nd}$ treatment stage by Nymphoides peltata, $1314.6mg\;plant^{-1}$ in the $3^{rd}$ treatment stage by Iris pseudacorus, $1160.4mg\;plant^{-1}$ in the $4^{th}$ treatment stage by Nymphaea tetragona GEORGI, respectively. The maximum amount of T-P uptake by water plants in August was $121.7mg\;plant^{-1}$ by Nymphoides peltata in the $2^{nd}$ treatment stage, $268.7mg\;plant^{-1}$ by Iris pseudacorus in the $3^{rd}$ treatment stage and $212.0mg\;plant^{-1}$ by Nymphaea tetragona GEORGI in the $4^{th}$ treatment stage, respectively. Organic matter contents in sediments were not different. Contents of T-N and T-P in sediments were higher in spring. Microbial biomass C:N:P ratios in sediments in spring, summer, autumn and winter were 117~140:1~4:1, 86~126:5~6:1, 68~101:2~6:1 and 47~138:2~4:1, respectively. We could conclude that Juksancheon constructed wetlands show high removal efficiencies of COD and SS. However, improvements of management in winter season should be considered to improve the removal efficiencies of pollutants.

• Economic and Environmental Geology
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• v.36 no.2
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• pp.89-101
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• 2003

River deposits and farmland soils were analyzed to investigate the pollution level of heavy metals in the vicinity of the Goro abandoned Zn-mine. Surface (0-40 cm) and subsurface (40-100 cm) soils were collected around a main river located at the lower part of the Goro mine, and analyzed by ICP-MS for Cd, Cu, Pb, Zn and Cr after 0. 1N HCI extraction and by AAS for As after IN HCI extraction. Concentrations of cadmium and lead at the surface river deposits close to the mine were over the Soil Pollution Warning Limit (SPWL), and 43% of sample sites (6 of 14 samples) were over SPWL for As suggesting that river deposits were broadly contaminated by arsenic. Results from farmland soil analysis showed that surface soils were contaminated by heavy metals, while only arsenic was over SPWL at 50% of sampling sites. Main pollution mechanism around the Goro mine was the discharge of mine tailing and waste rocks from the storage site to the river and to adjacent farmland during flood season. Pollution Grades for sample locations were prescribed by the Law of Soil Environmental Preservation, suggesting that the pollution level of heavy metals around the Goro mine was serious, and the remediation operation fur arsenic and the isolation of mine tailing and waste rocks from river and farmland should be activated to protect further contamination. The area needed to clean up was estimated from pollution distribution data and the remediation methods such as a soil washing method and a soil improvement method were considered as the further remediation operation for arsenic contaminated soils and river deposits around the Goro abandoned mine.

• Korean Journal of Environmental Agriculture
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• v.24 no.2
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• pp.77-82
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• 2005

This study was conducted to identify the characteristics of non-point pollutants discharge in a small agricultural watershed during farming season. for this purpose, the Neoungchon watershed in Goesangun was selected as a typical agricultural area. Runoff and water quality data in the stream, the domestic sewage and the precipitation of the watershed were analyzed periodically from June 1 to November 6 in 2004 and pollutant loads were estimated. As a result the mean concentrations of BOD, SS, TN and TP in the stream were 3.0, 76.7, 8.7, 0.16 mg/L in rainy season and 2.4, 10.0, 3.5, 0.11 mg/L in dry season respectively. Daily discharge of non-point pollutant occurred above of 95% in rainy period. Measured pollutant loads in the watershed were $26.63kg/km^2/day$ of T-N and $0.62kg/km^2/day$ of T-P, within the range of other research results. Effluent loads based on guideline of total pollutant to stream management of MOE (Ministry of Environment) were less than delivery loads since the guideline could not reflect the agricultural practices, geomorphic and meteorological characteristics in an agricultural watershed.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.12
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• pp.1381-1389
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• 2007

Wastewater discharged by industrial activities of metal finishing and electroplating units is often contaminated by a variety of toxic or otherwise harmful substances which have a negative effects on the water environment. The treatment method of heavy metal-cyanide complexes wastewater by alkaline chlorination have already well-known($1^{st}$ Oxidation: pH 10, reaction time 30 min, ORP 350 mV, $2^{nd}$ Oxidation: ORP 650 mV). In this case, the efficiency for the removal of ferro/ferri cyanide by this general alkaline chlorination is very high as 99%. But the permissible limit of Korean waste-water discharge couldn't be satisfied. The initial concentration of cyanide was 374 mg/L(the Korean permissible limit of cyanide is 1.0 mg/L max.). So a particular focus was given to the treatment of heavy metal-cyanide complexes wastewater by $Zn^{+2}/Fe^{+2}$ ion and coprecipitation after alkaline chlorination. And we could meet the Korean permissible limit of cyanide(the final concentration of cyanide: 0.30 mg/L) by $Zn^{+2}/Fe^{+2}$ ion and coprecipitation(reaction time: 30 min, pH: 8.0, rpm: 240). The removal of Chromium ion by reduction(pH: 2.0 max, ORP: 250 mV) and the precipitation of metal hydroxide(pH: 9.5) is treated as 99% of removal efficiency. The removal of Copper and Nickel ion has been treated by $Na_2S$ coagulation-flocculation as 99% min of the efficiency(pH: $9.09\sim10.0$, dosage of $Na_2S:0.5\sim3.0$ mol). It is important to note that the removal of ferro/ferri cyanide of heavy metal-cyanide complexes wastewater should be employed by $Zn^{+2}/Fe^{+2}$ ion and coprecipitation as well as the alkaline chlorination for the Korean permissible limit of waste-water discharge.

• Analytical Science and Technology
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• v.29 no.2
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• pp.57-64
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• 2016

Many phthalic acid esters (PAEs), including DMP, DEP, DBP, BBP, and DEHP, as well as DEHA are widely used as plasticizers in plastics. An analytical method was developed and used to analyze these compounds at 41 industrial facilities. The coefficient of determination (R²) for each constructed curve was higher than 0.98. The method detection limit (MDL) values were 0.4–0.7 μg/L for PAEs and 0.6 μg/L for DEHA. In addition, the recovery rate was shown to be 77.0–92.3%, while the relative standard deviation was shown to be in the range of 5.8-10.5%. DMP (n = 3), DEP (n = 2), DBP (n = 2), BBP (n = 2), and DEHA (n = 3) were detected in the range of 2.2-11.1% in the influent. DEHP was a predominant compound and was detected at > MDL in both the influent (n = 16, 35.6%) and the effluent (n = 4, 10.0%) at a high removal efficiency (92–100%). The highest levels of residue in industrial wastewater influent were 137.4 μg/L of DEHP at plastic products manufacturing facility, 12.5 μg/L of DEHA at a chemical manufacturing facility, and 14.0 μg/L of DEP at an electronics facility. The highest concentration of effluent was 12.5 μg/L of DEHP at a chemical manufacturing facility, which indicated that the effluent was below the allowable concentration (800 μg/L). Therefore, the levels of PAEs and DEHA that are discharged into nearby streams could not influence the health of the ecosystem.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.20 no.2
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• pp.126-135
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• 1987

The physical properties, coliform groups, and nutrients were investigated to evaluate the sanitary Quality of the environmental water at Chinju area from May to October, 1986. The results were as follows : The pH ranged from 5.4 to 7.8 : water temperature ranged from 12.0 to $30.3^{\circ}C$ : electrical conductivity ranged from $0.51\times10^2\;to\;8.095\times10^2\mu\mho/cm$; chloride ion ranged from 3.6 to 126.8 mg/l, respectively. Especially, the concentration of the chloride ion at St.9 was 109mg/l which was higher than those of others. The $NO_3^--N$ ranged from 0.2336 to 14.1648 mg/l and the mean value was 5.4774 mg/l, the concentration of $NO_3^--N$ at St. 2 was higher as 40 times than that of St.4. The $PO_4^{3-}-P$ ranged from 0.0013 to 0.8315 mg/l, and the mean value was 0.0745 mg/l, the concentration of$PO_4^{3-}-P$ at St.8 was higher than that of others. The $SiO_2-Si$ ranged 1.7 to 15.28 mg/1 and the mean value was 5.81 mg/l. The value of St.8 and St.9 were higher than those of other stations but this value were lower $10\~13\;mg/l$ than the criterion for drinking water as 50 mg/l. The bacterial density of the spring waters ranged 9.1 to 4,600/100 ml (geometric mean : 205/100 ml) for total coliform 0 to 4s0/100 ml and 28.2/100 ml for fecal coliform. Composition of coliform was $38.2\%$ Escherichia coli, $25\%$ Entrobacter aerogenes, $13.2\%$ Citrobecter freundii and the others.

• Journal of Korea Soil Environment Society
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• v.3 no.3
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• pp.93-107
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• 1998

Because of its stable quantity and quality, groundwater has long been a reliable source of drinking water for domestic users. Rapid economic growth and rising standards of living have in recent years put severe demands on drinking water supplies in Korea. Groundwaters that are currently being used for natural mineral water were hydrochemically evaluated and investigated in order to maintain their quality to satisfy strict health standards. There exist 15 natural mineral water plants in the Okcheon metamorphic belt. Characteristics of groundwaters are different from those of other areas in that electrical conductivity, hardness, contents of Ca, Mg and $HCO_3$are relatively high. The content of major cations is in the order of Ca>Mg, Na>K, whereas that of major anions shows the order of $HCO_3$>$SO_4$>Cl>F. The fact that the Ca-Mg-HCO$_3$type is mostly predominant among water types reflects that dissolution of carbonates that are abundantly present in the metamorphic rocks plays an important part in groundwater chemistry. Representative correlation coefficients between chemical species show Mg-$HCO_3$(0.92), Ca-$HCO_3$(0.88), Ca-Mg(0.80), Ca-Cl(0.78), Mg-$SO_4$(0.78), Ca-$SO_4$(0.71), possibly due to the effect by dissolution of carbonates, gypsum or anhydrite. Determinative coefficients between some chemical species represent a good relationship, especially for EC-(K+Na+Ca), Ca-$HCO_3$, Ca-Mg, indiacting that they are similar in chemical behaviors. According to saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. Groundwater is slightly undersaturated with respect to calcite and dolomite, whereas it is still greatly undersaturated with respect to gypsum, anhydrite and fluorite, Based on the Phase equilibrium in the systems $NA_2$O-$Al_2$$O_3$-$SiO_2$-$H_2$O and $K_2$O-$Al_2$$O_3$-$SiO_2$-$H_2$O, it is clear that groundwater is in equilibrium with kaolinite, evolved from the stability area of gibbsite during water-rock interaction. It is expected that chemical evolution of groundwater continue to proceed with increasing pH by reaction of feldspars, with calcite much less reactive.

• Korean Journal of Microbiology
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• v.39 no.2
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• pp.95-101
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• 2003

The total bacterial numbers, Eubacterial community structures and environmental factors which affect bacterial community were estimated monthly using DAPI and fluorescent in situ hybridization monthly, from June to November 2000 to evaluate the correlation between the bacterial community and environmental factors in eutrophic agricultural Masan reservoir in Asan. Average water temperatures varied from 12.3 to $27.5^{\circ}C$, pH 7.5 to 9.0, DO 7. I~12.8 mg/L, COD 6.4~13.0 mg/L, chlorophyll a 30.5~99.0 mg/㎥, SS 7.S~25.7 mg/L, TN 1.748~3.543 mg/L., and TP 0.104~0.581 mg/L, respectively. Total bacterial numbers showed high ranges from 0.4 to 9.6$\times$ $10^{6}$ cells/ml, and these indicated the mesotrophic or eutrophic state. The ratio of Eubacteria to total bacteria was 67.6-88.0%, which was higher than that in other reservoir. The relationships of total bacteria and Eubacteria community were more significant with organic nitrogen (Org-N), and organic phosphorus (Org-P) than with water temperature. Proteobacteria groups showed strongly significant relationships with Org-P and Org-N and significant relationships with water temperature, conductivity, COD, and inorganic nitrogen. C-F group was the most significant with Org-N, and HGC group with water temperature. However, relationships of Chl-a, pH, DO and SS showed no significance with any bacterial community. These results were different from other studies, because of the specific characteristics of Masan reservoir such as old, shallow and eutrophic states. The seasonal variation of bacterial community in Masan reservoir does not seem to depend on phytoplankton dynamics but on storm event and organic materials from watershed and the sediment of reservoir.

• Korean Journal of Ecology and Environment
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• v.38 no.3 s.113
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• pp.372-381
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• 2005

This study was conducted to test the efficiency of water quality improvement using the dissolved air flotation (DAF) technique in a shallow eutrophic reservoir. The application of DAF was followed by the addition of a chemical coagulant (poly aluminum chloride; PAC). The experiment was conducted in the mesocosm scale (wide ${\times}$ length ${\times}$ depth: 6 m ${\times}$ 6 m ${\times}$ 3 m). Suspended solids (SS) and volatile SS (VSS) concentration decreased by 54 ${\sim}$ 71% and 57 ${\sim}$ 79% of the initial concentrations, respectively. Total phosphorus and Chl- a concentration also decreased by 74 ${\sim}$ 92% and 54 ${\sim}$ 98%, respectively. BOD decreased by>86% while COD decrease ranged 29 ${\sim}$ 63%. Dissolved inorganic P (DIP) and dissolved total P (DTP) concentration decreased by 34 ${\sim}$ 88% and 62 ${\sim}$ 88%, respectively. After DAF application further onto the sediment, DIP-release rates from the sediment decreased by 17% (0.82 ${\to}$ 0.68 mg $m^{-2}$$day^{-1}$ in the oxic condition and 23% (2.27 ${\to}$ 1.76 mg $m^{-2}$$day^{-1}$) in the anoxic condition, compared to the release rate from the untreated sediment. DTP-release rate from both the oxic and anoxic sediments also decreased by 33% (5.62 ${\to}$ 3.78 mg $m^{-2}$$day^{-1}$) and 20% (6.23 ${\to}$ 4.99 mg $m^{-2}$$day^{-1}$), respectively. These results suggest that the DAF application both to the water column and onto the sediment be effective to improve water quality by removing particulate matters in the water column as well as reducing P-release from the sediment.