• Title/Summary/Keyword: 이산화탄소 활용

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The Prediction Model of Carbonation Process by CO2 Diffusion Using the Air Permeability Coefficient for Concrete (콘크리트의 투기계수를 이용한 CO2확산 탄산화진행 예측모델)

  • Kang, Suk-Pyo;Kim, Young-Sun;Song, Ha-Won;Kim, Gyu-Yong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.209-217
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    • 2010
  • Recently, some mathematical models for the prediction on progress of carbonation of concrete were reported. These models take account for $CO_2$ diffusion and chemical reaction between $Ca(OH)_2$ and $CO_2$. Based on the assumption that $CO_2$ diffuses in the carbonation zone and reacts with $Ca(OH)_2$ at the outer face of carbonation zone and non-carbonation zone. In this study, a mathematical model to predict the progress of carbonation of concrete has been established based on the reducing concentration of $Ca(OH)_2$ in the carbonation progress zone, where $Ca(OH)_2$ reacts with $CO_2$ and $Ca(OH)_2$ and $CaCO_3$ coexist. Also, the prediction model of carbonation progress rate of concrete using the air permeability coefficient regarding to $CO_2$ diffusion is developed. As a result of this study, an expression, the model equation is obtained for the prediction of carbonation based on the time and interaction velocity between $CO_2$ and Ca(OH)$_2$ dependent air permeability coefficient. The prediction by the model satisfied the experimental data of the accelerated carbonation for painted concrete. Consequently, the model can predict the rate of carbonation and the potential service life of concrete structure exposed to atmosphere.

The study on performance evaluation of heat resistance and smoke control system using air-curtain system in tunnel (터널용 에어커튼 시스템의 내열 및 제연 성능 평가 연구)

  • Park, Byoung-Jik;Shin, Hyun-Jun;Yoo, Yong-Ho;Park, Jin-Ouk;Kim, Yang-Kyun;Kim, Hwi-Seong
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.4
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    • pp.743-755
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    • 2018
  • Tunnel is a semi-closed structure similar to underground space where the smoke generated from fire fills the space fast while escaping from the space slow. Because of such characteristics, when the fire breaks out by traffic accident, the vehicles are jammed making it difficult for the people to evacuate from the scene as well as for the fire engine to gain access to the scene. For such reasons, tunnels are globally categorized into some disaster classes for differentiated facilities and operation approaches. In Korea, less than a 1 km-long tunnel accounts for 80.0% and such a short tunnel which is categorized into Class III is not required to have smoke control system. In this study, a full-scale fire test was conducted in a bid to apply air curtain system using heat-resistant sirocco fan to a less than 1 km-long tunnel. To that end, heat resistance test to verify the normal operation at $250^{\circ}C$ for 60 minutes was conducted. Consequently, despite of rapid rising-temperature and increasing-carbon dioxide inside the air curtain (direction of fire in tunnel), initial condition was found to have been sustained outside the air curtain (opposite direction of fire in tunnel).

Numerical Simulation of Local Atmospheric Circulations in the Valley of Gwangneung KoFlux Sites (광릉 KoFlux 관측지 계곡에서의 국지순환 수치모의)

  • Lee, Seung-Jae;Kim, Joon;Kang, Minseok;Malla-Thakuri, Bindu
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.16 no.3
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    • pp.246-260
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    • 2014
  • A 90-m horizontal-resolution numerical model was configured to study the micrometeorological features of local winds in the valley of Gwangneung KoFlux (Korea Flux network) Sites (GDK: Gwangneung Deciduous forest site in Korea, GCK: Gwangneung Coniferous forest site in Korea) during summer days. The U. S. Geological Survey (USGS) Shuttle Radar Topography Mission (SRTM) data were employed for high-resolution model terrain height. Model performance was evaluated by comparing observed and simulated near-surface temperature and winds. Detailed qualitative analysis of the model-simulated wind field was carried out for two selected cases which are a clear day (Case I) and a cloudy day (Case II). Observed winds exhibited that GDK and GCK, as well as Case I and Case II, had differences in timing, duration and strength of daytime and nighttime wind direction and speeds. The model simulation results strongly supported the existence of the drainage flow in the valley of the KoFlux tower sites. Overall, the simulated model fields realistically presented the diurnal cycle of local winds in and around the valley, including the morning drainage-upslope transition and the evening reversal of upslope wind. Also, they indicated the complexity of local winds interactions by presenting that daytime westerly winds in the valley were not always pure mountain winds and were often coupled with larger-scale wind systems, such as synoptic-scale winds or mesoscale sea breezes blowing from the west coast of the peninsula.

A Research on PV-connected ESS dissemination strategy considering the effects of GHG reduction (온실가스감축효과를 고려한 태양광 연계형 에너지저장장치(ESS) 보급전략에 대한 연구)

  • Lee, Wongoo;KIM, Kang-Won;KIM, Balho H.
    • Journal of Energy Engineering
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    • v.25 no.2
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    • pp.94-100
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    • 2016
  • ESS(Energy Storage System) is an important source that keeps power supply stable and utilizes electricity efficiently. For example, ESS contributes to resolve power supply imbalance, stabilize new renewable energy output and regulate frequency. ESS is predicted to be expanded to 55.9GWh of installed capacity by 2023, which is 30 times more than that of 2014. To raise competitiveness of domestic ESS industry in this increasing world market, we have disseminated load-shift ESS for continuous power supply imbalance with FR ESS, and also necessity to secure domestic track record is required. However in case of FR ESS, utility of installing thermal power plant is generally generated within 5% range of rated capacity, so that scalability of domestic market is low without dramatic increase of thermal power plant. Necessity of load-shift ESS dissemination is also decreasing effected by surplus backup power securement policy, raising demand for new dissemination model. New dissemination model is promising for $CO_2$ reduction effect in spite of intermittent output. By stabilizing new renewable energy output in connection with new renewable energy, and regulating system input timing of new renewable energy generation rate, it is prospected model for 'post-2020' regime and energy industry. This research presents a policy alternatives of REC multiplier calculation method to induce investment after outlining PV-connected ESS charge/discharge mode to reduce GHG emission, This alternative is projected to utilize GHG emission reduction methodology for 'Post-2020' regime, big issue of new energy policy.

A Study on the Integration Costs in Korean Electric System in Accordance with Increasing Solar and Wind Power Generation (태양광·풍력 발전 증가에 따른 한국의 전력시스템 내 통합비용에 관한 연구)

  • Kim, Doo Chun;Kim, Kwang Jin;Park, Jung Gu
    • Journal of Energy Engineering
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    • v.28 no.3
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    • pp.42-54
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    • 2019
  • The solar and wind power is spreading as a means to $CO_2$ reduction, but it has the characteristics of the volatility depending on the weather changes. This article aims to estimate the additional integration costs in Korea electric system in response to such volatility of increasing solar and wind power generation, using Korea electric power trading analyzer(KEPTA). The analysis utilizes the statistics of "8th Basic Plan for Long-term Electricity Supply and Demand" and "Renewable Energy Plan 3020". As the results, integration costs will be estimated 13.94Won/kWh~32.55Won/kWh, consisting of 8.94Won/kWh as back-up costs, 1.03Won/kWh~4.45Won/kWh as balancing costs, and 3.97Won/kWh~19.16Won/kWh as grid-costs. These results suggest that when the integration costs are secured, Korea electric system will be expected in the stable situation. This article leaves the further studies with taking the technological development of solar and wind power generation, the introduction of energy storage system, and wholesale price of electricity into consideration.

Efficient Spent Sulfidic Caustic wastewater treatment using Adsorption Photocatalysis System (흡착광산화 시스템을 이용한 효과적인 SSC 페수처리)

  • Kim, Jong Kyu;Lee, Min Hee;Jung, Yong Wook;Joo, Jin Chul
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.520-520
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    • 2016
  • 석유 화학공장에서 발생하는 spent sulfidic caustic (SSC) 폐수는 액화석유가스(LPG)나 천연가스(NG)의 정제과정에서 발생되는 것으로 고농도의 sulfide와 cresylic, phenolic 그리고 mercaptan 등이 포함된 독성과 냄새를 유발하는 물질이다. 이러한 물질들은 LPG나 NG의 정제과정에서 높은 산도를 가진 휘발성 황화합 물질들을 제거하기 위해 사용된 NaOH가 $H_2S$와 반응하여 발생하는 것이다. 진한 갈색 또는 검은색을 띄는 SSC 폐수는 12 이상의 높은 pH를 가지고 있으며 5~12 wt%의 높은 염분도를 가지고 있다. 또한 강한 부식성과 독성을 가진 황화합물의 농도가 1~4 wt%이며, 방향족 탄화수소 물질 (i.e. methanethiol, benzene, tolune and phenol)들도 다량 함유되어 있다. 따라서 이러한 유해 물질들은 기존의 하수처리 공정으로 방류하기 전에 완벽하게 처리해야만 하수처리 공정의 오염 부하량을 줄일 수 있다. 습식산화공정은 SSC 폐수를 처리하기 위해 흔히 사용되고 있는 물리-화학적 처리 공정이지만 고비용, 고에너지가 필요하며, 고온 및 고압에서만 작동되어 안전상의 문제점을 갖고 있다. 또한 습식산화공정을 거친 폐수는 배출허용기준을 만족하기 위해 생물학적 2차 처리가 반드시 필요하다. 철-과산화수소를 이용하는 펜톤산화 공정, 그리고 sulfide를 sulfate로 전환시키는 생물학적 처리 공정은 황화합물의 완전한 무기물화가 힘들며, 현장 적용 시 기술적 경제적 부담이 크다. 이러한 단점을 극복하고, SSC 폐수를 효과적으로 처리하기 위해 본 연구는, 높은 흡착력과 광산화력을 가진 흡착광산화 반응 시스템(Adsorption Photocatalysis System, APS)을 개발하였다. APS는 SSC 폐수를 시스템 내부로 유입하여 수중의 오염물질을 흡착광산화제로 구성된 반응구조체가 흡착하고, 흡착된 오염물질을 UV에너지와 이산화티타늄 광촉매의 광화학반응에 의해 최종적으로 무해한 물질로 환원시키는 폐수처리시스템이다. APS의 반응구조체는 태양에너지 및 인공에너지원에 의해 활용 가능하며, 난분해성 유기화합물질을 물과 이산화탄소로 분해할 수 있는 친환경적이고 경제적인 소재로서 널리 쓰이고 있는 이산화티타늄 광촉매와 화력발전소의 높은 소성온도에 의해 연소된 후 발생되는 bottom ash를 이산화티타늄의 지지체로 사용하여 높은 흡착력과 광촉매 산화력을 가진 복합물이다. 개발된 APS에 의해 SSC 폐수를 처리한 결과, COD 86.1%, 탁도 98.4%, sulfide 99.9%의 높은 처리효율을 보여주고 있다. 따라서 본 연구를 통해 개발된 APS는 강한 부식성과 독성 그리고 높은 농도를 가지고 있는 SSC 폐수를 효과적으로 처리할 수 있다.

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Measurements and Calculation of Injection Mass Rate of LFG for Intake Injection in Spark Ignition Engines (불꽃점화 엔진의 흡기관 분사를 위한 매립지가스 분사량의 측정 및 계산)

  • Kim, Kyoungsu;Choi, Kyungho;Jeon, Wonil;Kim, Bada;Lee, Daeyup
    • Journal of the Korean Institute of Gas
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    • v.25 no.4
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    • pp.36-42
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    • 2021
  • When the landfill gas generated at the landfill site is released into the atmosphere, methane gas with a high global warming potential is emitted, which adversely affects climate change. When methane contained in landfill gas is used as fuel for internal combustion engines and burned to generate electricity, it is emitted into the atmosphere in the form of carbon dioxide, which can contribute to lowering the global warming potential. Therefore, in order to use the landfill gas as fuel for power generation using an internal combustion engine, it is important to increase the thermal efficiency of the engine. Thus, it is necessary to use a fuel supply system in which gas is injected using an electronically controlled injector at an intake port for each cylinder rather than a fuel supply technology using the conventional mixer technology. In order to use the electronically controlled gas injection method, it is important to accurately measure the mass flow rate according to the conditions of using landfill gas. For this, a study was conducted to measure the injection amount and calculate them in order for the intake port gas injection of landfill gas.

Anthracite Oxygen Combustion Simulation in 0.1MWth Circulating Fluidized Bed (0.1 MWth 급 순환유동층에서의 무연탄 연소 전산유체역학 모사)

  • Go, Eun Sol;Kook, Jin Woo;Seo, Kwang Won;Seo, Su Been;Kim, Hyung Woo;Kang, Seo Yeong;Lee, See Hoon
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.417-428
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    • 2021
  • The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MWth Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MWth Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m3. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO2 concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.

ICT Convergenced Cascade-type Incubator for mass production of microalgae (미세조류 대량생산을 위한 ICT 융합 계단식 연속 배양 장치)

  • Lee, Geon Woo;Lee, Yong Bok;Yoo, Yong Jin;Baek, Dong Hyun;Kim, Jin Woo;Kim, Ho Seob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.5
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    • pp.379-386
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    • 2021
  • This study was undertaken to develop a cascade-type continuous culture system (CCCS) that combines both ICT and biotechnology (BT), for the mass production of microalgae. This system is capable of maintaining the essential culture conditions of pH, temperature, carbon dioxide, and illuminance control, which are key parameters for the growth of microalgae, and is economical for producing microalgae regardless of the season or location. It has the added advantage of providing stable and high productivity. In the current study, this system was applied to culture microalgae for 71 days, with subsequent analysis of the experimental data. The initial O.D. of the culture measured from incubator 1 was 0.006. On the 71st day of culture, the O.D.s obtained were 0.399 (incubator 1), 0.961 (incubator 2), 0.795 (incubator 3), and 0.438 (incubator 4), thereby confirming the establishment of continuous culture. Thus, we present a smart-farm based on ISMC (in-situ monitoring and control) for a mass culture method. We believe that this developed technology is suitable for commercialization, and has the potential to be applied to hydroponics-based cultivation of microalgae and cultivation of high-value-added medicinal plants as well as other plants used in functional foods, cosmetics, and medical materials.

Evaluation of Mechanical Test Characteristics according to Welding Position in FCAW Heterojunction (FCAW 이종접합에서 용접자세에 따른 기계적 시험 특성 평가)

  • Cho, Byung-Jun;Lee, Soung-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.8
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    • pp.649-656
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    • 2019
  • Flux cored arc welding (FCAW), which is used widely in many fields, such as shipyards, bridge structures, construction machinery, and plant industry, is an alternative to shielded metal arc welding (SMAW). FCAW is used largely in the welding of carbon and alloy steel because it can be welded in all poses and obtain excellent quality in the field under a range of working conditions. In this study, the mechanical properties of welded parts were analyzed after different welding of SS400 and SM490A using FCAW. The following conclusions were drawn. The tensile test results satisfied the KS standard tensile strength in the range of 400~510 N/mm2 in all welding positions. The bending test confirmed that most of the specimens did not show surface breakage or other defects during bending and exhibited sufficient toughness, even after plastic deformation. The hardness test results were lower than the standard value of 350 Hv of KS B 0893. Similar to the hardness test, were greater than the KS reference value. The macro test revealed no internal flaws, non-metallic inclusions, bubbles or impurities on the entire cross section of the weld, and there were no concerns regarding lamination.