• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.30 no.3
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• pp.259-268
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• 2012

This paper aims to estimate the carbon dioxide stocks in forests using airborne LiDAR data with a density of approximate 4.4 points per meter square. To achieve this goal, a processing chain consisting of bare earth Digital Terrain Model(DTM) extraction and individual tree top detection has been developed. As results of this experiment, the reliable DTM with type-II errors of 3.32% and tree positions with overall accuracy of 66.26% were extracted in the study area. The total estimated carbon dioxide stocks in the study area using extracted 3-D forests structures well suited with the traditional method by field measurements upto 7.2% error level. This results showed that LiDAR technology is highly valuable for replacing the existing forest resources inventory.

• Applied Chemistry for Engineering
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• v.21 no.3
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• pp.272-277
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• 2010

To replace current expensive photobioreactor, this study was conducted to develop low-cost photobioreactor made of polyethylene bag. In previous study, optimal culture conditions of Spirulina platensis NIES 39 have been established, and based on these, the study of biological carbon dioxide fixation has been conducted. The maximum growth was the biomass 2.677 g/L at conditions of 10% $CO_2$, 0.1 vvm. It was shown that $F_{CO_2}$ was 4.056 g $CO_2$/L and $R_{CO_2}$ was 0.312 g $CO_2$/L/day. But, compared with the data at conditions of 5% $CO_2$, 0.1 vvm, $FE_{CO_2}$ was shown 52.372% which is half of it. Regarding the effect of $CO_2$ following illumination, the growth revealed that the input conditions, for 10 min per 3 h, were excellent in the light. $CO_2$ in absent light. $CO_2$ concentration and flow rate were 5% $CO_2$, 0.1 vvm, respectively. Finally, the addition of $CO_2$ was ineffective in the absence of light.

• Applied Chemistry for Engineering
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• v.21 no.1
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• pp.24-28
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• 2010

Since the reaction of mineral fixation proceeds with a very slow rate, the pretreatment method to increases the rate of carbonation reaction should be required. To increase the reactivity of serpentine with $CO_{2}$, two pretreatment methods are performed in this study. The heat treatment is done at $630^{\circ}C$. A heat-treated serpentine shows that the strength of -OH has a lower peak in FT-IR spectrum. Chemical pretreatment is the method of leaching of magnesium from serpentine using sulfuric acid at $75^{\circ}C$ for 1 h. Because the protonation of the oxygen atoms polarizes and weakens the Mg-O-Si bond, the removal of magnesium atoms from the crystal lattice was facilitated. After performing the pre-treatment of serpentine, $CO_{2}$ fixation experiments are performed with treated serpentine in the batch reactor. Heat-treated serpentine is converted into 43% magnesite conversion, whereas untreated serpentine has 27% of magnesite conversion. Although the results of the heat-pretreatment are encouraging, this method is prohibited due to excessive energy consumption. Furthermore chemical pretreatment serpentine routes have been proposed in an effort to avoid the cost prohibitive heat pretreatment, in which the carbonation reaction was conducted at 45 atm and $25^{\circ}C$. Chemical-treated serpentine, in particularly is corresponded to a conversion of 42% of magnesite compared to 24% for the un-treated serpentine.

• Applied Chemistry for Engineering
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• v.19 no.5
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• pp.526-532
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• 2008

The proposed $CO_2$ storage technology in the present study is a one-step sequestration process that stabilizes $CO_2$ in a reactor with Serpentine. The advantage of this technology is associated with its high stability of final product so that the entire system is recognized as permanent environment-friendly $CO_2$ removal method. Since the sequestration reaction mechanisms are generally understood that carbonation reaction proceeds with very slow rate, so that pretreatment method to increases reaction rate of $CO_2$ carbonation reaction should be developed. To increase the reactivity of Serpentine with $CO_2$, two different methods of pretreatment are carried out in the present investigation. One is heat-treatment, the other is chemical pretreatment. In this study, only chemical pretreatment is considered leaching method of magnesium from Serpentine using sulfuric acid at the various reaction temperatures, times, and acid concentrations. Experimental results illustrated that pretreatment by sulfuric acid increases surface area of serpentine from $11.1209m^2/g$ to $98.7903m^2/g$ and extracts magnesium compounds. Single variable experiment demonstrated the enhancements of magnesium extraction with increased reaction temperature and time. Amount of magnesium extraction is obtained by using the data of ICP-AES as maximum extraction condition of magnesium is 2 M acid solution, $75^{\circ}C$ and 1hr. After performing chemical pretreatment, carbonation yield increased from 23.24% to 46.30% of weight.

• KSBB Journal
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• v.13 no.1
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• pp.101-107
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• 1998

Carbon dioxide is estimated to be responsible for 60% of the global warming effect, and this percentage is tending upward. Studies on removal and fixation of $CO_2$ in the flue gas are recognized as one of the important roles of the future biotechnology. Photobiological systems have considerably higher photosynthetic efficiency than conventional biomass system. The experiment for the photosynthetic fixation of $CO_2$ and the biomass production was performed with various initial cell concentration in a tubular photobioreactor and a bubble column $CO_2$ contactor with a gas sparger of $CO_2$ -enriched air(0.03~20%). Synechocystis PCC 6803 could grow at 10~20% $CO_2$ content under pH control. The highest specific growth rate, 0.0258 $h^{-1}$ , was obtained at 5% $CO_2$-air mixture. The maximum cell production rate, 0.2784 g/L.day, was obtained when the initial cell concentration was 0.45 g/L at 5% $CO_2$ -air mixture. The maximum cell concentration was 2.03 g/L in the tubular photobioreactor when the light intensity was $45.5{\mu}$ $E/m^2$ . s. This system showed 0.482 g $CO_2$ /L . day of the $CO_2$ fixation.

• Journal of the Korean GEO-environmental Society
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• v.13 no.11
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• pp.11-17
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• 2012

This study focused on application of various $CO_2$ philic adsorbents with amine to improve $CO_2$ uptake in mortar. TGA, phenolphthalein method, FT-IR XRD, and FE-SEM analysis methods were used to evaluate $CO_2$ capture in mortar. When $CO_2$ philic adsorbents was used, $CO_2$absorption efficiency was improved maximum of 58.5%. Carbonation depth was increased 3 times compared with original mortar. Chemical reactions between bicarbonate ion, $CO_2$, $CO_2$ philic adsorbents aqueous solution, and $Ca^{2+}$ ions dissolved from cement formed $CaCO_3$ in the mortar. Therefore, impregnation of the $CO_2$ philic adsorbent on the surface of the mortar can increase the adsorbed $CO_2$.

• The Korean Journal of Ecology
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• v.26 no.3
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• pp.129-134
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• 2003

Amounts of CO₂ fixed by net primary production and released by soil respiration were determined on big-cone pine plantation. Net primary production, which was determined by allometric method, was converted into CO₂. CO₂ evolution in forest ecosystems are mainly through soil and root respiration. In order to separate root respiration from soil respiration, root-free sites were made in stand. Litter removal sites were prepared to estimate CO₂ evolution through litter layer. Respiration was measured at every two weeks intervals from April 2001 through April 2002, and soil temperature and soil moisture were measured at the same time. Net primary production of this big-cone pine plantation was 25.7 t·ha/sup -1/·yr/sup -1/. The amount of CO₂ fixed by this plantation was 42.5 t CO₂·ha/sup -1/·yr/sup -1/, The amount of CO₂ released by soil respiration was 5.0 t CO₂·ha/sup -1/·yr/sup -1/. The relative contribution of root respiration and litter layer respiration to total respiration was 46% and 32%, respectively. Net amount of fixed CO₂ was 37.5 t CO₂·ha/sup -1/·yr/sup -1/ in this big-cone pine plantation. From this result, this big-cone pine plantation play a carbon sink source from the atmosphere.

• Journal of Environmental Policy
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• v.9 no.1
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• pp.137-154
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• 2010

These objectives of this study were to compute heavy metal and accumulation carbon dioxide fixing quantity from urban green space(street trees and urban parks) in Cheong-ju city and Chungju-city and thus to estimate the effect of urban green space for improving the urban environment. The results are summarized below. 1. Results of the total accumulation of the carbon dioxide fixing quantity of street trees, Cheong-ju city and Chungju-city street tree was 1, 230,000kg-C, 1,270,000 kg-C, respectively. Total accumulation carbon dioxide fixing quantity of Balssan urban park had a 25,000kg-C in Cheong-ju city, Degami sports park had a 6,400kg-C in Chungju-city. 2. Results of heavy metal for street trees, fell in the order Zn > Cu > Cr > Ni >, the highest accumulated heavy metal was Zn, and the lowest was Ni. Total heavy metal concentration according to land-use area, was observed in order, for residental areas(157.26 mg/kg) > industrial areas(141.71 mg/kg) > commercial areas(118.55 mg/kg) > and greenspace areas(61.95 mg/kg) in Cheong-ju city. 3. Total heavy metal concentration for street trees fell in the order of commercial areas(84.48 mg/kg) > residental areas(83.70 mg/kg) > and greenspace(48.23 mg/kg) according to land-use area in Chungju-city. Comparatively, Cheong-ju city had more total heavy metal concentration than Chungju-city. 4. Heavy metal for soil that planted street trees was observed in order of Zn > Cu > Pb( > Ni > Cr > As > Cd), and Zn was highest, and Cd was lowest. Total heavy metal concentration for soil fell in the order commercial area(91.82mg/kg) > industrial area(85.96mg/kg) > residental area(67.55mg/kg) > greenspace(43.13mg/kg) according to land-use area in Cheong-ju city. 5. Heavy metal for soil that planted street trees was observed in order of Zn > Pb > Cu( > Ni > Cr > As > Cd, and Zn was highest. Total heavy metal concentration for soil fell in the order commercial area(87.66mg/kg) > greenspace(72.73mg/kg) $${\geq_-}$$ residental area(70.10mg/kg) in Chungju-city.

• Applied Chemistry for Engineering
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• v.22 no.3
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• pp.301-307
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• 2011

Optimal culture conditions of Spirulina platensis NIES 39 have been established using different types of light sources. Several types of photobioreactors were designed and the increase of biomass, the amount of $CO_2$, fixation and the production of chlorophyll content were studied. The result revealed that the input conditions of a 10 min period per 4 h at the condition of 5% $CO_2$ and 0.1 vvm, were excellent in the growth. The growth showing the maximum biomass accumulation is limited to 1.411 g/L when using the fluorescent bulb and the low powered surface mount device (SMD) type LEDs which were equipped-inside in the photobioreactor. However, the biomass exceeded up to 1.758 g/L level when a high powered red LED (color temperature : 12000 K) photobioreactor system was used. The $CO_2$ fixation speed and rate were increased. Although the total production of chlorophyll content undergoes a proportional increase in the biomass, the net content per dry cell weight (DCW) showed the higher production with a blue LED (color temperature : 7500 K) light than that of any other wavelengths. The carbon dioxide loss was marked as 0.15% of the inlet gas (5% $CO_2/Air$, v/v) at the maximum biomass culture condition.

• Resources Recycling
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• v.31 no.3
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• pp.40-52
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• 2022

This study analyzed the amount of carbon dioxide reduction and economic benefits of detailed processes of CO₂ 6,000 tons plant facilities with mineral carbonation technology using carbon dioxide and coal materials emitted from domestic circulating fluidized bed combustion power plants. Coal ash reacted with carbon dioxide through carbon mineralization facilities is produced as a complex carbonate and used as a construction material, accompanied by a greenhouse gas reduction. In addition, it is possible to generate profits from the sales of complex carbonates and carbon credits produced in the process. The actual carbon dioxide reduction per ton of complex carbonate production was calculated as 45.8 kgCO₂eq, and the annual carbon dioxide reduction was calculated as 805.3 tonCO₂, and the benefit-cost ratio (B/C Ratio) is 1.04, the internal rate return (IRR) is 10.65 % and the net present value (NPV) is KRW 24,713,465 won, which is considered economical. Carbon mineralization technology is one of the best solutions to reduce carbon dioxide considering future carbon dioxide reduction and economic potential.