• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.2
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• pp.121-127
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• 2024

In this study, the applicability of replacing DG(Desulfurized Gypsum) from oil refinery with CCCMs(Carbon dioxide Conversion Capture Materials) as an ALC(Auto-claved LIghtweight Concrete) raw material was examined, and basic properties of ALC was measured. The main chemical components of DG and CCCMs were CaO and SO₃, and an increase in LOI(Loss of ignition) due to mineral carbonation reaction was verified. The crystalline phases of CCCMs were CaCO₃, CaSO₄, Ca(OH)₂, and CaSO₄·2H₂O. When DG, a raw material for ALC production, was replaced with CCCMs, foaming height, pore shape, absolute dry gravity, and compressive strength results measured similar for all binders. In addition, the formation of tobermorite which is main crystalline phase of ALC was shown for all specimens in microstructural analysis.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.34 no.3
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• pp.86-91
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• 2024

In this study, the characteristics of mortar using carbondioxide conversion capture materials (CCMs), fabricated by reacting CO₂ with desulfurization gypsum (DG) by-produced from a oil refinery, as a cement mixture. Based on the chemical component and particle size analysis results, it estimated that desulfurized gypsum reacted with carbon dioxide to produce carbonate crystals such as CaCO₃. Using CCMs as a cement mixture, physical property and durability analysis were conducted by measuring such as workability, compressive strength, compressive strength ratio after freezing-thawing and accelerated carbonation depth. The experimental results showed that as the content of the admixture increased, workability and compressive strength characteristics decreased. Compressive strength after freezing-thawing and accelerated carbonation depth also showed similar characteristics to the physical property measurement results. In addition, compared to desulfurized gypsum, using CCMs showed better physical properties and durability. This was assumed to be due to differences in the crystal phases of the mixed materials such as free-CaO and CaCO₃.