• Title/Summary/Keyword: 이산화탄소법

Search Result 353, Processing Time 0.024 seconds

Study on CO2 Decomposition using Ar/CO2 Inductively Coupled Plasma (아르곤/이산화탄소 혼합가스의 유도 결합 플라즈마를 이용한 이산화탄소 분해 연구)

  • Kim, Kyung-Hyun;Kim, Kwan-Yong;Lee, Hyo-Chang;Chung, Chin-Wook
    • KEPCO Journal on Electric Power and Energy
    • /
    • v.1 no.1
    • /
    • pp.135-140
    • /
    • 2015
  • Decomposition of carbon dioxide is studied using $Ar/CO_2$ mixture inductively coupled plasmas (ICP). Argon gas was added to generate plasma which has high electron density. To measure decomposition rate of $CO_2$, optical emission actinometry is used. Changing input power, pressure and mixture ratio, the plasma parameters and the spectrum intensity were measured using single Langmuir probe and spectroscope. The source characteristic of Carbon dioxide ICP observed from the obtained plasma parameters. The decomposition rate is evolved depending on the reaction and discharge mode. This result is analyzed with both the measurement of the plasma parameters and the dissociation mechanism of $CO_2$.

Distribution of CO2 produced from fossil fuel by accelerator mass spectrometry: in Daejeon (가속기 질량분석법에 의한 화석연료 기원 이산화탄소의 농도 분포: 대전지역을 중심으로)

  • Park, Junghun;Hong, Wan;Park, Ji Youn;Sung, Ki Seok;Eum, Chul-Hun
    • Analytical Science and Technology
    • /
    • v.21 no.1
    • /
    • pp.9-13
    • /
    • 2008
  • We have collected a batch of leaf samples at several main crossroads in Daejeon and a background site to obtain distribution of $CO_2$ (greenhouse gas) due to fossil fuel combustion. The leaf samples were treated with AAA method and ${\Delta}^{14}C$ values of them were measured using AMS. ${\Delta}^{14}C$ values of downtown sites were found to be lower by 27-102 ‰ than that of the background site, and the ratio of $CO_2$ originated from fossil fuel combustion in the atmosphere of Daejeon could be calculated from the differences of ${\Delta}^{14}C$ values. The average ${\Delta}^{14}C$ of the background site, around Kyeryong mountain, was measured to be $35{\pm}8$ ‰, and this value is lower than 66.3 ‰, which have been known as the backgdound values in USA.

A Study on Adsorption Equilibrium and Adsorption Rates for CO2 and N2 (CO2 및 N2의 흡착평형과 흡착속도에 관한 연구)

  • Lee, Hwa-Yeong;Yu, Hong-Jin
    • Clean Technology
    • /
    • v.7 no.4
    • /
    • pp.265-272
    • /
    • 2001
  • 본 연구는 지구 온난화 현상의 주원인이 되는 $CO_2$ 를 화력발전소 연도가스로부터 분리 회수하기 위한 PSA 공정 개발용 기초자료를 습득하기 위하여 실시하였다. 연도가스와 유사한 조건하에서 국내에서 제조된 활성탄을 이용하여 이산화탄소 및 밸런스를 이루고 있는 질소 가스의 흡착평형 및 흡착속도 실험을 실시하였으며, 분석을 위하여 자체 제작한 장치(부피측정법) 및 TGA 장치를 각각 사용하였다. 이 연구에서 획득한 흡착등온선으로부터 사용된 흡착제가 이산화탄소의 분리에 적절한지 판단할 수 있었다. 또한, TGA에 의해 측정된 흡착속도 자료는 향후 사용될 흡착탑의 파과곡선 예측에 사용될 수 있다. 연구결과로부터 다음과 같은 사실을 알 수 있었다. 첫째, 낮은 흡착온도 일수록 흡착량이 많고 빠른 흡착속도를 나타내었다. 둘째, 압력이 높아질수록 흡착량은 증가하였다. 셋째, SGT활성탄이 SGA-100 및 SGP-100활성탄 보다 다소 많은 흡착량과 빠른 흡착속도를 보였다.

  • PDF

LDPE필름포장이 복숭아의 품질변화에 미치는 영향

  • 김진성;이상덕;하영선
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
    • /
    • 2003.04a
    • /
    • pp.133.1-133
    • /
    • 2003
  • 복숭아는 다른 과일에 비해 조직이 연약하고 저장성이 매우 낮은 여름철 과일이므로 선별, 포장 및 유통과정에 세심한 주의가 필요하다. 따라서 출하.유통시 선도를 유지시켜 유통기한을 연장시킨다면 경제적 효과가 클 것이다. 국내에서 일반화되어 있는 PE필름 밀봉 저장방식은 과실의 호흡에 의해 산소농도의 감소와 이산화탄소의 증가로 호흡이 억제되고, 이에 따라 노화가 지연됨으로 과실의 저장수명을 증가시키는 방식이며, PE필름내 기체조성에 영향을 미치는 요소는 필름의 두께와 저장온도이고 저장온도가 필름의 두께, 즉 MA효과보다 과실연화에 더 큰 영향을 미치는 것으로 알려져 있다. 이는 필름의 두께가 얇을수록 봉지 내 산소농도가 높아져 호흡대사를 촉진하기 때문인 것으로 이해된다. 과육의 연화가 시작되면서 이취를 유발하는 아세트알데히드와 에탄올의 축적이 증가한다고 보고되고 있고 이는 저장고 내 고농도의 이산화탄소 처리 시에 나타난다. 따라서 본 실험에서는 상온 2$0^{\circ}C$에서 복숭아를 0.05mm LDPE필름으로 포장하여 경도, 당도, pH를 측정하였으며 $O_2$(1, 3, 5%), $CO_2$(5, 10, 15%)를 9구분으로 환경기체를 조성하고 중심합성계획법에 의해 반응 표면분석(RSM)을 하였고 갈변도검사 결과와 함께 종합적으로 복숭아저장에 필요한 최적조건을 규명하고자 하였다.

  • PDF

Analysis of the $CO_2$ emission amount and characteristics of combined heat and power plants in industrial complex by using the fuel analysis method (연료분석 방법을 적용한 산업단지 열병합발전소 이산화탄소 배출량 및 배출특성분석)

  • Kang, Seok-Hun;Chung, Dae-Hun
    • Proceedings of the SAREK Conference
    • /
    • 2008.06a
    • /
    • pp.1243-1248
    • /
    • 2008
  • $CO_2$ emission amount and characteristics of combined heat and power (CHP) plant in industrial complex of Korea is evaluated by using the fuel analysis method. Fuel analysis methods of several foreign countries and developed one which is developed considering the operation characteristics of the surveyed CHP plants are used. The operation data is surveyed for all of the CHP plants in industrial complex and is composed of fuel consumption amount, generation, sale and efficiency of heat and electricity, condensed steam enthalpy, and etc of the each CHP.

  • PDF

Preparation of Poly(N-vinyl-2-pyrrolidone) Microparticles Using Supercritical Anti-solvent (초임계 반용매법을 이용한 폴리비닐피롤리돈 미세입자의 제조)

  • Shin, Moon-Sam;Kim, Hwa-Yong
    • Clean Technology
    • /
    • v.14 no.4
    • /
    • pp.242-247
    • /
    • 2008
  • Poly(N-vinyl-2-pyrrolidone) (PVP) has been used as biocompatible and biodegradable polymer in cosmetics, pharmaceuticals and electronics. Micro-particles of PVP were produced using an aerosol solvent extraction system (ASES). Dichloromethane (DCM) and supercritical carbon dioxide were used as solvent and antisolvent, respectively. The mean diameter of the obtained polymer particles ranged from 0.184 to $0.249\;{\mu}m$. The relationship between particle size and initial drop size was also considered.

  • PDF

A Study on the Functional Unit Trend of Carbon Dioxide Emission in the Construction Materials between 2000, 2003 and 2005 (건축재료의 이산화탄소 배출원단위 변화추이연구)

  • Lee, KangHee;Lee, HaShik;Yang, JaeHyuk
    • KIEAE Journal
    • /
    • v.10 no.5
    • /
    • pp.123-129
    • /
    • 2010
  • This study aimed at analyzing the trend of carbon dioxide emission for direct and indirect areas by using inter industry relations table between 2000, 2003 and 2005 in the key building materials and components. Results of this study are as follows; First, the material and components for this study was selected in 20 industries of products such as sand, gravel, cement, concrete articles, rebar, and steel bar. Second, among the 20 selected key building materials, the group with the highest carbon-dioxide emission was shown in ready-mixed concrete, concrete articles, and primary aluminum goods. Third, as a result of analyzing the changes to the units of carbon dioxide emission according to passage of time, the number of items which is changed in such as sustained increase or decrease over time was insignificant in carbon-emission change trend.

Preparation of Micronized Anti-dandruff Agents Using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 미립 항비듬제 제조)

  • Shin, Moon-Sam
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.34 no.3
    • /
    • pp.209-215
    • /
    • 2008
  • Iodopropynyl butylcarbamate and climbazole as anti-dandruff agents widely used in cosmetics and pharmaceutics were micronized using supercritical fluid. Supercritical carbon dioxide was selected due to relatively low critical temperature and critical pressure. Iodopropynyl butylcarbamate and climbazole were chosen because of their solubility in supercritical carbon dioxide. The rapid expansion of supercritical solution (RESS) experiments involved investigations of the effect of pressure, temperature on particle size and morphology.

A Study on the Ventilation Performance Evaluation Method of the Window-Integrated Ventilation System (창호 일체형 환기 시스템의 환기 성능 평가 방법 연구)

  • Sanghoon Park
    • Journal of Urban Science
    • /
    • v.13 no.1
    • /
    • pp.65-74
    • /
    • 2024
  • This study is a preliminary study to establish the criteria for evaluating the performance of the window-integrated ventilation system. This study analyzed various references that can evaluate the performance of the ventilation system and established the evaluation method. In addition, the performance evaluation method was quantitatively evaluated by conducting a pilot experiment to verify and supplement the performance evaluation method of the ventilation system. The performance of the ventilation system was categorized into ventilation, air quality, airtightness, noise, visibility and view according to the evaluation category. In particular, according to the ventilation and air quality evaluation, it was found that the indoor carbon dioxide concentration can be reduced by about 14 % when the window-integrated ventilation system is applied. The ventilation performance evaluation method and experimental data of this study will serve as basic data for subsequent studies to establish comprehensive performance evaluation criteria for similar ventilation systems.

  • PDF

The Comparison of Analytical Methods for Gypsum and Gypsum Slurry (석고 및 석고 슬러리에 대한 분석방법의 비교)

  • Kim, Kyeongsook;Yang, Seugran;Park, Hyunjoo;Lim, Chunsik
    • Analytical Science and Technology
    • /
    • v.13 no.2
    • /
    • pp.158-165
    • /
    • 2000
  • The purity of gypsum and quantitation of impurities of flue gas gypsum will not only play an important role in deciding of the optimal condition during a trial run of FGD (flue gas desulfurization), but also can be utilized in quality control of gypsum. The purity of gypsum can be determined from combined water, sulfur trioxide and calcium concentration. We found that the thermal analysis by TGA (thermogravimetric analysis) was the most accurate and convenient method to determine the purity of gypsum. This method will be done in a hour and the results were reproducible. On the other hand, the best way of the analysis of impurities in gypsum was fusion method using $LiBO_2$ as a fusion agent. We also determined the amount of $CO_2$ gas to analyze magnesium carbonate and calcium carbonate contents. The analyses of combined water by TGA, fusion method followed by ICP-AES (inductively coupled plasmaatomic emission spectroscopy) and determination of $CO_2$ amount can lead to more accurate and convenient method for gypsum analysis.

  • PDF