• Transactions of the KSME C: Technology and Education
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• v.4 no.2
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• pp.75-83
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• 2016

Since fire is one of the most dangerous threats to the safety of the ship, from the safety device is installed on the vessel the digestive apparatus can be viewed as the most important safety device. The fire-extinguishing device to be mounted to the vessel structure affected the stability of the structure in accordance with the blue of the sea. In particular, the Rack part of the basic safety of a fixed fire extinguishing system in the absence of a $CO_2$ container. In this paper, by utilizing simulation techniques to apply the pressure data being ejected in each direction by ship motion and $CO_2$ containers Rack perform an analysis of the structural safety assessment was part of the digestive system accordingly.

• The Journal of the Korea Contents Association
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• v.16 no.5
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• pp.660-667
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• 2016

Conventional decontamination methods utilize water-based systems, which generate high amounts of secondary wastes. Herein, we describe an environmentally benign decontamination method using liquid and supercritical $CO_2$. The use of $CO_2$ as a solvent affords effective waste reduction by its ability to be recycled, thereby leaving be hind only the contaminants upon its evaporation. In this study, a $CO_2$ solution process was assessed using t-salen(t-butylsalen), DC18C6 (dicyclohexano-18Crown6), 8-HQN(8-hydroxyquinoline), NEt4PFOSA(perfluoro-1-octanesulfonic acid tetra-ethyl ammonium salt), and NEt4PFOA(pentadecafluorooctanoic acid ammonium salt) to extract spiked radioactive contaminants(Nb,Zr,Co,Sr) from an inert sample matrix, namely filter paper. With the static extraction method, Sr was extracted with a maximum extraction rate of 97%, and Nb was extracted with a maximum extraction rate of 75%. Additionally, we were also able to extract Co and Zr with maximum extract ion ratesof 73% and 64%, respectively.

• Membrane Journal
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• v.25 no.3
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• pp.248-255
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• 2015

Aminated polyetherimide membrane synthesized in the laboratory according to amine ratio was used for measurement of gas permeability, diffusivity, and solubility about carbon dioxide, nitrogen, methane, oxygen, and sulfur dioxide with Time-lag method at room temperature. Generally, gas permeability is totally decreased because the more amination rate reacted to the main chain of amine groups, the more intermolecular space became narrow. However, gas permeability of sulfur dioxide was increased due to combination of sulfur dioxide and amine groups have acid and base properties respectively. Diffusivity and solubility of dry gas are totally decreased excluding sulfur dioxide as increasing amination rate. In case of sulfur dioxide, however, diffusivity as well as solubility was increased as increasing amination rate. Selectivity of carbon dioxide/nitrogen showed 60 when amination rate was 3. In case of humid gas, gas permeability of carbon dioxide was 70 barrer when relative humidity showed 100, and selectivity with nitrogen approximately showed 18.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.402-406
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• 2008

A series of random copolymers, composed of 1H,1H,2H,2H-perfluoro decyl methacrylate (FDMA) as a $CO_2$-philic monomer and tert-butyl methacrylate (TBMA) as an acid labile monomer, were synthesized by free radical polymerization. The solubility of copolymers in carbon dioxide, light sensitivity at 365 nm exposure, and photoresist pattern formation properties were investigated. Furthermore, sub micron-sized poly(styrenesulfonate) : poly(3,4-ethylenedioxythiophene) (PSS : PEDOT) conducting polymer patterns were successfully prepared by pattern transfer.

• Applied Biological Chemistry
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• v.41 no.5
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• pp.363-366
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• 1998

Supercritical fluid(SCF) carbon dioxide was used to extract safflower yellow pigments from Carthamus tinctorius L. In this work, supercritical fluid extractions were performed at various conditions; pressure (2000, 3000, 4000, 5000 psig), temperature $(40,\;50,\;60,\;70,\;80^{\circ}C)$ and co-solvent $(0,\;3,\;6,\;10,\;14\;wt%\;H_2O)$. Total concentrations of safflower yellow pigments extracted were determined by spectrophotometric method. A maximum yield of yellow pigments was obtained at 4000psig, $60^{\circ}C$ and 10% co-solvent. The extraction yield of pigments was also closely related to moisture content of the raw material. Extraction yield of safflower yellow pigments by SCF extraction at optimized conditions was 6% higher than that by solvent extraction. Supercritical carbon dioxide was proved to be suitable for the extraction of safflower yellow pigments from Carthamus tinctorius L.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.470-475
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• 2013

Zr-benzendicarboxylate structure, UiO-66 was prepared in 1-L batch scale by using a unique sonochemical-solvothermal combined synthesis method. The produced UiO-66 showed uniform particles of ca. $0.2{\mu}m$ in size with the BET surface area of $1,375m^2/g$ in high product yield (>95%). The UiO-66 showed 198 and 84 mg/g $CO_2$ adsorption capacity at 273 K and 298 K, respectively, with excellent $CO_2$ selectivity ($CO_2:N_2=32:1$) at ambient conditions. The isosteric heat of $CO_2$ adsorption varied from 33 to 25 kJ/mol as the adsorption progressed. The UiO-66 tested for xylene isomer separation in a liquid-phase batch mode confirmed preferential adsorption of the adsorbent for o-xylene over m-, and p-xylene.

• The Journal of the Convergence on Culture Technology
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• v.7 no.2
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• pp.359-366
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• 2021

It's been more than 30 years since global warming by the increase in CO2 became a cause celebre worldwide. Recently the government promulgated Framework Act on on Low-Carbon Green Growth and has been continuously putting much effort into saving energy and reducing carbon dioxide emissions such as an international climate change conference to prevent the increase in CO2. However, because most cities are not planned for energy saving, new cities should be planned as the active energy-efficient urban structure for 'sustainable urban development' from a long-term perspective. This study aims to design a new prototype for the sustainable energy-independent and environment-friendly housing estates which is the nation's new vision in the era of the Fourth Industrial Revolution. A study on the energy-independent site planning and the quantitative standardization of its factor will be conducted.

• Membrane Journal
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• v.25 no.3
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• pp.203-215
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• 2015

Chlor-alkali (CA) membrane process is based on salined water electrolysis employing cation condutive polymer electrolytes, which has been used for the conventional production of both sodium hydroxide and chlorine gas. The CA membrane process has advantages such as relatively low environmental impacts and fairly reduced energy consumption, when compared with diaphragm and mercury process. In this review articles, basic concepts, fundamental characteristics, key technologies of CA membrane process are dealt with in detail. In addition, advanced technologies associated with CA membrane process are described. They include zerogap and oxygen depolarized cathode technologies to improve energy efficiency during the electrolysis. Carbon dioxide mineralization technology will also be introduced as an example of hybridization with different technologies. Finally, current market trend in CA membrane process will be presented.

• Journal of the Korean Institute of Educational Facilities
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• v.21 no.6
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• pp.28-32
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• 2014

본 투고에서는 2008년 환경부의 용역으로 실시된 "보육시설의 실내공기질 진단 및 개선 시범사업"의 결과를 바탕으로 우리나라 보육시설의 실내공기 오염 실태와 함께 개선방안, 그리고 개선효과에 대하여 소개하였다. 서울, 경기, 인천 지역의 61개 시설을 대상으로 실내공기질 측정과 설문조사를 실시한 결과 폼알데하이드와 총 휘발성유기화합물은 일부시설에서 "다중이용시설 등의 실내공기질 관리법" 기준치를 초과하는 것으로 나타났다. 반면 이산화탄소와 미세먼지는 조사 대상 시설 중 50 % 이상이 기준치를 초과하는 것으로 나타났다. 따라서 보육시설의 실내공기질 개선을 위해서는 각 오염물질의 발생원별로 유지관리 대책이 필요한 것으로 조사되었다. 또한 오염원인별 분석결과, 대부분 시설의 실외오염물질 농도가 실내보다 낮게 나타나 외기의 오염이 실내에 미치는 영향은 미비한 것으로 나타났으며, 계절에 따른 실내공기오염은 동절기에 낮은 외기온도로 인하여 실내를 하기 때문에 하절기에 비해 더 높게 나타났다. 공간에 따른 오염물질의 농도는 이산화탄소와 미세먼지의 경우 아동이 늘 상주하는 교실의 오염이 가장 심한 것으로 나타났으며 폼알데하이드와 총휘발성유기화합물의 경우 놀이실의 오염도가 교실에 비해 더 높게 나타났다. 개선방안별 개선효과에 있어서는 환기계획 몇 환기설비 설치, 지하공간 습기 문제 개선에서 가장 높은 효과가 나타났다. 향후 보육시설의 쾌적하고 건겅한 실내환경의 유지관리를 위해서는 보육종사자들이 활용할 수 있는 유지관리 지침 또는 매누얼에 대한 보급이 필요할 것으로 판단된다.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.115-116
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• 2023

This study aims to investigate and improve the carbon dioxide sequestration capability and the mechanical properties of non-hydraulic low calcium silicate cement especially designed for CO₂ reaction and ordinary Portland cement subjected to the carbonation curing facilitating pH swing method. Nitric acid (HNO₃) was utilized as an liquid for the mixing of cement paste to enhance the initial dissolution of Ca ions from the cements by promoting low pH environment and prevent the direct precipitation of Ca with the anion, owing to the high solubility of Ca(NO₃)₂ in water. The results presented that the higher the concentration of HNO₃, the higher the compressive strength and CO₂ sequestration (until 0.1 M). Ca dissolution caused by the harsh acid attack onto the anhydrous cement particle lead to the higher carbonation reaction degree, forming abundant CaCO₃ crystals after the reaction. However, cement paste mixed with excessively high concentration of HNO₃ presented deterioration due to the too harsh pH environment and abundant NO₃- ions which are known to retard the reaction of cement.