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Selective Catalytic Oxidation of Hydrogen Sulfide Using $V_{2}O_{5}-TiO_2$ Catalyst Prepared by Nonhydrolytic Sol-Gel Method (비가수분해 솔-젤법으로 제조한 $V_{2}O_{5}-TiO_2$ 촉매를 이용한 황화수소의 선택 산화반응)

  • Kim, Sang-Yun;Cho, Dal-Rae;Park, Dae-Won
    • Clean Technology
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    • v.14 no.3
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    • pp.204-210
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    • 2008
  • A series of $V_{2}O_{5}-TiO_2$ xerogel catalysts were prepared by nonhydrolytic sol-gel method and analysed by various characterization techniques. These catalysts showed much higher surface areas and total pore volumes than conventional V$V_{2}O_{5}-TiO_2$ xerogel and impregnated $V_{2}O_{5}/TiO_2$ catalysts. It was found that the textural property of $V_{2}O_{5}-TiO_2$ material varies with the method and conditions of synthesis. Surface vanadates and $TiO_2$ anatase phase are the crucial factors to obtain high catalytic activities. The selective oxidation of hydrogen sulfide in the presence of excess water and ammonia was studied over these catalysts. Xerogel catalysts prepared by non-hydrolytic sol-gel method showed very high conversion of $H_{2}S$ without harmful emission of $SO_2$. The highest catalytic activity shown by these $V_{2}O_{5}-TiO_2$ catalysts may be due to their high surface area and good dispersion of vanadia species in the titania matrix.

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Studies on the Residual Contents of Sulfur Dioxide in Herbal Medicines Distributed at Domestic (국내 유통 한약재에서 이산화황 잔류량에 대한 연구)

  • Kim, Jae-I;Kim, Woo-Seong;Park, Kun-Sang;Kim, Jong-Myoung;Chae, Kab-Ryong;Cho, Dae-Hyun;Kim, Dae-Byung;Kim, Ok-Hee;Sin, Yeong-Min
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.21 no.4
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    • pp.1039-1044
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    • 2007
  • We investigated the residual contents of sulfur dioxide ($SO_2$) on the 280 kinds of herbal medicines distributed at 8 cities including in Seoul, Busan, Daegu, Gwangju, Jecheon, Yeongju, Geumsan and Jeonju in Korea. The residual contents of $SO_2$ were determinated by modified Monier-Williams method. The residual contents of $SO_2$ were not detected at 206 products in total 280 products. However, it was detected below 100 ppm in 39 products, between 101 and 1000 ppm in 30 products and exceeded 1000 ppm in 5 products. $SO_2$ contents ranged 11 ${\sim}$ 2339 mg/kg (mean 293 mg/kg) at domestic samples distributed. Regardless of region, $SO_2$ contents were not found at Notopterygii Rhizoma, Ligustici Scinensis Rhizoma et Radix, Bombyx Batryticatus, Coicis Semen, Cnidii Rhizoma, Anemarrhenae Rhizoma, Gardeniae Fructus, Alismatis Rhizoma. But it's found at Batatatis Rhizoma, Paeoniae Radix and Codonopsitis Radix of every region collected the samples. $SO_2$ contents were not detected at 58 products which collected cultural fields of dometic. After treated with water wash and hot water extraction, the reduction rates of sulfur dioxide were appeared with 14.3% ${\sim}$ 40.4% and 55.2% ${\sim}$ 100.0%, respectively. These data will be used to establish a criteron of residual sulfur dioxide in herbal medicines.

A-team Based Approach for Reactive Power/Voltage Control Considering Steady State Security Assessment (정태 안전성 평가를 고려한 무효전력 전압제어를 위한 A-team기반 접근법)

  • Kim, Doo-Hyun
    • Journal of the Korean Society of Safety
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    • v.11 no.2
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    • pp.150-159
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    • 1996
  • In this paper, an A-team(Asynchronous Team ) based approach for Reactive power and volage control considering static security assessment in a power system with infrastructural deficiencies is proposed. Reactive power and voltage control problem is the one of optimally establishing voltage level given several constraints such as reactive generation, voltage magnitude, line flow, and other switchable reactive power sources. It can be formulated as a mixed-integer linear programming(MILP) problem without deteriorating of solution accuracy to a certain extent. The security assessment is to estimate the relative robustness of the system in Its present state through the evaluation of data provided by security monitoring. Deterministic approach based on AC load flow calculations is adopted to assess the system security, especially voltage security. A security metric, as a standard of measurement for power system security, producting a set of discrete values rather than binary values, is employed. In order to analyze the above two problems, reactive power/voltage control problem and static security assessment problem, in an integrated fashion for real-time operations, a new organizational structure, called an A-team, is adopted. An A-team is an organization for agents which ale all autonomeus, work in parallel and communicate asynchronously, which is well-suited to the development of computer-based, multi-agent systems for operations. This A-team based approach, although it is still in the beginning stage, also has potential for handling other difficult power system problems.

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Computing Algorithm for Genetic Evaluations on Several Linear and Categorical Traits in A Multivariate Threshold Animal Model (범주형 자료를 포함한 다형질 임계개체모형에서 유전능력 추정 알고리즘)

  • Lee, D.H.
    • Journal of Animal Science and Technology
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    • v.46 no.2
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    • pp.137-144
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    • 2004
  • Algorithms for estimating breeding values on several categorical data by using latent variables with threshold conception were developed and showed. Thresholds on each categorical trait were estimated by Newton’s method via gradients and Hessian matrix. This algorithm was developed by way of expansion of bivariate analysis provided by Quaas(2001). Breeding values on latent variables of categorical traits and observations on linear traits were estimated by preconditioned conjugate gradient(PCG) method, which was known having a property of fast convergence. Example was shown by simulated data with two linear traits and a categorical trait with four categories(CE=calving ease) and a dichotomous trait(SB=Still Birth) in threshold animal mixed model(TAMM). Breeding value estimates in TAMM were compared to those in linear animal mixed model (LAMM). As results, correlation estimates of breeding values to parameters were 0.91${\sim}$0.92 on CE and 0.87${\sim}$0.89 on SB in TAMM and 0.72~0.84 on CE and 0.59~0.70 on SB in LAMM. As conclusion, PCG method for estimating breeding values on several categorical traits with linear traits were feasible in TAMM.

Comparison of Runoff Models for Small River Basins (소하천 유역에서의 유출해석모형 비교)

  • 강인식
    • Water for future
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    • v.29 no.4
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    • pp.209-221
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    • 1996
  • It may be difficult to make exact estimates of peak discharge or runoff depth of a flood and to establish the proper measurement for the flood protection since water stages or discharges have been rarely measured at small river basins in Korea. Three small catchments in the Su-Young river basin in Pusan were selected for the study areas. Various runoff parameters for the study areas were determined, and runoff analyses were performed using three different runoff models available in literatures; the storage function method, the discrete, linear, input-output model, and the linear reservoir model. The hydrographs calculated by three different methods showed good agreement with the observed flood hydrographs, indicating that the models selected are all capable of sucessfully modeling the flood events for small watersheds. The storage function method gave the best results in spite of its weakness that it could not be applicable to small floods, while the linear reservoir model was found to provide relatively good results with less parameters. The capabilities of simulating flood hydrographs were also evaluated based on the effective rainfall from the storage function parameters, the $\Phi$-index method, and the constant percentage method. For the On-Cheon stream watershed, the storage function parameters provided better estimates of effective rainfall for regenerating flood hydrographs than any others considered in the study. The $\Phi$-index method, however, resulted in better estimates of effective rainfall for the other two study areas.

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Effect of Temperature on Growth of Tin Oxide Nanostructures (산화주석 나노구조물의 성장에서 기판 온도의 효과)

  • Kim, Mee-Ree;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.497-502
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    • 2019
  • Metal oxide nanostructures are promising materials for advanced applications, such as high sensitive gas sensors, and high capacitance lithium-ion batteries. In this study, tin oxide (SnO) nanostructures were grown on a Si wafer substrate using a two-zone horizontal furnace system for a various substrate temperatures. The raw material of tin dioxide ($SnO_2$) powder was vaporized at $1070^{\circ}C$ in an alumina crucible. High purity Ar gas, as a carrier gas, was flown with a flow rate of 1000 standard cubic centimeters per minute. The SnO nanostructures were grown on a Si substrate at $350{\sim}450^{\circ}C$ under 545 Pa for 30 minutes. The surface morphology of the as-grown SnO nanostructures on Si substrate was characterized by field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). Raman spectroscopy was used to confirm the phase of the as-grown SnO nanostructures. As the results, the as-grown tin oxide nanostructures exhibited a pure tin monoxide phase. As the substrate temperature was increased from $350^{\circ}C$ to $424^{\circ}C$, the thickness and grain size of the SnO nanostructures were increased. The SnO nanostructures grown at $450^{\circ}C$ exhibited complex polycrystalline structures, whereas the SnO nanostructures grown at $350^{\circ}C$ to $424^{\circ}C$ exhibited simple grain structures parallel to the substrate.

Comparison of Two Methods for Analyzing Stress-Strain Behavior of Soil Beam (지반보의 응력-변형률 거동에 대한 해석법 비교)

  • Lee, Seung-Hyun;Han, Jin-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.294-302
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    • 2018
  • To analyze the behavior of a soil beam under pore water pressure, the results of analytical solutions and finite element analysis (FEM) were compared quantitatively. In contrast to the results of the analytical solution, the horizontal stress obtained from the FEM did not show a symmetrical distribution. On the other hand, the horizontal stress became closer to symmetrical distribution as the number of elements of the soil beam were increased. A comparison of the horizontal stresses from the analytic solution with those obtained from Gaussian points of FEM showed that the magnitude of the tensile stress from the FEM using 3 elements was 6% of the maximum value of the analytical solution and the compressive stress from the FEM using the same elements was 37% of the maximum value of the analytical solution. The magnitude of the tensile stress from the FEM using 6 elements was 61% of the maximum value of the analytical solution and the magnitude of the compressive stress from the FEM using the elements was 83% of the maximum value of the analytical solution. Vertical stresses, which were obtained from the analytical solution, showed a continuous distribution with the depth of the soil beam, whereas the vertical stresses from the FEM showed a discrete distribution corresponding to each element. The results also showed that the average value of the vertical stresses of each element was close to that of the pore water pressure. A comparison of the vertical displacements computed at the near vertical center line of the soil beam from the FEM with those of the analytical solution showed that the magnitude of the vertical displacement from FEM using 3 elements was 35% of the value of the analytical solution and the magnitude of the vertical displacement from FEM using 6 elements was 57% of the value of the analytical solution.

Gubong Song IK- Pil's Thought of Statecraft(經世思想) (구봉 송익필의 경세사상)

  • Lee, Young-Ja
    • The Journal of Korean Philosophical History
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    • no.59
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    • pp.313-342
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    • 2018
  • Gubong Song Ik-pil could not behave according to his aspiration directly due to restrictions in his social standing. Despite that, he actually did so indirectly through either close friends or younger students by exhibiting 'cheobyeonwigwon (處變爲權) with the goal of jichijuui (至治主義). He insisted on people-oriented politics grounded on cheonmyeongsasang (天命思想) and also suggested the humbleness of the royal family and jinhyulchaek (賑恤策) based on love of the people. In addition, he promoted public welfare and stability to enhance patriotism and also insisted on the policy of strengthening national defense with seoeolgongsacheon (庶?公私賤)'s provision of military service through the enforcement of yangcheonjongbujongmobeop (良賤從父從母法). Also, according to the letter sent to Lee San-bo, he suggested public service ethics, for instance, personally, getting rid of ulterior motives, exhibiting diligence, integrity, and wisdom, and doing one's utmost to handle tasks fairly without causing any problems and externally, being actively involved in managing and utilizing persons of ability and also relieving the poor and managing masters as well. In brief, we can assume that Song Ik-pil's thought of statecraft (經世思想) is the concrete methodology to reach the politics of kingcraft called 'jichi (至治)' by stabilizing public welfare grounded on benevolent and benign administration. He is often compared to Jegalryang on account of his innate qualities and cleverness. He was equipped with the excellent capacity of gyeongse even referred to as the moju (謀主) of four persons, Yi Yi, Seong Hon, Jeong Cheol, and Lee Gwi, and harshly criticized as a slick evil (奸鬼), too. His gyeongsesasang, however, ended up being incomplete due to restrictions in his social status. He was a person who loved the people more than anyone else, kept suggesting innovative reform plans to stabilize the people's lives, and was capable of practicing them all. His ideal of jichi was left unfulfilled, however.

Development of a surrogate model based on temperature for estimation of evapotranspiration and its use for drought index applicability assessment (증발산 산정을 위한 온도기반의 대체모형 개발 및 가뭄지수 적용성 평가)

  • Kim, Ho-Jun;Kim, Kyoungwook;Kwon, Hyun-Han
    • Journal of Korea Water Resources Association
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    • v.54 no.11
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    • pp.969-983
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    • 2021
  • Evapotranspiration, one of the hydrometeorological components, is considered an important variable for water resource planning and management and is primarily used as input data for hydrological models such as water balance models. The FAO56 PM method has been recommended as a standard approach to estimate the reference evapotranspiration with relatively high accuracy. However, the FAO56 PM method is often challenging to apply because it requires considerable hydrometeorological variables. In this perspective, the Hargreaves equation has been widely adopted to estimate the reference evapotranspiration. In this study, a set of parameters of the Hargreaves equation was calibrated with relatively long-term data within a Bayesian framework. Statistical index (CC, RMSE, IoA) is used to validate the model. RMSE for monthly results reduced from 7.94 ~ 24.91 mm/month to 7.94 ~ 24.91 mm/month for the validation period. The results confirmed that the accuracy was significantly improved compared to the existing Hargreaves equation. Further, the evaporative demand drought index (EDDI) based on the evaporative demand (E0) was proposed. To confirm the effectiveness of the EDDI, this study evaluated the estimated EDDI for the recent drought events from 2014 to 2015 and 2018, along with precipitation and SPI. As a result of the evaluation of the Han-river watershed in 2018, the weekly EDDI increased to more than 2 and it was confirmed that EDDI more effectively detects the onset of drought caused by heatwaves. EDDI can be used as a drought index, particularly for heatwave-driven flash drought monitoring and along with SPI.

Hydration properties of OPC with Synthesized Calcium Alumino Ferrite(CAF) (합성 Calcium Alumino Ferrite(CAF) 치환량에 따른 시멘트 수화 특성)

  • Woong-Geol Lee;Myong-Shin Song
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.9-15
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    • 2023
  • The cement is a typical CO2 emission industry. Manufacturing process improvements and increased use of alternative materials are needed to reduce energy consumption and CO2 emissions. This study confirmed the basic characteristics of cement hydration by sintering CAF at low temperature as a CO2 adsorbent material. For the hydration product of the synthetic CAF, crystal phase analysis, porosity, and structural images were confirmed, and the compressive strength was measured. The replacement rate of SCAF was 10, 20, and 100 %, and the compressive strength tended to decrease as the replacement rate increased. In addition, when the SCAF substitution rate is 100 %, the hydration products of the early age are calcium aluminum oxide hydrate (Ca3Al2O6 x H2O) and calcium iron hydroxide (Ca3Fe(OH)12), and at substitution rates of 10 and 20 %, CAF compounds other than general cement hydrates brownmillerite was observed. As for the porosity, the pore size increased and the porosity increased with the increase of the replacement ratio. As a result of this study, CAF manufactured by low-temperature sintering seems to be difficult to use alone and general curing for utilization as a CO2 adsorbing material.