• Title/Summary/Keyword: 이민 음이온

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Surface Properties of Liposomes Modified with Poly(ethylenimine) (폴리에틸렌이민으로 개질된 리포솜의 표면 특성)

  • 박윤정;남다은;서동환;한희동;김태우;김문석;신병철
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.502-508
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    • 2004
  • Cationic liposomes for cancer treatment have been developed in the field of chemotharpy. It was well combined on the surface of anionic tumor cell membrane by electrostatic interaction. Thus, the object of this study was to prepare the cationic liposomes capable of forming an ionic complex with the anionic cell membrane. To prepare the cationic liposomes, 1,2-distearoyl-sn-glycero-3-phosphoethanolamine (DSPE) as a cationic lipid material and polyethylenimine (PEI) as a cationic polymer were synthesized. Ionic property on the surface of liposomes was determined by the zeta potential. The adsorption characteristics of plasma protein for liposome in bovine serum were determined by the particle size and turbidity change. To estimate the stability of liposome in buffered solution, the change of particle size was measured at room temperature for seven days. The cationic liposomes were absorbed a large amount of plasma protein in bovine serum because plasma protein having anionic charge was fixed on the surface of cationic liposomes. This result indicate that the modification on the surface of liposomes using cationic polyethylenimine enhances the protein adsorption in bovine serum. Additionaly, cationic liposomes showed good stability in buffered solution for seven days.

Basic Study for Development of Denitrogenation Process by lon Exchange I. Batch Experiment (이온교환법에 의한 탈질소공정개발의 기초연구 I. 회분식 실험)

  • Chae, Yong-Gon;Lee, Dong-Hwan;Kim, Jang-II;Yoon, Tae-Kyung;Ju, Chang-Sik;Lee, Min-Gyu
    • Journal of Life Science
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    • v.7 no.2
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    • pp.73-78
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    • 1997
  • Ion exchange performence to remove nitrate in water studied using commercially available strong vase anin exchange resin of $Cl^{-}$ type in the batch reactors. Anion exchange resin was more effective than activated carbon or zeolite. With large resin amount or high temperature or low initial concentration, nitrate removal characteristics for a typical gel-type resin was increased. The curves showed the generally accepted selectivity sequence as ${SO_4}^{2-}>{No_3}^->NO_{2-}>{HCO_3}^-$.

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Studies on the Preparation of Anion Exchange Membrane through Blending of the Poly(ethylenimine) and the Poly(vinyl alcohol) (폴리비닐알코올과 폴리에틸렌이민과의 혼합을 통한 음이온교환막의 제조 연구)

  • Kim, Sung-Pyo;Kim, Baek-Kyun;Lee, Hak-Min;Rhim, Ji-Won;Jeong, Sung-Il
    • Membrane Journal
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    • v.20 no.4
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    • pp.335-341
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    • 2010
  • This study focuses on the investigation of the anion exchange membrane through blending poly(ethylenimine) (PEI) and poly(vinyl alcohol) (PVA) varying the mixing ratio. To characterize the resulting membranes, the water content, contact angle, FT-IR, thermal gravimetric analysis, ion exchange capacity, ion conductivity and elastic modulus were measured. The PVA / PEI = 90 / 10 membrane showed the ion conductivity, $5.16{\times}10^{-2}S/cm$ and simultaneously the contact angle, $78.3^{\circ}$. According to TGA measurement, the resulting membranes seemed durable at room temperature. Through the modulus test, the mechanical properties increased with increasing PVA content and apparently the membranes looked very robust.

Removal of Anionic Dyes and Heavy Metal Ions Using Silica Nanospheres or Porous Silica Micro-particles Modified with Various Coupling Agents (다양한 커플링제로 표면 개질된 실리카들을 활용한 음이온성 염료 및 중금속의 제거)

  • Sung, Sohyeon;Lee, Minjun;Cho, Young-Sang
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.596-610
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    • 2021
  • For application in adsorption process, we synthesized silica nanospheres by Stober method, and silica particles with wrinkled surface as well as macroporous silica particles were also fabricated by utilizing emulsion droplet as micro-reactors, followed by modification of the particle surface using suitable coupling agents containing amine groups. These particles exhibited improved adsorption capacity for heavy metal ions and anionic dyes, which were difficult to be removed by conventional silica particles without surface modification. Anionic dye, methyl orange could be removed almost completely by adsorption using porous silica particles modified using APTES. The adsorption efficiency of heavy metal like copper ions was close to 100%, when porous silica was used as adsorbent particles modified with AAPTS.

Recent Biomedical Applications of Functionalized Polyethylenimine Derivatives (기능성 폴리에틸렌이민 유도체의 생의학적 활용)

  • Jaebaek, Jang;Jongho, Jeon
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.1-8
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    • 2023
  • Polyethylenimine (PEI) is a cationic polymer that can bind to negatively charged biomaterials such as nucleic acids through strong electrostatic interactions. Based on these properties, PEI has been used as an efficient drug delivery system for a long time. However, the strong cationic nature of PEI has the problem of causing cytotoxicity by non-specific interaction with anionic biological materials in the cells. In order to overcome these problems, many researchers have developed various types of biocompatible PEI-based materials. In this review, we would like to introduce the recent developments of functional PEI and their applications in biomedical research.

Preparation of Poly(ethylenimine) Anionic Exchnage Membrane Impregnated in Porous Polyethylene Membranes (다공성 폴리에틸렌 막에 폴리에틸렌이민을 함침 시킨 음이온교환막의 제조 연구)

  • Park, Chan-Jong;Kim, Il-Hyung;Kim, Sung-Pyo;Lee, Hak-Min;Cheong, Seong-Ihl;Choi, Ho-Sang;Rhim, Ji-Won
    • Membrane Journal
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    • v.21 no.1
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    • pp.91-97
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    • 2011
  • In this study, the anionic exchange membranes were prepared through the impregnation of polyethylenimine (PEI) into porous polyethylene (PE) separator and then crosslinking with isophrhaloyl dichloride (IPC). To characterize the resulting membranes, the contact angles, FT-IR, ion exchnage capacity and ion conductivity were measured. The amide group is produced the reaction between amines in PEI and -COCl in IPC. In case of ion exchange capacity, 1.96 meq./g dry membrane at the reaction time, 30 sec was decreased to 1.14 meq./g dry membrane at 600 sec reaction time. The ion conductivity, $9.15{\times}10^{-2}S/cm$ at 30 sec reaction time, was obtained.