• Title/Summary/Keyword: 응고과정

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Difference in Solidification Process between Al-Mg Alloy and Al-Si Alloy in Die-Casting (Al-Mg계 합금과 Al-Si계 합금의 다이캐스팅 응고과정의 차이)

  • Choi, Se-Weon;Kim, Young-Chan;Cho, Jae-Ik;Kang, Chang-Seog;Hong, Sung-Kil
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.82-85
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    • 2012
  • The effect of the alloy systems Al-Mg alloy and Al-Si alloy in this study on the characteristics of die-casting were investigated using solidification simulation software (MAGMAsoft). Generally, it is well known that the casting characteristics of Al-Mg based alloys, such as the fluidity, feedability and die soldering behaviors, are inferior to those of Al-Si based alloys. However, the simulation results of this study showed that the filling pattern behaviors of both the Al-Mg and Al-Si alloys were found to be very similar, whereas the Al-Mg alloy had higher residual stress and greater distortion as generated due to solidification with a larger amount of volumetric shrinkage compared to the Al-Si alloy. The Al-Mg alloy exhibited very high relative numbers of stress-concentrated regions, especially near the rib areas. Owing to the residual stress and distortion, defects were evident in the Al-Mg alloy in the areas predicted by the simulation. However, there were no visible defects observed in the Al-Si alloy. This suggests that an adequate die temperature and casting process optimization are necessary to control and minimize defects when die casting the Al-Mg alloy. A Tatur test was conducted to observe the shrinkage characteristics of the aluminum alloys. The result showed that hot tearing or hot cracking occurred during the solidification of the Al-Mg alloy due to the large amount of shrinkage.

Graphite Spheroidization in Cast Iron by Addition of Misch Metal Hydrides (주철(鑄鐵)의 흑연(黑鉛)구상화에 미치는 Misch Metal Hydride의 첨가효과(添加效果))

  • Kim, Kwan-Hyu;Lee, Doh-Jae;Choi, Dap-Chun;Park, Choong-Nyeun
    • Journal of Korea Foundry Society
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    • v.8 no.3
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    • pp.322-328
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    • 1988
  • 3.9%C-2.0%Si-Fe 조성의 압분체(壓粉體)를 $1350^{\circ}$, Ar가스 분위기에서 50분간 용해한 용탕에 시판(市販) misch metal과 misch metal hydride인 MmH와 $MmH_2$를 각각 여러비율로 첨가(添加)한후 서냉(徐冷)및 급냉(急冷)한 시편의 흑연형상(黑鉛形狀)의 변화로부터 misch metal hydride의 구상화능(球狀化能)과 흑연구상화(黑鉛球狀化) 기구(機構) 로서의 기포설(氣泡說)의 타당성을 고찰한 결과 다음과 같은 결론을 얻었다. 1) Misch metal은 0.5% 이상, 그리고 misch metal hydride는 0.25% 이상 첨가한 때 구상흑연(球狀黑鉛)과 CV 흑연(黑鉛)이 나타났으며, misch metal hydride를 첨가한 때가 misch metal에 비하여 흑연립수(黑鉛粒數)가 더 많았다. 이와같이 misch metal hydride의 첨가량이 misch metal에 비하여 적었음에도 흑연립수(黑鉛粒數)가 더 많은 것을 보면 Mm으로부터 방출되는 다수(多數)의 수소기포(水素氣泡)가 구상흑연(球狀黑鉛)의 정출장소로 되는 것으로 해석되기 때문에 기포설(氣泡說)이 타당하다고 생각된다. 2) Misch metal 과 misch metal hydride의 첨가량(添加量)이 1.0%로 증가되면 두경우 모두 흑연립수(黑鉛粒數)가 감소하였다. 이는 용탕중에 개재된 수소기포(水素氣泡)의 실수율차이에 의한 잔류 수소기포수의 증가율둔화와 첨가량(添加量)의 증가에 따른 잔류 misch metal량의 상대적(相對的) 증가로 인한 다량의 잔류 misch metal이 응고과정에서 수소를 재흡수 용해하여 흑연입수를 결정하는 용탕중의 유효수소기포수(有效水素氣泡數)를 감소시켰기 때문으로 생각된다.

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Study of the Characteristics and Crystal Growth of a shorted Wire by Overcurrent (과전류에 의해 단락된 전선의 결정성장 특성에 관한 연구)

  • Park, Jin-Young;Bang, Sun-Bae;Ko, Young-Ho
    • Fire Science and Engineering
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    • v.31 no.6
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    • pp.83-90
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    • 2017
  • If an overcurrent exceeding the rated value is applied to an electric wire, the temperature of the electric wire increases, and the electric wire covering deteriorates to cause a short circuit. The upper limit temperature of the wire varies according to the magnitude of the overcurrent. When a short circuit occurs at each upper temperature limit, a cooling speed difference occurs during the solidification process due to the temperature difference between the short circuit temperature and the wire surface temperature. At this time, the pattern characteristics of the dendritic structure formed on the molten cross section are different. In this study, the upper temperature limit, which varied according to the overcurrent magnitude, was measured. At the time a short circuit occurred, the second branch spacing (dendrite Arm Spacing : DAS) of the dendrite was analyzed and the numerical value was quantified. The experimental results showed that the upper temperature limit increases with the magnitude of the overcurrent, and that the second branch spacing increases with increasing wire temperature.

Effects of the Dosing Regimen of Tissue-type Plasminogen Activator on Blood Coagulation System in Experimental Pulmonary Embolism (실험적 폐색전증에서 조직형플라스미노겐활성체의 투여방법이 혈액응고기전에 미치는 영향)

  • Chung, Hee-Soon;Kim, Ho-Joong;Shim, Young-Soo
    • Tuberculosis and Respiratory Diseases
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    • v.40 no.5
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    • pp.474-482
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    • 1993
  • Background: As a physiologic plasminogen activator, tissue-type plasminogen activator (t-PA) could induce effective thrombolysis in massive pulmonary embolism, without the risk of systemic hemorrhage. However, therapeutic doses of t-PA has been associated with systemic lytic state, and fibrin selectivity may be influenced by the dosing regimen of t-PA. To investigate the effects of duration of t-PA infusion on blood coagulation system, we performed this study. Method: In a canine model of pulmonary embolism, which was induced by injection of autologous blood clots, we administered equal doses of t-PA (1 mg/kg) over 15 minutes in $t-PA_{15}$ group, over 180 minutes in $t-PA_{180}$ group, and only saline in control group. Then serial blood samplings were made to check complete blood count, prothrombin time, activated partial thromboplastin time, thrombin time, fibrin, plasminogen, ${\alpha}_2$-antiplasmin, coagulation factor V and VIII, and fibrin(ogen) degradation products. Results: 1) In all 3 groups, complete blood count showed same changes. Hemoglobin, hematocrit and platelet count decreased, but WBC count increased. 2) Prothrombin time, activated partial thromboplastin time, and thrombin time were prolonged during 15-60 minutes after t-PA administration in $t-PA_{15}$ group, and from 30 minutes through 180 minutes after administration in $t-PA_{180}$ gorup. 3) Fibrin, ${\alpha}_2$-antiplasmin, and cogulation factor V and VIII decreased in both $t-PA_{15}$ and $t-PA_{180}$ group, but returned to basal levels earlier in $t-PA_{15}$ group. 4) Fibrin(ogen) degradation products increased after pulmonary embolism in all groups, and further increased in both $t-PA_{15}$ and $t-PA_{180}$ groups after t-PA infusion. But more pronounced increment was noted in $t-PA_{180}$ gorup. Conclusion: In pulmonary embolism, the shorter (15 minutes) infusion of t-PA would have less risk of systemic hemorrhage than the longer (180 minutes) infusion when the doses is equal. And, this suggests that manipulating the duration of t-PA infusion can reduce the risk of major bleeding.

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Effect of Casting Temperature and Speed on Formation of Surface Defect in Al-8Zn-2Mg-2Cu Billets Fabricated by Direct-Chill Casting Process (수직 연속주조 공정으로 제조된 Al-8Zn-2Mg-2Cu 빌렛의 표면 결함 형성에 미치는 주조 온도와 주조 속도의 영향)

  • Lee, Yoon-Ho;Kim, Yong-You;Lee, Sang-Hwa;Kim, Min-Seok;Euh, Kwangjun;Lee, Dong-Geun
    • Journal of Korea Foundry Society
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    • v.41 no.3
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    • pp.241-251
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    • 2021
  • 7000-series aluminum alloys are noted for their superior strength compared with other Al alloys, and their billets are generally fabricated by direct-chill (DC) casting. Surface defects in a DC-cast aluminum billet are mainly related to exudation and the meniscus freezing phenomenon, which are influenced by alloy compositions, casting speed, and casting temperature. 7000-series aluminum alloys have a wide freezing range during solidification, which makes it easy for casting defects to occur. In this study, we investigated surface defect evolution in casting billets of Al-8Zn-2Mg-2Cu alloy fabricated by a DC casting process. The billets showed "wavy" or "dotted" surfaces. The wavy surface was formed by meniscus freezing at a lower casting speed (200 mm/min) and temperature (655 ℃). In the wavy surface, refined dendritic cells were observed in a concave region due to the constitutional supercooling caused by meniscus freezing. Meanwhile, at a higher casting temperature (675 ℃), the dotted surface was formed by pore formation. In the dotted surfaces in the billet formed at a high casting speed (230 mm/min), an exudation layer was formed by the high metallostatic head pressure. The dotted region and the smooth region had a refined dendritic morphology and a columnar morphology at the exudation layer, respectively. This is attributed to the formation of gas pores in the dotted region.

A Study of a Simultaneous Filling and Solidification During Casting Process (충전과 상변화 현상을 포함한 주조과정에 대한 연구)

  • Im, lk-Tae;Kim, Woo-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.8
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    • pp.987-996
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    • 1999
  • An algorithm for modeling the filling of metal into a mold and solidification has been developed. This algorithm uses the implicit VOF method for a filling and a general implicit source-based method for solidification. The model for simultaneous filling and solidification is applied to the two-dimensional filling and solidification of a square cavity. The effects of the wall temperature and gate position on the solidification are examined. The mixed natural convection flow and residual flow resulting from the completion of a filling are included in this study to investigate the coupled effects of the filling and natural convection on solidification. Two different filling configurations (assisting flow and opposite flow due to the gate position) are analysed to study the effects of residual flow on solidification. The results clearly show the necessity to carry out a coupled filling and solidification analysis including the effect of natural convection.

Development of Viscose Rayon Process (I. Dissolution of Cellulose in $CO_2$/NaOH System)

  • 오상연;박근후;류동일;최창남;양갑승;박원호;오영세
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.315-319
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    • 1998
  • 셀룰로오스 용매계는 크게 직접용매계와 간접용매계로 나뉠 수 있으며, 잘 알려진 "비스코스 레이온(viscose rayon)"공정은 공정 중간단계에 이황화탄소(CS$_2$)를 사용하여 셀룰로오스 크산테이트 유도체를 만들고 이를 다시 수산화나트륨에 용해시키는 간접용매계에 속한다. 수산화나트륨 수용액에 용해된 비스코스 용액은 응고 욕내에서 황산과 반응하여 셀룰로오스로 재생이 되는데 비스코스 용액의 재생과정에서 발생하는 이황화탄소는 그 자체가 독성이 심한 가연성 액체일 뿐만 아니라 부반응을 통하여 삼황화소다(sodium trithiocarbonate) 및 황화수소(H$_2$S)를 발생한다.(중략)

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Determination of the Position and Velocity of the Solid-Liquid Interface During Directional Solidification of Metals based on Guided Ultrasonic Waves (유도초음파를 이용하여 금속의 방향성 고체화과정에서 고체-액체 경계면의 위치와 속도결정)

  • 김태진;슈마크텔미샤엘;그릴볼프강;쉬벤부쉬안드레;찜머만게르하르트
    • The Journal of the Acoustical Society of Korea
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    • v.17 no.2
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    • pp.79-83
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    • 1998
  • 높은 온도에서 금속물질이 응고되는 동안에 물질의 구조는 결정성장속도비율에 따 라 크게 좌우된다. 유도초음파를 기초로 한 펄스-에코 초음파실험기술과 함께 고체-액체 경 계면의 위치와 속도를 실시간으로 측정할 수 있어 고체화되는 동안의 용광로 파라메터들을 조절하는데 사용될 수 있다. 실험은 Bridgman형의 용광로에서 CuMn-막대시료에 대하여 서로 다른 냉각비율로 수행되었다. 열적평형상태에서 경계면의 위치에 대한 측정분해능은 약10㎛이다.

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Selective Adsorption of a Symmetrie Theophylline Imprinted Membrane Prepare by a Wet Phase Inversion Method (습식 상 전이법으로 제조된 Theophylline 각인 대칭 막의 선택적 흡착)

  • 박중곤;오창엽;서정일
    • KSBB Journal
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    • v.17 no.2
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    • pp.207-211
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    • 2002
  • The theophylline imprinted membrane was prepared by a wet phase inversion method. Theophylline was implanted during copolymerization of acrylonitrile with acrylic acid or implanted in the dimethyl sulfoxide solution containing10 wt% copolymer, p(AN-co-AA). Rolling the glass plate, on which the copolymer solution was cast, in water removed the sponge layer and thus made the membrane symmetric. The adsorption selectivity of the membrane toward template molecule was increased with the coagulation temperature of the membrane and the initial concentration of the theophylline and caffeine mixture.

A Study of Heat Transfer during Freezing Process of Water in a Vertical Cylinder. (수직 원통형 축열조내 물의 응고 과정시 열전달에 관한 실험적 연구(작동 유체의 유동방향에 따른 열저장 성능 비교))

  • Heo, Gyeong;Kim, Young-Ki;Kim, Young-Jung;Kim, Jun-Geun;Lim, Jang-Sun
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1995.05a
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    • pp.223-229
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    • 1995
  • Heat transfer phenomena during freezing process of the water in a vertical cylinder were experimentally studied. Purified water was inserted into the vertical cylinder Experiment was performed with two conditions ; the inlet temperature of the working fluid was maintained to be -1$0^{\circ}C$ and the direction of the working fluid was to be upward or downward. Both the mean temperature of the liquid and temperature difference of cylinder tube wall in the upward were lower than those in the downward. In addition, shape of ice layer in the upward was more uniform than that in the downward. Finally, time-varying total heat energy stored in the water in the upward was higher than that in the downward.

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